Heat pumps are a vital part of each building for their role in keeping the space conditioned for the occupant. This study focuses on developing a model for the ground-source heat pump at the Zero Energy lab at the University of North Texas, and finding the minimum data required for generating the model. The literature includes many models with different approaches to determine the performance of the heat pump. Each method has its pros and cons. In this research the equation-fit method was used to generate a model based on the data collected from the field. Two experiments were conducted for the cooling mode: the first one at the beginning of the season and the second one at the peak of the season to cover all the operation conditions. The same procedure was followed for the heating mode. The models generated based on the collected data were validated against the experiment data. The error of the models was within ±10%. The study showed that the error could be reduced by 20% to 42% when using the field data to generate the model instead of the manufacturer’s catalog data. Also it was found that the minimum period to generate the cooling …

Corpus Christi among of the largest industrialized coastal urban areas in Texas. The strategic location of the city along the Gulf of Mexico allows for many important industries and an international business to be located. The cluster of industries and businesses in the region contribute to the air pollution from emissions that are harmful to the environment and to the people living in and visiting the area. Volatile organic compounds (VOC) constitute an important class of pollutants measured in the area. The automated gas chromatography (Auto GC) data was collected from Texas Commission of Environmental Quality (TCEQ) and source apportionment analysis was conducted on this data to identify key sources of VOC affecting this study region. EPA PMF 3.0 was employed in this sources apportionment study of measured VOC concentration during 2005 - 2012 in Corpus Christi, Texas. The study identified nine optimal factors (Source) that could explain the concentration of VOC at two urbane monitoring sites in the study region. Natural gas was found to be the largest contributor of VOC in the area, followed by gasoline and vehicular exhaust. Diesel was the third highest contributor with emissions from manufacturing and combustion processes. Refineries gases and evaporative fugitive emissions …

Poor air quality can greatly affect the public health. Research studies indicate that indoor air can be more polluted than the outdoor air. An indoor air quality monitoring system will help to create an awareness of the quality of air inside which will eventually help in improving it. The objective of this research is to develop a low cost wireless sensor system for indoor air quality monitoring. The major cost reduction of the system is achieved by using low priced sensors. Interface circuits had to be designed to make these sensors more accurate. The system is capable of measuring carbon dioxide, carbon monoxide, ozone, temperature, humidity and volatile organic compounds. The prototype sensor node modules were developed. The sensor nodes were the connected together by Zigbee network. The nodes were developed in such a way that it is compact in size and wireless connection of sensor nodes enable to collect air quality data from multiple locations simultaneously. The collected data was stored in a computer. We employed linear least-square approach for the calibration of each sensor to derive a conversion formula for converting the sensor readings to engineering units. The system was tested with different pollutants and data collected was …

The effect of shale gas activities on ground-level ozone pollution in the Dallas-Fort Worth area is studied in detail here. Ozone is a highly reactive species with harmful effects on human and environment. Shale gas development, or fracking, involves activities such as hydraulic fracturing, drilling, fluid mixing, and trucks idling that are sources of nitrogen oxides (NOX) and volatile organic compounds (VOC), two of the most important precursors of ozone. In this study two independent approaches have been applied in evaluating the influences on ozone concentrations. In the first approach, the influence of meteorology were removed from ozone time series through the application of Kolmogorov-Zurbenko low-pass filter, logarithmic transformation, and subsequent multi-linear regression. Ozone measurement data were acquired from Texas Commission on Environmental Quality (TCEQ) monitoring stations for 14 years. The comparison between ozone trends in non-shale gas region and shale gas region shows increasing ozone trends at the monitoring stations in close proximity to the Barnett Shale activities. In the second approach, the CAMx photochemical model was used to assess the sensitivity of ozone to the NOX and VOC sources associated with shale oil and gas activities. Brute force method was applied on Barnett Shale and Haynesville Shale emission …

Corrosion represents the single most frequent cause for product replacement or loss of product functionality with a 5% coat to the industrial revenue generation of any country in this dissertation the efficacy of using filled coatings as a protection coating are investigated. Fillers disrupt the polymer-substrate coating interfacial area and lead to poor adhesion. Conflicting benefits of increasing surface hardness and corrosion with long term durability through loss of adhesion to the substrate are investigated. The effects of filler type, filler concentration and exposure to harsh environments such as supercritical carbon dioxide on salt water corrosion are systematically investigated. The constants maintained in the design of experiments were the substrate, AISI-SAE 1018 steel substrate, and the corrosive fluid synthetic sea salt solution (4.2 wt%) and the polymer, Bismaleimide (BMI). Adhesion strength through pull-off, lap shear and shear peel tests were determined. Corrosion using Tafel plots and electrochemical impedance spectroscopy was conducted. Vickers hardness was used to determine mechanical strength of the coatings. SEM and optical microscopy were used to examine dispersion and coating integrity. A comparison of fillers such as alumina, silica, hexagonal boron nitride, and organophilic montmorillonite clay (OMMT) at different concentrations revealed OMMT to be most effective with …

High entropy alloys (HEAs) are alloys with five or more principal elements. Due to these distinct concept of alloying, the HEA exhibits unique and superior properties. The outstanding properties of HEA includes higher strength/hardness, superior wear resistance, high temperature stability, higher fatigue life, good corrosion and oxidation resistance. Such characteristics of HEA has been significant interest leading to researches on these emerging field. Even though many works are done to understand the characteristic of these HEAs, very few works are made on how the HEAs can be applied for commercial uses. This work discusses the application of High entropy alloys in biomedical applications. The coronary heart disease, the leading cause of death in the United States kills more than 350,000 persons/year and it costs $108.9 billion for the nation each year in spite of significant advancements in medical care and public awareness. A cardiovascular disease affects heart or blood vessels (arteries, veins and capillaries) or both by blocking the blood flow. As a surgical interventions, stent implants are deployed to cure or ameliorate the disease. However, the high failure rate of stents has lead researchers to give special attention towards analyzing stent structure, materials and characteristics. Many works related to …

Electrospinning has been recognized as an efficient technique for the fabrication of polymer fibers. These electrospun fibers have many applications across a broad range of industries. In this research, optical transparent composites were successfully fabricated by embedding polyacrylonitrile (PAN) hollow nanofibers into poly (methyl methacrylate) (PMMA) matrix. The hollow PAN nanofibers were prepared by coaxial electrospinning. The PAN was used as the shell solution, and the mineral oil was used as the core solution. The resulting fibers were then etched with octane to remove the mineral oil from the core. The hollow PAN fibers were then homogeneously distributed in PMMA resins to fabricate the composite. The morphology, transmittance and mechanical properties of the PAN/PMMA composite were then characterized with an ESEM, TEM, tensile testing machine, UV-vis spectrometer and KD2 Pro Decagon device. The results indicated that the hollow nanofibers have relatively uniform size with one-dimensional texture at the walls. The embedded PAN hollow nanofibers significantly enhanced the tensile stress and the Young's modulus of the composite (increased by 58.3% and 50.4%, respectively), while having little influence on the light transmittance of the composite. The KD2 Pro device indicated that the thermal conductivity of the PMMA was marginally greater than the …

Knee osteoarthritis (KOA) is the primary cause of chronic immobility in populations over the age of 65. It is a joint degenerative disease in which the articular cartilage in the knee joint wears down over time, leading to symptoms of pain, instability, joint stiffness, and misalignment of the lower extremities. Without intervention, these symptoms gradually worsen over time, decreasing the overall knee range of motion (ROM) and ability to walk. Current clinical interventions include offloading braces, which mechanically realign the lower extremities to alleviate the pain experienced in the medial compartment of the knee joint. Though these braces have proven effective in pain management, studies have shown a significant decrease in knee ROM while using the brace. Concurrently, development of active exoskeletons for rehabilitative gait has increased within recent years in efforts to provide patients with a more effective intervention for dealing with KOA. Though some developed exoskeletons are promising in their efficacy of fostering gait therapy, these devices are heavy, tethered, difficult to control, unavailable to patients, or costly due to the number of complicated components used to manufacture the device. However, the idea that an active component can improve gait therapy for patients motivates this study. This study …

Cellular materials, often called lattice materials, are increasingly receiving attention for their ultralight structures with high specific strength, excellent impact absorption, acoustic insulation, heat dissipation media and compact heat exchangers. In alignment with emerging additive manufacturing (AM) technology, realization of the structural applications of the lattice materials appears to be becoming faster. Considering the direction dependent material properties of the products with AM, by directionally dependent printing resolution, effective moduli of lattice structures appear to be directionally dependent. In this paper, a constitutive model of a lattice structure, which is an octet-truss with a base material having an orthotropic material property considering AM is developed. In a case study, polyjet based 3D printing material having an orthotropic property with a 9% difference in the principal direction provides difference in the axial and shear moduli in the octet-truss by 2.3 and 4.6%. Experimental validation for the effective properties of a 3D printed octet-truss is done for uniaxial tension and compression test. The theoretical value based on the micro-buckling of truss member are used to estimate the failure strength. Modulus value appears a little overestimate compared with the experiment. Finite element (FE) simulations for uniaxial compression and tension of octet-truss lattice materials …

Natural disasters are affecting a significant number of people around the world. Sheltering is the first step in post-disaster activities towards the normalization of the affected people's lives. Temporary housing is being used in these cases until the construction of permanent houses are done. Disposal of temporary housing after use is leading to a significant environmental impact because most of them are filled with thermally insulative polymer foams that do not degrade in a short period. To reduce these problems this work proposes to use foams made with compostable thermoplastic polylactic acid (PLA) and degradable kenaf core as filler materials; these foams are made using CO2 as blowing agent for insulation purposes. Foams with PLA and 5%, 10% and 15% kenaf core were tested. Different properties and their relations were examined using differential scanning calorimetry (DSC), thermal conductivity, mechanical properties, scanning electron microscopy (SEM), x-ray μ-computed tomography (μ-CT) and building energy simulations were done using Energy Plus by NREL. The results show that mechanical properties are reduced with the introduction of kenaf core reinforcement while thermal conductivity display a noticeable improvement.

While many investigations have been performed to establish a better understanding of the effects that magnetic fields and nanoparticles have on cells, the fundamental mechanisms behind the interactions are still yet unknown, and investigations on concurrent exposure are quite limited in scope. This study was therefore established to investigate the biological impact of concurrent exposure to magnetic nanoparticles and extremely-low frequency magnetic fields using an in-vitro CHO-K1 cell line model, in an easily reproducible manner to establish grounds for further in-depth mechanistic, proteomic, and genomic studies. Cells were cultured and exposed to 10nm Fe3O4 nanoparticles, and DC or low frequency (0Hz, 50Hz, and 100Hz) 2.0mT magnetic fields produced by a Helmholtz coil pair. The cells were then observed under confocal fluorescence microscopy, and subject to MTT biological assay to determine the synergistic effects of these concurrent exposures. No effects were observed on cell morphology or microtubule network; however, cell viability was observed to decrease more drastically under the combined effects of magnetic field and nanoparticle exposures, as compared to independent exposures alone. It was concluded that no significant difference was observed between the types of magnetic fields, and their effects on the nanoparticle exposed cells, but quite clearly there are …

In this study, a series of denim fiberboards are fabricated using two different resins, malamine urea formaldehyde (MUF) and polymeric methylene diphenyl diisocyanate (pMDI). Two experimental design factors (1) adhesive content and (2) MUF-pMDI weight ratio, were studied. All the denim fiberboard samples were fabricated following the same resin blending, cold-press and hot-press procedures. The physical and mechanical tests were conducted on the fiberboard following the procedures described in ASTM D1037 to obtain such as modulus of elasticity (MOE), modulus of rupture (MOR), internal bond (IB), thickness swell (TS), and water absorption (WA). The results indicated that the MOE was significantly affected by both factors. IB was affected significantly by weight ratio of different glue types, with 17 wt% more MDI resin portion in the core layer of the denim boards, the IB for total adhesive content 15% fiberboard was enhanced by 306%, while for total adhesive content 25% fiberboard, enhanced by 205%. TS and WA, with higher adhesive content used in denim boards' fabrication, and more pMDI portion in the core layer of the boards, the boards' TS and WA was reduced by up to 64.2% and 78.8%, respectively.

Thermal transport behavior of austenite stainless steel stripe (304) and the carbon nano-tubes (CNTs) films of varying thickness are studied using a micropipette thermal sensor. Micropipette sensors of various tip sizes were fabricated and tested for the sensitivity and reliability. The sensitivity deviated by 0.11 for a batch of pipette coated under same physical vapor deposition (PVD) setting without being affected by a tip size. Annealing, rubber coating and the vertical landing test of the pipette sensor proved to be promising in increasing the reliability and durability of the pipette sensors. A micro stripe (80µm × 6µm × 0.6µm) of stainless steel, fabricated using focused ion beam (FIB) machining, was characterized whose thermal conductivity was determined to be 14.9 W/m-K at room temperature. Similarly, the thermal characterization of CNT films showed the decreasing tendency in the thermal transport behavior with the increase in the film thickness.

Dynamic tensile characterization of geo-materials is critical to the modeling and design of protective structures that are often made of concrete. One of the most commonly used techniques currently associated with this type of testing is performed with a Kolsky bar and is known as the spall technique. The validity of the data from the spall technique is highly debated because the necessary boundary conditions for the experiment are not satisfied. By using a technique called pulse shaping, a new “controlled” spall technique was developed to satisfy all boundary conditions so that the analyzed data may be useful in modeling and design. The results from this project were promising and show the potential to revolutionize the way Kolsky bar testing is performed.

Texas is the second largest state in U.S.A. based on geographical area, population and the economy. It is home to several large coastal urban areas with major industries and infrastructure supporting the fossil-fuel based energy sector. Most of the major cities on the state have been impacted by significant air pollution events over the past decade. Studies conducted in the southern coastal region of TX have identified long range transport as a major contributor of particulate matter (PM) pollution along with local emissions. Biomass burns, secondary sulfates and diesel emissions sources are comprise as the dominant mass of PM2.5 have been noted to be formed by the long range transport biomass from Central America. Thus, the primary objective of this study was to identify and quantify local as well as regional sources contributing to the PM pollution in the coastal area of Brownsville located along the Gulf of Mexico. Source apportionment techniques such as principal component analysis (PCA) and positive matrix factorization (PMF) were employed on the air quality monitoring data to identify and quantify local and regional sources affecting this coastal region. As a supplement to the PMF and PCA, conditional probability function (CPF) analysis and potential source contribution …

The Barnett shale basin, the largest onshore gas field in the state of Texas, mainly produces natural gas. The basin’s oil and gas productions have dramatically increased over the past two decades with the enhancement via shale fracturing (fracking) technology. However, recent studies suggest that air emissions from shale fracking have significantly contributed to the growing air pollution problem in North Texas. In this study, air emissions from the Barnett shale basin during the production phase of the oil and gas activities (once the product is collected from the wells) are quantified. Oil and gas production data were acquired from the Texas Railroad Commission for the baseline years of 2010 through 2013. Methodology from prior studies on shale basins approved by the Texas Commission on Environmental Quality was employed in this study and the emission inventories from the production phase sources were quantified. Accordingly, the counties with the most gas operations in the basin, Tarrant, Johnson, Denton and Wise, were found to be the highest emitters of air pollutants. Tarrant County was responsible for the highest emitted NOx (42,566 tons) and CO (17,698 tons) in the basin, while Montague County released the maximum VOC emissions (87,601 tons) during the study …

Incorporating insulation material with phase change materials (PCMs) could help enhance the insulation capability for further building energy savings by reducing the HVAC loadings. During the phase change process between the solid and liquid states, heat is being absorbed or released by PCMs depending on the surrounding temperature. This research explores the benefits of a polyurethane (PU)-PCM composite insulation material through infiltrating paraffin wax as PCM into PU open cell foam. The new PU-PCM composite provides extra shielding from the exterior hot temperatures for buildings. Through this study, it was demonstrated that PU-PCM composite insulation could potentially help building energy savings through reducing the loads on the HVAC systems based on the building energy modeling using EnergyPlus. The Zero Energy Lab (ZØE) at the University of North Texas was modeled and studied in the EnergyPlus. It is a detached building with all wall facades exposed to the ambient. It was determined that the new PU-PCM insulation material could provide 14% total energy saving per year and reduce the electricity use due to cooling only by around 30%.

A recent trend in the development of renewable and biodegradable materials has led to the development of composites from renewal sources such as natural fibers. This agricultural activity generates a large amount of waste in the form of peanut shells. The motivation for this research is based on the utilization of peanut shells as a viable source for the manufacture of biocomposites. High-density polyethylene (HDPE) is a plastic largely used in the industry due to its durability, high strength to density ratio, and thermal stability. This research focuses in the mechanical and thermal properties of HDPE/peanut shell composites of different qualities and compositions. The samples obtained were subjected to dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), and mechanical tensile strength tests. TO prepare the samples for analysis, the peanut shells were separated into different mesh sizes and then mixed with HDPE at different concentrations. The results showed that samples with fiber size number 10 exhibited superior strength modulus of 1.65 GPa versus results for HDPE alone at 1.32 GPa. The analysis from the previous experiments helped to determine that the fiber size number 10 at 5%wt. ratio in HDPE provides the most optimal mechanical and thermal results. From tensile …

Conventional sources of emissions have been a prime target for policymakers in designing pollution control strategies. However, the evolution of shale gas activities is a growing concern over the impact of unconventional sources on urban and regional air quality. Owing to the development of Barnett Shale production, the fast-growing Dallas-Fort Worth (DFW) metroplex has encountered both types of these emissions. Oil and gas activities result in emissions of ozone precursors, notably volatile organic compounds (VOC). The major objective of this study was to evaluate the spatio-temporal distribution of VOC in order to highlight the influence of unconventional emissions. The study utilized measurements from automated gas chromatography (AutoGC) monitors to analyze the patterns of the total non-methane organic compounds (TNMOC) and relative contributions from marker species of traffic versus oil and gas activities. In this study, data from 2001-2014 was obtained from the Texas Commission on Environmental Quality (TCEQ) for fifteen monitoring sites within the North Texas region. With over a thousand wells in a 10 mile radius, two of the rural sites measured twice as much TNMOC as compared to the urban site in Dallas. Source apportionment analysis was conducted using Positive Matrix Factorization (PMF) technique. The target site located …

The following report chronicles the University of North Texas Wind Turbine Project at Apogee Stadium. The timeline of events will include the feasibility study conducted by and for the university, grant awards from the Texas State Energy Conservation Office to fund the project, and a three-year sample of real time performance data since installation. The purpose of this case study is to compare the energy generation estimates by various stakeholders to the measured energy generation using a new but uniform performance relationship. In order to optimize energy generation in wind turbine generator systems, the most common wind speeds measured at the site should also be the most efficient wind speeds at which the wind turbine can convert the kinetic energy in the wind into mechanical energy and ultimately electrical energy. The tool used to convey this relationship will be a figure plotting the wind speed profile against the efficiency curve of the wind turbine. Applying this relationship tool to the UNT Apogee Stadium wind turbines provided valuable results. The most common wind speeds at Apogee Stadium are not the most efficient wind speed for the turbine. Also, the most common wind speeds were near the lower limit of the wind …

In several areas around the world, clean water is a precious asset that at anytime, and mainly due to circumstances of weather and climate, can become scarce. Mainly in the dry and remote places, people suffer with lack of water. A solution for this suffering can be a water desalination system, which makes water potable and usable for industry. That solution inherently, brings the problem of power requirement, which is sometimes arduous to accomplish in such remote areas of difficult access and long distances to overcome to build the infrastructure required to operate an electric power plant. Texas and the USA also face this scenario for many regions, for which the government has been creating some programs and driving forward incentives, looking for solutions to support water desalination. Water desalination has future applications for municipalities water-consuming or for arid and remote regions, as well as for industries that rely on heavy water usage, such as natural gas drilling operations, for which millions of gallons are trucked overland to the site and also hauled away afterwards, when the waste water produced must be treated. This thesis created the concept of autonomy for water desalination plants replacing the actual power supply from …

Different ways to measure human affective and deceptive reactions to stimulus have been developed. One method is a multimodal approach using web camera, thermal imaging camera and physiological sensors data to extract different features in the human face (verbal and non-verbal behavior) such as breathing rate, heart rate, face temperature, skin conductance, eye tracking, language analysis and facial expressions among others. Human subjects from different ages and ethnicity were exposed to two different experiments were they watched videos (affection recognition) and others answered an interview session (deception recognition). With the data collected from videos (thermal and visual), different regions of interest (ROI) of the face were selected as well as the whole picture. The ROI were determined based on the most sensitive parts of the face where larger changes of temperature or other physiological features are recorded. It was also analyzed the language (written and spoken) in order to obtain the verbal modalities. The data has been compared among the subjects to determine whether the deceptive and affective reactions of a person can be predicted using multimodal approach. From the multiple data obtained, a characterization of reactions is proposed when subjects are exposed to different stimulus, positive or negative, as …

This work investigated a novel vapor chamber for efficient heat spreading and heat removal. A vapor chamber acting as a heat spreader enables for more uniform temperature distribution along the surface of the device being cooled. First, a vapor chamber was studied and compared with the traditional copper heat spreader. The thickness of vapor chamber was kept 1.35 mm which was considered to be ultra-thin vapor chamber. Then, a new geometrical model having graphite foam in vapor space was proposed where the graphite foam material was incorporated in vapor space as square cubes. The effects of incorporating graphite foam in vapor space were compared to the vapor chamber without the embedded graphite foam to investigate the heat transfer performance improvements of vapor chamber by the high thermal conductivity graphite foam. Finally, the effects of various vapor chamber thicknesses were studied through numerical simulations. It was found that thinner vapor chamber (1.35 mm thickness) had better heat transfer performance than thicker vapor chamber (5 mm thickness) because of the extreme high effective thermal conductivities of ultra-thin vapor chamber. Furthermore, the effect of graphite foam on thermal performance improvement was very minor for ultra-thin vapor chamber, but significant for thick vapor chamber. …

Fluidization of biomass particles is an important process in the gasification, pyrolysis and combustion in order to extract energy from biomass. Studies on the fluidization of biomass particles (corn cob and walnut shell), inert particles (sand, glass bead, and alumina), which are added to facilitate fluidization of biomass, and biomass/sand mixture were performed. Experiments were carried out in a 14.5 cm internal diameter cold flow fluidization bed to determine minimum fluidization velocities with air as fluidizing medium. On the of basis of experimental data from both present work and those found in the literature, new correlations were developed to predict minimum fluidization velocity for inert particles as well as biomass particles. It was found that the proposed correlations satisfactorily predict minimum fluidization velocities and was in well agreement with experimental data. Furthermore, effect of weight percentage of biomass in the biomass/sand mixtures was studied. The weight fraction of biomass particles in the mixture was chosen in the range of 0 ~ 100 wt. %. The results show that minimum fluidization velocity of the mixtures increases with an increase in biomass content. Using the present experimental data, a new correlation was developed in terms of mass ratio for predicting values of …