This study investigated a new approach to achieving high energy density supercapacitors (SCs) by using high surface area self-activated carbon from waste coffee grounds (WCGs) and modifying 3D printed electrodes' porous structure by varying infill density. The derived activated carbons' surface area, pore size, and pore volume were controlled by thermally treating the WCGs at different temperatures (1000˚C, 1100˚C, and 1200˚C) and post-treating with HCL to remove water-soluble ashes and contaminants that block activated carbon pores. Surface area characterization revealed that the carbon activated at 1000˚C had the highest surface of 1173.48 m2 g-1, and with the addition of HCL, the surface area increased to 1209.35 m2 g-1. This activated carbon was used for fabricating the electrodes based on the surface area and having both micropores and macropores, which are beneficial for charge storage. Direct ink writing (DIW) method was utilized for 3D printing SC electrodes and changing the electrode structure by increasing the infill densities at 30%, 50%, and 100%. Upon increasing the infill densities, the electrodes' mass increased linearly, porosity decreased, and the total surface area increased for the 30% and 50% infill electrodes but decreased for the 100% infill electrode. Cyclic voltammetry (CV) test on the assembled …

This study analyzed the effects of acculturation, locus of control, and incidence of inhalant use on Mexican Americans. Information was collected from 275 subjects at three middle schools and one treatment center. The instrument consisted of Levenson's Locus of Control Scale, the Acculturation Rating Scale for Mexican Americans, and an incidence of use and family relationship questionnaire developed for this study. Statistical analysis indicated a relationship between acculturation and inhalant use. Further examination revealed relationships between a family members' use and subjects' inhalant use; subjects' alcohol use and inhalant use; and subjects' marijuana use and inhalant use. Information implied that prevention and intervention programs should focus on children of substance users and further research is needed surrounding the role of acculturation.

The current study aimed to explore the direct effect of insecure adult attachment on subjective wellbeing and its indirect effect via racial-ethnic identity. Additionally, the present study examined the extent to which racial-ethnic socialization practices may moderate adult attachment and racial-ethnic identity link. The final sample included 213 emerging adults (M = 20.94; SD = 2.96) with diverse racial-ethnic backgrounds. PROCESS Model 4 and 1 were used to examine the direct and indirect effect of insecure attachment on subjective wellbeing via racial-ethnic identity variables and the interaction effect between insecure attachment and racial-ethnic socialization on racial-ethnic identity variables. Results indicated the direct effect of insecure attachment on subjective wellbeing but did not support hypotheses for the indirect effect of insecure attachment on subjective wellbeing via the racial-ethnic identity variables. Additionally, results indicated that overt socialization buffered the negative impact of attachment avoidance on racial-ethnic identity exploration. Furthermore, racial-ethnic identity variables and subjective wellbeing significantly differed across racial-ethnic groups and socioeconomic statuses. Findings provide insight on the distinct concepts of attachment and racial-ethnic identity as they highlight inter- and intra-personal components, respectively. Mental health professionals may utilize overt socialization to help clients develop a sense of purpose and meaning related to …

The bristlenose pleco (Ancistrus cirrhosus) is a species of armored catfish in the Loricariidae family that breathes air facultatively when the aquatic environment becomes hypoxic. The bristlenose pleco uses its highly vascularized stomach as an air breathing organ. The two main goals of this developmental study were to determine the size of onset of air breathing and to determine the frequency of air breathing behavior in bristlenose plecos from juveniles to adults. Developing juveniles reach functional maturity within four to six months of hatching and grow to an adult size of eight to ten cm in length. To examine the developmental timing for the onset of air breathing, we tested different sized juveniles beginning at one cm up until 8 cm in length. The developmental timing for the onset of air breathing was measured by exposing each fish to a slowly decreasing aquatic oxygen content from 100% air saturation down to 8% air saturation. Fish were first able to breathe air at just over 2 cm and 1 gram in mass. There was a weak negative correlation between fish length and % air saturation at which air breathing began. When exposed to 15% air saturation, frequency of air breathing was …

This thesis centers around a certain twentieth-century compositionaI device, the method of composition with twelve tones. There are many terms to designate this device, for example: "basic set," "tone-row," "note-series," "serialism," "serial technique," "twelve-note series," "twelve-tone technique" or "twelve-tone method." TI is thesis is a methodical research demonstrating the contemporary conventional way of scientifically and artfully manipulating twelve equal tempered degrees of the chromatic scale to produce a desirable system. In order to arrive at any substantial conclusions, it is necessary to make a critical examination and evaluation of known twelve-tone compositional procedures from as many angles as possible, so as virtually to exhaust every practical and speculative potentiality included in the technique, that is, within the range and limits of our present needs. This examination and evaluation will also involve a comparative investigation of various uses of the device, in order to produce and suggest ideas for further theoretical insights. The ultimate purpose of this thesis is to pinpoint the "hows" and "whys" of Rochberg's use of the twelve equal tones in Sonata-Fantasia.

The third volume of A.B. Marx's theory treatise Die Lehre von der musikalischen Komposition is discussed. His definitions of rondo and sonata formal types are demonstrated in the first chapter in addition to the manner of their derivation through a developmental process originating in the Liedform. Musical examples chosen by Marx are examined in chapter two. These examples, taken from Mozart's and Beethoven's piano works, are evaluated in relation to Marx's definitions of the various types of form. The third chapter is concerned with the progression from microstructure to macrostructure and the functional interrelation of the parts to the whole. In addition, Marx's opinion on musical form is compared with perspectives of philosophers from his time period and the immediate past.

Beneficial consumer outcomes are most likely when behavior-analytic interventions are implemented with high procedural fidelity (i.e., degree to which the procedure is implemented as intended). Video self-monitoring, which involves teaching staff members to monitor their own procedural fidelity when watching recordings of themselves, can be used to improve and maintain high procedural fidelity, but video self-monitoring requires additional staff time and resources. In-vivo self-monitoring, which involves monitoring procedural fidelity during or immediately following implementing a behavior-analytic intervention, could be a cost-effective option. However, in-vivo self-monitoring needs additional research to understand its effects on procedural fidelity. This current study analyzed the effects of in-vivo self-monitoring on the procedural fidelity of three behavior technicians implementing discrete trial instruction with children with autism. We used a nonconcurrent multiple baseline across participants design to teach participants how to score their procedural fidelity during their discrete trial instruction session. Data suggested that in-vivo self-monitoring was effective for two out of three participants, and those two participants were more likely to be accurate in their self-scored procedural fidelity. Procedural fidelity for the third participant did not increase with in-vivo or video self-monitoring, and the third participant was less likely to be accurate in their self-scored procedural …

In model reaction systems to test amino acids in chlorinated waste effluents, several amino acids were chlorinated at high chlorine doses. (2000-4000 mg/1). Amino acids present in municipal waste effluents before and after chlorination were concentrated and purified using cation exchange and Chelex resins. After concentration and cleanup of the samples, the amino acids were derivatized by esterification of the acid functional groups and acylation of the amine groups. Identification and quantification of the amino acids and chlorination products was carried out by gas chromatography/mass spectrometry, using a digital computer data system. Analysis of the waste products revealed the presence of new carbon-chlorine bonded derivatives of the amino acid tyrosine when the effluents were treated with heavy doses of chlorine.

Recent research suggests that race and ethnicity influence post-buyout land management in Harris County, Texas, yet lacked systematic empirical evidence to fully understand the relationship between management and demographics. To address this gap, this study analyzes post-buyout land use management practices and compares them with the socio-economic characteristics of the adjacent neighborhood at the block level in Harris County, Texas, an area with a long buyout history. I first identified post-buyout land use management practices in Harris County through county records and photo documentation of approximately 2000 buyout sites through fieldwork from 2017-2022. Second, using Ode and colleagues' framework for identifying visual characteristics on the landscape, I developed an index and evaluated post-buyout land use management practices for aesthetics, utility, and function. Finally, I spatially analyzed the socio-demographic composition of buyout neighborhoods using U.S. Census American Community Survey 5-year data (2017-2021) and compared it with post-buyout land use management practices in ArcGIS. From this spatial analysis, I identified differences in post-buyout land management that homeownership status, race, and ethnicity affected post-buyout land management. Most buyout properties in Harris County are managed as mowed, vacant lots regardless of socio-demographics; however, litter and debris were more prominent in predominantly Black neighborhoods. Of …

The problem with which this investigation is concerned is that of comparing the medieval musical traditions of two of the world's most influential religions. The similarities are discussed in two major categories: the comparison of liturgical texts and ritual, and the comparison of the music appearing in each ritual. This study has one main purpose. That purpose is to demonstrate how, through musical traditions, each religion has developed through the influence of the other. Samples of the liturgies from the musical portions of the services were obtained from prayer books and references dealing with those religions. Investigations of English translations from the Latin and Hebrew revealed a close identity between the two, not only in scriptural uses, but also in prayers and responses. Musical examples demonstrating similar elements in Hebrew and Christian worship were found in the extensive research of A. Z. Idelsohn and Eric Werner. Due to the dispersal of world Jewry, the best examples of Hebrew medieval music were obtained from the most isolated Jewish communities, such as those of Yemen, Musical similarities included modes, melodic formulas, and hymns and songs. This report concludes that the musical portions of the services of Christianity and Judaism in the Middle …

On April 16, 2014 the Sewol Ferry became one of the worst maritime disasters in South Korea with the loss of 304 passenger, the majority being high school students. South Korea is a collectivist culture, structured as a hierarchical system that teaches their students and children to always respect, listen, and trust authority figures especially in dangerous situations. This study explores how collectivist cultural elements impacted the response of the Sewol Ferry. By examining the timeline of the disaster through interviews, documentaries, news articles and media; this thesis offers insight into what happened that day by providing perspectives from the rescue crew, government officials, survivors, volunteers, and family members of those who died. The analysis showed that in collectivist culture, children and students are taught to trust and listen to authority figures when in dangerous situations, however because of the Sewol disasters, the culture of adhering to the hierarchical systems started to collapse. Students who survived stated that they no longer can trust and respect adults after the incident along with family members of the students who passed away and the public. Also, the government withheld information and failed to protect the children aboard the ferry, because they didn't want …

Radio map estimation (RME) is the task of predicting radio power at all locations in a two-dimensional area and at all frequencies in a given band. This thesis explores four deep learning approaches to RME: dual path autoencoders, skip connection autoencoders, diffusion, and joint learning with transmitter localization.

The relationship between Erasmus of Rotterdam and the religious movement called the Devotio Moderna, especially the latter's relevance to Erasmian piety, has been a somewhat contentious historiographical issue. This thesis examines that relationship, and asserts that the Devotio Moderna was a crucial formative aspect of Erasmus' religiosity. However, its relevance ought not be overstated, due to the humanist's significant developments away from his spiritual forerunners.

Tabletop role-playing games (TRPGs) present a unique opportunity to study political behavior. In educational settings, role-playing games (RPGs) of all kinds have proven to be valuable educational tools, and even when played for fun, participating in role playing games has been shown to increase one's level of confidence. Knowing this, I designed an experiment to attempt to increase internal political efficacy through the use of a politically-themed TRPG. I took inspiration from the original TRPGs of the 1970s and 1980s which were used purely for entertainment purposes to create my own game in a traditional TRPG setting with current issues woven into the story of the game (also called a campaign), and utilized quantitative and qualitative methods to analyze participants' reactions to the campaign and levels of efficacy. In doing so, I seek to determine whether players will recognize real-world issues when presented in a science fiction or fantasy-themed campaign. Furthermore, given that TRPGs have the potential to shape players' understanding of how the world works and their place in it, will players be more motivated to act on said issues presented in-game, even if they do not consciously make the connection between the real-life issues presented in the science …

Considering that both cardiovascular disease (CVD) and congenital heart diseases (CHD) are still the leading cause of morbidity and mortality worldwide, there is a need for a robust and reliable cardiac model. Cardiac organoids are complex, three-dimensional cellular constructs that recapitulate the processes of the human embryonic heart. However, certain vital morphological features within the fetus are not yet replicable with cardiac organoids. Here we report our investigation to generate cardiac organoids with chamber formations. Our method involves modulating the Wnt pathway at two different instances while also implementing two cell seeding densities, all to determine the most optimized that to produce chamber formations within cardiac organoids.

It is generally accepted among scholars that increases in descriptive representation result in increases in substantive representation. Although women's descriptive representation has increased in recent years, women are still underrepresented in politics. One reason for women's underrepresentation is that female candidates must overcome additional barriers in order to get elected, including on the low number of women in the pipeline to elected office, party gatekeeping, women's lower levels of political ambition, and voters' negative gender stereotypes about female candidates. Changes in women's descriptive representation and recent salience of women-friendly policies, such as abortion and paid maternity leave, has caused me to investigate whether implementation of these women-friendly policies result in an increase in women's descriptive representation. I assert that women-friendly policies reduce the barriers women must overcome to get elected to office. Specifically, the presence of more women-friendly abortion and paid maternity leave policies will result in an increase in women's descriptive representation at the state level. I find partial support for a relationship between these women-friendly policies and higher levels of women's descriptive representation. State-level abortion protections are associated with higher levels of women's descriptive representation in the state legislature.

The goal of this study was to determine if performance -based tests should be routinely administered to students in computer application courses. The purpose was to determine the most appropriate mode of testing for individuals taking a computer applications course. The study is divided into areas of assessment, personality traits, and computer attitudes.

The concept of "creativity" has been studied under the perspective of variability in behavior analysis. Creativity and variable responding contributes to problem solving in novel situations, learning new responses in different environments, and promote interactions that would otherwise be prohibited by repetitive behaviors and routines. During childhood, play contributes to the emergence of creativity and variability. Children develop many skills that are important to their lives while engaging in play behaviors. Some of those skills include self-advocacy, communication, and problem solving. Researchers have investigated different methods to promote variable play skills in children with autism spectrum disorder (ASD). There is limited research on prompting as an isolated variable in increasing variability in play responses. The purpose of this study was to investigate the effects of prompting on variable play skills. Results indicated that verbal instructions and modeling were effective in increasing variable play responses. Both participants displayed a sustained increase in novel item engagement when exposed to prompting.

Despite the evidence that supports the benefits of a holistic, collaborative approach to autism intervention, but there is little training to teach those skills to professionals. Behavior analysts working in applied settings will often partner with different individuals from very different backgrounds and disciplines. Skilled Dialogue has been recommended as an approach to conversations that values everyone's contributions in fostering compassionate, collaborative, and culturally responsive care to benefit the children served. The purpose of this study was to evaluate the effects of a training workshop to teach the concept and strategies of skilled dialogue to behavior analysts in training. The participants were taught and practiced using the six strategies of Skilled Dialogue: welcoming, allowing, sense-making, appreciating, joining, and harmonizing through use of instructions, rationales, activities, simulations, and feedback. The success of the training was evaluated using a multiple baseline design across training components. Audio and video responses to role-play scenarios were recorded, transcribed, and scored to measure the results of the training workshop on communication skills. The results suggested that the training workshop was an effective method to teaching future behavior analysts how to engage in the strategies and components of skilled dialogue, increasingly the likelihood of collaborative, and children …

This MFA graduate thesis explores the intersection of therapeutic photography, generational trauma, and Christian spirituality in promoting spiritual healing in disabled veterans diagnosed with post-traumatic stress disorder (PTSD). Drawing from personal experience, rigorous biblical training, and extensive research, I argue that incorporating faith-based practices and beliefs can complement existing PTSD support and enhance spiritual and mental well-being. Through the lens of generational trauma, the thesis analyzes the complex interplay between individual and collective trauma. It posits that the healing process is intrinsically linked to the restoration of the individual and community. I present a framework for therapeutic photography that incorporates Christian spiritual principles and offers practical guidelines for implementation in conjunction with therapeutic photography. The thesis concludes with a call to action for faith-based communities, mental health practitioners, and policymakers to recognize and address the spiritual and artistic therapeutic needs of disabled veterans with PTSD.

It would be impossible to trace the evolution of the form of the scherzo without treating also to some extent the history of the minuet, as the scherzo would hardly have come into being in the way it did had there not been the minuet, even though as the scherzo grew to maturity it resembled less and less its parent-form. This thesis examines the early use and origin of the scherzo, and its use and evolution in the works of Beethoven.

This study aimed to broaden the understanding of young South Asian women's experiences/relationships and participation in leisure physical activities at universities in the United States. Using a phenomenological design, semi-structured interviews of 20-30 minutes duration were conducted with 5 South Asian women about their relationships and experiences when participating or attempting to participate in physical activity while attending university in the US. The following criteria were set for participants to be included in this study: they should be between the ages of 18 and 24, non-US citizens from a South Asian country, attend a university in the US, and engage in other physical activities. The interviews were audio recorded via Zoom and then the audio data were transcribed verbatim and then coded to identify the major barriers commonly experienced by participants. Results indicated that many girls and women perceived the US as a "safer" place with excellent infrastructure, ample opportunities to engage in physical activities, and convenient access to gyms, which encourage them (women) to remain active. Most participants were hesitant to participate in physical activities because of the culturally non-responsiveness of the system. This research study was done in a shorter time span with a small sample size. Further …

The purpose of this study was to develop an experimental technique to objectively measure the deviation between an individual's perception of his body image and his actual image. In addition, this technique was utilized to compare the accuracy of perception of body image between institutionalized and non-institutionalized individuals. Half of each subject category was also compared in terms of performance on an additional perceptual task unrelated to body image.

The aim of this thesis is to advance the field of solid lubrication science by developing coatings that provide reliable performance in ambient conditions, work on rough surfaces, and are amenable to industrial size and design complexities. Two different coating systems, Ti3C2Tx-MoS2 and Ti3C2Tx-Graphene Oxide blends, were studied in this work. The Ti3C2Tx-MoS2 nanocomposites were spray-coated onto rough 52100-grade steel surfaces, and their tribological performance was evaluated in a ball-on-disk configuration in a unidirectional sliding mode. The test results indicate that Ti3C2Tx-MoS2 coatings achieved superlubricity, which has not been previously reported for either pristine material under macroscale sliding conditions. The observed synergistic mechanism enabled the superlative performance, which was explained by the in-situ formation of a robust tribolayer responsible for sustained lubricity even at high contact pressures (>1.1 GPa) and sliding speeds (0.1 m/s). Processing, structure, and property correlation studies were conducted to understand the underlying phenomena. Raman spectroscopy, scanning electron microscopy, and transmission electron microscopy were used to reveal the formation of the tribolayer. The Ti3C2Tx-Graphene Oxide blends were also spray-coated onto rough-bearing steel surfaces, and their tribological assessment was carried out in ambient environmental conditions and high contact pressures in a ball-on-disc experimental setup. The coatings led to …