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An Analytical Study of the Variations on the Theme of Paganini's Twenty-Fourth Caprice, Op. 1 by Busoni, Friedman, and Muczynski (open access)

An Analytical Study of the Variations on the Theme of Paganini's Twenty-Fourth Caprice, Op. 1 by Busoni, Friedman, and Muczynski

The purpose of this study is to analyze sets of variations on Paganini's theme by three twentieth-century composers: Ferruccio Busoni, Ignaz Friedman, and Robert Muczynski, in order to examine, identify, and trace different variation techniques and their applications. Chapter 1 presents the purpose and scope of this study. Chapter 2 provides background information on the musical form "theme and variations" and the theme of Paganini's Twenty-fourth Caprice, Op. 1. Chapter 2 also deals with the question of which elements have made this theme so popular. Chapters 3,4, and 5 examine each of the three sets of variations in detail using the following format: theme, structure of each variation, harmony and key, rhythm and meter, tempo and dynamics, motivic development, grouping of variations, and technical problems. Chapter 6 summarizes the findings from this study and attempts to compare those elements among the three variations. Special attention is given to the application of the motivic cells, which are drawn from the original Paganini theme, in the development of succeeding variations. This study shows how these motivic cells contribute to the construction of new motives and melodies in each variation. Additionally, this study attempts to examine each composer's efforts in expanding variation procedure …
Date: May 2000
Creator: Ahn, Kwang Sun
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Rhapsody for Piano and Small Orchestra (open access)

Rhapsody for Piano and Small Orchestra

Rhapsody for Piano and Small Orchestra is a one-movement composition in a concerto fashion for seventeen players, and is about nine minutes in duration. The overall form of this work is A B C D E D1 C1 B1 A1. This work contains various hidden compositional devices such as the golden section principle and a palindrome structure. These devices are applied not only to the structure of the work, but also to the pitch related and rhythm-related matters. Also, certain melodic and rhythmic cells are employed for each section in the developmental procedure of that section almost exclusively. Since this work is a concerto-like piece, there are two cadenza-like passages for the piano with an accompanying solo instrument, which plays the obbligato passage. The following essay addresses the form, pitch materials, harmony, rhythm and technical difficulties, orchestration, and variant elements between the corresponding sections used in this work.
Date: December 2001
Creator: Ahn-Kim, Yong Hee
Object Type: Thesis or Dissertation
System: The UNT Digital Library
An Analysis of the Characteristics of Female Juvenile Offenders as Predictors of Resocialization or Recidivism. (open access)

An Analysis of the Characteristics of Female Juvenile Offenders as Predictors of Resocialization or Recidivism.

Because there has been a paucity of research on the educational needs of females with academic, behavioral, and emotional problems involved with the juvenile justice system, this study has been an attempt to classify and compare specific characteristics of this population. In particular, it examined their demographics, disability prevalence rates, along with academic, behavioral, and emotional functioning levels, in order to further understand their relationship to the resocialization or recidivism of the different groups of female juveniles incarcerated in the state of Texas, and contribute to the research for further developing successful prevention and intervention programs. Various demographic factors of the female juveniles in this study were examined: (a) offender type, (b) county of commitment, (c) race/ethnicity, (d) age at first referral, and (e) English language proficiency. Prevalence rates of special education disabilities were determined. Academic functioning was measured by (a) IQ; (b) last school grade completed; (c) Test of Adult Basic Education (TABE) reading gain score; and (d) TABE math gain score. Behavioral functioning was indicated through (a) offense history, (b) documented behavior incidents, and (c) total risk score. Emotional functioning included DSM-IV diagnoses and treatment needs. Due to the design of the research being a descriptive exploration, the …
Date: May 2007
Creator: Aiello, Jan Elizabeth
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Determination of Habitat Preferences of Pronghorn (Antilocapra americana) on the Rolling Plains of Texas Using GIS and Remote Sensing (open access)

Determination of Habitat Preferences of Pronghorn (Antilocapra americana) on the Rolling Plains of Texas Using GIS and Remote Sensing

The Rocker b Ranch on the southern Rolling Plains has one of the last sizeable populations of pronghorn (Antilocapra americana) in Texas. To investigate habitat utilization on the ranch, pronghorn were fitted with GPS/VHF collars and were released into pastures surrounded by a variety of fences to determine how fence types affected habitat selection. Habitat parameters chosen for analysis were vegetation, elevation, slope, aspect, and distances to water, roads, and oil wells. Results showed that pronghorn on the ranch crossed modified fencing significantly less than other types of fencing. Pronghorn selected for all habitat parameters to various degrees, with the most important being vegetation type. Habitat selection could be attributed to correspondence of vegetation type with other parameters or spatial arrangements of physical features of the landscape. Seasonal differences in habitat utilization were evident, and animals tended to move shorter distances at night than they did during daylight hours.
Date: May 2005
Creator: Aiken, Robin A.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Understanding and preventing police use of excessive force: An analysis of attitudes toward police job satisfaction and human rights laws. (open access)

Understanding and preventing police use of excessive force: An analysis of attitudes toward police job satisfaction and human rights laws.

Although governments try to create strict policies and regulations to prevent abuses, use of excessive force is still a problem for almost every country including Turkey. This study is intended to help Turkish National Police administrators to understand and prevent police use of excessive force. Studies on police brutality categorize three factors that explain why police officers use excessive force; these are individual, situational and organizational. In addition to brutality theories, job satisfaction literature is examined in this study to understand the use of excessive force. Job satisfaction is found to be related with burnout, turnover, stress, commitment, and performance. The impact of officers' attitude toward the criminal justice system and/or laws has not been tested widely. Police officers attitudes toward human rights laws are examined in this study to measure its impact on attitude toward use of excessive force. A secondary data collected in Turkey are analyzed by structural equation modeling which provides confirmatory factor analysis, path analysis, and causal relationships between variables. It is found that police officers' attitude toward human rights laws is a significant predictor of their attitudes toward use of excessive force. Job satisfaction and education level are the other significant variables affecting attitude toward …
Date: December 2009
Creator: Akdogan, Huseyin
Object Type: Thesis or Dissertation
System: The UNT Digital Library
The Russian trumpet sonata: a study of selected representative sonatas for trumpet and piano with an historical overview of the Russian trumpet school (open access)

The Russian trumpet sonata: a study of selected representative sonatas for trumpet and piano with an historical overview of the Russian trumpet school

The impact of training on virtual team effectiveness was assessed in five areas: communication, planning tasks and setting goals, solving problems and making decisions, resolving conflict, and responding to customer requirements. A 12-page survey was developed exploring all aspects of virtual teams. 180 surveys were distributed, 52 were returned representing 43 companies. Training led to higher effectiveness in planning tasks and setting goals, solving problems and making decisions, and conflict resolution, but not in communication and responding to customer requirements. Training may not solve all the problems that virtual teams will encounter; however, training will make the challenges easier to handle.
Date: May 2003
Creator: Akhmadullin, Iskander
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Perturbation of renewal processes (open access)

Perturbation of renewal processes

Renewal theory began development in the early 1940s, as the need for it in the industrial engineering sub-discipline operations research had risen. In time, the theory found applications in many stochastic processes. In this thesis I investigated the effect of seasonal effects on Poisson and non-Poisson renewal processes in the form of perturbations. It was determined that the statistical analysis methods developed at UNT Center for Nonlinear Science can be used to detect the effects of seasonality on the data obtained from Poisson/non-Poisson renewal systems. It is proved that a perturbed Poisson process can serve as a paradigmatic model for a case where seasonality is correlated to the noise and that diffusion entropy method can be utilized in revealing this relation. A renewal model making a connection with the stochastic resonance phenomena is used to analyze a previous neurological experiment, and it was shown that under the effect of a nonlinear perturbation, a non-Poisson system statistics may make a transition and end up in the of Poisson basin of statistics. I determine that nonlinear perturbation of the power index for a complex system will lead to a change in the complexity characteristics of the system, i.e., the system will reach …
Date: May 2008
Creator: Akin, Osman Caglar
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Synthesis, characterization and properties of rigid macromolecules with extended conjugation, using palladium-catalyzed alkynylated polyhaloarenes. (open access)

Synthesis, characterization and properties of rigid macromolecules with extended conjugation, using palladium-catalyzed alkynylated polyhaloarenes.

A synthetic approach to macromolecules of acetylenic arrays and luminescent properties is proposed and the execution of initial steps is described. Palladium-catalyzed coupling of 1,3,5-triiodobenzene with trimethylsilylbuta-1,3-diyne, trimethylsilylocta-1,3,5,7-tetrayne, and trimethylsilylhexadeca-1,3,5,7,9,11,13,15-octayne to yield the new 1,3,5-tris(trimethylsilylbuta-1,3-diynyl)benzene and the proposed 1,3,5-tris(8-(trimethylsilyl)octa-1,3,5,7-tetraynyl)benzene and 1,3,5-tris(trimethylsilyl)hexadeca-1,3,5,7,9,11,13,15-octaynyl)benzene respectively. The proposed three-coordinate Au (I) complexed macromolecules will be derived from the metallation of the aforementioned alkynylated arenes.
Date: December 2007
Creator: Akintomide, Temiloluwa
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Makeshift Information Constructions: Information Flow and Undercover Police (open access)

Makeshift Information Constructions: Information Flow and Undercover Police

This dissertation presents the social virtual interface (SVI) model, which was born out of a need to develop a viable model of the complex interactions, information flow and information seeking behaviors among undercover officers. The SVI model was created from a combination of various philosophies and models in the literature of information seeking, communication and philosophy. The questions this research paper answers are as follows: 1. Can we make use of models and concepts familiar to or drawn from Information Science to construct a model of undercover police work that effectively represents the large number of entities and relationships? and 2. Will undercover police officers recognize this model as realistic? This study used a descriptive qualitative research method to examine the research questions. An online survey and hard copy survey were distributed to police officers who had worked in an undercover capacity. In addition groups of officers were interviewed about their opinion of the SVI model. The data gathered was analyzed and the model was validated by the results of the survey and interviews.
Date: August 2005
Creator: Aksakal, Baris
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Transnational Organized Crime and the Drug Business (open access)

Transnational Organized Crime and the Drug Business

This study analyzes the activities of the organized crime groups involved in the drug business, as well as examining national and international efforts to control these groups. Specifically, this study addresses the following questions: How is organized crime connected to the international drug business?; What are the major transnational organized crime groups involved in the international drug business?; What is the nature of the drug problem as it relates to organized crime internationally?; What international cooperative law enforcement efforts currently exist to deal with organized crime and the drug business? Findings indicate that efforts to create an effective international law enforcement network are needed to meet the challenges of drug trafficking and globalized crime. To date, such efforts have largely been unsuccessful.
Date: August 2002
Creator: Aksakal, Baris
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Problems Encountered in Money Laundering Investigations (open access)

Problems Encountered in Money Laundering Investigations

The purpose of this study is to identify how the U.S. is responding to money laundering and what kind of problems arise while countering it, beginning with a detailed description of money laundering, its stages, typologies, impacts, and complications. Due to the broad nature of this subject only three main issues form the focal point of this study: problems concerning the banking industry and other financial organizations, problems resulting from the limitations of law enforcement agencies, and problems arising from the lack of cooperation between and within financial institutions and law enforcement agencies. Several probable solutions to the above problems are identified: Considering the financial industry, there are loopholes in the Bank Secrecy Act (BSA) and in other regulations that apply to the industry. Thus, there is a comparison of the Subjective Model vs. Objective Model in terms of reporting systems for financial organizations. On the law enforcement side, the priority is the need to update and upgrade their technology and investigation mechanisms in order not to fall behind the criminals. Finally, cooperation is something that can be achieved through mutual respect and understanding of the priorities of each side, which can be achieved by the creation of an upper …
Date: August 2001
Creator: Akyay, Ilkay
Object Type: Thesis or Dissertation
System: The UNT Digital Library
An investigation of factors affecting Omani faculty members' adoption of information and computing technology. (open access)

An investigation of factors affecting Omani faculty members' adoption of information and computing technology.

The purpose of this study was to explore the factors influencing information and computing technology (ICT) adoption for Omani faculty members from a framework of Rogers' theory of diffusion of innovation. Three hundred Omani faculty members from Sultan Qaboos University (SQU) participated in the study. The survey consisted of five parts: (a) an 18-item questionnaire on ICT uses and skills, (b) a 1-item questionnaire on adopter category, (c) a 44-item self-constructed questionnaire on perception of barriers to adopting ICT, (d) a 50-item questionnaire on ICT attributes adapted from Moore and Benbasat, and (e) a 15-item questionnaire on demographic and job-related variables. Descriptive statistics indicated that the faculty members overall used ICT at the "Sometimes" level and had ICT skills at the "Intermediate" level. The most frequently used and skillful ICT functional areas were Website browsing, Internet search engine, and word processing. One-way ANOVAs found significant group differences of ICT uses and skills, perception of barriers, and perception of ICT attributes in the category of adopter. Early adopters used ICT more, had higher ICT skills, perceived fewer barriers in the adopting process, and recognized higher values of ICT attributes than later adopters did. Multiple regression analysis showed the level of ICT …
Date: August 2009
Creator: Al Senaidi, Said
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Preservice teachers' attitudes toward and knowledge about cooperative learning in Kuwait: A quasi-experimental study (open access)

Preservice teachers' attitudes toward and knowledge about cooperative learning in Kuwait: A quasi-experimental study

The issue of developing effective teacher preparation and professional programs by providing effective teaching and learning strategies to prepare teachers to teach in more challenging ways and change their old ways of teaching to more powerful ones has gained great attention around the world. Cooperative learning was one of the astonishing strategies introduced by many researchers to prepare effective teachers and to solve many educational problems. Teacher educators have taken different approaches to help teachers learn and change in powerful ways. They have focused on the knowledge and attitudes of teachers in promoting their adoption of new practices through educational courses, workshops, and training. After introducing the cooperative learning strategy through a training workshop, this study investigated the knowledge of and attitude of teachers at the College of Basic Education (CBE) in Kuwait towards cooperative learning as a new teaching and learning strategy. The literature reviewed the historical and practical use, theoretical roots, different models, and outcomes of cooperative learning. In addition, (1) teachers' knowledge and attitudes as factors affecting implementation and (2) preservice teacher preparation and training in the use of cooperative learning were reviewed. An attitude survey and a knowledge test were developed based on Bouas, (1993) survey …
Date: December 2001
Creator: Al-Dawoud, Afeefa
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Financial Transfer and Its Impact on the Level of Democracy: A Pooled Cross-Sectional Time Series Model. (open access)

Financial Transfer and Its Impact on the Level of Democracy: A Pooled Cross-Sectional Time Series Model.

This dissertation is a pooled time series, cross-sectional, quantitative study of the impact of international financial transfer on the level of democracy. The study covers 174 developed and developing countries from 1976 through 1994. Through evaluating the democracy and democratization literature and other studies, the dissertation develops a theory and testable hypotheses about the impact of the international variables foreign aid and foreign direct investment on levels of democracy. This study sought to determine whether these two financial variables promote or nurture democracy and if so, how? A pooled time-series cross-sectional model is developed employing these two variables along with other relevant control variables. Control variables included the presence of the Cold War and existence of formal alliance with the United States, which account for the strategic dimension that might affect the financial transfer - level of democracy linkage. The model also includes an economic development variable (per capita Gross National Product) to account for the powerful impact for economic development on the level of democracy, as well as a control for each country's population size. By addressing and the inclusion of financial, economic, strategic, and population size effects, I consider whether change in these variables affect the level of …
Date: May 2003
Creator: Al-Momani, Mohammad H.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
True Selves: Narrative Distance in Stories of Fiction and Nonfiction (open access)

True Selves: Narrative Distance in Stories of Fiction and Nonfiction

True Selves: Narrative Distance in Stories of Fiction and Nonfiction consists of a scholarly preface and four creative works. The preface discusses narrative distance as used in both fiction and nonfiction, and as compares to other narrative agents such as point of view, especially in contemporary creative writing. The selection of stories examines relationships, especially familial, and themes of isolation, community, and memory. Collection includes two chapters of a novel-in-progress, Fences, short fiction story "Trees and Furniture," and creative nonfiction essays, "Floating" and "On the Sparrow."
Date: December 2009
Creator: Al-Qasem, Ruby
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Higher Education and Entrepreneurship: The Relation between College Educational Background and Small Business Success in Texas (open access)

Higher Education and Entrepreneurship: The Relation between College Educational Background and Small Business Success in Texas

This study examined the relationship between success of small businesses and the educational backgrounds of their owners. A survey composed of questions concerning demographics, educational backgrounds, and business success was mailed to 1100 businesses in Dallas, Denton, and Tarrant counties in Texas. There were 228 usable responses which were analyzed by using the Statistical Package of Social Sciences (SPSS12). Data were sorted so that educational level, sales volume, number of employees, and longevity, were identified on a 5-point ordinal scale. Educational major was identified on a 5-point nominal scale. Pearson's correlation was used to determine whether relationships existed between founders' educational background and small business success. Spearman's correlation was used to determine the direction and strength of the relationships. Then educational level and major were combined with age, gender, ethnicity, and industry, to determine the relationships between founders' educational background, and business success. For this purpose a canonical correlation was used. Five opinion questions concerned influence of college education on business success among college graduates and non-college graduates were identified on a 5-point Likert scale and tested using one-way ANOVA, and independent sample t-test. When educational level and major were the only predictors of business success, a statistically significant relationship …
Date: May 2005
Creator: Al-Zubeidi, Mohammad
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Creating an Alaska Climate Impact Assessment Commission: Legislative Resolve Number 49 (open access)

Creating an Alaska Climate Impact Assessment Commission: Legislative Resolve Number 49

This legislation establishes a commission to assess the impact of climate change on the economy, population, and landscape of Alaska.
Date: 2006
Creator: Alaska. Legislature
Object Type: Text
System: The UNT Digital Library
Use of the Beck Depression Inventory in Northern Brazil (open access)

Use of the Beck Depression Inventory in Northern Brazil

The Beck Depression Inventory (BDI) is a popular screening and research instrument for measuring severity of depression. The instrument was translated to Portuguese for use in Brazil in 1979; however, it was not until recently that its psychometric properties have been tested empirically for the Brazilian population. The purpose of the present study was to explore the BDI's psychometric properties in a northern region of Brazil and to test for possible relationships between certain demographic variables and BDI outcomes. Samples used in this study were from an urban area in Roraima, the northernmost state of Brazil. The BDI showed adequate levels of internal consistency in nonclinical and clinical samples. Female respondents had significantly higher scores than male respondents. Those who had lower levels of education, income, or occupational status had significantly higher scores than those with higher levels of these variables. Adolescents had significantly higher scores than adults from all age groups except those from age 19 to 22. No significant difference was found between those who identified themselves as “indigenous” and those who identified themselves as “non-indigenous.” Regression analysis results showed that the combination of gender, education, and age best accounted for the variance in BDI scores. An ANCOVA …
Date: May 2002
Creator: Albert, Christopher
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Athletic Trainers and Psychological Disorders Among Athletes: An Examination of Their Abilities to Recognize, Diagnose and Intervene. (open access)

Athletic Trainers and Psychological Disorders Among Athletes: An Examination of Their Abilities to Recognize, Diagnose and Intervene.

Utilizing an analogue research design conducted via the Internet, this study assessed athletic trainers' abilities to recognize, diagnose, and intervene with a hypothetical athlete experiencing depression, and examined the impact of their gender, athlete gender, and athlete's presenting problem on their decisions. Athletic trainers' perceived competency in using psychosocial interventions with athletes, history of referring athletes to psychology professionals, and training backgrounds in psychology also were examined. Participants (270 male and 370 female certified athletic trainers) were randomly assigned to one of six conditions (Athlete Gender X Presenting Problem). After reading the appropriate vignette, they completed questions related to the athlete's psychological symptoms and diagnosis, referral recommendations, and use of psychosocial interventions if working with the athlete. The vignettes were identical except for the athlete's gender and problem. Overall, athletic trainers accurately identified the athlete's depressive symptoms/diagnosis and need for psychological referral. They rated the athlete significantly higher in Depressive Symptoms than in Anger/Agitation Symptoms and Compulsive Behavioral Symptoms, and as more likely to be experiencing a depressive disorder compared to an adjustment disorder, anxiety disorder, sleep disorder, or substance abuse disorder. Female athletic trainers provided significantly higher ratings of Depressive Symptoms than males and the injured athlete was rated …
Date: December 2006
Creator: Albinson, Courtney Brooks
Object Type: Thesis or Dissertation
System: The UNT Digital Library
The Anglo-Iraqi Relationship Between 1945 and 1948. (open access)

The Anglo-Iraqi Relationship Between 1945 and 1948.

This paper discuses the British Labour government's social, economic and military policies in Iraq between 1945 and 1948. The ability of the Iraqi monarchy to adapt to the British policies after World War II is discussed. The British were trying to put more social justice into the Iraqi regime in order to keep British influence and to increase the Iraqi regime's stability against the Arab nationalist movement.
Date: December 2008
Creator: Alburaas, Theyab M.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
The Influence Of Jazz On Timbre In Selected Compositions For Solo Trombone (open access)

The Influence Of Jazz On Timbre In Selected Compositions For Solo Trombone

A significant body of solo literature for the trombone has been written in the last fifty years that draws as much from the jazz tradition as from that of European classical music. While much attention has been paid to these works' use of characteristic jazz rhythms, harmonies and melodic inflections, there has been little focus on timbre, the musical element that perhaps most readily distinguishes jazz from other styles of Western music. This paper focuses on the important role jazz timbres should play in a performer's interpretation of those works that are significantly influenced by jazz. It includes explorations of the significant differences in concepts of timbre between European classical music and jazz, some of the ways in which these timbral differences are produced, and methods by which performers can develop the skills necessary to produce these varied timbres. Particular attention is paid to the importance of timbre to idiomatically appropriate performances of two significant works from the solo trombone repertoire, Robert Suderburg's Night Set (Chamber Music III) and Richard Peaslee's Arrows of Time.
Date: December 2002
Creator: Aldag, Daniel J.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
To Include or not to Include: Early Childhood Preservice Educators' Beliefs, Attitudes, and Knowledge about Students with Disabilities (open access)

To Include or not to Include: Early Childhood Preservice Educators' Beliefs, Attitudes, and Knowledge about Students with Disabilities

The first purpose of this study was to develop and validate the Inventory of Opinions About Persons with Disabilities (IOPD). The IOPD was developed to collect preservice early childhood educators’self-report data related to inclusion. A total of 332 participants enrolled in graduate programs in a college of education served as the validation sample. After validation and revision of the IOPD, the researcher used the instrument to investigate preservice early childhood educators’ beliefs, attitudes, and knowledge about students with disabilities and their inclusion in general education classrooms. Data were collected from 172 participants from 10 universities in Texas during their student teaching/final intern semesters. This research demonstrated that an instrument, the IOPD, could be developed to effectively measure preservice early childhood educators’ beliefs, attitudes, and knowledge about the inclusion of children with disabilities in their classrooms. The participants reported positive self-perceptions (mean = 2.0388) about their beliefs and attitudes toward inclusion. However, the participants reported less positive attitudes about training (mean = -.09884). Discriminant function analyses indicated a negligible statistical effect for type of program (professional development school or traditional) and a statistically significant effect for preferred classroom setting (non-inclusive, special education, inclusive). Further research with the same participants or similar …
Date: August 2000
Creator: Aldrich, Jennifer E.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Kinetic studies and computational modeling of atomic chlorine reactions in the gas phase. (open access)

Kinetic studies and computational modeling of atomic chlorine reactions in the gas phase.

The gas phase reactions of atomic chlorine with hydrogen sulfide, ammonia, benzene, and ethylene are investigated using the laser flash photolysis / resonance fluorescence experimental technique. In addition, the kinetics of the reverse processes for the latter two elementary reactions are also studied experimentally. The absolute rate constants for these processes are measured over a wide range of conditions, and the results offer new accurate information about the reactivity and thermochemistry of these systems. The temperature dependences of these reactions are interpreted via the Arrhenius equation, which yields significantly negative activation energies for the reaction of the chlorine atom and hydrogen sulfide as well as for that between the phenyl radical and hydrogen chloride. Positive activation energies which are smaller than the overall endothermicity are measured for the reactions between atomic chlorine with ammonia and ethylene, which suggests that the reverse processes for these reactions also possess negative activation energies. The enthalpies of formation of the phenyl and β-chlorovinyl are assessed via the third-law method. The stability and reactivity of each reaction system is further rationalized based on potential energy surfaces, computed with high-level ab initio quantum mechanical methods and refined through the inclusion of effects which arise from the …
Date: August 2009
Creator: Alecu, Ionut M.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Barriers to Adopting PREMIS in Cultural Heritage Institutions: An Exploratory Study (open access)

Barriers to Adopting PREMIS in Cultural Heritage Institutions: An Exploratory Study

Paper for the 2009 IS&T Archiving Conference. This paper discusses an exploratory study on barriers to adopting PREMIS in cultural heritage institutions.
Date: May 2009
Creator: Alemneh, Daniel Gelaw
Object Type: Paper
System: The UNT Digital Library