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The Influence of Selected Non-Bonded Interactions on Vicinal Carbon-Carbon Coupling Constants
The body of information concerning carbon-carbon spin-spin coupling constants now includes a large number of coupling constants, the establishment of a dihedral angular dependence on 3JCC, and the application of 3JCC to conformational analysis. This study adds another dimension to the growing wealth of information associated with 13 C-NMR: the influence of some non-bonded interactions on 3JCC Four types of non-bonded interactions that could influence vicinal carbon-carbon NMR coupling constants were investigated. To facilitate the NMR studies, a variety of 13C-labeled compounds were synthesized.
Date:
May 1982
Creator:
Canada, Edward D. (Edward Dee)
System:
The UNT Digital Library