Responses of phytoplankton productivity in the Red River to unbleached pulp and paper mill wastewaters were monitored using in situ ^14C incubation. Preoperational studies, conducted prior to the discharge of mill wastewaters varied seasonally, but revealed similar productivity trends when compared with postoperational studies, conducted after mill discharges began entering the Red River. Carbon assimilation rates measured downstream of mill discharge were generally greater than upstream levels in both preoperational and postoperational studies. Selected physical, chemical, and biological parameters varied seasonally, but showed similar upstream-downstream values and preoperational-postoperational values. Total Organic Carbon (TOC), Dissolved Organic Carbon (DOC), and Biochemical Oxygen Demand (BOD_5) were positively correlated with postoperational productivity rates. Apparent color was negatively correlated with productivity rates.

Nutrients are of critical concern in water quality assessment. The development of empirical models to estimate mean nutrient concentrations, based on satellite derived land use, could aid water resource managers. Models using land use acreages outperformed those using percentages, and discrete urban land uses were superior to lumped urban. Regressions of the combinations of two, three and four of the eight possible land use variables were investigated. Sensitivity analyses, with one stream deleted each series, identified robust combinations of variables at each level. Although uncertainty exists regarding the final regression coefficients, five of the six actual measured nitrate and total phosphorus mean concentrations were within the 95 percent confidence limits.