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Reactions of Chloroketenes with Ketene Acetals (open access)

Reactions of Chloroketenes with Ketene Acetals

The first objective of this investigation was to conduct a systematic study into the reactions of chloroketenes with ketene acetals. The second objective was to explore the synthetic utility of these reaction products and offer a rational explanation for these reaction products.
Date: May 1981
Creator: Watts, Ronald David, 1943-
System: The UNT Digital Library
The Effect of Ozonation in Reducing Trihalomethane Formation Potential (open access)

The Effect of Ozonation in Reducing Trihalomethane Formation Potential

Trihalomethanes such as chloroform, dichlorobromomethane, dibromochloromethane, and bromoform are formed when natural water is chlorinated in water treatment. This investigation explores the use of ozone to remove organic precursors from natural water, thus decreasing trihalomethane formation potential. The data suggest a mechanism involving formation of secondary precursors after prolonged contact with ozone, suggesting that trihalomethane precursors may be minimized by using low doses of ozone and short contact time.
Date: May 1981
Creator: Lin, Simon H.
System: The UNT Digital Library
Synthesis of Aziridine Analogues of Pyrethroids (open access)

Synthesis of Aziridine Analogues of Pyrethroids

Rules which correlate structure and insecticidal activity of pyrethroids have evolved over the last thirty years from the results obtained in the testing of various synthetic pyrethroids. The major portion of these rules have dealt either with the development of new alcohol moieties or variations in the unsaturated side chain of the cyclopropane ring. There has been very little work done concerning modifications of the cyclopropane ring. This study was initiated to discover the affect of substituting an aziridin ring for the cyclopropane ring found in pyrethroids.
Date: May 1981
Creator: Sheppard, Rex Gerald
System: The UNT Digital Library