Understanding the thermodynamic properties of multicomponent mixtures is of critical importance in many chemical and industrial applications. Experimental measurements become progressively difficult as the number of solution components increases -- producing the need for predictive models. Problems in development of predictive models arise if the mixture has one or more components that interact through molecular complexation or association. Experimental solubilities of anthracene and pyrene dissolved in binary systems containing one or more alcohols were measured in order to address this problem. Alcohols examined in this study were: 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-1-propanol, 3-methyl-1-butanol, and 1-octanol. In binary solvent mixtures containing only a single self-associating alcoholic solvent, the alkane cosolvents studied were: n-hexane, n-heptane, n-octane, 2,2,4-trimethylpentane, cyclohexane, methylcyclohexane, tert-butylcyclohexane. Predictive solubility equations were developed using mobile order theory. This approach differs from classical solution models by representing hydrogen bonding with a probability term rather than with expressions derived from stepwise equilibria or expressions to represent hypothetical solution aggregates. Results were compared with the predicted solubilities found from using expressions developed using the Kretschmer-Wiebe and Mecke-Kempter approaches for modeling associated solutions. It was found that the mobile order approach provided reasonably accurate predictions for the solute solubilities in the systems studied. The …

The focus of this study was three fold. First, modeling and feedback were investigated as a training package for social interactions between siblings. Second, the effects of social phrases taught to the sibling with autism were investigated. Third, the magnitude of these social phrases was measured by timing duration of parallel play. The experimental design is an A-B-A1-A2 design conducted in a clinic, with a probe for generalization in the home environment. This intervention was replicated across an additional sibling dyad to indicate its effectiveness. This study ascertained that the sibling with autism was a viable participant in learning new social skills that could function as a behavioral cusp and increase sibling interactions.

Minoru Miki's first two marimba compositions, Time for Marimba (1968) and Concerto for Marimba and Orchestra (1969) were composed at a revolutionary time-period for the marimba. Due to unique and innovative compositional techniques, Miki helped establish the marimba as a true concert instrument capable of performing music of the highest quality. As a pioneer in composing for marimba literature, Miki was able to capture the true essence of the marimba; a timeless quality that has helped Time for Marimba remain a part of the standard solo repertoire for the past forty years. The purpose of this study is to analyze and compare Minoru Miki's compositions, Time for Marimba and Concerto for Marimba and Orchestra. Composed within a year of each other, these works possess similar compositional techniques, and rhythmic and thematic relationships. This thesis includes a formal analysis and detailed comparisons of compositional techniques used in both works. Performance considerations, a brief biographical sketch of Miki and historical significance of Time for Marimba and Concerto for Marimba and Orchestra are also included.

Online/offline signature schemes are useful in many situations, and two such scenarios are considered in this dissertation: bursty server authentication and embedded device authentication. In this dissertation, new techniques for online/offline signing are introduced, those are applied in a variety of ways for creating online/offline signature schemes, and five different online/offline signature schemes that are proved secure under a variety of models and assumptions are proposed. Two of the proposed five schemes have the best offline or best online performance of any currently known technique, and are particularly well-suited for the scenarios that are considered in this dissertation. To determine if the proposed schemes provide the expected practical improvements, a series of experiments were conducted comparing the proposed schemes with each other and with other state-of-the-art schemes in this area, both on a desktop class computer, and under AVR Studio, a simulation platform for an 8-bit processor that is popular for embedded systems. Under AVR Studio, the proposed SGE scheme using a typical key size for the embedded device authentication scenario, can complete the offline phase in about 24 seconds and then produce a signature (the online phase) in 15 milliseconds, which is the best offline performance of any known …

This study analyzes students' use of the French second-person pronouns tu (T) and vous (V) in small-group (2-3 students) inter-learner online chat sessions. The influence of internal linguistic factors (i.e., turn type and morphosyntactic environment) on learners' appropriate vs. inappropriate use of these pronouns is considered. The study also investigates the influence of Instructional Level on tu-vous use and the extent to which students from different instructional levels provide various types of peer assistance (e.g., lexical, morphosyntactic, and sociolinguistic/pragmatic) . Pronoun use was extremely unstable for learners of all levels, and a Kruskal-Wallis analysis revealed that Instructional Level did not significantly affect appropriate T/V use overall. Instructional Level and Syntax did, however, significantly affect interrogative T/V use, as shown through multivariate analyses. Peer-assisted performance was limited to lexical retrieval. Pedagogical recommendations are presented for teaching and learning second-person pronouns in French.

Aluminum was deposited onto both Teflon AF and Parylene AF surfaces by chemical vapor deposition of trimethylaluminum. This work shows that similar thin film (100 Angstroms) aluminum oxide adlayers form on both polymers at the low temperature dosing conditions used in the studies. Upon anneal to room temperature and above, defluorination of the polymer surfaces increased and resulted in fluorinated aluminum oxide adlayers; the adlayers were thermally stable to the highest temperatures tested (600 K). Angle-resolved spectra showed higher levels of fluorination toward the polymer/adlayer interface region. Copper films were also deposited at low temperature onto Teflon AF using a copper hexafluoroacetylacetonate-cyclooctadiene precursor. Annealing up to 600 K resulted in the loss of precursor ligands and a shift to metallic copper. As with aluminum adlayers, some polymer defluorination and resulting metal (copper) fluoride was detected. Parylene AF and polystyrene films surfaces were modified by directly dosing with water vapor passed across a hot tungsten filament. Oxygen incorporation into polystyrene occurred exclusively at aromatic carbon sites, whereas oxygen incorporation into parylene occurred in both aromatic and aliphatic sites. Oxygen x-ray photoelectron spectra of the modified polymers were comparable, indicating that similar reactions occurred. The surface oxygenation of parylene allowed enhanced reactivity …

Traditionally, juvenile sex offenders have been ignored in the literature. More recently the research has expanded particularly in the area of assessment and treatment. This study focused on the assessment of sexual arousal to deviant stimuli using the penile plethysmography (PPG) since it likely plays a significant role in juvenile sex offending behaviors. The goal of this study assessed its validity and reliability using Becker et al.'s set of PPG scenarios with a population of juvenile sex offenders. Significant differences were found between groups of (a) admitters versus partial admitters and (b) offenders with and without male victims. This study also examined the latent structure of the PPG results and found three dimensions: arousal to male stimuli, arousal to females and paraphilias, and arousal to non-sexual acts. These findings provide important implications for assessment of juvenile sex offenders and add to the clinical utility of PPG assessments.

This study aimed to test the effectiveness of classroom translations of some laboratory procedures for teaching simple auditory discriminations to learners with developmental disabilities. Three participants with autism and mental retardation were trained to make topographically distinct responses in the presence of two different stimuli, either a pure tone and silence, or two tones. A portable electronic piano keyboard was used to produce tones. Delayed prompt and differential reinforcement procedures were used to teach the responses. None of the participants performed the discriminations accurately without prompting despite numerous revisions to the procedures.

Consisting of both theoretical and empirical inquires, this study examines the primary functions of narrative and the relationship between narrative and mental imagery. The study proposes a new framework to interpret semiotic resources. Combining this with the linguistic functional theory of Halliday (1978), a functional method to empirically investigate semiotic representations was also developed. In the empirical inquiry, the study developed a latent construct method to empirically test the effects of narrative in a real learning situation. This study is the first to investigate the functional relationship between narrative and mental imagery, and among the first to suggest a theory and empirically investigate representations of a multimodal nature. The study is also among the first to use latent constructs to investigate the learning experience in a real educational setting. Data were collected from 190 library professionals who enrolled in three sections (two in narrative and one in plain text) of an online course administered through Vista 4.0 and who completed the course and responded to several instruments. Essay data (n = 82 x 2) were analyzed using content analysis based on the narrative analysis framework developed. Quantitative data analysis methods include univariate data analysis, factor analysis, and structural equation modeling …

As a museum educator who embraces social education and reflects on the postmodern condition, I found working within a traditional museum context to present challenges. As a result, I conducted an action research project focusing on ways to improve my own practice and affect change based on my engagement with visual culture discourse and the docents I teach. Having chosen action research, I implemented various teaching approaches and collected data over the course of several months. These data collection methods included interviews, museum documents, observational notes, recorded teaching practice, and daily journal entries. Narrative analysis was then used to interpret the collected data, specifically focusing how participants, including myself, make sense out of our experiences and how we value them.

In the current study, I examined the general sociocultural model of eating disorders that suggests that sociocultural pressures leads to internalization, which in turn leads to body dissatisfaction and ultimately disordered eating. Because I am testing this model with a sample of African American women, I also am including acculturation as a variable of interest. Specifically, I hypothesized that (a) the experience of more societal pressure to be thin will be related to greater internalization, (b) higher levels of acculturation will be related to greater internalization, (c) internalization of the thin ideal will be directly and positively related to body image concern, and (d) body image concern will be associated with higher levels of disordered eating. It was determined that there is a direct, negative relationship between Level of Identification with Culture of Origin and Internalization. Perceived Pressure was directly and positively related to both Internalization and Body Image Concerns. Body Concerns and Internalization were both directly and positively related to Disordered Eating. These findings suggest that although many of the same constructs related to disordered eating in other ethnic groups are also related to disordered eating among African American women, the relationships between the factors differs across racial/ethnic groups. …

The purpose of this thesis is to establish what specific forces influence whether or not a democratic setback within one nation will diffuse to peripheral states. Past studies devoted to this topic have largely suggested that diffusion essentially functions like a contagious disease, where the likelihood of "infection" is primarily based upon the level of interaction between states. This thesis however proposes that the interaction of the signal generated from a democratic state's collapse and the receptiveness of neighboring nations to this signal ultimately determines when and where diffusion will occur. In order to test the validity of this thesis' claims, the level of democracy within the neighboring states of all failed democratic governments spanning the years 1842-2002 are examined during the first years following such system breakdowns within a large-N quantitative research design. Ultimately this study leads to the conclusion that the interaction of signals and receptivity play a major role in the diffusion of democratic setbacks.

Pigeons worked in a titrating delay match-to-sample (TDMTS) procedure in which selecting the correct comparison stimulus increased the delay between sample offset and comparison-array onset and incorrect comparison selections decreased that delay. Prior research in our lab has shown that the stable adjusted value of the retention interval is a curvilinear function of the observing response requirement. The current study examined the effect of the distribution and predictability of observing response requirements on adjusted retention interval values. The data show that unpredictable observing response requirements were more effective in attenuating the deleterious effects of delay on matching accuracy. The data have implications for our understanding of attending and encoding in performances involving remembering over short temporal durations.

The purpose of this study is to explore the representation of national political freedom on web interface design by using power distance, one of the culture dimensions identified by Geert Hofstede, as a measurement. This study also aims to determine if there are any differences between government-based websites and business-oriented websites in representing national political freedom. A pilot study was conducted to validate ten power distance indicators identified from previous research on cultural dimensions with the intent of establishing a measurement for determining a country's national political freedom on web content and interface design. The result showed that six out of ten proposed indicators are valid power distance indicators. The seventh indicator, symmetric layout, demonstrated that its Web representation correlates with national political freedom level. Consequently, the principal research applied these seven indicators in coding 312 websites selected from 39 countries and analyzed national political freedom represented on these websites with content analysis method. The result of two-way analysis of variance (ANOVA) indicated that large differences exist in web interface design, which in turn reflects the aforementioned national political freedom. The research showed that the mean effect of freedom level between free-country group, partly-free-country group and not-free-country group was statistically …

The novel instrumentation of nanomanipulation coupled to nanospray mass spectrometry and its applications are presented. The nanomanipulator has the resolution of 10nm step sizes allowing for specific fine movement used to probe and characterize objects of interest. Nanospray mass spectrometry only needs a minimum sample volume of 300nl and a minimum sample size of 300attograms to analyze an analyte making it the ideal instrument to couple to nanomanipulation. The nanomanipulator is mounted to an inverted microscope and consists of 4 nano-positioners; these nano-positioners hold end-effectors and other tools used for manipulation. This original coupling has been used to enhance the current abilities of cellular probing and trace fiber analysis. Experiments have been performed to demonstrate the functionality of this instrument and its capabilities. Histidine and caffeine have been sampled directly from single fibers and analyzed. Lipid bodies from cotton seeds have been sampled indirectly and analyzed. The few applications demonstrated are only the beginning of nanomanipulation coupled to nanospray mass spectrometry and the possible applications are numerous especially with the ability to design and fabricate new end-effectors with unique abilities. Future study will be done to further the applications in direct cellular probing including toxicology studies and organelle analysis of …

The sample used for evaporative cooling system is Fabric defender 750 with Shelltite finish. From the experimental data and equations we have diffusion coefficient of 20.9 ± 3.71 x 10-6 m2/s for fabric with one layer with 17%-20% fluctuations from the theory, 27.8 ± 4.5 x 10-6 m2/s for fabric with two layers with 6%-14% fluctuations from the theory and 24.9 ± 4.1 x 10-6 m2/s for fabric with three layers with 13%-16% fluctuations from the theory. Since the thickness of the fabric increases so the mass transport rate decreases so the mass transport resistance should be increases. The intrinsic mass resistances of Fabri-1L, Fabri-2L and Fabri-3L are respectively 104 ± 10.2 s/m, 154 ± 23 s/m and 206 ± 26 s/m from the experiment.

Frederick Fox's contributions to contemporary music are substantial, including eighty-three compositions written between 1966 and 1998. These include pieces for orchestra, wind ensemble, choir, solo instruments, and a variety of chamber ensembles. This study serves as a complete annotated bibliography of Frederick Fox's eight compositions which feature the saxophone in a prominent role, all of which were written between 1979 and 1998. They include a piece for unaccompanied solo alto saxophone, Hear Again in Memory (1991), two works for alto saxophone and piano, Annexus (1980), and When the Thunder Speaks (1998), a saxophone duet, Visitations (1982), two saxophone quartets, 3 Diversions (1987) and The Avenging Spirit (1989), a saxophone quartet with solo alto saxophone, S.A.X. (1979), and a chamber piece for soprano and alto saxophone accompanied by piano and two percussionists, Shaking the Pumpkin (1986). In addition, an analysis of Fox's first composition for saxophone, S.A.X. for Solo Alto Saxophone and Saxophone Quartet, offers an insight into the compositional style of the composer. A complete listing of all of Fox's compositions, formal schemata of selected saxophone compositions, and a discography of his recorded saxophone compositions are included as appendices.

Analog technology has been around for a long time. The use of analog technology is necessary since we live in an analog world. However, the transmission and storage of analog technology is more complicated and in many cases less efficient than digital technology. Digital technology, on the other hand, provides fast means to be transmitted and stored. Digital technology continues to grow and it is more widely used than ever before. However, with the advent of new technology that can reproduce digital documents or images with unprecedented accuracy, it poses a risk to the intellectual rights of many artists and also on personal security. One way to protect intellectual rights of digital works is by embedding watermarks in them. The watermarks can be visible or invisible depending on the application and the final objective of the intellectual work. This thesis deals with watermarking images in the discrete wavelet transform domain. The watermarking process was done using the JPEG2000 compression standard as a platform. The hardware implementation was achieved using the ALTERA DSP Builder and SIMULINK software to program the DE2 ALTERA FPGA board. The JPEG2000 color transform and the wavelet transformation blocks were implemented using the hardware-in-the-loop (HIL) configuration.

In its earliest stages, acceptance and commitment therapy (ACT; Hayes, Strosahl, & Wilson, 1999) with youths appears to be a promising therapeutic approach. Experiential willingness and committed action are two foci of ACT, making their assessment an integral part of therapy. Field tests have found validity problems with the Willingness and Action Measure for Children and Adolescents (WAM-C/A). The current study utilized the Story Version of the Willingness and Action Measure for Children and Adolescents (SWAM-C/A). Results supported the relationship between the SWAM-C/A and measures of experiential avoidance and mindfulness. Factor analysis indicated the presence of several distinct willingness and action factors. These results support the need for continued work on measurement of willingness and action in youth.

In this study I analyzed the 1089 desegregation outcomes in federal district courts that occurred between 1994 and 2004 in order to identify a) the legal and non-legal factors in the litigation process that predict pro-desegregation outcomes and b) the judicial patterns that impact the future of desegregation policy. Twenty-one legal and non-legal variables were analyzed via logistic regression analysis to identify factors that predict pro-desegregation outcomes. Only three predictor variables were statistically significant: Government Litigants; Region 3 (West) and Region 4 (Northeast.) Descriptive analyses of the data identified two trends in the pattern of litigation: The percentage of defendant wins increased after 1991 at a lesser rate than has been previously reported. I conclude that based on the results of both the quantitative and qualitative analyses the federal district courts are not a barrier to desegregation and can still be a part of a comprehensive desegregation strategy.

Gods, Have Merced! chronicles the struggle of Jose Merced, a Santeria priest, with the city of Euless, Texas, where he has been residing for 17 years in an effort to overrule an ordinance that bans the most critical element of his faith: animal sacrifice. As the city officials justify the ban on the basis of public health, Merced thinks he is merely a victim of selective code enforcement aimed a restricting his freedom of religion. Local and national media covered the lawsuit he filed against the City of Euless, and Merced seems ready to take the fight over animal sacrifice to the United States Supreme Court. He wants American justice to give his African-originated religion recognized in a city where people seem uneasy about a practice that brings back the historic fears of Voodoo and its popularly assumed malefic practices. The film explores the complex structure of Santeria, its African roots, its renaissance in the Americas and the very controversial issue of animal sacrifice in the US.

This qualitative study uses narrative analysis to explore the outcomes of information seeking and use among public library users. Twelve women between the ages of 51 and 72, all residents of Fayetteville, Arkansas who self-identified as regular library users, were interviewed to gather their life stories and their experiences using the public library. The participants in this study used information to enable learning and, often, a change in their affective state. The participants used the new information they encountered constructively, to engage with the knowledge and experience they possessed; this use of information always involved reflection, dialogue, or both. The outcomes from these actions are the creation of new knowledge, a change in the participants' meaning schemes, and/or an affective change. In addition, the narratives strongly suggest that information seeking and use by adults in public libraries can sometimes facilitate or, on its own, precipitate a perspective transformation and the adoption of new meanings. Overall, the findings support Mezirow's theory of transformative learning as a model for understanding information use and outcomes among users of the public library. The major implications of this study are two-fold. One, it introduces to information science Mezirow's theory of transformative learning which could provide …

Weekly collections were conducted from May to December, 2007 (153 trap nights, total) in Denton, Texas, in and around large storm drains and overpass drainage facilities in residential and non-residential areas, using Centers for Disease Control (CDC) light traps and gravid traps. A total of 1964 mosquitoes were collected, representing 24 species within 6 genera: Aedes, Anopheles, Culiseta, Culex, Psorophora, and Uranotaenia. Culex was the most abundant genus, representing 75% of all mosquitoes collected; Aedes was the second most abundant, representing 12 % of all mosquitoes collected. Cx. quinquefasciatus was the dominant species collected via gravid traps; Cx. (Melanoconion) species were the dominant species collected via CDC light traps. Data of gravid traps and light traps were analyzed separately using nonparametric correlation analysis, comparing environmental data and physical characteristics to total abundance of mosquitoes. There was no significant correlation found when comparing the three dominant species collected in light traps (unidentified Cx. (Melanoconion) sp, Cx. quinquefasciatus, and Ae. vexans) to environmental characteristics and physical characteristics. Analysis of Cx. quinquefasciatus collected in gravid traps indicated no significant correlation between abundance, environmental data, and physical characteristics. Linear regression models were analyzed to determine if either environmental variables or physical characteristics of the …

The purpose of the study was to determine the relationship between scores of the new teachers' classroom effectiveness with numerical indexes of mentor support, mentor infrastructure, and workplace ecology. In addition, this study sought to determine the effect of various demographics (i.e., gender, age, race, degree, teaching level, and certification route) on the Classroom Effectiveness Index (CEI) scores of first-year teachers, and to determine the differences, if any, between the Classroom Effectiveness Index scores of first-year teachers who remained on campus, switched campuses, or left the district. This study is primarily correlational in nature - looking for relationships between quantifiable variables. The subjects are 68 first-year teachers. The mandatory mentoring program the subjects were involved in consisted of a paid, veteran teacher who worked on the same campus as the first-year teacher and assisted in instructional or behavioral needs. This study measured the impact of the first-year teachers' mentoring experiences to the Classroom Effectiveness Index scores and teacher retention. The findings suggest that the Classroom Effectiveness Index scores might not be an appropriate tool for uncovering which aspects of mentoring contribute to student achievement and retention. Adding the value-added measurement tool to the categories of mentor support (MS), mentor infrastructure …