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Development and Testing of Gold(I) and Europium(III) Based Sensors for Environmental Applications

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This dissertation focuses on the development, characterization, and analysis of luminescent materials and coatings for sensing applications, including CO2, heavy metals, and silver. Chapter 2 involves the use of a gold(I) pyrazolate trimer that is able to detect silver ions with an AgNP medium. Detection of silver is vital, because there is an influx of silver into our environment caused by the increased use of AgNP. Therefore, having a sensor that is able to differentiate between and detect only Ag ions is an important first step to solving the toxicity mystery of AgNPs. Chapter 3 focuses on the development of sensor coatings containing a Eu(III) based luminescent system for sensing dissolved CO2 without the aid of an absorption-based dye. It is well-known that monitoring CO2 levels in our environment is important since even at low concentrations it can cause adverse health effects to the human body. This work demonstrates a pH-sensitive Eu complex being used directly as a CO2 sensor without the aid of any other absorption-based dye. Chapter 4 explores the idea of developing a heavy metal sensor for lead and its ability to detect lead in wide concentration range upon changing the pH of the medium and the …
Date: May 2019
Creator: Benton, Erin Nicole
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Treatment efficacy in a chronic pain population: Pre- to post-treatment.

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The purpose of the current study was to investigate the effects of a multidisciplinary pain management program on five measures of subjective psychosocial factors. Ninety-five participants in the comprehensive multidisciplinary treatment group and the standard medical intervention control group were surveyed about various psychosocial factors using Axis II of the West Haven - Yale Multidimensional Pain Inventory (MPI), pre- to post-treatment. It was hypothesized that post-treatment levels would be significantly lower than pre-treatment levels for all five psychosocial variables. Additionally, gender and ethnicity variables were examined. Based on preliminary analyses indicating pre-treatment differences between the experimental and control group, five 2 x 2 x 3 analyses of covariances (ANCOVAs) were used to examine the above hypotheses. Results indicated significant differences between the treatment conditions on measures of control, with the comprehensive group feeling more in control than the standard group at post-treatment. No other significant main effects for treatment condition were found on the measures of pain severity, interference with daily activities, negative mood, or social support. However, a significant gender main effect was found for social support at post-treatment, with females reporting more social support than males. A significant gender x ethnicity interaction was also found for post-treatment control, …
Date: December 2004
Creator: Bernstein, Dana N.
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Knowledge management in virtual organizations: A study of a best practices knowledge transfer model.

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Knowledge management is a major concern for organizations today, and in spite of investments in technology, knowledge transfer remains problematic. This study sought to determine whether a relationship exists among participant group demographics (experience), implementation of an integrated knowledge transfer system (best practices model), knowledge transfer barriers, and knowledge transfer project (Web-based training) outcome in a virtual organization. The participant organization was a network of individuals and groups who practice patient advocacy in the research and treatment of cancer. These advocates volunteer in various capacities and are not collocated nor do they report to any single organizational entity. Volunteer participants were randomly assigned to a treatment or control condition. The treatment participants received a training supplement based upon a best practices knowledge transfer model. All participants reviewed a Web-based communications training module scheduled for deployment by the participant organization. Upon completion of the training program, participants were instructed to practice specific techniques from the program. At the end of this period, participants completed an online survey that measured demographics, perceived barriers to the knowledge transfer, and project outcome. Knowledge transfer barriers were defined as knowledge, source, recipient, and organizational context characteristics that inhibit the expected transfer. Project outcome was a …
Date: May 2005
Creator: Berryman, Reba
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Job Embeddedness as a Predictor of Voluntary Turnover: Validation of a New Instrument

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Voluntary turnover has become a problem for many organizations in today's society. The cost of this turnover reaches beyond organizational impact, but also affects the employees themselves. For this reason, there has been a plethora of research conducted by both academicians and practitioners on the causes and consequences of voluntary turnover. The purpose of this study is to test the validity and generalizability of the job embeddedness model of voluntary turnover to the information technology (IT) industry. The IT field has been plagued with high turnover rates in recent years. In this study, the job embeddedness model (Mitchell et al., 2001) is applied to a population sample consisting of health care information technology employees.
Date: December 2003
Creator: Besich, John S.
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Performance appraisal impact on employee career development and performance: A longitudinal study.

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The purpose of this study was to determine the effectiveness of the implementation of an internally created performance appraisal system as well as the subjects' overall satisfaction with the implementation. The system was implemented at a major technology consulting firm in the US. The subjects of this study were three levels of employees of the firm. An employee survey conducted annually at the firm included questions relating to the implementation of the performance appraisal system. Eight years of employees' responses to three key questions were analyzed. Employees' perceptions of the appraisal feedback aiding increased performance, their belief about the implementation assisting with their career management, satisfaction with the initiative, and their understanding of the requirements for promotion were captured by this survey. Trend analysis indicates that employees at the firm perceived their career path knowledge unimproved, their understanding of promotion criteria unimproved as a result of the implementation. Employees did not indicate overall satisfaction with the implementation and the employee's belief about their skills and abilities utilization did not improve post implementation.
Date: December 2006
Creator: Bhagwat, Tanya A.
Object Type: Thesis or Dissertation
System: The UNT Digital Library

UV Magnetic Plasmons in Cobalt Nanoparticles

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The main goals of this research were to fabricate magnetic cobalt nanoparticles and study their structural, crystal structure, optical, and magnetic properties. Cobalt nanoparticles with average particle size 8.7 nm were fabricated by the method of high temperature reduction of cobalt salt utilizing trioctylphosphine as a surfactant, oleic acid as a stabilizer, and lithium triethylborohydride as a reducing reagent. Energy-dispersive X-ray spectroscopy (EDX) analysis confirmed the formation of cobalt nanoparticles. High resolution transmission electron microscopy images show that Co NPs form both HCP and FCC crystal structure. The blocking temperature of 7.6 nm Co NPs is 189 K. Above the blocking temperature, Co NPs are single domain and hence showed superparamagnetic behavior. Below the blocking temperature, Co NPs are ferromagnetic. Cobalt nanoparticles with a single-domain crystal structure support a sharp plasmon resonance at 280 nm. Iron nanoparticles with average particle size 4.8 nm were fabricated using chemical reduction method show plasmon resonance at 266 nm. Iron nanoparticles are ferromagnetic at 6 K and superparamagnetic at 300 K.
Date: May 2019
Creator: Bhatta, Hari Lal
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Hyperspectral and Multispectral Image Analysis for Vegetation Study in the Greenbelt Corridor near Denton, Texas

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In this research, hyperspectral and multispectral images were utilized for vegetation studies in the greenbelt corridor near Denton. EO-1 Hyperion was the hyperspectral image and Landsat Thematic Mapper (TM) was the multispectral image used for this research. In the first part of the research, both the images were classified for land cover mapping (after necessary atmospheric correction and geometric registration) using supervised classification method with maximum likelihood algorithm and accuracy of the classification was also assessed for comparison. Hyperspectral image was preprocessed for classification through principal component analysis (PCA), segmented principal component analysis and minimum noise fraction (MNF) transform. Three different images were achieved after these pre-processing of the hyperspectral image. Therefore, a total of four images were classified and assessed the accuracy. In the second part, a more precise and improved land cover study was done on hyperspectral image using linear spectral unmixing method. Finally, several vegetation constituents like chlorophyll a, chlorophyll b, caroteoids were distinguished from the hyperspectral image using feature-oriented principal component analysis (FOPCA) method and which component dominates which type of land cover particularly vegetation were correlated.
Date: August 2006
Creator: Bhattacharjee, Nilanjana
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Proud Warriors: African American Combat Units in World War II

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During World War II, tens of thousands of African Americans served in segregated combat units in U.S. armed forces. The majority of these units were found in the U.S. Army, and African Americans served in every one of the combat arms. They found opportunities for leadership unparalleled in the rest of American society at the time. Several reached the field grade officer ranks, and one officer reached the rank of brigadier general. Beyond the Army, the Marine Corps refused to enlist African Americans until ordered to do so by the president in June 1942, and two African American combat units were formed and did see service during the war. While the U.S. Navy initially resisted extending the role of African American sailors beyond kitchens, eventually the crew of two ships was composed exclusively of African Americans. The Coast Guard became the first service to integrate—initially with two shipboard experiments and then with the integration of most of their fleet. Finally, the famous Tuskegee airmen are covered in the chapter on air warfare. Proud Warriors makes the case that the wartime experiences of combat units such as the Tank Battalions and the Tuskegee Airmen ultimately convinced President Truman to desegregate the …
Date: October 2021
Creator: Bielakowski, Alexander M.
Object Type: Book
System: The UNT Digital Library

Cure Kinetics and Processing Parameters of Neat and Reinforced High Performance Epoxy Resins: Evaluation of Techniques

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Kinetic equation parameters for the curing reaction of a commercial glass fiber reinforced high performance epoxy prepreg composed of the tetrafunctional epoxy tetraglycidyl 4,4-diaminodiphenyl methane (TGDDM), the tetrafunctional amine curing agent 4,4’-diaminodiphenylsulfone (DDS) and an ionic initiator/accelerator, are determined by various thermal analysis techniques and the results compared. The reaction is monitored by heat generated determined by differential scanning calorimetry (DSC). The changes in physical properties indicating increasing conversion are followed by shifts in glass transition temperature determined by DSC and temperature-modulated DSC (TMDSC), thermomechanical (TMA) and dynamic mechanical (DMA) analysis and thermally stimulated depolarization (TSD). Changes in viscosity, also indicative of degree of conversion, are monitored by DMA. Thermal stability as a function of degree of cure is monitored by thermogravimetric analysis (TGA). The parameters of the general kinetic equations, including activation energy and rate constant, are explained and used to compare results of various techniques. The utilities of the kinetic descriptions are demonstrated in the construction of a useful time-temperature-transformation (TTT) diagram for rapid determination of processing parameters in the processing of prepregs. Copyright is held by the author, unless otherwise noted. All rights reserved. Files: Thesis.pdf Special Conditions
Date: December 1999
Creator: Bilyeu, Bryan
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Hopfield Networks as an Error Correcting Technique for Speech Recognition

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I experimented with Hopfield networks in the context of a voice-based, query-answering system. Hopfield networks are used to store and retrieve patterns. I used this technique to store queries represented as natural language sentences and I evaluated the accuracy of the technique for error correction in a spoken question-answering dialog between a computer and a user. I show that the use of an auto-associative Hopfield network helps make the speech recognition system more fault tolerant. I also looked at the available encoding schemes to convert a natural language sentence into a pattern of zeroes and ones that can be stored in the Hopfield network reliably, and I suggest scalable data representations which allow storing a large number of queries.
Date: May 2004
Creator: Bireddy, Chakradhar
Object Type: Thesis or Dissertation
System: The UNT Digital Library

A preliminary study of the effects of selective-serotonin re-uptake inhibitors (SSRIs) on central auditory processing

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his study compared auditory behavioral and physiological measures among three subject groups: 1) Normal control subjects, 2) subjects who were on a prescribed SSRI for depression, and 3) subjects who were prescribed an SSRI for depression, but were not medicated at the time of testing. Test measures included: Standard audiological tests (audiometry and tympanometry), electrophysiological procedures for analysis of auditory- evoked brainstem and late responses, and standardized behavioral speech tests (SCAN-A, SSI, and the low predictability sentence list of the R-SPIN). Analysis of results indicated a statistically significant increase of group mean amplitude of the ABR peak V, from 15dBnSL to 55dBnSL, in the non-medicated group compared to controls. Also, the non-medicated group scored significantly less favorably than controls on the most challenging listening condition (-20 MCR) of the SSI, in the left ear. Although other test measures indicated consistent differences between these two groups, they were not, however, significant.
Date: August 2001
Creator: Bishop, Charles E.
Object Type: Thesis or Dissertation
System: The UNT Digital Library

The Pink Papers

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The Pink Papers is a collection of three short stories and a novel in progress consisting of four chapters. Each piece is a work of original fiction. The preface addresses the female writer and the female voice in fiction. "Broken Clock" and "Pink Paper" are the stories of two girls coping with endometriosis. "Normal Capacity" looks at the loss of a dream through the eyes of a first-year law student. The novel in progress, titled Blanchard, OK, is set in a rural farming town in Oklahoma. The novel tells the stories of 24-year-old Robin, her Aunt Paula, and Paula's boyfriend, Sam.
Date: August 2003
Creator: Blagg, Caroline
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Images of women shopping in the art of Kenneth Hayes Miller and Reginald Marsh, ca 1920-1930.

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This thesis examines images of women shopping in the art of Kenneth Hayes Miller and Reginald Marsh during the 1920s and 1930s. New York City's Fourteenth Street served Kenneth Hayes Miller and Reginald Marsh, respectively, as a location generating the inspiration to study and visually represent its contemporaneity. Of particular interest to this thesis are relationships between developments in shopping and the images of women shopping in and around Fourteenth Street that populate the paintings of Miller and Marsh. Although, as Ellen Todd Wiley has shown, the emerging notion of the New Woman helped to shape female identity at this time, what remains unstudied are dimensions that geographically specific, historical developments in shopping contributed to the construction of female identity which, this thesis argues, Marsh and Miller related to, by locating in, the department store and bargain store.
Date: August 2006
Creator: Blake, Amanda Beth
Object Type: Thesis or Dissertation
System: The UNT Digital Library

ETS Corpus of Non-Native Written English

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ETS Corpus of Non-Native Written English was developed by Educational Testing Service and is comprised of 12,100 English essays written by speakers of 11 non-English native languages as part of an international test of academic English proficiency, TOEFL (Test of English as a Foreign Language). The test includes reading, writing, listening, and speaking sections and is delivered by computer in a secure test center. This release contains 1,100 essays for each of the 11 native languages sampled from eight topics with information about the score level (low/medium/high) for each essay. The corpus was developed with the specific task of native language identification in mind, but is likely to support tasks and studies in the educational domain, including grammatical error detection and correction and automatic essay scoring, in addition to a broad range of research studies in the fields of natural language processing and corpus linguistics. For the task of native language identification, the following division is recommended: 82% as training data, 9% as development data and 9% as test data, split according to the file IDs accompanying the data set.
Date: June 16, 2014
Creator: Blanchard, Daniel; Tetreault, Joel; Higgins, Derrick; Cahill, Aoife & Chodorow, Martin
Object Type: Dataset
System: The UNT Digital Library

The Leadership Path of R. Jan LeCroy

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Recent studies reveal that a considerable number of U.S. community college leaders will be retiring in the next several years. The concern is that with the large turnover, history, culture, and important lessons of leadership will be lost. The current research on the lives of presidents, their career paths, and experiences in community college leadership centers on approaches to the study of leadership at the macro level. Limited research exists in the published literature that reports and analyzes the development of individuals as community college leaders at the micro level. This results in a gap regarding understanding leadership development and strategies to prepare leaders. This study addresses this gap by providing a critical description of the leadership development of one individual who became a community college chancellor and who the literature on the community context indicates contributed to the local and national context for community colleges. Biography is gaining prominence as a legitimate and viable tool in the study of leadership. Few biographical studies currently exist which focus on leadership development in context at the micro level. This dissertation is a biographical, qualitative study of the leadership path and legacy of R. Jan LeCroy, a community college leader. The study …
Date: December 2006
Creator: Blankenbaker, Zarina A.
Object Type: Thesis or Dissertation
System: The UNT Digital Library

The Effects of Response Restriction on Non-Socially Maintained Self-Injury

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This study examined the effects of response restriction (blocking and protective equipment) on subsequent durations of self-injury with two female participants with developmental disabilities. First, a functional analysis was conducted with each participant to identify potential maintaining variables of the self-injury. Second, access to the response was systematically restricted in a multiple schedule restriction paradigm. A baseline extended alone was conducted without the restriction component in place as a control condition. For one participant the results suggested that response restriction may have increased subsequent durations of responding once the restriction element was removed. For a second participant responding did not appear to be affected by the restriction component.
Date: May 2003
Creator: Blevins, Travis
Object Type: Thesis or Dissertation
System: The UNT Digital Library

The Nightingale in Poetry and Music

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This thesis surveys a variety of songs and arias for high soprano which feature the nightingale; examines the musical elements that symbolize, refer to, or imitate the nightingale; and compares these musical elements with transcriptions of the nightingale's song. The first chapter reviews the symbolic development of the nightingale and its role in poetry and literature. The interior chapters address a selection of musical compositions that feature the nightingale and its song. The final chapter establishes a relationship between the sound of the actual sound of the nightingale and the musical gestures created by composers to imitate the nightingale.
Date: May 2003
Creator: Blizzard, Amy
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Gunther Schuller and John Swallow: Collaboration, Composition, and Performance Practice in Eine Kleine Posaunenmusik, with Three Recitals of Selected Works by Berio, Bogle, Gregson, Pryor, Suderburg and Others

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Gunther Schuller is credited with coining the term Third Stream, meaning compositions where twentieth-century art music forms exist simultaneously with jazz. Furthermore, Schuller specifically states in the liner notes to the debut recording of Eine Kleine Posaunenmusik "The work is not a Third Stream piece." Yet the concerto alludes to jazz through a multitude of slide glissandi and plunger mute effects, Solotone mute passages, specific references to the jazz trombone styles of Tommy Dorsey and Lawrence Brown, musical quoting or indirect reference, and the use of a walking bass line in Movement V, Finale. What makes one piece Third Stream and another simply a modern composition with jazz implications? Is Third Stream primarily a compositional designation or a performance practice stipulation? How does a celebrated trombone soloist inspire and collaborate with a distinguished composer in the creation of a major work? The somewhat conspicuous title, Eine Kleine Posaunenmusik, seems to point towards Mozart's famous string serenade Eine Kleine Nachtmusik. What connection to Mozart, if any, does Schuller's title suggest? All of these questions are elucidated in this study through careful investigation and research of Gunther Schuller's Eine Kleine Posaunenmusik. New interviews with John Swallow and Gunther Schuller are included.
Date: May 2000
Creator: Bogle, James Michael
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Use of Geographic Information System and Remote Sensing Technologies to Describe Mosquito Population Dynamics in the Ray Roberts Greenbelt, Denton County, Texas

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A population survey was conducted from April through September 2002 on mosquito species occurring on the Ray Roberts Greenbelt, a riparian corridor used for public recreation on the Elm Fork of the Trinity River, in Denton County, Texas. ArcGIS software was used to set up a stratified random sampling design based on habitat parameters. Multivariate analyses of sampling data and climatic variables were used to describe spatial and temporal patterns of mosquito species. A total of 33 species were collected during this study belonging to the following genera: Aedes, Anopheles, Coquillettidia, Culex, Mansonia, Ochlerotatus, Orthopodomyia, Psorophora, Toxorhynchites, and Uranotaenia. Seasonal distributions of the dominant species revealed population fluctuations. Aedes vexans was the primary species collected in April and May, occurring in low numbers throughout the rest of the sampling period. Psorophora columbiae reached its highest population density in June, with a smaller peak occurring in late July. Present from May through the end of September, Culex erraticus was the most abundant species collected with major peaks in mid-June and the end of July. Abundance of Culex salinarius followed the same general trend as that for Cx. erraticus, but with smaller numbers. The specimens were tested for a variety of arboviruses …
Date: May 2003
Creator: Bolling, Bethany G.
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Distance Education in the Preparation of Special Education Personnel: An Examination of Videoconferencing and Web-based Instruction

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This study examined the effectiveness of employing videoconferencing and Web-based instruction in the preparation of special education personnel. Due to the acute shortage of special education personnel, it was anticipated that the use of videoconferencing and online instruction would provide a convenient way for students to attend class without having to travel to the actual location of the educational site. Further, it was believed that this initiative would result in higher student enrollment in special education teacher certification programs, consequently leading to an increase of personnel in the field. Moreover, the increase in personnel would enhance the ability of educational institutions to address the dismal academic, social, and behavioral outcomes of students with disabilities. Information for the study was collected from surveys that investigated how students perceived the use of videoconferencing and web-based instruction in the preparation of special education personnel. Ninety-four graduate students responded to the videoconferencing surveys while 88 responded to the Web-based instruction surveys. Six respondents were randomly selected to participate in face-to-face interviews designed to investigate the effectiveness of both approaches. Findings indicated that videoconferencing and Web-based instruction are convenient ways for students to attend class although videoconferencing sites may not be conveniently located to all …
Date: August 2005
Creator: Bore, Julia Chelagat
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Conspicuous Consumption and American Political Behavior

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The following premise is based on the ideas of social theorists who have contributed to understanding the importance of image in society. This proposal argues that political participation is susceptible to exploitation in the form of conspicuous consumption as defined by Thorstein Veblen. The analyses that follow will test the degree to which Americans who demonstrate more traditional forms of conspicuous consumption also tend to show more activity in political venues. While the correlation of these two variables is not sufficient to demonstrate cause and effect, it may be significant enough to attract more researchers to this question: are Americans using political involvement to positively influence the way that their social status is perceived by others?
Date: August 2005
Creator: Bouressa, Andrea Kelly
Object Type: Thesis or Dissertation
System: The UNT Digital Library

The Construct Validity of Self-Reported Historical Physical Activity

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The purpose of this study was to determine the construct validity of self-reported historical walking, running, and jogging (WRJ) activity. The criterion measure was concurrent performance on a maximal treadmill test. Subjects completed a medical exam and treadmill test between the years 1976 and 1985, and completed a follow-up questionnaire in 1986. Questionnaire included an item that assessed WRJ for each year from 1976 through 1985. Data analysis included Spearman correlations, partial correlations, ANOVA, and ANCOVA. Results indicated self-reported historical WRJ can be assessed with reasonable validity when compared with concurrently measured treadmill performance, and there is no decay in the accuracy of this reporting for up to ten years in the past.
Date: May 2002
Creator: Bowles, Heather R.
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Condom Use Among College Students

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With the spread of the Human Immuno-Deficiency Virus and sexually transmitted diseases, it is extremely important for sexually active individuals to protect themselves properly if they decide to engage in sexual intercourse. Knowledge of HIV and the Acquired Immune Deficiency Syndrome has been associated with safer sexual practices, but knowledge alone does not totally explain risky sexual practices. This study examined how 154 college students' knowledge of HIV/AIDS, relationship status, perceptions of condom use, and perceptions of personal risk affect condom use during sexual intercourse. The impact of trust and love justifications along with the approval of peers were also examined. Perceptions of condom use and perceptions of personal risk were compared by gender and ethnicity; how perception of personal risk is related to condom use and condom use intentions was also examined. Condom use intention was found to be a significant predictor of condom use, and a significant difference of means for condom use intentions was reported between individuals who used condoms during their last experience with sexual intercourse and those who did not use condoms during their last sexual experience
Date: August 2001
Creator: Bradshaw, Joe W.
Object Type: Thesis or Dissertation
System: The UNT Digital Library

Characterizing the Municipal Solid Waste Stream in Denton, Texas

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Forty-two commercially collected dumpsters from Denton’s Municipal Solid Waste Stream were emptied, sorted and weighed to characterize the material types and make preliminary recycling policy recommendations. The general composition of Denton’s solid waste stream was not significantly different from the composition of the nation’s solid waste stream. Fifty-eight percent of the observed waste stream was recyclable. Paper made up the largest portion of recyclable materials and the "grocery" source category had more paper than any of the other five categories. Based on these findings, an incrementally aggressive approach is recommended to reduce certain types of wastes observed in the waste stream. This would include a Pay-As-You-Throw Program followed by an Intermediate Processing Center that can be converted to a Materials Recovery Facility.
Date: August 2000
Creator: Brady, Patricia D.
Object Type: Thesis or Dissertation
System: The UNT Digital Library