Benzenesulfonates, para-substituted with amine, chloride and methyl groups were successfully incorporated into layered double hydroxides of two different compositions, 2:1 Mg-Al LDH and 2:1 Zn-Al LDH. These parent materials were also doped with small amounts of nickel and the differences in the two systems were studied. The hexamethylenetetramine route of layered double hydroxide synthesis was investigated to verify if the mechanism is indeed homogeneous. This included attempting preparation of 2:1 Mg-Al LDH, 2:1 Zn-Al LDH and 2:1 Zn-Cr LDH with two different concentrations of hexamethylenetetramine. The analytical data of the products suggest that the homogeneous precipitation may not be the true mechanism of reaction involved in LDH synthesis by this method.

The relative efficacy of training procedures emphasizing accuracy versus those which add a rate criterion is a topic of debate. The desired learning outcome is fluent responding, assessed by measures of retention, endurance, stability, and application. The current study examined the effects of these two procedures on fluency outcomes using a matching-to-sample paradigm to train participants to match English to Japanese characters. An explicit FR-3 observing response was added to an accuracy-only condition to assess the extent to which it may facilitate learning. Total time spent responding in practice drills in accuracy-only conditions was yoked to total time spent in drills achieving rate aims in accuracy+rate (AR) conditions. One participant clearly demonstrated superior fluency outcomes after AR training while another displayed superior endurance and stability outcomes after such training. The remaining two participants did not demonstrate significantly different fluency outcomes across conditions.

A "complex" system typically has a relatively large number of dynamically interacting components and tends to exhibit emergent behavior that cannot be explained by analyzing each component separately. A biological neural network is one example of such a system. A multi-agent model of such a network is developed to study the relationships between a network's structure and its spike train output. Using this model, inferences are made about the synaptic structure of networks through cluster analysis of spike train summary statistics A complexity measure for the network structure is also presented which has a one-to-one correspondence with the standard time series complexity measure sample entropy.

This thesis is an analysis and synthesis of the geologic and archaeological history of the Dickie Carr site, 41PR26, on Mill Creek in north central Texas. Included are analyses of the stratigraphy, sedimentary environments, and soils of the locality. A regional comparison is made with respect to the Late Quaternary geology of the upper Trinity River basin, Texas to interpret the geologic data. Two stratigraphic units were identified that record the Pleistocene-Holocene transition. The buried lower unit is comprised of terrace, floodplain, and channel deposits with extensive pedogenesis. The unit is Late Pleistocene in age and contains the remains of Mammuthus columbi. The upper stratigraphic unit is comprised of terrace and floodplain sediments with well-expressed pedogenesis. The unit is Early Holocene in age with Late Paleoindian and Late Archaic occupations. The archaeological components are compared and contrasted with documented sites from the Elm and East Forks of the Trinity River. The occupations are examined in a geoarchaeological context. The Late Paleoindian occupation is post-depositional and located in terrace deposits. The Late Archaic occupation is syndepositional and located in floodplain deposits.

In the immediate future, multimedia product distribution through the Internet will become main stream. However, it can also have the side effect of unauthorized duplication and distribution of multimedia products. That effect could be a critical challenge to the legal ownership of copyright and intellectual property. Many schemes have been proposed to address these issues; one is digital watermarking which is appropriate for image and video copyright protection. Videos distributed via the Internet must be processed by compression for low bit rate, due to bandwidth limitations. The most widely adapted video compression standard is MPEG-4. Discrete cosine transform (DCT) domain watermarking is a secure algorithm which could survive video compression procedures and, most importantly, attacks attempting to remove the watermark, with a visibly degraded video quality result after the watermark attacks. For a commercial broadcasting video system, real-time response is always required. For this reason, an FPGA hardware implementation is studied in this work. This thesis deals with video compression, watermarking algorithms and their hardware implementation with FPGAs. A prototyping VLSI architecture will implement video compression and watermarking algorithms with the FPGA. The prototype is evaluated with video and watermarking quality metrics. Finally, it is seen that the video qualities …

The purpose of this thesis is to explore the importance of the orphan hero in film and his resonance with the American people. It explores the orphan and the American identities, the archetypes found in myths, and the hero in American culture. The three heroes (Batman, Anakin Skywalker, and Harry Potter) represent certain aspects of orphan heroes: the capacity for sacrifice and the need to resist focusing on oneself. The type of hero each becomes has its source in the response he takes to his orphanhood. These young men suffered great loss early in their lives, but found the strength to sacrifice themselves for others, the ultimate sign of a hero.

The topic of this thesis is the confrontations between William Gladstone and the Bank of England. These confrontations have remained a mystery to authors who noted them, but have generally been ignored by others. This thesis demonstrates that Gladstone's measures taken against the Bank were reasonable, intelligent, and important for the development of nineteenth-century British government finance. To accomplish this task, this thesis refutes the opinions of three twentieth-century authors who have claimed that many of Gladstone's measures, as well as his reading, were irrational, ridiculous, and impolitic. My primary sources include the Gladstone Diaries, with special attention to a little-used source, Volume 14, the indexes to the Diaries. The day-to-day Diaries and the indexes show how much Gladstone read about financial matters, and suggest that his actions were based to a large extent upon his reading. In addition, I have used Hansard's Parliamentary Debates and nineteenth-century periodicals and books on banking and finance to understand the political and economic debates of the time.

The fact that Davis changed his mind radically several times throughout his life appeals to the curiosity. This thesis considers what could be one of the most important and definitive changes: the change from hard bop to modal jazz. This shift, although gradual, is best represented by and culminates in Kind of Blue, the first Davis album based on modal style, marking a clear break from hard bop. This thesis explores the motivations and reasons behind the change, and attempt to explain why it came about. The purpose of the study is to discover the reasons for the change itself as well as the reasons for the direction of the change: Why change and why modal music?

This research attempts to confirm the reliability and construct validity of a personnel selection instrument called a Situational Judgment Test (SJT) through reliability analysis and factor analysis. The existing literature on SJTs is reviewed, including the advantages of using SJTs in personnel selection as well as the debate on whether SJTs measure a single construct or whether they can be multidimensional depending on the content. The specific SJT in this research was theoretically developed and received expert ratings to assess four general constructs: problem solving, planning, priority setting, and leadership. No support from alpha internal consistency reliability analysis was found for the assembly of these items into the four a priori subscales, thus assembly of these items into the theoretical subscales and scales was not supported.

Meniscus is a collection of poems with a critical preface that examines the nature of "silence" and oblique language.

A novel luminescence resonance energy transfer (LRET) nanocircuit assay involving a donor and two acceptors in tandem was developed to study the dynamic interaction of skeletal muscle contraction proteins. The donor transmits energy relayed to the acceptors distinguishing myosin subfragment-1 (S1) lever arm orientations. The last acceptor allows the detection of S1's bound near or in between troponin complexes on the thin filament. Additionally, calcium related changes between troponin T and myosin were detected. Based on this data, the troponin complex situated every 7 actin monomers, hinders adjacently bound myosins to complete their power stroke; whereas myosins bound in between troponin complexes undergo complete power strokes.

A creative, multi-genre collection that includes three personal essays (non-fiction) and two short stories (fiction). The pieces in this collection primarily focus on the themes of loneliness and waiting. It includes pieces dealing with homosexual relationships, friendships and heterosexual relationships. Collection includes the essays "The Line," "Why We Don't Talk about Christmas," and "Boys Who Kiss Back," and includes the short stories "I Am Allowed to Say Faggot" and "Dear Boy."

While many riddles exist in the Anglo-Saxon Exeter Book containing female characters, both as actual human females and personified objects and aspects of nature, few scholars have discussed how the anthropomorphized “females” of the riddles challenge and broaden more conventional portrayals of what it meant to be “female” in Anglo-Saxon literature. True understanding of these riddles, however, comes only with this broader view of female, a view including a mixture of ferocity and nobility of purpose and character very reminiscent of the valkyrie (OE wælcyrige), a figure mentioned only slightly in Anglo-Saxon literature, but one who deserves more prominence, particularly when evaluating the riddles of the Exeter Book and two poems textually close to the riddles, The Wife's Lament and Wulf and Eadwacer, the only two poems with a female voice in the entire Old English corpus. Riddles represent culture from a unique angle. Because of their heavy dependence upon metaphor as a vehicle or disguise for the true subject of the riddle, the poet must employ a metaphor with similar characteristics to the true riddle subject, or the tenor of the riddle. As the riddle progresses, similarities between the vehicle and the tenor are listed for the reader. Within …

German industrialization in the nineteenth century had brought forward a variety of conflicting ideas when it came to the agrarian community. One of them was the agrarian romantic movement led by Adam Műller, who feared the loss of the traditional German peasant. Műller influenced Reichdeutsche Richard Walther Darré, who argued that large cities were the downfall of the German people and that only a healthy peasant stock would be able to ‘save' Germany. Under Darré's definition, “Geopolitik” was the defense of the land, the defense with Pflug und Schwert (plow and sword) by Wehrbauern, an ‘Űberbauer-fusion' of soldier and peasant. In order to accomplish these goals, new settlements had to be established while moving from west to east. The specific focus of this study is on the original Hegewald resettlement ideas of Richard Walther Darré and how his philosophy was taken over by Himmler and fit into his personal needs and creed after 1941. It will shed some light on the interaction of Darré and Himmler and the notorious internal fights and power struggles between the various governmental agencies involved. The Ministry for Food and Agriculture under the leadership of Darré was systematically pushed into the background and all previous, …

The present study compared the effects of an errorless stimulus shaping procedure to an errorful fluency based procedure for teaching difficult letter sound discriminations using a counterbalanced multielement experimental design. For 2 participants, letters fsteai were taught using the errorless procedure and letters bpdvou were taught using the errorful procedure. For the other 2 participants the conditions were reversed. All participants had considerably fewer errors and fewer trials to criterion with the errorless than with the errorful procedure. Tests of retention and generalization indicate that the errorful procedure generalized and was retained at a higher frequency than the errorless procedure. For 3 participants preference for the errorless procedure over the errorful procedure was demonstrated; whereas, the fourth participant demonstrated preference for the errorful procedure.

I provide in my preface a brief account of my development as a creative writer. Through this development I draw an analogy to the evolution of modern science by stating that my need for personal clarity is analogous to the charge for empirical clarity of modern science. Furthermore, I contrast the objectivism of modern science to the subjectivism of creative writing. The four short stories in my thesis range from a semi-autobiographical story, to two short stories that stem out further and further from the subjective origin of the first story. The story of greatest distance is “Fireflies,” which is not semi-autobiographical, but pure fiction. The final short story returns to the subjective origin of the first. The drive of Distances is thereby to create a sort parabola: a subjective, semi-autobiographical origin, to an objective, purely fictional crest, then a return to that subjective, semi-autobiographical origin. The entire collection is a holistic, ultimately subjective, and therefore personal experience; yet, through the use certain tropes,metaphors others can relate to, the stories are paradoxically sharable.

Mama D's 2 Blocks tells the story of a neighborhood home in New Orleans that was transformed into a distribution center and used to assist residents impacted by Hurricane Katrina's devastation in 2005. Mama D stayed at her home throughout the storm and remained there until the floodwaters had subsided. After the water had drained, socially minded youth from all over the country were drawn to Mama D's home and stayed there while supporting local renewal efforts. The film documents their joining together, without electricity or running water, and assisting in the rebuilding process undertaken by Mama D and other neighborhood residents. This film captures a community in action, how it survived, and the first steps taken towards the rebuilding of New Orleans.

This thesis examines southern reactions to events that occurred in May 1856: the outbreak of civil war in Kansas and the caning of Senator Charles Sumner of Massachusetts. I researched two newspapers from the upper South state of Virginia, the Richmond Enquirer and the Richmond Daily Whig, and two newspapers from the lower South state of Louisiana, the New Orleans Times-Picayune and the New Orleans Bee to determine the extent to which political party sentiment and/or geographic location affected southern opinion towards the two events. Political party ties influenced the material each newspaper printed. Each newspaper worried that these events endangered the Union. Some, however, believed the Union could be saved while others argued that it was only a matter of time before the South seceded.

This study was designed to investigate 1) the cultural factors involved with Mexican citizens' attitudes toward seeking professional psychological help and 2) Mexican citizens' explanatory models of mental distress. Questionnaire data from 110 Mexican college students indicate that those who report a higher tolerance for stigma report lower endorsement of both the construct of personalismo and the machismo. Respondents who reported more interpersonal openness also reported a lower endorsement of the machismo construct. Participants from a large city reported significantly more stigma tolerance than those from a small city. Regression analyses reveal machismo as a significant predictor of stigma tolerance. Qualitative data was collected to provide additional in-depth information. Study results could be used to provide culturally appropriate mental health services.

Superior swimming stamina in adult fish is presumably passed on to their offspring, but the ontogeny of the appearance of superior stamina and the requisite enhanced cardio-respiratory support for locomotion in larval fishes has not been determined. Is the expression of the suite of parental traits enabling superior swimming stamina in their offspring dependent upon their achieving juvenile/adult morphology, or does it appear earlier in their larvae? To answer this, adults were classified into three groups based on swimming stamina, followed by measurement of length, mass, and width. Larval offspring from the two parental groups -high stamina larvae (HSL) and low stamina larvae (LSL)- were reared at 27°C in aerated water (21% O2). Routine and active heart rate, routine and active mass specific oxygen consumption were recorded through 21dpf, and cost of transport (COT) and factorial aerobic scope were derived from oxygen consumption measurements. Routine heart rate at 2dpf of LSL was 164 ± 1 b·min-1, compared to only 125 ± 2 b·min-1 for HSL. Routine heart rate subsequently peaked at 203 ± 1 b·min-1 at 5dpf in the HSL group, compared to 207 ± 1 b·min-1, at 4dpf in the LSP larvae. Active heart rate at 5 dpf of …

Performance appraisal ratings provide the basis for numerous employment decisions, including retention, promotion, and salary increases. Thus, understanding the factors affecting the accuracy of these ratings is important to organizations and employees. Leniency, one rater error, is a tendency to assign higher ratings in appraisal than is warranted by actual performance. The proposed study examined how personality factors Agreeableness and Conscientiousness relate to rater leniency. The ability of narrower facets of personality to account for more variance in rater leniency than will the broad factors was also examined. The study used undergraduates' (n = 226) evaluations of instructor performance to test the study's hypotheses. In addition to personality variables, students' social desirability tendency and attitudes toward instructor were predicted to be related to rater leniency. Partial support for the study's hypotheses were found. The Agreeableness factor and three of the corresponding facets (Trust, Altruism and Tender-Mindedness) were positively related to rater leniency as predicted. The hypotheses that the Conscientiousness factor and three of the corresponding facets (Order, Dutifulness, and Deliberation) would be negatively related to rater leniency were not supported. In the current sample the single narrow facet Altruism accounted for more variance in rater leniency than the broad Agreeableness …

Fear is one of the oldest and most basic of human emotions. In this thesis, I will explore the topic of fear in relation to literature, both a staple of the horror genre as well as a device in literary works, as well as in my own writings. In addition, I will use Sigmund Freud's theory of the “uncanny” as a possible device to examine the complexities of fear and its effects both on the mind and body through the medium of literature, and, more specifically, where and how these notions are used within my own short stories. By exploring how and why certain fears are generated, we may be able to better examine our own reactions in this regard.

Storm water sediment runoff from disturbed landscapes has the potential to impair aquatic environments. Small construction sites of 1-5 acres in the United States are currently regulated by the United States Environmental Protection Agency to minimize storm water runoff damages to the environment. Gas well construction sites are similar to other construction sites in how the landscape is altered, but are not similarly regulated. This study identified sediment runoff from gas well development sites by collecting it in traps and weirs, and by measuring sediment debris lobes. Sediment primarily consisted of silt and clay sized particles. Sediments from two gas well sites formed five debris lobes that ranged in size from 325 to 3,290 square feet. Sediment loadings estimated from the debris lobes averaged 57.1 tons per year/acre. Future studies should focus on further quantification of sediment movement off of gas well sites and identify effective erosion control methods.

The purpose of this qualitative interview study is to examine the lives and experiences children of incarcerated parents from a theoretical perspective through an application of the social stress process. Previous research on children of incarcerated parents has neglected to add a theoretical component to their research, which is the intention of this research. The results will be organized around the theoretical domains of the stress process applied to findings from the analysis of eleven qualitative interviews of mothers and/or caregivers of youth(s) of an incarcerated parent. Guided by analytic induction, the themes that emerged from the transcripts were applied to the theoretical propositions of the social stress process: stressors, mediators, and manifestations. Stressors experienced by children of incarcerated parents include: the incarceration of a parent, financial difficulties, and residential instability. Stress mediators include: coping mechanisms and the importance of maintaining familial ties during parental incarceration. The manifestations or outcomes include: internalizing and externalizing behaviors.