Presentation used to report the evaluation of UNT Libraries’ holdings supporting the curriculum and research in the area of languages and literatures. This collection analysis was focused on the four languages which undergraduates and graduate degrees are offered, including literatures and cultures.

Book chapter exploring approaches and methods of engaging with an institutional repository (IR) remotely.

Article describes how the complexity of usage reporting for open access content continues to grow, particularly with content syndication to organizations such as ScienceDirect and ResearchGate, which deliver content across multiple platforms at an unprecedented scale. This paper brings together four different perspectives and walk through what is known, then start to unpack the questions for which they do not have answers.

The current research examines the use of social media and its security settings using the Social Exchange Theory (SET) within a Saudi student environment. This research includes an introduction, literature review, methodology, results, and conclusion with the results section presenting the findings from the three essays. The first essay employs the PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) methodology of SET. PRISMA's systematic and exhaustive approach to literature evaluation increases the likelihood of obtaining high-quality, reproducible findings. In the second essay, which focuses on awareness of X's (Twitter) security settings, a quantitative research approach was utilized. A sample of former and current Saudi students (graduate and undergraduate) at the University of North Texas participated in the investigation. This research provides an empirical examination of the use of X (Twitter) and its security features within this community by employing statistical analysis of the data from respondents. Likewise, the same sample of Saudi students from the University of North Texas was used for the third essay in which the use of Facebook's security settings was examined. Having a consistent sample across both studies enables a comparison and a greater understanding of the security awareness and practices of this group across …

This thesis explores the influence of the legend of Troy on Sir Gawain and the Green Knight, Chaucer's Troilus and Criseyde, and Lydgate's Troy Book. This study seeks to understand why medieval English Christians held the pagan myth of Troy in such high regard beyond the common postcolonial critique of Trojan ancestry as a justification for political power. I begin by demonstrating how Vergil's Aeneid presents a new heroic ideal much closer to Christian virtue than Homeric values, Aeneas submitting his will to fate and earning his piety through suffering. I then turn to Sir Gawain and the Green Knight, assessing how Gawain is not only descended from Aeneas but how the major events of his quest echo Aeneas' journey, especially in both heroes' submission of their wills to fate. Next, I reveal how Chaucer's Troilus enacts a platonic ascent from a state of ignorance to a state of truth, but as Troilus' name is also linked to the city of Troy itself, the fate of Troilus becomes the fate of Troy. In this way, Chaucer dramatizes the spiritual ascent of his Trojan ancestors in that they move from sin to salvation as a culture. Finally, I investigate how Lydgate …

This thesis presents a series of neural network classifiers for object detection in both optical and infrared images. The focus of this work is on efficient and accurate solutions. The thesis discusses the evolution of the highly efficient and tiny network Binary Classification Vision Transformer (BC-ViT) and how through thoughtful modifications and improvements, the BC-ViT can be utilized for tasks of increasing complexity. Chapter 2 discusses the creation of BC-ViT and its initial use case for underwater image classification of optical images. The BC-ViT is able to complete its task with an accuracy of 99.29\% while being comprised of a mere 15,981 total trainable parameters. Chapter 3, Waste Multi-Class Vision Transformer (WMC-ViT), introduces the usefulness of mindful algorithm design for the realm of multi-class classification on a mutually exclusive dataset. WMC-ViT shows that the task oriented design strategy allowed for a network to achieve an accuracy score of 94.27\% on a five class problem while still maintaining a tiny parameter count of 35,492. The final chapter demonstrates that by utilizing functional blocks of BC-ViT, a simple and effective target detection algorithm for infrared images can be created. The Edge Infrared Vision Transformer (EIR-ViT) showed admirable results with a high IoU …

In this dissertation, I explored the effects of developmental hypoxia on heart contractility in three separate species of ectotherms: the common snapping turtle (Chelydra serpentina), the American alligator (Alligator mississippiensis), and the zebrafish (Danio rerio). I began with the common snapping turtle and tested whether the utilization of the sarcoplasmic reticulum was altered in response to developmental hypoxia. In the next two chapters, developmental hypoxia of the American alligator was explored studying how the cardiac tissue was affected, specifically in physiological stressors, sarcoplasmic reticulum utilization and sensitivity to pharmacological increases in contractility. The last chapter explored how zebrafish heart contractility was altered in response to chronic hypoxia from egg to adult. Findings from these chapters suggest that while developmental hypoxia did alter cardiac contractility, it did not alter the response of the heart to physiological stressors such as increased heart rate or under hypoxia. Overall, these findings contribute to increasing the current understanding of how developmental hypoxia alters the cardiovascular system but with an emphasis on the cardiac tissue level.

Donor-acceptor systems exhibit distinctive attributes rendering them highly promising for the emulation of natural photosynthesis and the efficient capture of solar energy. This dissertation is primarily devoted to the investigation of these unique features within diverse donor-acceptor system typologies, encompassing categories such as closely covalently linked, push-pull, supramolecular, and multi-modular donor- acceptor conjugates. The research encompasses an examination of photosynthetic analogs involving compounds such as chelated azadipyromethene (AzaBODIPY), N,N-dimethylaminophenyl (NND), phenothiazine (PTZ), triphenylamine (TPA), phenothiazine sulfone (PTZSO2), tetracyanobutadiene (TCBD), and expanded tetracyanobutadiene (exTCBD). The strategic configuration of the donor (D), acceptor (A), and spacer elements within these constructs serves to promote intramolecular charge transfer (ICT), which are crucial for efficient charge and electron transfer. The employment of cutting-edge analytical techniques, such as ultrafast transient absorption spectroscopy, is integral to the study. Furthermore, a comprehensive suite of analytical methodologies including steady-state UV-visible absorption spectroscopy, fluorescence and phosphorescence spectroscopies, electrochemical techniques (including cyclic voltammetry and differential pulse voltammetry), spectroelectrochemistry, and density functional theory calculation (DFT), collectively contribute to the comprehensive characterization of push-pull donor-acceptor systems, with a particular emphasis on their potential as highly effective solar energy harvesting application.

Wanghua Chu (b. 1941) is an outstanding Chinese composer and pianist, who has written extensively for piano. This dissertation offers a pedagogical analysis of Seven Chinese Folk Songs (1999), one of his most famous and well-regarded piano solo works. The present study has two broad and related aims: to introduce Wanghua Chu's Seven Chinese folk songs to a broader community of pianists outside of China; and to provide a pedagogical analysis so that pianists of a late-intermediate level and higher can learn it effectively and teachers can teach it successfully. Chapter 2 provides an overview of Wanghua Chu's artistic career and major works, as well as the composition background of Seven Chinese Folk Songs. Chapter 3 introduces the seven original Chinese folk songs that are used in this work, both the actual songs and the song types. Chapter 4 provides an analysis of the musical form of each movement of Seven Chinese Folk Songs. Chapter 5 analyzes the technical difficulties of this work and provides specific practice methods to solve them. Seven Chinese Folk Songs exposes the pianist to the diversity and richness of Chinese folk songs and offers them a different kind of learning opportunity in which they not …

All oxide heterostructure Cr2O3/TiO2-x was deposited on Al2O3(0001) single crystal via MBE. The analysis of interfacial interactions involving two metal oxides resulting in magnetic properties gave insights for using such heterostructures as potential spintronic device materials. The corundum phase epitaxial growth of TiO2-x on Al2O3 was characterized using XPS, AES, EELS, and LEED. The data obtained gives evidence of presence of two-dimensional electron gas at titania surface due to oxygen vacancies formation after deposition. On titania, the deposition of chrome in UHV results in the formation of oxidized chromia overlayer by abstraction of oxygen from the TiO2-x underlayer further increasing the number of vacancies present. In industrial R&D project, dry etching of multiple optical device components was performed using a novel angled etch prototype tool. The first set of experiments involved plasma etching of SiC thin films optimized for target application. The best-known method (BKM) worked from 300mm full wafer to 200mm product. In second experimentation, a variety of gray-tone photoresist received from customers were etched using BKM. Customer received etch rate on each gray-tone material. The third experiments compared recipe R1 to test recipe R2 on the test vehicle VDC. R2 showed faster etch rate but lower process repeatability …

Halogen and nitrogen containing compounds play a key role in the atmospheric chemistry of the Earth. Through a mixed computational and experimental approach, the kinetics of these compounds with radicals common to the atmosphere have been explored. Using fundamental measurements such as the IR absorption cross-section, the rate constants of atmospheric reactions and the properties of product molecules have been derived. These results have been further extended to environmental applications such as the Global Warming Potential for a species. The present results can be used as a calibration for further experiments and as checks on computational predictions of environmental properties. Such modeling can aid in the development of future industrial reagents that are less hazardous to the atmosphere.

To determine the impact that school leaders have on school culture and teacher retention, a sequential explanatory mixed methods approach was used to study schools in a district feeder pattern in in a large, suburban district in Texas with a student population of approximately 25,000. In Phase 1, teachers at one elementary, one middle, and one high school were asked to complete a 26-question Likert scale survey about school culture. The last statement in the survey asked participants if they were willing to participate in a focus group about school culture and teacher retention. In Phase 2, focus group interviews were conducted with volunteer participants who took the survey and stated they would be interested in participating in a focus group. Three focus groups were held to divide the participants by grade level grouping taught: elementary, middle, and high school. Focus group participants stated that they believe school leaders play a vital role in creating the culture of the school and in teachers' desire to remain not only teaching at their school, but also remaining in the field of education. The survey data supported these findings. By examining teachers' perspectives, the findings of the study may positively inform and influence …

This research proposes FruitPAL and FruitPAL 2.0. They are full automatic devices that can detect fruit consumption to reduce the risk of disease. Allergies to fruits can seriously impair the immune system. A novel device (FruitPAL) detecting fruit that can cause allergies is proposed in this thesis. The device can detect fifteen types of fruit and alert the caregiver when an allergic reaction may have happened. The YOLOv8 model is employed to enhance accuracy and response time in detecting dangers. The notification will be transmitted to the mobile device through the cloud, as it is a commonly utilized medium. The proposed device can detect the fruit with an overall precision of 86%. FruitPAL 2.0 is envisioned as a device that encourages people to consume fruit. Fruits contain a variety of essential nutrients that contribute to the general health of the human body. FruitPAL 2.0 is capable of analyzing the consumed fruit and then determining its nutritional value. FruitPAL 2.0 has been trained on YOLOv5 V6.0. FruitPAL 2.0 has an overall precision of 90% in detecting the fruit. The purpose of this study is to encourage fruit consumption unless it causes illness. Even though fruit plays an important role in people's …

Peruvian composers Armando Guevara Ochoa (1926–2013) and César Vivanco (b. 1949) borrow and transplant musical elements from Andean folk tradition into their compositions for the modern classical flute. Guevara Ochoa's Yaraví, Danza y Huayno and Vivanco's Fantasía Andina are solo flute pieces rooted in Peruvian folklore traditions and Andean instrumental performance. The purpose of this dissertation is to provide flutists with technical and interpretative guidance in preparing these pieces. Yaraví, Danza y Huayno, a suite of three short dances, and Fantasía Andina, a free-meter piece in an improvisational style, incorporate elements that utilize the performance techniques of Andean instruments, with use of quotations from traditional Andean folk music. References to quenas (traditional vertical flutes), zampoñas (panpipes), pututos (ceremonial natural horns), charangos (Andean guitars) and Andean harps are integrated within the works and fused with themes borrowed from iconic pieces such as El cóndor pasa, and traditional harmonic, melodic and rhythmic structures of the huayno (fast festive dance) and yaraví (slow melancholic song). The techniques and traditions borrowed from Andean folk music are not notated in these scores due to the limitations of musical notation. Performers are expected to portray the Andean musical identity of the composers' intent. This dissertation assists …

Ligand design is important due to a ligand's ability to tune properties of the transition metals, such as catalytic activity and selectivity. Gold(I) catalysts can be directly impacted by ligands electronically as well as with steric bulk when undergoing enantioselective and regioselective reactions. In the dissertation, a series of gold(I) acyclic diaminocarbenes were synthesized and used to explore the 1,6 enyne cyclization/hydroarylation. The use of metal templated synthesis of the gold(I) acyclic diaminocarbenes allowed for the gradual increase in steric bulk of the catalysts. In the end, it was shown that electronics play the major role in the regioselectivity for the 1,6 enyne cyclization/hydroarylation but localized steric bulk can control the catalytic reaction if placed strategically. Cross-coupling reactions used to form carbon-carbon or carbon-heteroatom bonds are important in the production of pharmaceutical chemicals on a large scale. Iron, an extremely cheap and earth abundant first row transition metal, has had some success in cross-coupling reactions. Iron does not go through the same catalytic cycle for cross-coupling as most transition metals, the most common of which is palladium. In the dissertation, a ligand was developed to induce Iron to undergo the same cycle as palladium. In addition, the same ligand was …

In this research, we aimed to develop thin-film devices on a polymer substrate and an alternative 3D-printed device with macroelectrodes for treating gastrointestinal (GI) conditions. First, the fabrication of thin-film devices was demonstrated on a softening thiol-ene/acrylate polymer utilizing titanium nitride (TiN) as electrode material. This was achieved by utilizing cleanroom fabrication processes such as photolithography, wet and dry etching. The functionality of the device was shown by performing electrochemical characterization tests, mainly cyclic voltammetry, electrochemical impedance spectroscopy, and voltage transient. We synthesized a novel thiol-ene/acrylate polymer based on 1,3,5-triallyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione (TATATO), trimethylolpropanetris (3-mercaptopropionate) (TMTMP), and polyethylene glycol diacrylate (PEGDA). We show that this stretchable shape memory polymer substrate is well suited for cleanroom processes. Finally, for the high throughput of the wearable devices with electrodes size 10 mm in diameter, we implemented single electrode fabrication using printed circuit boards (PCBs) and depositing gold (Au) and TiN on the plated side of PCBs utilizing the sputtering tool. This step was followed by the assembly of those single electrodes on the flexible 3D printed device. We showed that the TiN electrode material performed better in terms of charge storage capacity and charge injection capacity than the widely used stainless steel electrode material …

Residential facilities for adults with developmental disabilities offer essential accommodations and support services, with fostering communication for residents as an important aspect of care. Despite the importance of communication, previous research has identified concerns about staff performance (SP) in facilitating positive social interactions, such as engaging in consequent-mediating behavior for residents' mands. Previous research has primarily focused on improving SP through skills-based training. Yet, Skinner's theory of verbal behavior emphasizes the social and reciprocal nature of mands. Skinner suggests that the listener's behavior, engaging in consequence-mediating behavior, must be conditioned by the verbal community. However, empirical investigations into the reinforcing practices of staff in residential facilities, such as the shaping and sustaining of different types of resident mands, is limited. The current investigation sought to address this gap in research by evaluating if distinct mand topographies, disguised or specific mands, influenced the likelihood of staff engaging in consequence-mediated behavior across three staff-resident dyads. Results suggest a low probability of staff responding to, or reinforcing, mands, thus limiting conclusions on the effects of mand topographies on staff performance. Future directions and considerations regarding resident-staff interactions are discussed.

Early college entrance programs have existed in the United States since the 1950s, but in-depth research on academic success in these programs is lacking. Every year, early college entrance programs utilize a variety of data-gathering and candidate-screening techniques to select hundreds of students for admission into these accelerated programs. However, only a smattering of research articles has discussed the factors that predict academic success in these programs. This exploratory study investigated commonly-relied-upon admissions data points—such as high school GPA and ACT scores—and demographic information—such as sex, ethnicity, and locality—to see if any of these factors predicted academic success: namely, graduation and early college entrance program GPA. Secondary data from nearly 800 students admitted over an 11-year period to a state-supported, residential early college entrance program located at a large Southern university in the United States were utilized for this study. Logistic regression failed to yield a model that could accurately predict whether or not a student would graduate from the program. Multiple regression models showed that high school GPA and ACT scores were predictive of performance, and that factors like locality and ethnicity can have predictive power as well. However, the low variance in performance explained by the variables included …

Innovative Learning Environments are increasingly built and implemented in schools, but are not necessarily being used according to designers' intentions. The goal of this study was to examine teacher perceptions of the innovative learning spaces they were charged with using and to determine if they were being used effectively and as designed. The research was guided by three basic questions: what were the teachers' perceptions of these spaces, was the teacher pedagogy need to change to accommodate the space, and did the teacher feel support by campus leadership. The fourth research question centered around the goals and vision of the design team that created the innovative learning space. The crux of the issue was that the districts vision for the space came to fruition once the teachers were in the actual space with the students. This qualitative study interviewed seven teachers in the educational setting and separately interviewed the design team. The results indicated that some of the teachers were unaware of the definition of an innovative space and believed that they were utilizing the space in ways that met the designs of the campus leadership. Furthermore, teachers felt the new designs caused a classroom management issue as well as …

Using multiple theoretical methods, comprehensive calculations are performed to create a new and more comprehensive data set for elastic scattering and related transport cross sections for collisions of (H$^+$ + H), (H + H) and (He$^{2+}$ + H) in the center-of-mass energy frame. In proton-atomic hydrogen collisions, we have significantly updated and extended previous work of elastic scattering, charge transfer and related transport integral and differential cross sections in the center-of-mass energy range $10^{-4} - 10^4$ eV where the multi-channel molecular orbital approach (MO3) is used. For atomic hydrogen-hydrogen collisions, similar updates have been made of elastic scattering and spin exchange differential and integral cross sections, also for the H + H collision the ionization and negative ion formation cross sections are provided in energy range (1-20 KeV) by use of the 'hidden crossing' theoretical framework. For collisions of alpha particles with atomic hydrogen we have computed the elastic scattering cross section in the center-of-mass energy range $10^{-4} - 10^8$ eV. In this case, at the lowest energies where elastic scattering greatly dominates other reaction channels, a single-channel quasi-molecular-orbital approach (MO1) is used. With the opening of inelastic channels at higher energies the multi-channel atomic-orbital, close-coupling method is applied, and …

Verbal behavior is a critical repertoire for children with autism spectrum disorder to acquire. Tacts—verbal behavior evoked by nonverbal stimuli—are important for communicating about the world around oneself. Noun-verb tacts are part of a robust tact repertoire and may be addressed during applied behavior analytic intervention. When acquiring noun-verb tacts, it is important that the speaker learn to respond to many variations of stimuli like novel combinations of learned nouns and verbs, which is called recombinative generalization. One strategy to teach multi-component targets, such as the noun-verb tact, and lead to recombinative generalization is matrix training. Matrix training is a framework utilized to arrange targets that can be combined in order to facilitate recombinative generalization by teaching a subset of combinations and then probing others. With three children with ASD, we used matrix training and evaluated the acquisition of trained and novel combinations of noun-verb tacts with GIFs as stimuli arranged in three matrices. We used a concurrent multiple probe design across sets, and our results indicated that all participants acquired trained noun-verb tact targets in the presence of the GIFs. The degree of recombinative generalization varied across participants, but each participant demonstrated recombinative generalization with some stimuli. We analyzed …

Zou Xiangping is one of the most significant Chinese composers who writes music for the saxophone. These works, however, are not well-known in the classical saxophone repertoire. The purpose of this dissertation is to help international saxophonists develop an enlightened understanding and ultimately, performance of two selected pieces by Chinese composer Zou Xiangping (邹向平) (b. 1951), Images of Yalong River for Alto Saxophone and Piano (雅砻江印：为中音萨克斯管和钢琴) and Song of Chuanjiang River Boatman for Saxophone Quartet (川江纤夫之歌: 为萨克斯管四重奏) (2022). The compositional background, the relevant introduction about Chinese culture, the manner in which the composer combined this with Western compositional techniques, and comprehensive performance advice of each piece are provided.

The presented dissertation encompasses three distinct investigations into novel complexes with diverse applications. Firstly, a Europium-based complex, K[Eu(hfa)4], exhibits remarkable potential for detecting dissolved CO2 in an ethylene glycol medium, offering a low limit of detection, rapid response times, and high signal-to-noise ratios. This complex demonstrates promise for quantifying CO2 concentrations and finds utility in sugar fermentation monitoring. Secondly, an innovative ratiometric optical sensor, Eu(tta)3([4,4'-(t-bu)2-2,2'-bpy)], showcases exceptional sensitivity and selectivity in detecting aluminum ions, making it suitable for environmental and biological applications. It exhibits reliable quantification in both methanol and aqueous samples, with remarkable accuracy validated by ICP-OES. Lastly, modifications to the Au3Pz3 complex synthesis enable the development of a silver ion sensor, paving the way for detecting silver ion leaching in real-life scenarios, such as silver nanoparticle-embedded bandages. The research extends to the synthesis of silver nanoparticles using various methods and foresees expanded in vitro and in vivo studies. These investigations collectively offer insights into the development of advanced sensing technologies with significant implications for a wide range of practical applications.

Farm to school programs are becoming a popular intervention to address childhood obesity. The hope is to prevent later chronic illnesses such as diabetes and cardiovascular disease that can result from eating high-fat/high-calorie diets that are low in consumption of fresh fruits and vegetables. This study explores the impacts of one such program, Farm to Keiki, on students, their families, and teachers at two Native Hawaiian preschools on the island of Kauaʽi, Hawaiʽi. This program combined lessons about plants and nutrition with gardening at school and tastetesting in the classroom. Rooted in critical medical anthropology, this study utilized a combination of quantitative and qualitative methods to understand these impacts, as well as the historical and cultural contexts that have contributed to dietary changes among Native Hawaiians. Through in-depth interviews and focus groups, families and teachers described how the program encouraged the children to try new foods and eat more produce, and how the children demonstrated new knowledge about plants and healthy eating. Participants also spoke of ways in which their own knowledge and eating habits changed, and families reported carrying over many of the program's activities at home by gardening and preparing meals together. Additionally, participants offered valuable feedback on …