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Atomic layer deposition of h-BN(0001) multilayers on Ni(111) and chemical vapor deposition of graphene on h-BN(0001)/Ni(111) (open access)

Atomic layer deposition of h-BN(0001) multilayers on Ni(111) and chemical vapor deposition of graphene on h-BN(0001)/Ni(111)

Article studying atomic layer deposition. In situ direct, epitaxial growth of multilayers of hexagonal boron nitride (h-BN) and graphene without physical transfer is of significant interest for the scalable production of graphene/h-BN heterostructures for device applications. Deposition on magnetic substrates is of particular interest for spin tunneling applications. X-ray photoelectron spectroscopy and low energy electron diffraction demonstrate epitaxial atomic-layer deposition (ALD) of multilayer h-BN(0001) on Ni(111) and subsequent deposition of azimuthally-aligned multilayer graphene on h-BN(0001)/Ni(111) by chemical vapor deposition. Boron nitride ALD was accomplished with alternating cycles of BCl₃/NH₃ at a 600 K substrate temperature, and subsequent annealing in ultrahigh vacuum. Subsequent deposition of graphene was achieved by chemical vapor deposition using ethylene (CH₂CH₂) at 1000 K.
Date: September 17, 2019
Creator: Kelber, Jeffry A.; Jones, Jessica; Pilli, Aparna; Lee, Veronica; Beatty, John; Beauclair, Brock et al.
System: The UNT Digital Library
A Combined Metabolomics and Fluxomics Analysis Identifies Steps Limiting Oil Synthesis in Maize Embryos (open access)

A Combined Metabolomics and Fluxomics Analysis Identifies Steps Limiting Oil Synthesis in Maize Embryos

Article comparing the metabolism of embryos from two different maize lines, Alex and LH59, to test the hypothesis that directly changing their carbon metabolism may be the key to increasing oil content in maize kernels without affecting yield.
Date: September 17, 2019
Creator: Alonso, Ana Paula; Cocuron, Jean-Christophe; Koubaa, Mohamed; Kimmelfield, Rebecca & Ross, Zacchary
System: The UNT Digital Library
Multiple levers for overcoming the recalcitrance of lignocellulosic biomass (open access)

Multiple levers for overcoming the recalcitrance of lignocellulosic biomass

The article evaluates the impacts of physical, chemical and genetic interventions to improve biomass processing singly and in combination. Based on their results and literature studies, some form of non-biological augmentation will likely be necessary for the foreseeable future to achieve high total carbohydrate solubilization (TCS) for most cellulosic feedstocks. The results show that this need not necessarily involve thermochemical processing, and need not necessarily occur prior to biological conversion.
Date: January 17, 2019
Creator: Holwerda, Evert; Worthen, Robert; Kothari, Ninad; Lasky, Ronald; Davison, Brian H. (Brian Henry), 1957-; Fu, Chunxiang et al.
System: The UNT Digital Library