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3D Reconstruction Using Lidar and Visual Images (open access)

3D Reconstruction Using Lidar and Visual Images

In this research, multi-perspective image registration using LiDAR and visual images was considered. 2D-3D image registration is a difficult task because it requires the extraction of different semantic features from each modality. This problem is solved in three parts. The first step involves detection and extraction of common features from each of the data sets. The second step consists of associating the common features between two different modalities. Traditional methods use lines or orthogonal corners as common features. The third step consists of building the projection matrix. Many existing methods use global positing system (GPS) or inertial navigation system (INS) for an initial estimate of the camera pose. However, the approach discussed herein does not use GPS, INS, or any such devices for initial estimate; hence the model can be used in places like the lunar surface or Mars where GPS or INS are not available. A variation of the method is also described, which does not require strong features from both images but rather uses intensity gradients in the image. This can be useful when one image does not have strong features (such as lines) or there are too many extraneous features.
Date: December 2012
Creator: Duraisamy, Prakash
System: The UNT Digital Library
American Blitzkrieg: Courtney Hodges and the Advance Toward Aachen (August 1 - September 12, 1944) (open access)

American Blitzkrieg: Courtney Hodges and the Advance Toward Aachen (August 1 - September 12, 1944)

This is an analysis of combat operations of US First Army under the command of Courtney Hodges, between August 1 and September 12, 1944, with an emphasis upon 1st, 4th, 9th, and 30th Divisions. However, other formations are necessarily discussed in order to maintain context. Indeed, many historians have failed to emphasize the complex interdependent nature of these efforts, and the traditional narrative has been distorted by inadequate situational awareness. This study argues that the army's operations were exceedingly difficult, resulting in approximately 40,000 casualties over a six week period. Although historians claim that the Germans were essentially defeated by the end of July, and that the Allied advance was subsequently halted by logistical difficulties, the official combat records clarify that logistical shortages were a tertiary factor, as the enemy remained capable of strong resistance. Consequently, defensive efforts were the primary factor hindering the advance, in conjunction with deteriorating weather conditions, rugged terrain, and surprisingly severe traffic congestion. Although this was mobile warfare, military theorists have overestimated the effectiveness of mechanization and underestimated the potential for antitank defenses. Ultimately, this study asserts that First Army was the primary American combat formation, and historians have exaggerated the importance of George Patton's …
Date: December 2012
Creator: Rinkleff, Adam J.
System: The UNT Digital Library
Aphorismen, Capriccio, and Heptameron for Piano Solo By Jürg Baur: a Performer's Guide (open access)

Aphorismen, Capriccio, and Heptameron for Piano Solo By Jürg Baur: a Performer's Guide

The purpose of this dissertation is to give instruction regarding the performance of three important piano works by Jürg Baur (1918-2010). Aphorismen, Capriccio, and Heptameron stand out as his most significant piano works both because of their length and because of their pianistic complexity. Since Baur had a successful career as both teacher and composer during his lifetime, his acclaimed works received many honors in Germany. His works can be performed by intermediate to advanced students. Intermediate students can easily offer simpler pieces like Aphorismen in competitions, while pieces like Capriccio and Heptameron better are suited to a more advanced level. Although some of his compositions are difficult to perform compared with other modern German works, Baur's music is more accessible. In the article, "Auf der Spuren der alten Zeit" Baur is quoted to state that Paul Hindemith and Bela Bartok's music influenced his own compositional ideas. However, although Baur is a modern composer, he didn't write in a totally atonal style, but rather attempted to broaden tonality. While Heptameron is atonal, Aphorismen and Capriccio give the impression of tonality, thus they are more accessible to the audience. I was fortunate enough to study Aphorismen with Baur as well as …
Date: December 2012
Creator: Park, Esther
System: The UNT Digital Library
Behavioral Aspects of Latino Familialism: a Three Study Analysis (open access)

Behavioral Aspects of Latino Familialism: a Three Study Analysis

The existing research on Latino familialism draws a distinction between the attitudes associated with familialism and familialism-based action. Because attitudes tend to be more stable when considering variables such as immigration generation status, etc., social science researchers tend to employ measures based on attitudinal aspects of familialism, rather than action or behavior. Because of this preference, there is a lack of studies that examine familialism-based action and behaviors. This dissertation consists of three unique studies that examine actions and behaviors associated with familialism, while taking into account the methodological concerns expressed by previous researchers. The first study uses nationally representative U.S. data to compare the differences in the frequency of contact with various family members, among black non-Hispanics, Hispanics, and white non-Hispanics. The central finding of this study is that Hispanics maintain more frequent contact with family than white non-Hispanics, but there is no difference between Hispanics and black non-Hispanics, with the exception of contact with fathers. The second study, which employs qualitative data collected from a metropolitan area in the Southwest U.S., examines the locus of educational aspirations and expectations among a sample of Hispanics and white non-Hispanics. Among other things, this study finds that Hispanic females were more …
Date: December 2012
Creator: Comeau, Joseph Adrien
System: The UNT Digital Library
British Labour Government Policy in Iraq, 1945-1950 (open access)

British Labour Government Policy in Iraq, 1945-1950

Britain during the Labour government's administration took a major step toward developing Iraq primarily due to the decision of Ernest Bevin, the Foreign Minister, to start a new British policy toward the Iraqi regimes that would increase the British influence in the area. This led to Bevin's strategy of depending on guiding the Iraqi regime to make economic and political reforms that would lead to social justice.
Date: December 2012
Creator: Alburaas, Theyab
System: The UNT Digital Library
Broad-band Light Emission From Ion Implanted Silicon Nanocrystals Via Plasmonic and Non-plasmonic Effects for Optoelectronics (open access)

Broad-band Light Emission From Ion Implanted Silicon Nanocrystals Via Plasmonic and Non-plasmonic Effects for Optoelectronics

Broad band light emission ranging from the ultraviolet (UV) to the near infrared (NIR) has been observed from silicon nanoparticles fabricated using low energy (30-45 keV) metal and non-metal ion implantation with a fluence of 5*1015 ions/cm2 in crystalline Si(100). It is found from a systematic study of the annealing carried out at certain temperatures that the spectral characteristics remains unchanged except for the enhancement of light emission intensity due to annealing. The annealing results in nucleation of metal nanoclusters in the vicinity of Si nanoparticles which enhances the emission intensity. Structural and optical characterization demonstrate that the emission originates from both highly localized defect bound excitons at the Si/Sio2 interface, as well as surface and interface traps associated with the increased surface area of the Si nanocrystals. The emission in the UV is due to interband transitions from localized excitonic states at the interface of Si/SiO2 or from the surface of Si nanocrystals. The radiative efficiency of the UV emission from the Si nanoparticles can be modified by the localized surface plasmon (LSP) interaction induced by the nucleation of silver nanoparticles with controlled annealing of the samples. The UV emission from Si nanoclusters are coupled resonantly to the LSP …
Date: December 2012
Creator: Singh, Akhilesh K.
System: The UNT Digital Library
A Collective Case Study of Veterans Inside an Arts and Crafts Room and Their Perceptions Regarding Empowerment (open access)

A Collective Case Study of Veterans Inside an Arts and Crafts Room and Their Perceptions Regarding Empowerment

This dissertation is "A Collective Case Study of Veterans Inside an Arts and Crafts Room and Their Perceptions Regarding Empowerment." This research examined to what degree art making, and in what ways a community of learning contributed to veterans' self-worth and empowerment through their creative activities and interactions inside an arts and crafts room at the VA hospital in Dallas, Texas. Furthermore, an essential reason for this study is to examine veterans in the arts and crafts environment to explore whether their experiences were important, meaningful, and empowering, and especially important in this regard are the interactions among veterans. Empowerment in this context is defined as gaining self-esteem and motivation within oneself. This includes becoming more confident and positive, as well as gaining the ability to learn about one's own identity. It also described how the interactions between the participants are shaped by the social contexts within which they come together. Using post-modern feminist theory, narrative inquiry and care theory, this dissertation describes the ways that the processes and products of creative activity bring empowerment through dialogue and personal stories while using the component of caring during teaching and learning.
Date: December 2012
Creator: Hasio, Cindy Lee
System: The UNT Digital Library
The Creation of a Performance Edition of Gustav Mahler's Lieder Und Gesänge Aus Der Jungendzeit and Its Role in Bass Tuba Pedagogy (open access)

The Creation of a Performance Edition of Gustav Mahler's Lieder Und Gesänge Aus Der Jungendzeit and Its Role in Bass Tuba Pedagogy

When the tubist is first introduced to the bass tuba, Mahler's songs can be used as effective solo material. Through transcription, practice, and performance of art songs, novice bass tubists focus primarily on fundamental musical components such as tone quality, intonation, breathing, and musicianship. By identifying deficiencies in the current solo repertoire as related to the early stages of development on the bass tuba, I intend to address the need for more solo works through the transcription and performance of Mahler's Lieder und Gesänge aus der Jugendzeit.
Date: December 2012
Creator: Baker, Jeffrey T.
System: The UNT Digital Library
A Descriptive Law and Policy Analysis of Corporal Punishment in Florida Public School Districts (open access)

A Descriptive Law and Policy Analysis of Corporal Punishment in Florida Public School Districts

Corporal punishment is banned by state statute in 31 of the 50 U.S states. The 19 states that still allow the practice are largely located in the South and the Rocky Mountain West. However, data indicate that the practice of corporal punishment is still largely a Southern phenomenon. In the 19 states that allow the practice to continue in schools, many have seen the use of the disciplinary technique decline. Existing research documents the negative effects and very little research supports any positive benefits of corporal punishment. This study analyzes school board policies from the 67 public school districts in the state of Florida to determine if trends in policies and incidents of corporal punishment are similar Texas and North Carolina. Research on Texas and North Carolina indicate corporal punishment is used more frequently in districts with smaller enrollments, and in more rural areas. Data from this study suggests that the decrease in the number of incidents of corporal punishment as well as the concentration of the practice among school districts in Florida school follows the same trends of declining use that exist in Texas and North Carolina public schools. Findings illustrate a need for continued research of corporal punishment …
Date: December 2012
Creator: Goodson, Christopher B.
System: The UNT Digital Library
Developing Culturally Responsive Literacy Teachers: Analysis of Academic, Demographic, and Experiential Factors Related to Teacher Self-efficacy (open access)

Developing Culturally Responsive Literacy Teachers: Analysis of Academic, Demographic, and Experiential Factors Related to Teacher Self-efficacy

This mixed-methods study examined teachers' culturally responsive teaching (CRT) self-efficacy beliefs and the relationships among selected academic, demographic, and experiential factors. Guided by theoretical and empirical research on CRT, teacher dispositions, and assessment in teacher education (TE) programs for culturally and linguistically diverse (CLD) students, this study utilized an extended version of Siwatu's 2007 Culturally Responsive Teaching Self-Efficacy (CRTSE) Scale to conduct correlational and comparative statistical analyses. Data sources included surveys from 265 participants enrolled in TE classes in the spring 2012 in Texas (one private and one public university). Content analyses were also conducted on participants' descriptions of CRT activities using a priori and inductive coding methods to triangulate and elaborate the explanation of quantitative results. In this population, those with higher CRTSE were typically young (undergraduates), specializing in ESL and bilingual certification coursework, who felt their TE program prepared them well for working with CLD student populations. Regression analyses showed that certain certification areas (ESL, bilingual, elementary, and advanced) and perceptions of better quality in TE program preparation for working with CLD students emerged as significant predictors of increased CRTSE. Those with second language skills were more efficacious in delivering linguistically-responsive instruction, and those professing more experiences with …
Date: December 2012
Creator: Sarker, Amie
System: The UNT Digital Library
Development of a Laponite Pluronic Composite for Foaming Applications (open access)

Development of a Laponite Pluronic Composite for Foaming Applications

The focus of the following research was to provide an optimized particle stabilized foam of Laponite and Pluronic L62 in water by understanding (1) the Laponite-Pluronic interactions and properties for improved performance in a particle stabilized foam and (2) the interfacial properties between air and the Laponite-Pluronic complex. These studies were conducted using both bulk and interfacial rheology, XRD, sessile droplet, TGA and UV-vis. Two novel and simple techniques, lamella break point and capillary breakup extensional rheometry, were used to both understand the Laponite Pluronic L62 interaction and determine a different mechanism for foaming properties. Bulk rheological properties identified an optimal Laponite concentration of 2% with Pluronic L62 ranging from 2.5% and 6.5%, due to the ease of flow for the dispersion. The Pluronic L62 was observed to enhance the Laponite bulk rheological properties in solution. Additionally TGA showed a similar trend in thermal resistance to water with both addition of Laponite and Pluronic L62. XRD demonstrated that 0.25% Pluronic intercalated into Laponite from dried 2% Laponite films. XRD demonstrated that the Laponite matrix was saturated at 1% Pluronic L62. UV-vis demonstrated that a monolayer of Pluronic L62 is observed up to 0.65% Pluronic L62 onto Laponite. Interfacial rheology showed …
Date: December 2012
Creator: Davis, James William
System: The UNT Digital Library
The Development of Algebraic Reasoning in Undergraduate Elementary Preservice Teachers (open access)

The Development of Algebraic Reasoning in Undergraduate Elementary Preservice Teachers

Although studies of teacher preparation programs have documented positive changes in mathematical knowledge for teaching with preservice teachers in mathematics content courses, this study focused on the impact of a mathematics methods course and follow-up student teaching assignment. The presumption was that preservice teachers would show growth in their mathematical knowledge during methods since the course was structured around active participation in mathematics, research-based pedagogy, and was concurrent with a two-day-per-week field experience in a local elementary school. Survey instruments utilized the computer adaptive test version of the Mathematical Knowledge for Teaching (MKT) measures from the Learning Mathematics for Teaching Project, and the Attitudes and Beliefs (towards mathematics) survey from the Mathematical Education of Elementary Teachers Project. A piecewise growth model analysis was conducted on data collected from 176 participants at 5 time-points (methods, 3 time-points; student teaching, 2 time-points) over a 9 month period. Although the participants' demographics were typical of U.S. undergraduate preservice teachers, findings suggest that initial low-level of mathematical knowledge, and a deep-rooted belief that there is only one way to solve mathematics problems, limited the impact of the methods and student teaching courses. The results from this study indicate that in (a) number sense, there …
Date: December 2012
Creator: Hayata, Carole Anne
System: The UNT Digital Library
Does Euroscepticism Matter? the Effect of Public Opinion on Integration (open access)

Does Euroscepticism Matter? the Effect of Public Opinion on Integration

This dissertation seeks to test the proposition that public opinion is a driving force in integration, and thus examines the effect of euroscepticism on EU integration. Utilizing an understanding of integration as the process of European states achieving similar legal, social, cultural, political and economic policy outcomes while ceding greater policy power to European institutions, the relationship between aggregate level euroscepticism in EU member states (the United Kingdom, Germany, Ireland, Greece, Spain, France, Italy, the Netherlands, Austria, and Sweden) and speed of compliance with EU policies is examined. More specifically, this dissertation examines the relationship between aggregate level euroscepticism in an EU member state, and the speed at which that state transposes EU directives. In testing this relationship a number of contextual conditions are examined, including the role of issue salience, domestic party systems, and electoral conditions. The findings of this dissertation suggest that the widely held belief that public opinion is driving European integration may be false.
Date: December 2012
Creator: Williams, Christopher J.
System: The UNT Digital Library
Educational Performance: Texas Open Enrollment Charter High Schools Compared to Traditional Public High Schools (open access)

Educational Performance: Texas Open Enrollment Charter High Schools Compared to Traditional Public High Schools

The study examined mathematics and English student achievement, attendance rates, dropout rates, and expenditures per pupil for Texas high school students in both open-enrollment charter schools and traditional public high schools for the 2009–2010 school year. All data were assembled using archived information found at the Texas Education Agency (TEA). This information included the TEA report entitled Texas Open Enrollment Charter Schools Evaluation; TEA Snapshot Yearly Report; and Academic Excellence Indicator System (AEIS) data files. Microsoft Excel (Version 2010) was used to randomly select traditional public high schools categorized as Title 1 and non-Title 1 for comparison with Title 1 and non-Title 1 open-enrollment charter high schools. The IBM Statistical Package for the Social Sciences (SPSS) (IBM Statistics Version 20) was used for a one-way analysis of variance (ANOVA) conducted between one independent variable (charter or traditional school) and five dependent variables (mathematics exit-level TAKS scores, English exit-level TAKS scores, attendance rates, dropout rates, and expenditures per pupil). Traditional public high school students had higher or better average mean values than charter schools for mathematics exit-level TAKS scores, English exit-level TAKS scores, attendance rates, dropout rates, and expenditures per pupil. The ANOVA found that four of the five dependent variables …
Date: December 2012
Creator: Jackson, Nokomis “Butch,” Jr.
System: The UNT Digital Library
Effects of a Self-care Intervention for Counselors on Compassion Fatigue and Compassion Satisfaction (open access)

Effects of a Self-care Intervention for Counselors on Compassion Fatigue and Compassion Satisfaction

This study investigated the impact of a psychoeducational and experiential structured counselor self-care curriculum, developed by Drs. Charles and Kathleen Figley, on compassion fatigue and the prevention of professional impairment as measured by the Professional Quality of Life (ProQOL), Version 5. Volunteer licensed professional counselors, supervisors, and interns from four children's advocacy centers in Texas were assigned to treatment group (n = 21; 20 females, 1 male; mean age 34.4 years) or waitlist control group (n = 21; 19 females, 2 males; mean age 34.6 years). Participating counselors identified themselves ethnically as 64% Caucasian, 26% Hispanic, 7% African-American, and 2% Native-American. Employing a quasi-experimental design, three reliability-corrected analysis of covariance (ANCOVA) were utilized to analyze the data with an alpha level of .05 to assess statistical significance and partial eta squared to assess effect size. With pre-test scores as the covariate, results revealed in the experimental group a statistically significant reduction with large treatment effect for burnout (p = .01; partial ?2 = .15), a statistically nonsignificant reduction with a medium effect for secondary traumatic stress (p = .18; partial ?2 = .05), and a statistically nonsignificant increase with a medium effect for compassion satisfaction (p = .06; partial ?2= …
Date: December 2012
Creator: Koehler, Christine Marie Guthrie
System: The UNT Digital Library
Effects of Peripheral Nerve Injury on the Cells of the Dorsal Root Ganglion: a Role for Primary Cilia (open access)

Effects of Peripheral Nerve Injury on the Cells of the Dorsal Root Ganglion: a Role for Primary Cilia

Primary cilia are ubiquitous sensory organelles found on most cell types including cells of the dorsal root ganglia (DRG). The DRG are groups of peripheral neurons that relay sensory information from the periphery to the CNS. Other cell types in the DRG include a type of glial cell, the satellite glial cells (SGCs). The SGCs surround the DRG neurons and, with the neurons, form functional sensory units. Currently are no reports describing the numbers of DRG cells that have cilia. We found that 26% of the SGCs had primary cilia. The incidence of cilia on neurons varied with neuron size, a property that roughly correlates with physiological characteristics. We found that 29% of the small, 16% of the medium and 5% of the large neurons had primary cilia. Primary cilia have been shown to have a role in cell proliferation in a variety of cell types. In some of the cells the cilia mediate the proliferative effects of Sonic hedgehog (Shh). In the CNS, Shh signaling through primary cilia affects proliferation during development as well as following injury, but no studies have looked at this function in the PNS. The SGCs and neurons of the DRG undergo complex changes following …
Date: December 2012
Creator: Smith, Sarah K.
System: The UNT Digital Library
Endogenous Information and Inter-state War Expansion (open access)

Endogenous Information and Inter-state War Expansion

Scholars have long debated the causes of late third party state joining in ongoing inter-state wars. This research has generally concluding that peace-time conditions, measured in terms of: third party capabilities; proximity to warring states; and inter-state alliances, are determining factors in the decision to join. However, these studies utilize theories derived from static pre-war measures of capabilities and motivation to explain late joining; indeed, the same measures that fail to predict participation at war's outset. Further, extant research has no explanation for why weak and non-proximate states every participate. Existing theory thus fails to provide a comprehensive explanation of joining behavior. This project contends that a resolution lies the interaction between pre-war conditions and intra-war events. Intra-war events that are allowed to vary on a per battle basis, including change in combat location and alliance entry and exit from combat, reveal new information about the war and its progress, thereby forcing third party states to recalculate their initial decision to abstain in relation to their pre-existing situation. Incorporation of intra-war processes helps to better explain decisions by third party states to join ongoing inter-state wars late in their development, and why states that frequently choose to abstain (e.g., weak …
Date: December 2012
Creator: Liebel, Steven R.
System: The UNT Digital Library
An Exploratory Study of the Comprehension, Retention and Action of the Denton County Older Population in Regards to Disaster Preparedness Education (open access)

An Exploratory Study of the Comprehension, Retention and Action of the Denton County Older Population in Regards to Disaster Preparedness Education

The purpose of this exploratory study was to operationalize the responses from a sample of the community dwelling older population from Denton County, Texas on disaster preparedness education given by Denton County Health Department (DCHD) personnel. The goals and objectives were drawn from the Texas Public Health and Medical Emergency Management 5-Year Strategic Plan 2012-2016. It was hypothesized that after the disaster preparedness education was received, then comprehension, retention, and application of the information would increase and the goals set forth by the DCHD would be reached. Thirteen sites were used to educate the 224 participants between August 2011 and April 2012. The data were received using a pre-test survey before the training, a post-test immediately after the training, and a follow-up survey call approximately 30 days later. Using Cronbach's alpha, logistic regression and regression analysis through SAS, the data revealed that all DCHD goals were met by this training method and outcome which include the sample population increasing comprehension, retention, and action on the information learned.
Date: December 2012
Creator: Knight, Rebekah P.
System: The UNT Digital Library
Fidget, Sway, and Swerve: Three Works Inspired By Movement From the Intricate Maneuvers Series (open access)

Fidget, Sway, and Swerve: Three Works Inspired By Movement From the Intricate Maneuvers Series

Intricate Maneuvers is a series of musical works that were composed using movement as a model for compositional processes and forms. This essay presents in-depth analyses of three works from the series; Fidget, Sway: The Mildest Form of Falling, and Swerve for Chamber Ensemble. The analysis of each work highlights correlations between the musical characteristics of that work and the temporal, spatial, contextual, and psychological implications of the motion after which it was modeled. The third chapter also demonstrates the ways in which the creation of Sway was influenced by materials and processes taken from Ruth Crawford's String Quartet 1931. In order to investigate the question of how life experiences can function as models for compositional processes, the essay examines precedents for the compositional modeling of extra-musical ideas and images in the works of Bed?ich Smetana, Elliott Carter and Roger Reynolds. It also discusses approaches to modeling movement in music created for dance. Throughout the Intricate Maneuvers series, movement is modeled not merely to create an association between a musical work and a particular movement pattern, but rather to infuse the compositions with the dynamism that defines a particular kinetic experience.
Date: December 2012
Creator: Summar, Sarah Page
System: The UNT Digital Library
The Fifth Humor: Ink, Texts, and the Early Modern Body (open access)

The Fifth Humor: Ink, Texts, and the Early Modern Body

This dissertation tracks the intimate relationship between writing and the body to add new dimensions to humoral criticism and textual studies of Renaissance literature. Most humor theory focuses on the volatile, permeable nature of the body, and its vulnerability to environmental stimuli, neglecting the important role that written texts play in this economy of fluids. I apply the principles of humor theory to the study of handwritten and printed texts. This approach demonstrates that the textual economy of the period—reading, writing, publishing, exchanging letters, performing all of the above on stage—mirrors the economy of fluids that governed the humoral body. Early modern readers and writers could imagine textual activities not only as cerebral, abstract concepts, but also as sexual activities, as processes of ingestion and regurgitation. My study of ink combines humoral, historical materialist, and ecocritical modes of study. Materialist critics have examined the quill, paper, and printing press as metaphors for the body; however, the ink within them remains unexamined. This dissertation infuses the figurative body of the press with circulating passions, and brings to bear the natural, biochemical properties that ink lends to the texts it creates. Considering the influence of written and printed materials on the body …
Date: December 2012
Creator: Polster, Kristen Kayem
System: The UNT Digital Library
Group 10 Catalyzed Olefin Hydroarylation (open access)

Group 10 Catalyzed Olefin Hydroarylation

Alkyl-arenes are important industry feedstock chemicals that are used as solvents, pharmaceutical precursors, and polymer monomer units. One alkyl-arene, ethylbenzene, is the main focus of this dissertation, and is produced in the million ton a year scale. As alkyl-arenes are important commodity chemicals, catalytic olefin hydroarylation is a lucrative alternative for their production rather than Friedel-Crafts alkylation or various coupling reactions that have lower atom economy, require strong acids, or are energetically demanding. Currently catalytic olefin hydroarylation still suffers from decomposition pathways of the active catalytic complexes, side reactions that lead to waste products, and unfavorable activation barriers, which represent high temperature and pressure. Modifications to the catalytically active system bipyridine platinum(II) (bpyPtII), through computational methods, are explored herein. The work presented here investigates catalytic olefin hydroarylation in order to mitigate the aforementioned difficulties. Included in this study are changes to the electronic profile of the supporting ligand, bpy, through the addition of electron withdrawing or electron donating R groups (methoxy, nitro), definite ligand replacements such as bpy to hydridotris(pyrazolyl)borate (Tp), changes in metal oxidation (II to IV), and replacing the metal center from Pt to Ni. Nickel was selected as a possible alternative to platinum as it is more …
Date: December 2012
Creator: Gonzalez, Hector Emanuel
System: The UNT Digital Library
Identity of African American Characters in Newbery Medal and Newbery Honor Award Winning Books: a Critical Content Analysis of Books From 1991 to 2011 (open access)

Identity of African American Characters in Newbery Medal and Newbery Honor Award Winning Books: a Critical Content Analysis of Books From 1991 to 2011

The purpose of this study was to conduct a critical content analysis of the African American characters found in Newbery Medal award winning books recognized between the years of 1991 and 2011. The John Newbery Medal is a highly regarded award in the United States for children's literature and esteemed worldwide. Children's and adolescents' books receive this coveted award for the quality of their writing. Though these books are recognized for their quality writing, there is no guideline in the award criteria that evaluated the race and identity of the characters. Hence, there are two overarching research questions that guided this study. The first question asked: To what extent are the African American characters in each award winning book represented? Foci in answering this question were the frequency of African American characters and the development of their ethnic identities. The second question asked: How are the African American characters' intergroup attitudes and interactions represented? Foci in answering this question examined the frequency of intergroup interactions and the characters' attitudes within the context of each book. The theoretical framework that undergirded this study is critical literacy, which encourages adults and youth to examine issues of diversity and social justice through their …
Date: December 2012
Creator: Morton, Tami Butler
System: The UNT Digital Library
Impact of Video Presentation Features on Instructional Achievement and Intrinsic Motivation in Secondary School Learners (open access)

Impact of Video Presentation Features on Instructional Achievement and Intrinsic Motivation in Secondary School Learners

This study analyzed instructional achievement and intrinsic motivation among 21st century secondary students utilizing a video lecture incorporating both student reaction cutaway images and immediate content interaction within the lecture. Respondents (n = 155) were from multiple classes and grade levels at a suburban Texas high school. Four groups of students viewed the identical lecture with differing video and content interaction treatments. Students responded to a pretest/posttest survey to assess academic achievement in addition to an intrinsic motivation instrument to assess student interest. Group one (the control group) viewed the 12 minute lecture without enhancement. A second group viewed the identical lecture with student reaction shots inserted in the video. Another group viewed the lecture with content question intervention inserted into the video. The final group saw the lecture with the student reaction shots and content question intervention combined in the video. A repeated measures multivariate analysis of variance (MANOVA) was used to compare results from a 14 item pretest/posttest. Combined, the groups showed no significance (p = .069) indicating no associations were identified by the experiment. Although no association was identified, this may be a reflection of the generic nature of the video lecture and the lack of association …
Date: December 2012
Creator: Bland, Ronald B.
System: The UNT Digital Library
Impacts of Postmodernity Factors on the Association Between Maternal Distress and Children's Delinquency Among Low-income Families (open access)

Impacts of Postmodernity Factors on the Association Between Maternal Distress and Children's Delinquency Among Low-income Families

This study investigates the effects of postmodern factors on the relationship between maternal distress and children's delinquency. It seeks to understand the factors associated with distress levels of mothers whose children exhibit delinquency in order to potentially decrease the cost associated with mental health problems especially in mothers. Another goal of this study is to contribute to the sociological analysis of mental health problems which seem to be the reserved domain of the discipline of psychology and related subfields. The data came from the third wave of the 3-city study with N = 1835. The ages of the children range from 5 to 18 years old. The analysis of the data using regression analysis suggests children's delinquency significantly affects maternal distress in mothers. The study also indicates postmodernity factors did not moderate the association between maternal distress and children's delinquency. However, postmodern factors have significant, separate, and direct effects on maternal distress. For example, employment and religion have positive influences on maternal distress. The research points toward weakness in the postmodern perspective. It also underlines the importance of a sociological approach to the assessment and treatment of distress problems among mothers with low-income. Agencies working with low-income families should integrate …
Date: December 2012
Creator: Bessa, Yawo
System: The UNT Digital Library