This dissertation challenges Charles W. Ramsdell's needless war theory, which argued that profitable slavery would not have existed west of the 98th meridian and that slavery would have died a natural death. It uses statistical information that is mined from the county tax records to show how slave-owners on the northwestern frontier of Texas raised livestock rather than market crops, before and during the Civil War. This enterprise was so strong that it not only continued to expand throughout this period, but it also became the foundation for the recovery of the Texas economy after the war.

Since 2004, the number of people living with HIV (PLWH) has steadily increased by about 5% and currently, the number in Texas is about 86,000. Though the National HIV/AIDS Strategic Plan seeks to ensure “unfettered access to quality healthcare”, barriers to access still exist especially among minority populations. This study examines the relationship between HIV infection rates and the geographic location of HIV service centers with a focus on 4 counties: namely, Dallas, Denton, Harris and Tarrant. The goal is to show whether there is a spatial mismatch between HIV rates and service providers. Are service facilities located in zip codes where they are most needed? Using the vulnerability framework and the Inverse Care Law (ICL), we address the research question using demographic variables (race/ethnicity, sex, poverty, education attainment) and HIV data. Our results show that extreme vulnerable zip codes have high HIV rates and closest proximity to HIV service providers.

The purpose of this study was to understand the experiences and expectations of community college students attending Temple College and Central Texas College regarding what they may expect as part of the vertical transfer process in order to improve the likelihood of their persistence to graduation at Texas A&M University-Central Texas (TAMUCT). The target population was approximately 700 students enrolled in two feeder Texas community colleges who had expressed intent to transfer to TAMUCT. The response rate was 19%, and 136 useable surveys were used for analysis. The sample was 74% female, 45% White with the majority minority. To assess the relationships between community college experiences and transfer expectation variables, correlations and logistic regression were used. No linear relationships were found regarding gender, age, ethnicity, highest level of parents' education, the aspirational variables of highest academic degree intend to obtain at any college or university and at TAMUCT, and the feeder community college attended and the two scales. A statistically significant relationship was found between parental income level and reported community college experiences (F(4, 79) = 2.612, p = .042) and vertical transfer expectations (F(4, 52) = 3.318, p = .017). Community college students from lower socioeconomic backgrounds may utilize …

Metastable b-Ti alloys are titanium alloys with sufficient b stabilizer alloying additions such that it's possible to retain single b phase at room temperature. These alloys are of great advantage compared to a/b alloys since they are easily cold rolled, strip produced and can attain excellent mechanical properties upon age hardening. Beta 21S, a relatively new b titanium alloy in addition to these general advantages is known to possess excellent oxidation and corrosion resistance at elevated temperatures. A homogeneous distribution of fine sized a precipitates in the parent b matrix is known to provide good combination of strength, ductility and fracture toughness. The current work focuses on a study of different mechanisms to engineer homogeneously distributed fine sized a precipitates in the b matrix. The precipitation of metastable phases upon low temperature aging and their influence on a precipitation is studied in detail. The precipitation sequence on direct aging above the w solvus temperature is also assessed. The structural and compositional evolution of precipitate phase is determined using multiple characterization tools. The possibility of occurrence of other non-classical precipitation mechanisms that do not require heterogeneous nucleation sites are also analyzed. Lastly, the influence of interstitial element, oxygen on a precipitation …

The kinetic energy in river streams, tidal currents, or other artificial water channels has been used as a feasible source of renewable power through different conversion systems. Thus, hydrokinetic energy conversion systems are attracting worldwide interest as another form of distributed alternative energy. Because these systems are still in early stages of development, the basic approaches need significant research. The main challenges are not only to have efficient systems, but also to convert energy more economically so that the cost-benefit analysis drives the growth of this alternative energy form. One way to view this analysis is in terms of the energy conversion efficiency per unit cost. This study presents a detailed assessment of a prototype hydrokinetic energy system along with power output costs. This experimental study was performed using commercial low-cost blades of 20 in diameter inside a tank with water flow speed up to 1.3 m/s. The work was divided into two stages: (a) a fixed-pitch blade configuration, using a radial permanent magnet generator (PMG), and (b) the same hydrokinetic turbine, with a variable-pitch blade and an axial-flux PMG. The results indicate that even though the efficiency of a simple blade configuration is not high, the power coefficient is …

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The current study focuses on improving the wear resistance of femoral head component and enhancing the osseo-integration properties of femoral stem component of a hip implant made of a new generation low modulus alloy, Ti-35Nb-7Zr-5Ta or TNZT. Different techniques that were adopted to improve the wear resistance of low-modulus TNZT alloy included; (a) fabrication of graded TNZT-xB (x= 0, 1, 2 wt%) samples using LENS, (b) oxidation, and (c) LASER nitriding of TNZT. TNZT-1B and TNZT-O samples have shown improved wear resistance when tested against UHMWPE ball in SBF medium. A new class of bio-ceramic coatings based on calcium phosphate (CaP), was applied on the TNZT sample surface and was further laser processed with the objective of enhancing their osseo-integration properties. With optimized LASER parameters, TNZT-CaP samples have shown improved corrosion resistance, surface wettability and cellular response when compared to the base TNZT sample.

Hidas composed more than 135 compositions. Of these 135 compositions 67 feature the trumpet, horn, trombone, euphonium, and tuba in a solo setting, a homogenous chamber setting, or a heterogeneous chamber setting. The first section of this project presents the significance of the topic, state of research, and methodology. Chapter one provides a narrative detailing the collaboration of Hidas with Gusztáv Höna and László Szabó, Sr. Chapter two provides a brief description of characteristics found in Hidas' compositions. Appendix A and B provides a survey of the 67 works for brass instruments that Hidas composed. Included in this survey is information pertaining to the title, editor, publisher and date of publication, total measures, duration, ranges, degree of difficulty, clefs, special effects/techniques, instrumentation, dedications, analytical information, general comments, recordings, and rental details.

In this thesis the general Chebyshev filter synthesis procedure to generate transfer and reflection polynomials and coupling matrices were described. Key concepts such as coupled resonators, non-resonant nodes have been included. This is followed by microwave duplexer synthesis. Next, a technique to design dual band filter has been described including ways to achieve desired return loss and rejection levels at specific bands by manipulating the stopbands and transmission zeros. The concept of dual band filter synthesis has been applied on the synthesis of microwave duplexer to propose a method to synthesize dual band duplexers. Finally a numerical procedure using Cauchy method has been described to estimate the filter and duplexer polynomials from measured responses. The concepts in this thesis can be used to make microwave filters and duplexers more compact, efficient and cost effective.

The reaction of 2-[(diphenylphosphino)methyl]-6-methylpyridine (PN) with Os3(CO)12-n(MeCN)n [where n = 0 (1), 1 (2), 2 (3)] has been investigated. Os3(CO)12 reacts with PN in the presence of Me3NO to afford the clusters Os3(CO)11(1-PN) (4) and 1,2-Os3(CO)10(1-PN)2 (5). X-ray diffraction analyses confirm the equatorial coordination of the phosphine(s) in 4 and 5, with the two phosphines in the latter cluster exhibiting a 1,2-trans orientation about the Os-Os vector that contains the two ligands. Treatment of the MeCN-substituted cluster Os3(CO)11(MeCN) and PN (1:1 ratio) in CH2Cl2 gives clusters 4 and 5, in addition to HOs3(η1-Cl)(CO)10(1-PN) (6) as a result of competitive activation of the reaction solvent. Cluster 6 contains 48e- and the diffraction structure reveals the presence of axial chloride and equatorial phosphine ligands which are located on adjacent osmium atoms. The bridging hydride ligand in 6 spans the Cl,P-substituted Os-Os vector. The reaction of Os3(CO)10(MeCN)2 with PN furnishes 5, 6, and 1,1-Os3(CO)10(2-PN) (7) in yields that are dependent on the reagent stoichiometry and reaction solvent. The solid-state structure of 7 confirms the chelation of the PN ligand to a single osmium atom via the pyridine and phosphine moieties at axial and equatorial sites, respectively. The bonding in 7 relative to other …

Hypertrophic cardiomyopathy (HCM), a heart-related abnormality, is the most prevalent cause of sudden death in young athletes at sporting events. A cluster of cardiomyopathy mutations are localized in β-cardiac myosin at the N-terminal region of subfragment-2. Using resonance energy transfer probes, a synthetic peptide model system was developed to study stability of the coiled coil (S2 fragment) structure by determining monomer-dimer equilibrium of the peptide. Fluorescence resonance energy transfer and MacroModel software suite were used to obtain distance measurements along with measurement of coiled coil formation. The model peptide was used to characterize the effects of disease-causing-mutations and examine potential candidate drugs (polyamines) to counteract effects of mutations causing HCM. Distance measurements between donor and acceptor probes obtained by computational simulation and fluorescence resonance energy transfer (FRET) were consistent. Measurements also agreed with simulations of unlabeled wildtype, indicating coiled coil structural stability of the peptide. Interaction of the site-specific antibody with the peptide strongly inhibited dimerization and destabilized coiled coil structure of the peptide. Presence of negatively charged glutamate residues in the region of subfragment-2 strongly suggested a potential interaction site for positively charged polyamines. Binding of certain polyamines, such as poly-L-Lysine 11 residues and poly-D-Lysine 17 residues, demonstrated the …

Many taxing authorities, including those in the United States (U.S.), rely on voluntary tax compliance and continually search for ways to increase tax revenues. Most of these methods are costly and labor intensive, such as audits and penalties for noncompliance. Prior tax compliance research has heavily investigated the influence that economic factors, such as tax rates and penalties, have on individual compliance intentions. However, economic models fail to fully predict individual tax compliance. Psychology literature suggests that social factors may also play an important role in individual tax compliance decisions. The purpose of this study is to examine the influence that social and psychological factors have on individuals' tax compliance intentions. Specifically, a model of taxpayer compliance is hypothesized that suggests that norms, perceived fairness of the tax system, and trust in government have a significant influence on compliance intentions. Results of a survey of 217 U.S. taxpayers found support for the influence of social factors on tax compliance. This research concludes that social norms have an indirect influence on compliance intentions through internalization as personal norms. Specifically, as the strength of social norms in favor of tax compliance increase, personal norms of tax compliance also increase, and this leads …

This qualitative study addressed the question: What are the perceptions of preschool and elementary bilingual and ESL teachers on how technology-enhanced classroom environments support native Spanish-speaking English language learners in the acquisition of English as a second language? With the support of six school districts representing three different regions and 15 schools in Texas, this research investigated technology-enhanced learning environments and the influence of emerging technologies on language acquisition by focusing on classroom interactions and learner engagement in preschool and elementary settings. Forty-six teachers completed the self-identified online questionnaire and from that initial group of participants, 10 were chosen for the face-to-face semi-structured interviews. A two-cycle progressive refinement coding technique was used for the analysis of the teacher interviews. In Vivo coding was selected for the first-cycle coding methodology to study teacher perspectives using their direct language. For the second-cycle methodology, focus coding was chosen as a continuation of the analytical process examining the developing patterns resulting in the initial codes being grouped to form salient categories. This process of reanalyzing and reorganizing coded data led to the creation of four emergent themes and in the views of the teachers interviewed describes how emerging technologies influences English language acquisition. The …

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Due to the wide spread occurrence of medroxyprogesterone acetate (MPA), a pharmaceutical compound, in wastewater effluent and surface waters, the objectives of this work were to determine the tissue specific uptake and bioconcentration factor (BCF) for MPA in common carp. BCFs were experimentally determined for MPA in fish using a 14-day laboratory test whereby carp where exposed to 100 μg/L of MPA for a 7-day period followed by a depuration phase in which fish were maintained in dechlorinated tap water for an additional 7 days. MPA concentrations in muscle, brain, liver and plasma were determined by liquid chromatography/mass spectrometry (LC/MS). The results from the experiment indicate that MPA can accumulate in fish, however, MPA is not considered to be bioaccumulative based on regulatory standards (BCF ≥ 1000). Although MPA has a low BCF value in common carp, this compound may cause reproductive effects in fish at environmentally relevant concentrations.

CO2 activation and conversion mediated by transition metal (TM) catalysts were investigated. Homogeneous catalysis of the reverse water gas shift reaction CO2+H2→H2O+CO was studied as a means to reduce CO2. β-diketiminato metal models L'MI ( L' =C3N2H5-; M = first-row TMs) were considered as potential catalysts. The thermodynamics of prototypical reaction pathways were simulated using B3LYP/aug-cc-pVTZ. Results show that middle series metal complexes result in more thermodynamically favorable properties; therefore, more detailed thermodynamic and kinetic studies were carried out for Mn, Fe, and Co complexes. On the other hand, heterogeneous catalysis of the reduction of CO2 to CO was carried out on Fe, Co, Ni, and Cu surfaces, using the PBE functional. Reaction barriers were calculated using the climbing image nudged elastic band method. Late 3d and 4d transition metal ion (Fe, Co, Ni, Cu, Ru, Rh, Pd, and Ag) mediated activation of dimethyl ether was studied to investigate the intrinsic catalytic properties of metals for C-O bond cleavage. A set of density functional theory (DFT) methods (BLYP, B3LYP, M06, M06-L, B97-1, B97-D, TPSS, and PBE) with aug-cc-pVTZ basis sets was calibrated with CCSD(T)/CBS calculations on reaction energies and barriers.

Ultimate is the fastest growing field sport in America. Created in 1968, forty-five years later the sport was still on the periphery of the mainstream but reached new heights in 2013 – two professional leagues, over 800 college teams and a broadcasting deal with ESPN – and the discussions throughout the sports’ history have never been as relevant. Self-officiation and the Spirit of the Game are the main tenets that make up the ethos of the sport and its community. These unique aspects differentiate Ultimate’s predominate culture from that of mainstream sports culture. This study shows the countercultural ties and survival of the ethos during the adolescent period of Ultimate’s evolution (1987-2010). It examines the progression of the community’s established grassroots culture and the governing body of the sport alongside the influx of young players with mainstream sports attitudes who bolstered certain organizers’ attempts to alter Ultimate in the hopes of gaining “legitimacy” through adding third-party officials, commercialization and corporate sponsorship.

The present study aimed to understand the relationship between the use of visual-performance feedback and its effects on behavior-specific positive praise in classrooms for students who exhibit behavioral challenges. The current study included 15 children being served by four teachers in elementary self-contained behavior classrooms. Data collection and instrumentation included (a) a pre-service training for all four teachers, (b) two weeks of baseline data on behavior-specific positive praise, (c) eight weeks of data collection in which visual-performance feedback was reported to all four teachers, (d) one consultation session, and (e) two weeks of additional data collection. Observational data attempted to determine the functional relationship between visual-performance feedback, behavior-specific positive praise, and student outcomes using a mixed methods research model. Analysis revealed identified patterns in the relationship between visual-performance feedback, the amount of behavior-specific positive praise, and student behavioral and academic outcomes. These patterns are displayed through both quantitative results taken from the observational data as well as qualitative information given by teachers. Conclusions surrounding the positive outcomes for students were derived from the strongest correlations of between behavior-specific positive praise and visual-representation feedback. Implications drawn from the study were: (a) behavior-specific positive praise training should be a standard for teachers …

This study examines factors that influence the intent to use and actual use of decision support software (DSS) technology by emergency management officials to facilitate disaster response management. The unified theory of acceptance and use of technology popularized by scholars from the field of information sciences (IS) for the private sector is adapted and extended to examine technology use in the public sector, specifically by emergency managers. An e-survey was sent to 1, 452 city and county emergency management officials from FEMA region VI and complete responses obtained from 194 were analyzed. Findings suggest that social influence is the strongest predictor of intent to use DSS technology by emergency managers, unlike private sector studies where performance expectancy was the strongest predictor. Additionally, effort expectancy, collaboration, social vulnerability, professionalism, performance expectancy, and gender explained 40 percent of their intent to use DSS technology. Factors explaining actual use of technology were intent to use technology, having an in house GIS specialist, and age of the emergency manager. This research successfully closes the gap in IS and disaster literature by being the first to focus on factors influencing technology use by emergency managers for decision making in disaster response. It underscores the importance …

Values and valuing behavior have many conceptualizations. Despite how they are defined, values have a significant impact on behavior and are idiosyncratic in nature. The present study reviewed values research and sought to explore values identification and successful valued living among an archived sample of university students. Specifically, in a convenience sample of 282 undergraduate students, variables that affect values identification and behavior such as ethnicity, gender, psychological distress, and psychological flexibility were identified. Results indicated that university students identified with more than one valued living domain (as measured by the PVQ) and that contextual factors such as ethnicity, gender, age, and religiosity/spirituality were associated with specific values endorsed. Furthermore, psychological distress, including depression and anxiety (as measured by the DASS) was negatively correlated with values purity – the extent to which values are freely chosen. Finally, psychological flexibility (low experiential avoidance as measured by the AAQ-2), predicted values purity and successful living in accordance with identified values, and the relationship between these two variables was mediated by psychological flexibility.

Demand of automobiles are significantly growing despite various factors, steadily increasing the average number of vehicles on the road. Increase in the number of vehicles, subsequently increases the risk of collisions, characterized by the driving behavior. Driving behavior is influenced by factors like class of vehicle, road condition and vehicle maneuvering by the driver. Rapidly growing mobile technology and use of smartphones embedded with in-built sensors, provides scope of constant development of assistance systems considering the safety of the driver by integrating with the information obtained from the vehicle on-board sensors. Our research aims at learning a vehicle system comprising of vehicle, human and road by employing driving patterns obtained from the sensor data to develop better systems of safety and alerts altogether. The thesis focusses on utilizing together various data recorded by the in-built embedded sensors in a smartphone to understand the vehicle motion and dynamics, followed by studying various impacts of collision events, types and signatures which can potentially be integrated in a prototype framework to detect variations, alert drivers and emergency responders in an event of collision.

This work focuses on how to improve medical services for veterans in a manner that will result in high levels of satisfaction and attainment of needed services. This research assess how veterans access healthcare and receive service. The problem to be addressed relates to reports by veteran healthcare organizations regarding the presence of gaps in coverage and customer service disparities in healthcare. Common concerns involve the gaps between veterans’ expectations for services and the provided services. This study created a survey instrument that contextualized components of established scales along with demographics and constructs specific to the current study. This study assessed the relationships among a variety of constructs and dimensions with healthcare expectations and service quality using a series of simple regressions. The results showed a statistically significant relationship between quality and the use or intention to use technology. The study supports the contention that respondents are willing to use self-service technologies. Technology that incorporates digital devices into healthcare services offers an opportunity to bridge service gaps and holds a promise for giving veterans faster access to service and care in a beneficial manner.

Collegiate newsrooms serve two functions: to provide news and information to their campuses and to provide hands-on career preparation for student journalists. Student media professionals face having to do the latter in a way that keeps up with changing demands on entry-level employees, influenced by evolving technology and role consolidation within professional media. This study provides perspective from recent graduates with student media experience on the skills they felt most confident in upon graduating, where they gained those skills, and how they feel their student media experiences prepared them for the workplace. Using Everett Rogers’ theory of innovation diffusion to frame the issue, results show that student media professionals must recognize their roles as the change agent in shaping and pushing the opportunities to develop digital skills expected of entry-level journalists.

Yoichi Hiraoka was an amazing Japanese xylophone player who had significant influence on the development of the xylophone as a solo instrument. The purpose of this dissertation is to collect and record evidence of Mr. Hiraoka, to examine his distinguished efforts to promote the xylophone, to investigate his influences on keyboard percussion literature, and to contribute to the development of the art of keyboard percussion performance as a whole. This dissertation addresses Yoichi Hiraoka’s artistic life, his commissioned pieces, and his influence on the art of xylophone performance. Analyses of two of his most influential commissioned works, Alan Hovhaness’ Fantasy on Japanese Wood Prints and Toshiro Mayuzumi’s Concertino for Xylophone Solo and Orchestra, are also included to illustrate the art of the xylophone, and to explain why Hiraoka did not play all of his commissioned works.