Degree Level

Country

194 Matching Results

Results open in a new window/tab.

Adoptive Parenthood: an Exploratory Study of the Influence of Pre-adoption Communication Satisfaction on Post-adoption Family Adjustment and Coping (open access)

Adoptive Parenthood: an Exploratory Study of the Influence of Pre-adoption Communication Satisfaction on Post-adoption Family Adjustment and Coping

There are over a million adopted children in the United States, which makes up over 2% of the population. in spite of the fact that the majority of children are adopted into loving and caring homes, early life trauma puts them at higher risk for developing behavioral and emotional problems than non-adopted children. Due to these issues, many adoptive parents encounter post-adoption stress. This stress is often linked to minimal education regarding short- and long-term challenges associated with adoption. the adoption agency is likely the best group for addressing challenges, yet few researchers have studied adoption agency communication and adoptive parent adjustment. in this study I examined pre-adoption communication satisfaction, post-adoption adjustment (life change and parental adjustment), and coping strategies. Hypothesis 1 questioned the relationship between adoptive parents’ pre-adoption communication satisfaction with their social workers and post-adoption family adjustment; this hypothesis was supported only for problems related to home and work life adjustment. Hypothesis 2 predicted coping strategies would mediate the relationship between communication satisfaction and family adjustment. H2 was not supported for both life change and parental adjustment. Research Questions 1a and 1b inquired about the coping strategy that had an impact on life change and parental adjustment; escape-avoidance …
Date: May 2012
Creator: Seebeck, Lara N.
System: The UNT Digital Library
“Almost Astronauts”: Short Stories (open access)

“Almost Astronauts”: Short Stories

In this collection of short stories, I abduct experiences from my own life and take them on an imaginative journey. I experiment with elements of structure and point of view, often incorporating the magical or surreal to amplify the narrator’s internal landscape. As demonstrated in the title story, “Almost Astronauts,” these stories all deal with a sudden and sometimes destructive shift in the narrator’s perspective.
Date: May 2012
Creator: Miller, Laura I.
System: The UNT Digital Library
Alterations in Fatty Acid Amide Hydrolase (Faah) Transcript Levels and Activity Lead to Changes in the Abiotic Stress Susceptibility of Arabidopsis Thaliana (open access)

Alterations in Fatty Acid Amide Hydrolase (Faah) Transcript Levels and Activity Lead to Changes in the Abiotic Stress Susceptibility of Arabidopsis Thaliana

N-Acylethanolamines (NAEs) are a class of bioactive lipids, and FAAH is one of the enzymes responsible for degrading NAEs in both plants and animals. in plants, FAAH appears to be closely associated with ABA, a phytohormone which has long been associated with plant stress responses, since the overexpression of FAAH in Arabidopsis results in ABA hypersensitivity. Therefore, it is reasonable to speculate that alterations in FAAH transcript levels will result in altered stress responses in plants. to investigate this hypothesis experiments were carried out in which wild type (WT), FAAH-overexpressing (OE), and T-DNA insertional FAAH knockouts of Arabidopsis (faah) were grown in MS media under stress conditions. the stress conditions tested included chilling stress, heavy metal stress induced by cadmium or copper, nutrient limitations induced by low phosphorus or low nitrogen, salt stress induced with NaCl, and osmotic stress induced with mannitol. the OE plants were consistently hypersensitive to all stress conditions in relation to wild type plants. Inactive FAAH overexpressors did not have the hypersensitivity to the salt and osmotic stress of the active OE plants and were instead tolerant to these stresses. FAAH2 (faah2) knockouts and FAAH 1 and 2 double knockouts (faah 1+2) were based on some …
Date: May 2012
Creator: Gonzalez, Gabriel
System: The UNT Digital Library
Alternative Complementation in Partially Schematic Constructions:  a Quantitative Corpus-based Examination of COME to V2 and GET to V2 (open access)

Alternative Complementation in Partially Schematic Constructions: a Quantitative Corpus-based Examination of COME to V2 and GET to V2

This paper examines two English polyverbal constructions, COME to V2 and GET to V2, as exemplified in Examples 1 and 2, respectively. (1) the senator came to know thousands of his constituents (2) Little Johnny got to eat ice cream after every little league game. Previous studies considered these types of constructions (though come and get as used here have not been sufficiently studied) as belonging to a special class of complement constructions, in which the infinitive is regarded as instantiating a separate, subordinate predication from that of the “matrix” or leftward finite verb. These constructions, however, exhibit systematic deviation from the various criteria proposed in previous research. This study uses the American National Corpus to investigate the statistical propensities of the target phenomena via lexico-syntactic (collostructional analysis) and morpho-syntactic (binary logistic regression) features, as captured through the lens of construction grammar.
Date: May 2012
Creator: Lester, Nicholas A.
System: The UNT Digital Library
Analysis of Sources Affecting Ambient Particulate Matter in Brownsville, Texas (open access)

Analysis of Sources Affecting Ambient Particulate Matter in Brownsville, Texas

Texas is the second largest state in U.S.A. based on geographical area, population and the economy. It is home to several large coastal urban areas with major industries and infrastructure supporting the fossil-fuel based energy sector. Most of the major cities on the state have been impacted by significant air pollution events over the past decade. Studies conducted in the southern coastal region of TX have identified long range transport as a major contributor of particulate matter (PM) pollution along with local emissions. Biomass burns, secondary sulfates and diesel emissions sources are comprise as the dominant mass of PM2.5 have been noted to be formed by the long range transport biomass from Central America. Thus, the primary objective of this study was to identify and quantify local as well as regional sources contributing to the PM pollution in the coastal area of Brownsville located along the Gulf of Mexico. Source apportionment techniques such as principal component analysis (PCA) and positive matrix factorization (PMF) were employed on the air quality monitoring data to identify and quantify local and regional sources affecting this coastal region. As a supplement to the PMF and PCA, conditional probability function (CPF) analysis and potential source contribution …
Date: May 2012
Creator: Diaz Poueriet, Pablo
System: The UNT Digital Library
An Analysis of the Correspondence Between the Measures Collected by an Autism Treatment Center and its Stated Mission Goals (open access)

An Analysis of the Correspondence Between the Measures Collected by an Autism Treatment Center and its Stated Mission Goals

This study was a program evaluation for an autism treatment center for the period of April 2008 through August 2011. the study extended previous evaluations of the autism treatment center. the purpose of this evaluation was to determine the degree to which the center’s measures corresponded with its stated mission goals. a number of data sources were reviewed including client records of demographic and outcome information. Findings suggest the center maintained records that allow for the evaluation of most of its mission’s goals. There were, however, difficulties with data collection, storage, and retrieval. the present program evaluation found that missing information and lack of follow-up information hindered efforts toward mission evaluation.
Date: May 2012
Creator: Kowalchuk, Holly M.
System: The UNT Digital Library
The Argei: Sex, War, and Crucifixion in Rome and the Ancient Near East (open access)

The Argei: Sex, War, and Crucifixion in Rome and the Ancient Near East

The purpose of the Roman Argei ceremony, during which the Vestal Virgins harvested made and paraded rush puppets only to throw them into the Tiber, is widely debated. Modern historians supply three main reasons for the purpose of the Argei: an agrarian act, a scapegoat, and finally as an offering averting deceased spirits or Lares. I suggest that the ceremony also related to war and the spectacle of displaying war casualties. I compare the ancient Near East and Rome and connect the element of war and husbandry and claim that the Argei paralleled the sacred marriage. in addition to an agricultural and purification rite, these rituals may have served as sympathetic magic for pre- and inter-war periods. As of yet, no author has proposed the Argei as a ceremony related to war. By looking at the Argei holistically I open the door for a new direction of inquiry on the Argei ceremony, fertility cults in the Near East and in Rome, and on the execution of war criminals.The Argei and new year’s sacred marriage both occurred during the initiation of campaign and spring planting and harvest season. Both in the ancient Near East and in Rome, animal victims were sacrificed …
Date: May 2012
Creator: Foust, Kristan Ewin
System: The UNT Digital Library
Baseband Noise Suppression in Ofdm Using Kalman Filter (open access)

Baseband Noise Suppression in Ofdm Using Kalman Filter

As the technology is advances the reduced size of hardware gives rise to an additive 1/f baseband noise. This additive 1/f noise is a system noise generated due to miniaturization of hardware and affects the lower frequencies. Though 1/f noise does not show much effect in wide band channels because of its nature to affect only certain frequencies, 1/f noise becomes a prominent in OFDM communication systems where narrow band channels are used. in this thesis, I study the effects of 1/f noise on the OFDM systems and implement algorithms for estimation and suppression of the noise using Kalman filter. Suppression of the noise is achieved by subtracting the estimated noise from the received noise. I show that the performance of the system is considerably improved by applying the 1/f noise suppression.
Date: May 2012
Creator: Rodda, Lasya
System: The UNT Digital Library
Bearing Strength of Cold Formed Steel Bolted Connections in Trusses (open access)

Bearing Strength of Cold Formed Steel Bolted Connections in Trusses

The existing design provision in North American Specification for Cold- Formed Steel Structural Member (AISI S100) for the bearing strength of bolted connections were developed from tests on bolted connected sheets which were restrained by bolt nut and head with or without washers. However, in the cold-formed assemblies, particularly in trusses, the single bolt goes through both sides of the connected sections, making the connected sheets on each side unrestrained. the warping of the unrestrained sheet may reduce the bearing strength of the bolted connection. This research investigates the behavior and strength of bearing failure in bolted connections in cold-formed steel trusses. Tensile tests were conducted on trusses connections with various material thicknesses. It was found that the AISI S100 works well for thick connections but provides unconservative predictions for thin materials. Based on the experimental results, a modified bearing strength method is proposed for calculating the bearing strength of bolted truss connections. the proposed method can be used for any cold-formed steel connections with unrestrained sheet.
Date: May 2012
Creator: Panyanouvong, Mark
System: The UNT Digital Library
Branded Content: Understanding the Mechanisms of Strategic Messaging in Entertainment Television Formats (open access)

Branded Content: Understanding the Mechanisms of Strategic Messaging in Entertainment Television Formats

Branded content as an advertising tactic is a growing phenomenon that is not widely researched and is generally ambiguous in nature. This study uses qualitative methods to explain how branded content is defined, how it functions, and how it can influence a brand. Case studies of IKEA and Chevrolet were compared alongside four interviews with branded content professionals. the data collected suggests that branded content in structure and substance is varied, however it comprises engagement, the brand, and financial transaction. the data collected also suggested that brands take a variety of stances when controlling content to support their brand, and that branded content generally supports the intangible aspects of a brand, as opposed to product features.
Date: May 2012
Creator: Nicholson, Danielle Marie
System: The UNT Digital Library
Charlotte Perkins Gilman: Naturalist Playwright (open access)

Charlotte Perkins Gilman: Naturalist Playwright

This study explores Charlotte Perkins Gilman’s use of the dramatic form to challenge Herbert Spencer’s social Darwinism by offering feminist adaptations of Darwin’s theories of natural and sexual selection. As she does in her career-defining manifesto, Women & Economics (1898), Gilman in her lesser-known plays deploys her own brand of reform Darwinism to serve the feminist cause. Despite her absence in histories of modern drama, Gilman actively participated in the establishment and development of this literary, historical, and cultural movement. After situating Gilman in the context of nineteenth-century naturalist theater, this thesis examines two short dramatic dialogues she published in 1890, “The Quarrel,” and “Dame Nature Interviewed,” as well as two full-length plays, Interrupted (1909) and the Balsam Fir (1910). These plays demonstrate Gilman’s efforts to use the dramatic form in her early plays to “rehearse” for Women & Economics, and in her later drama, to “stage” the theories she presents in that book.
Date: May 2012
Creator: Tolle, Andrew
System: The UNT Digital Library
Childhood Bereavement and Parents’ Relationship With Children (open access)

Childhood Bereavement and Parents’ Relationship With Children

It has long been recognized that childhood bereavement is a risk factor for depression in adulthood. Research also has consistently demonstrated that parental depression is linked to poor parent-child relationship quality. The current study examined whether bereavement in childhood increases likelihood of current depressive symptoms among parents and explored whether this vulnerability in the parent then alters the quality of the parent-child relationship. Archival data for a sample of 86 families (N=176 parents) are drawn from the Family & Kid Connection project led by Dr. Shelley Riggs. Instruments utilized include the Background Information Questionnaire, the Symptom Assessment-45 Questionnaire, and the Parenting Relationship Questionnaire. Using the Actor-Partner Interdependence Model, Multilevel Modeling procedures explored the hypothesis that parental depression mediates the association between parents’ childhood bereavement and their perception of the parent-child relationship. Results show a significant relationship between parental (actor) depressive symptoms and parent-child attachment, indicating the need for therapeutic interventions targeting the parent-child relationship, and not just parents, for parents suffering from depression.
Date: May 2012
Creator: Benson, Karen M.
System: The UNT Digital Library
Comparing the 2010 and 2011 Appic Match: Applicant Characteristics and Unmatched Applicant Distress (open access)

Comparing the 2010 and 2011 Appic Match: Applicant Characteristics and Unmatched Applicant Distress

The internship is one of the most important components of doctoral training in professional psychology. Given the serious problem of the internship imbalance, applicant and program characteristics that constitute a good “fit” with internship training programs have become of greater interest as securing an internship becomes a more competitive process. This study surveyed internship applicants from programs part of the Council of University Directors of Clinical Psychology (CUDCP), before and after the 2010 and 2011 match days. Number of interview offers was found to be the factor most consistently associated with successfully matching, and several other applicant characteristics salient to matching and obtaining interview offers were identified, including applicant personality. Additionally, personal accounts, but not empirical evidence, of going unmatched have attested to the psychological distress associated with this event. in the current study, while going unmatched was not found to be equitable to a traumatic stressor, evidence was found to support significant decrease in subjective well-being with respect to immediate distress. Findings are discussed in terms of the predictability of and implications for the match process and internship imbalance, and recommendations are made for future research directions.
Date: May 2012
Creator: Hogan, Lindsey R.
System: The UNT Digital Library
A Comparison of Vocabulary Banks and Scripts on Native English-speaking Students’ Acquisition of Italian (open access)

A Comparison of Vocabulary Banks and Scripts on Native English-speaking Students’ Acquisition of Italian

The study applied behavior analytic principles to foreign language instruction in a college classroom. Two study methods, vocabulary banks and scripts, were compared by assessing the effects on Italian language acquisition, retention, and generalization. Results indicate that students without prior exposure to Italian engaged in more exchanges and emitted more words in script tests compared to vocabulary bank tests. Participants with at least two classes in Italian prior to the study engaged in more exchanges and emitted more words during vocabulary bank tests. Data suggest that different teaching strategies may work for different learners. More research is needed to determine efficient teaching methods and how to ascertain which approaches work best for learners with different histories.
Date: May 2012
Creator: Dean, Brittany L.
System: The UNT Digital Library
Continuity of Caste: Free People of Color in the Vieux Carré of New Orleans, 1804-1820 (open access)

Continuity of Caste: Free People of Color in the Vieux Carré of New Orleans, 1804-1820

Because of its trademark racial diversity, historians have often presented New Orleans as a place transformed by incorporation into the American South following 1804. Assertions that a comparatively relaxed, racially ambiguous Spanish slaveholding regime was converted into a two-caste system of dedicated racial segregation by the advent of American assumption have been posited by scholars like Frank Tannenbaum, Gwendolyn Midlo Hall, and a host of others. Citing dependence on patronage, concubinage, and the decline in slave manumissions during the antebellum period, such studies have employed descriptions of the city’s prominent free people of color to suggest that the daily lives of non-whites in New Orleans experienced uniform restriction following 1804, and that the Crescent City’s transformation from Atlantic society with slaves to rigid slave society forced free people of color out of the heart of the city, known as the Vieux Carré, and into “black neighborhoods” on the margins of town. Despite the popularity of such generalized themes in the historiography, however, the extant sources housed in New Orleans’s valuable archival repositories can be used to support a vastly divergent narrative. By focusing on individual free people of color, or libres, rather than the non-white community as a whole, this …
Date: May 2012
Creator: Foreman, Nicholas
System: The UNT Digital Library
Cuff-less Blood Pressure Measurement Using a Smart Phone (open access)

Cuff-less Blood Pressure Measurement Using a Smart Phone

Blood pressure is vital sign information that physicians often need as preliminary data for immediate intervention during emergency situations or for regular monitoring of people with cardiovascular diseases. Despite the availability of portable blood pressure meters in the market, they are not regularly carried by people, creating a need for an ultra-portable measurement platform or device that can be easily carried and used at all times. One such device is the smartphone which, according to comScore survey is used by 26.2% of the US adult population. the mass production of these phones with built-in sensors and high computation power has created numerous possibilities for application development in different domains including biomedical. Motivated by this capability and their extensive usage, this thesis focuses on developing a blood pressure measurement platform on smartphones. Specifically, I developed a blood pressure measurement system on a smart phone using the built-in camera and a customized external microphone. the system consists of first obtaining heart beats using the microphone and finger pulse with the camera, and finally calculating the blood pressure using the recorded data. I developed techniques for finding the best location for obtaining the data, making the system usable by all categories of people. …
Date: May 2012
Creator: Jonnada, Srikanth
System: The UNT Digital Library
Detection of Mercury Among Avian Trophic Levels at Caddo Lake and Lake Lewisville, TX (open access)

Detection of Mercury Among Avian Trophic Levels at Caddo Lake and Lake Lewisville, TX

Mercury (Hg) is a globally distributed toxicant that has been shown to have negative effects on birds. in the United States, avian taxa have been shown to possess high Hg concentrations in the northeast, Great Lakes and Everglades ecosystems; however, few studies have measured avian Hg concentrations in other geographic regions. Previous studies have documented high Hg concentrations in multiple organisms in east Texas, but birds were not included in these studies. the main objective of the present study was to quantify Hg concentrations in birds in differing trophic levels at Caddo Lake and Lake Lewisville, TX. Results suggest that Hg concentrations may be high enough to negatively impact some bird taxa, particularly those at high trophic levels, residing at both Caddo Lake and Lake Lewisville.
Date: May 2012
Creator: Schulwitz, Sarah E.
System: The UNT Digital Library
The Development of Anti-submarine Warfare in the Mediterranean: the American Contribution and the Bombardment of Durazzo (open access)

The Development of Anti-submarine Warfare in the Mediterranean: the American Contribution and the Bombardment of Durazzo

The Entente powers began World War I without any formal anti-submarine countermeasures. However, the Entente developed countermeasures through trial and error over time. Success was moderate until America joined the war. with America came the arrival of subchasers to the Mediterranean Theater of Operations. This highly specialized vessel helped turn the tide against U-boats. a true counter to the U-boat threat in the Mediterranean did not come until October 2, 1918 with the bombardment of Durazzo. This thesis discusses the development of Entente anti-submarine capabilities and illustrate how America's contribution led to success. a detailed analysis of the rarely discussed bombardment of Durazzo is included using archival documents.
Date: May 2012
Creator: Vaughan, Evan Michael
System: The UNT Digital Library
A Driver, Vehicle and Road Safety System Using Smartphones (open access)

A Driver, Vehicle and Road Safety System Using Smartphones

As vehicle manufacturers continue to increase their emphasis on safety with advanced driver assistance systems (ADAS), I propose a ubiquitous device that is able to analyze and advise on safety conditions. Mobile smartphones are increasing in popularity among younger generations with an estimated 64% of 25-34 year olds already using one in their daily lives. with over 10 million car accidents reported in the United States each year, car manufacturers have shifted their focus of a passive approach (airbags) to more active by adding features associated with ADAS (lane departure warnings). However, vehicles manufactured with these sensors are not economically priced while older vehicles might only have passive safety features. Given its accessibility and portability, I target a mobile smartphone as a device to compliment ADAS that can bring a driver assist to any vehicle without regards for any on-vehicle communication system requirements. I use the 3-axis accelerometer of multiple Android based smartphone to record and analyze various safety factors which can influence a driver while operating a vehicle. These influences with respect to the driver, vehicle and road are lane change maneuvers, vehicular comfort and road conditions. Each factor could potentially be hazardous to the health of the driver, …
Date: May 2012
Creator: Gozick, Brandon
System: The UNT Digital Library
Ecological Significance and Underlying Mechanisms of Body Size Differentiation in White-tailed Deer (open access)

Ecological Significance and Underlying Mechanisms of Body Size Differentiation in White-tailed Deer

Body size varies according to nutritional availability, which is of ecological and evolutionary relevance. The purpose of this study is to test the hypothesis that differences in adult body size are realized by increasing juvenile growth rate for white-tailed deer (Odocoileus virginianus). Harvest records are used to construct growth rate estimates by empirical nonlinear curve fitting. Results are compared to those of previous models that include additional parameters. The rate of growth increases during the study period. Models that estimate multiple parameters may not work with harvest data in which estimates of these parameters are prone to error, which renders estimates from complex models too variable to detect inter-annual changes in growth rate that this simpler model captures
Date: May 2012
Creator: Barr, Brannon
System: The UNT Digital Library
Effect of Resistance Training on Cytokines in Hiv+ Men with Chemical Dependence (open access)

Effect of Resistance Training on Cytokines in Hiv+ Men with Chemical Dependence

Human immunodeficiency virus (HIV) and substance abuse (drug and/or alcohol) independently impair the immune system; importantly, the combination of HIV infection and substance abuse might produce more than an additive effect on this system. Tumor necrosis factor-alpha (TNF-?) and Interferon gamma (IFN?) are pro-inflammatory cytokines involved in differentiation of Th0 cells into Th1 cells. Interleukin 4 (IL-4) and Interleukin 10 (IL-10) are anti-inflammatory cytokine involved in differentiation of Th0 cells to Th2 cells. Unbalanced Th1 and Th2 cells can lead to immune suppression. Thus, changes in these cytokines could have important implications for people infected with HIV (HIV+). Resistance training can counteract muscle wasting, improve strength, and improve muscle mass. The purpose of this study was to examine the effect of resistance training on resting concentrations of circulating TNF-?, IFN-?, IL-4, and IL-10. Sixteen men (42 ± 11 years, 180.4 ± 9.1 cm, 89.2 ± 20.7 kg) infected with HIV and enrolled in an intensive 60-day in-patient substance addiction/abuse treatment program were recruited shortly after admission to the treatment facility. Participants were assigned to one of two groups using randomization: supervised resistance exercise 3 times per week using a progressive and non-linear periodized program (Exercise) or no exercise training (Non-Exercise) …
Date: May 2012
Creator: Curtis, John Harper
System: The UNT Digital Library
Effects of Layer Double Hydroxide Nanoclays on the Toxicity of Copper to Daphnia Magna (open access)

Effects of Layer Double Hydroxide Nanoclays on the Toxicity of Copper to Daphnia Magna

Nanoparticles may affect secondary pollutants such as copper. Layer Double Hydroxides (LDH) are synthetically produced nanoparticles that adsorb copper via cation exchange. Pretreatment of copper test solutions with LDH nanoparticles followed by filtration removal of LDH nanoparticles demonstrated the smallest LDH aggregates removed the most copper toxicity. This was due to increased surface area for cation exchange relative to larger particle aggregates. Co-exposure tests of copper chloride and clay were run to determine if smaller clay particles increased copper uptake by D. magna. Coexposure treatments had lower LC50 values compared to the filtration tests, likely as a result of additive toxicity. LDH nanoclays do reduce copper toxicity in Daphnia magna and may serve as a remediation tool.
Date: May 2012
Creator: Blake, Deanne Renee
System: The UNT Digital Library
The Effects of Textual Fluency on the Rate of Acquisition and Application of Intraverbal Relations (open access)

The Effects of Textual Fluency on the Rate of Acquisition and Application of Intraverbal Relations

Intraverbal behavior governs core elements of academic and intellectual behavior. These intraverbal relations can be explicitly taught when an individual is prompted to provide an appropriate response with pictures, text, or other stimuli following a verbal stimulus. It is possible that a focus on fluency of the target repertoires may lead to more conclusive data. the current study assessed the effects of precision teaching based instruction for component textual repertoires on the acquisition of intraverbal relations. Specifically, this study compared the effectiveness of two textual prompting procedures (with and without fluency-based instruction) on the acquisition and application of intraverbal relations using time-delay and a carefully controlled set of intraverbal stimuli. Results indicate that the use of textual prompts and an errorless time-delay transfer of stimulus control procedure were effective strategies for teaching intraverbal responses regardless of the inclusion of fluency-based instruction.
Date: May 2012
Creator: Shrontz, Rachael E.
System: The UNT Digital Library
Electrochemical Depostion of Bismuth on Ruthenium and Ruthenium Oxide Surfaces (open access)

Electrochemical Depostion of Bismuth on Ruthenium and Ruthenium Oxide Surfaces

Cyclic voltammetry experiments were performed to compare the electrodeposition characteristics of bismuth on ruthenium. Two types of electrodes were used for comparison: a Ru shot electrode (polycrystalline) and a thin film of radio-frequency sputtered Ru on a Ti/Si(100) support. Experiments were performed in 1mM Bi(NO3)3/0.5M H2SO4 with switching potentials between -0.25 and 0.55V (vs. KCl sat. Ag/AgCl) and a 20mV/s scan rate. Grazing incidence x-ray diffraction (GIXRD) determined the freshly prepared thin film electrode was hexagonally close-packed. After thermally oxidizing at 600°C for 20 minutes, the thin film adopts the tetragonal structure consistent with RuO2. a hydrated oxide film (RuOx?(H2O)y) was made by holding 1.3V on the surface of the film in H2SO4 for 60 seconds and was determined to be amorphous. Underpotential deposition of Bi was observed on the metallic surfaces and the electrochemically oxidized surface; it was not observed on the thermal oxide.
Date: May 2012
Creator: Taylor, Daniel M.
System: The UNT Digital Library