Everything and Nothing at the Same Time (open access)

Everything and Nothing at the Same Time

This paradoxically titled collection of poems explores what the blues and blindness has come to mean to the author.
Date: May 1999
Creator: Ballenger, Hank D.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
An Investigation of the Efficacy of Play Therapy with Young Children (open access)

An Investigation of the Efficacy of Play Therapy with Young Children

This study was designed to determine the effectiveness of play therapy as a method of intervention for children with a variety of emotional and behavioral problems. Specifically, the study was aimed at determining the effectiveness of play therapy in: (a) improving self-concepts of children with adjustment difficulties; (b) reducing internalizing behavior problems, such as withdrawal, somatic complaints, anxiety, and depression; (c) reducing externalizing behavioral problems such as aggression and delinquent behaviors; (d) reducing overall behavior problems, social problems, thought problems, and attention problems of children with adjustment difficulties; and (e) reducing parenting stress of parents of children who were experiencing adjustment difficulties.The experimental group consisted of 15 children who were experiencing a variety of adjustment difficulties and received play therapy once per week for 7 to 10 weeks. The control group consisted of 14 children who were experiencing a variety of adjustment difficulties and who were on a waiting list to receive intervention, and therefore, did not receive any treatment during the time of data collection. Experimental and control group children were administered the Joseph Pre-School and Primary Self-Concept Screening Test and parents of all participants completed the Child Behavior Checklist and the Parenting Stress Index at pretest and posttest …
Date: May 1999
Creator: Brandt, Marielle Aloyse
Object Type: Thesis or Dissertation
System: The UNT Digital Library
A Comparison of Economic Development in Latin America, Middle Eastern Europe and Asia in the 1990s (open access)

A Comparison of Economic Development in Latin America, Middle Eastern Europe and Asia in the 1990s

The 1990s were characterized by severe turbulence in the global economy. Economic and financial crises occurred in Latin America, Middle and Eastern Europe and Asia. This analysis distinguishes between the two socioeconomic criteria "transitional" and "emerging" region. Transitional countries are former centrally planned socialist economies and emerging countries former agricultural-oriented classical developing economies with mostly a history of military or some other kind of autocratic dictatorship. The resources for the analysis are data sets regarding investment, exchange rate behavior, government finance, international liabilities of monetary authorities and inflation. The study reveals macroeconomic patterns associated with economic development in each socioeconomic region. It is shown that similar patterns are responsible for successful and non-successful performance in each region. A comparison of different regions shows many parallels between emerging economies, but only little similarity between transitional economies.
Date: May 1999
Creator: Marktanner, Marcus
Object Type: Thesis or Dissertation
System: The UNT Digital Library
What Spins Away (open access)

What Spins Away

What Spins Away is a novel about a man named Caleb who, in the process, of searching for a brother who has been missing for ten years, discovers that his inability to commit to a job or his primary relationships is both the result of his history with that older missing brother, and his own misconceptions about the meaning of that history. On a formal level, the novel explores the ability of traditional narrative structures to carry postmodern themes. The theme, in this case, is the struggle for a stable identity when there is no stable community against which or in relationship to an identity might be defined.
Date: May 1999
Creator: Irwin, Keith
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Nucleotide Inhibition of Glyoxalase II (open access)

Nucleotide Inhibition of Glyoxalase II

The glyoxalase system mediates the conversion of methylglyoxal, a toxic ketoaldehyde, to D-lactic acid. The system is composed of two enzymes, glyoxalase I (Glo-I) and glyoxalase II (Glo-II), and exhibits an absolute requirement for a catalytic quantity of glutathione (GSH). Glo-I catalyzes the isomerization of a hemithioacetal, formed non-enzymatically from methylglyoxal and GSH, to the corresponding a -D-hydroxyacid thioester, s-D-lactoylglutathione (SLG). Glo-II catalyzes the irreversible breakdown of SLG to D-lactate and GSH. We have observed that ATP or GTP significantly inhibits the Glo-II activity of tissue homogenates from various sources. We have developed a rapid, one step chromatography procedure to purify Glo-II such that the purified enzyme remains "sensitive" to inhibition by ATP or GTP (Glo-II-s). Studies indicate that inhibition of Glo-II-s by nucleotides is restricted to ATP, GTP, ADP, and GDP, with ATP appearing most effective. Kinetics studies have shown that ATP acts as a partial non-competitive inhibitor of Glo-II-s activity, and further suggest that two kinetically distinguishable forms of the enzyme exist. The sensitivity of pure Glo-II-s to nucleotide inhibition is slowly lost on storage even at -80° C. This loss is accelerated at higher temperatures or in the presence of ATP. Kinetics studies on the resultant "insensitive" …
Date: May 1999
Creator: Gillis, Glen S
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Attribution to Deviant and Nondeviant Social Roles (open access)

Attribution to Deviant and Nondeviant Social Roles

A questionnaire was used to study causal attribution to social roles as influenced by perceived deviance of the role, instructions to identify with the role, and participant gender. The perceived deviance or nondeviance of the roles was determined by a pilot study. The roles were varied randomly through 12 hypothetical events, and identification or nonidentification instructions randomly assigned. The participants were 194 male and female university students. Participants gave the cause of each event and rated the cause on five dimensions: internality, externality, stability, globality, and controllability. Causal attribution to deviant social roles was found to result in a significantly higher across-scales score and to be more internal, less external, and more global than attribution to nondeviant roles. Participant gender showed an interaction with deviance overall and on the dimensions of stability and globality due to significantly higher ratings by women participants than those by men. Identification instructions did not produce a significant effect.
Date: May 1999
Creator: Rohlman, James E.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Progress or Decline: International Political Economy and Basic Human Rights (open access)

Progress or Decline: International Political Economy and Basic Human Rights

This dissertation is a cross-national, empirical study of human rights conditions in a dynamic international political economy. The scope of the examination covers 176 developed and developing countries from 1980 through 1993. Through evaluating the numerous theoretical aspects of human rights conceptualization, I draw upon Shue's framework and consider whether there are indeed "basic rights" and which rights should fit into this category. Further, I address the debate between those who claim that these rights are truly universal (applying to all nations and individuals) and those who argue that the validity of a moral right is relative to indigenous cultures. In a similar vein, I empirically investigate whether various human rights are interdependent and indivisible, as some scholars argue, or whether there are inherent trade-offs between various rights provisions. In going beyond the fixation on a single aspect of human rights, I broadly investigate subsistence rights, security rights and political and economic freedom. While these have previously been addressed separately, there are virtually no studies that consider them together and the subsequent linkages between them. Ultimately, a pooled time-series cross-section model is developed that moves beyond the traditional concentration on security rights (also know as integrity of the person rights) …
Date: May 1999
Creator: Milner, Wesley T.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
From Skeletons to Orchards (open access)

From Skeletons to Orchards

This thesis is a creative work that is segmented into three main phases in order to display the developing poetic growth and control in the work of Paul Andrew Thies. The first phase is titled "Skeletons and Rhinoceri." It was a phase where I focused on more classical forms of poetry, namely accentual and syllabical sonnets. This phase was greatly influenced by both Charles Baudelaire and William Butler Yeats. The second phase, titled "Clandestinies," was one in which I tried to develop a more dense form. Lord Byron and Pablo Neruda were the two main influences on my work at this time, largely in terms of imaginative exoticism and figurative energy. The third section of this thesis, titled "Graffiti in the Orchard," is an exploration of my current work as a poet. In this phase, Rainer Maria Rilke was the primary influence as I began to develop a more fluid and expressive style.
Date: May 1999
Creator: Thies, Paul Andrew
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Ethnically Mixed Individuals: Cultural Homelessness or Multicultural Integration? (open access)

Ethnically Mixed Individuals: Cultural Homelessness or Multicultural Integration?

Studies addressing racial/ethnic identity development have often overlooked the developmental cultural context. The impact of growing up with contradictory cultures has not been well explored. Immersion in multiple cultures may produce mixed patterns of strengths deficits. This study reviews the literature's currently inconsistent usage of the terms race, ethnicity, and culture; introduces the concept and theoretical framework of Cultural Homelessness; relates CH to multicultural integration; and develops two study-specific measures (included) to examine the construct validity of CH. The sample’s (N = 448, 67% women) racial, ethnic, and cultural mixture was coded back three generations using complex coding criteria. Empirical findings supported the CH-specific pattern of cognitive and social strengths with emotional difficulties: social adaptability and cross-cultural competence but also low self-esteem and shame regarding diff
Date: May 1999
Creator: Navarrete-Vivero, Veronica
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Analyzing the Financial Condition of Higher Education Institutions Using Financial Ratio Analysis (open access)

Analyzing the Financial Condition of Higher Education Institutions Using Financial Ratio Analysis

The problem concerned the financial indicators used to evaluate the financial condition of the six sister higher education institutions under the authority of the Board of Regents of Oklahoma Colleges. The purposes were to determine the financial ratios that best indicate financial condition; to calculate those financial ratios for the six designated Oklahoma higher education institutions; and to evaluate and compare the financial condition of the six institutions. This study attempted to further the use of financial ratio analysis as an objective addition to subjective studies that examine an institution's definition of its mission, objectives, and goals and its own assessment of the degree to which its resources allow it to attain those goals. The data were obtained from the Integrated Postsecondary Education Data System; the financial reports were audited by independent certified public accountants and presented to the Board of Regents of Oklahoma Colleges; and John Minter Associates, Inc., provided the national norms. The set of financial ratios identified provides a means to study a single higher education institution through trend analysis and in comparison to national norms. It also works well with a sample of homogeneous institutions with interinstitutional comparison. The techniques are intended to provide a general …
Date: May 1999
Creator: Buddy, Nancy J.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Mentoring in Nursing Doctoral Education: Processes, Perceptions, Problems and Prospects (open access)

Mentoring in Nursing Doctoral Education: Processes, Perceptions, Problems and Prospects

This study described the mentoring relationship between doctoral nursing students and their committee chairs. Twenty-two public university doctoral programs responded to a request for names and addresses of their doctoral candidates. The Major Professor Mentoring Scale was used to measure the mentoring relationship. The survey also included demographic and open-ended questions regarding the student-committee chair relationship. Surveys were mailed to 269 doctoral students with an 86% return rate. A principal components analysis was performed to identify the structure underpinning the relationship. The typical doctoral student in this sample was found to be a 44 year old Caucasian female, married with children, working full or part time while pursuing a PhD degree. Students traveled an average of 85 miles each way to campus and nearly half had selected their program based on its location. The typical committee chair was a Caucasian, tenured, associate or full professor between 46 and 69 years of age. The majority of chairs were married and had funded research projects. The students in the study reported knowing their chairs for an average of five years. The study revealed that mentoring is occurring in the majority of relationships between doctoral nursing students and their committee chairs. Students identified …
Date: May 1999
Creator: Kirkley, Debra Lynn
Object Type: Thesis or Dissertation
System: The UNT Digital Library
A Theory for the Measurement of Internet Information Retrieval (open access)

A Theory for the Measurement of Internet Information Retrieval

The purpose of this study was to develop and evaluate a measurement model for Internet information retrieval strategy performance evaluation whose theoretical basis is a modification of the classical measurement model embodied in the Cranfield studies and their progeny. Though not the first, the Cranfield studies were the most influential of the early evaluation experiments. The general problem with this model was and continues to be the subjectivity of the concept of relevance. In cyberspace, information scientists are using quantitative measurement models for evaluating information retrieval performance that are based on the Cranfield model. This research modified this model by incorporating enduser relevance judgment rather than using objective relevance judgments, and by adopting a fundamental unit of measure developed for the cyberspace of Internet information retrieval rather than using recall and precision-type measures. The proposed measure, the Content-bearing Click (CBC) Ratio, was developed as a quantitative measure reflecting the performance of an Internet IR strategy. Since the hypertext "click" is common to many Internet IR strategies, it was chosen as the fundamental unit of measure rather than the "document." The CBC Ratio is a ratio of hypertext click counts that can be viewed as a false drop measure that determines …
Date: May 1999
Creator: MacCall, Steven Leonard
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Current and Future Trends in Computer Use in Elementary School Settings (open access)

Current and Future Trends in Computer Use in Elementary School Settings

The study examined current and future trends in computer use in elementary school settings. A survey instrument was developed and validated for distribution to a random sample of 200 technology coordinators in the public school districts in the state of Texas from whom 95 responses were received. The survey instrument was used to obtain information about five areas of computer use in elementary schools. These areas are: physical configurations, instructional uses, implementation issues, training and staff development, and Internet use. The study found that all public school districts that participated in the study have acquired computer hardware in their elementary schools. In addition, some other advanced computer technology components are starting to be found in elementary schools, such as teacher workstations, CD-ROM, interactive video, computer multimedia, LCD panels, and laser printers. Respondents reported that elementary school teachers in their districts have incorporated computers into their classrooms as an instructional tool and many changes have occurred in teachers’ teaching styles due to computers. However, there are some problems that hinder the effective use of computers. The major problem is lack of training. A high percentage of respondents, 81.3%, indicated that the majority of their elementary school teachers had completed less than …
Date: August 1999
Creator: Al-Awidi, Hamed M.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Vicarious Traumatization, Secondary Traumatic Stress, and Burnout in Sexual Assault and Domestic Violence Agency Staff and Volunteers (open access)

Vicarious Traumatization, Secondary Traumatic Stress, and Burnout in Sexual Assault and Domestic Violence Agency Staff and Volunteers

Two constructs, vicarious trauma (VT) and secondary traumatic stress (STS), describe therapists’ reactions to clients’ traumatic material. VT (TSI Belief Scale [BSL]), emphasizes cognitive belief system changes resulting from cumulative exposure to survivors. STS, (Compassion Fatigue Self-test for Psychotherapists [CFST]) combines PTSD and burnout symptomatology explaining sudden adverse reactions to survivors. Burnout (BO; Maslach Burnout Inventory [MBI]), links emotional exhaustion, depersonalization, and deficient personal accomplishment to inadequate institutional supports in interpersonally demanding work. This study investigated BSL and CFST validity, counselor trauma history, and client exposure-related VT, STS, and BO in 105 trauma counselors. Results demonstrate concurrent validity between BSL and CFST; other results dispute adequate validity. BO, and client exposure were related. Traumatized counselors scored higher than non-traumatized counselors on CFST, BSL, and SCL-90-R.
Date: August 1999
Creator: Baird, Stephanie
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Affective Reactions and Psychosocial Functioning in the Course of Psycho-Educational Assessment (open access)

Affective Reactions and Psychosocial Functioning in the Course of Psycho-Educational Assessment

Every day, children throughout the United States are given psychological evaluations for many different clinical and psycho-educational purposes. Very little research has attempted to investigate children's responses to the experience of having intellectual and achievement tests administered. The goal of the current research was to explore the effect a psycho-educational evaluation has on children in areas of self-concept and anxiety. Dependent variables consisted of pre- and post-test measures of anxiety and self-concept. A total of 75 children in the 4th 5th and 6th grades were recruited after referral for evaluation and possible placement in the Talented and Gifted Program or Special Education. This study employed Analysis of Variance (ANOVA), t-tests, multiple regression analysis, and correlational analysis. Findings included initial evidence that children endorsed decreased anxiety after psycho-educational assessments rather than increased anxiety, suggesting that fear of unknown situations may be more anxiety provoking than the actual situation itself, potentially beneficial findings for psychology and psychometric professionals who evaluate children daily. Students endorsement of academic self-concept significantly predicted anxiety after a psycho-educational evaluation, indicating that students who feel capable in academic areas may endorse less anxiety after an evaluation than students who do not feel academically capable. Finally, negative verbal interaction …
Date: August 1999
Creator: Buenrostro, Martha
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Work Function Study of Iridium Oxide and Molybdenum Using UPS and Simultaneous Fowler-Nordheim I-V Plots with Field Emission Energy Distributions (open access)

Work Function Study of Iridium Oxide and Molybdenum Using UPS and Simultaneous Fowler-Nordheim I-V Plots with Field Emission Energy Distributions

The characterization of work functions and field emission stability for molybdenum and iridium oxide coatings was examined. Single emission tips and flat samples of molybdenum and iridium oxide were prepared for characterization. The flat samples were characterized using X-ray Photoelectron Spectroscopy and X-ray diffraction to determine elemental composition, chemical shift, and crystal structure. Flat coatings of iridium oxide were also scanned by Atomic Force Microscopy to examine topography. Work functions were characterized by Ultraviolet Photoelectron Spectroscopy from the flat samples and by Field Emission Electron Distributions from the field emission tips. Field emission characterization was conducted in a custom build analytical chamber capable of measuring Field Emission Electron Distribution and Fowler-Nordheim I-V plots simultaneously to independently evaluate geometric and work function changes. Scanning Electron Microscope pictures were taken of the emission tips before and after field emission characterization to confirm geometric changes. Measurement of emission stability and work functions were the emphasis of this research. In addition, use of iridium oxide coatings to enhance emission stability was evaluated. Molybdenum and iridium oxide, IrO2, were characterized and found to have a work function of 4.6 eV and 4.2 eV by both characterization techniques, with the molybdenum value in agreement with previous …
Date: August 1999
Creator: Bernhard, John Michael
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Information Seeking in a Virtual Learning Environment (open access)

Information Seeking in a Virtual Learning Environment

Duplicating a time series study done by Kuhlthau and associates in 1989, this study examines the applicability of the Information Search Process (ISP) Model in the context of a virtual learning environment. This study confirms that students given an information seeking task in a virtual learning environment do exhibit the stages indicated by the ISP Model. The six-phase ISP Model is shown to be valid for describing the different stages of cognitive, affective, and physical tasks individuals progress through when facing a situation where they must search for information to complete an academic task in a virtual learning environment. The findings in this study further indicate there is no relationship between the amount of computer experience subjects possess and demonstrating the patterns of thoughts, feelings, and actions described by the ISP Model. The study demonstrates the ISP Model to be independent of the original physical library environments where the model was developed. An attempt is made to represent the ISP model in a slightly different manner that provides more of the sense of motion and interaction among the components of thoughts, feelings, and action than is currently provided for in the model. The study suggests that the development of non-self-reporting …
Date: August 1999
Creator: Byron, Suzanne M.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
A Structural Equation Model of Contributing Factors to Adolescent Social Interest (open access)

A Structural Equation Model of Contributing Factors to Adolescent Social Interest

The focus of the present study was to test through SEM the relationships between family influences (FI) and school influences (SI) on factors hypothesized to be associated with adolescent social interest: school belonging (SB), extracurricular participation (EP), and peer/romantic involvement (PRI). The final model consisted of FI and SI that contributed to the expression of adolescent social interest. FI included parental communication and parental caring. SI consisted of teacher fairness. SB consisted of a child's self-reported feelings of belonging at school, EP included self-reported involvement in sports or academic clubs, and PRI consisted of self-reported desire for romantic involvement or desire for participation with others. The proposed model suggested that FI contributed significantly to self-reported SB, EP, and PRI. Additionally, it was hypothesized that SI would contribute significantly to SB and EP, but not to PRI. The data used in the current study were part of an existing data set collected as part of the National Longitudinal Study on Adolescent Health. The total sample size for the present study was 2,561 male and female adolescents aged 12-19 years. The data consisted of adolescent and parent self-report information. Results suggested a significant relationship between FI and self-reported SB and PRI. As …
Date: August 1999
Creator: Craig, Stephen E.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Customer Induced Uncertainty and Its Impact on Organizational Design (open access)

Customer Induced Uncertainty and Its Impact on Organizational Design

How firms facing environmental uncertainty should organize their activities remains an important and challenging question for today's managers and organizational researchers. Proponents of contingency theory have argued that organizations must adjust their activities to fit the level of environmental uncertainty to ensure long-term survival. Although much work has been done on contingency theory, it is clear that our understanding of uncertainty is far from complete. One important aspect of today's organizations is their focus on service, mass customization, and continuous innovation. This focus often results in the customer being brought either into the organization or at least into closer contact with it. Even though the literature provides numerous evidences of the increasing customer focus, it is yet to empirically explain how the complications of customer-organizational interactions might create uncertainty for contemporary organizations. The traditional measure of uncertainty still considers customers as an environmental factor causing demand uncertainty while ignoring the complex nature of customer and organizational encounters. Seeking to further refine the concept of uncertainty and focusing on the contemporary business phenomena, this study develops measures aspects of customer induced uncertainty and examines their relationships with three organizational design variables. Specifically, this study explains the complicated nature of customer - …
Date: August 1999
Creator: Chowdhury, Sanjib Kumar
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Profile of the Youth Self-Report Among South Texas Adolescents and the Potential Relationship to Pesticide Exposure (open access)

Profile of the Youth Self-Report Among South Texas Adolescents and the Potential Relationship to Pesticide Exposure

The potential for human exposure to pesticides exists particularly for agricultural workers (i.e. migrant workers) and individuals within close proximity to pesticide-sprayed crops (i.e. those living on or near agricultural farms). Children, through biology and behavior, may be more susceptible and vulnerable to exposure to pesticides than adults. The purpose of this study was to examine young populations particularly at-risk for occupational or accidental exposure to pesticides and determine associated behavioral, emotional, and physical symptoms. A total of 444 students from two South Texas school districts completed questionnaires assessing level of risk of exposure to pesticides and were categorized into at-risk and low risk categories. Physical, emotional, and behavioral symptoms were obtained using the Youth Self-Report. Children who were at-risk demonstrated significantly higher scores on the Youth Self-Report (YSR) in the areas of anxious/depressed, attention problems, social problems, somatic complaints, thought problems, withdrawal, internalizing behaviors, and total problem behaviors than children who were at lower risk of pesticide exposure. Odds ratios were obtained and suggested that children in the at-risk category were more five times more likely to score in the clinically significant range on the Attention Problems subscale, and three times more likely to score in the clinically significant …
Date: August 1999
Creator: Hagar, Kristy S.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Ethnic Identity, Gay Identity and Sexual Sensation Seeking: HIV Risk-taking Predictors Among Men of Color Who Have Sex with Men (open access)

Ethnic Identity, Gay Identity and Sexual Sensation Seeking: HIV Risk-taking Predictors Among Men of Color Who Have Sex with Men

This study examined relationships among ethnic identity, gay identity, sexual sensation seeking, and HIV risk-taking behaviors among 302 men of color recruited from gay bars, bathhouses, community agencies, and the 1998 United States Conference on AIDS. The sample included 24% African American, 28% Latino, 25% Asian/ Pacific Islander, 19% Caucasian, 1% American Indian, and 3% other ethnicity. Logistic regression analysis identified sexual sensation seeking, having an undefined gay identity, being in a sexually exclusive relationship, not being HIV seronegative, and length of stay in the country (for those born overseas) as significant predictors of unprotected anal intercourse (insertive and penetrative) among men of color who have sex with men.
Date: August 1999
Creator: Géliga-Vargas, Jesús A.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Night of No Exile (open access)

Night of No Exile

Night of no Exile is a collection of poems preceded by a critical article entitled "‘Exile seems both a blessing and a curse': A Blissful Reading of Li-Young Lee's Poetry." That article discusses Lee's quest to achieve communication, truth, and transcendence through poetic language and concludes that he finally reaches his goal through a leap from narrative poetry to lyricism. The "exile" alluded to in the title of the article is not only geographic, but also interioran exile due to the natural limitations of all languages, and which can be bridged only in linguistic ways. Lee's solution to that problem (lyricism) turns his poetry into what Roland Barthes would call "a text of bliss," a text that manages to deeply destabilize language, while simultaneously achieving a new kind of meaning. In the main body of the manuscript, the first section contains short love lyrics. The second section, "Night of no Exile," is an attempt at the demanding genre of the longer lyric poem. The third section uses short lyrics to explore various topics, such as discovering one's identity, friendship and solidarity between women, family history, and childhood memories. Finally, the last section includes poems, four of them longer, attempting to …
Date: August 1999
Creator: Jones, Marie C.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Explorations with Polycarbocyclic Cage Compounds (open access)

Explorations with Polycarbocyclic Cage Compounds

A variety of novel cage-functionalized pyridyl containing crown ethers have been prepared for use in selective alkali metal complexation studies. A highly preorganized, cage-functionalized cryptand also has been designed and has been synthesized for use as a selective Li+ complexant. The alkali metal picrate extraction profiles of these cage-functionalized crown ethers also have been studied. Novel cage-functionalized diazacrown ethers have been prepared for selective alkali metal complexation studies. Alkali metal picrate extraction experiments have been performed by using this new class of synthetic ionophores to investigate the effects of cage-annulation and the influence of N-pivot lariat sidearms upon their resulting complexation properties. Novel pyridyl containing calix[4]arene receptors were prepared. Analysis of their respective 1H NMR and 13C NMR spectra suggests that calix[4]arene moieties in the ligand occupy the cone conformation. The complexation properties of these host molecules were estimated by performing a series of alkali metal picrate extraction experiments. An optically active cage-functionalized crown ether which contains a binaphthyl moiety as the chiral unit was prepared. The ability of the resulting optically active crown ether to distinguish between enantiomers of guest ammonium ions (i.e., phenylethylamonium and phenylglycinate salts) in transport experiments was investigated. Hexacyclo[11.2.1.02,12.05,10.05,15.010,14]hexadeca-6,8-diene-4,11-dione was prepared from hexacyclo[7.4.2.01,9.03,7.04,14.06,15] pentadeca-10,12-diene-2,8-dione. Unanticipated …
Date: August 1999
Creator: Chong, Hyun-Soon
Object Type: Thesis or Dissertation
System: The UNT Digital Library
Toward an Ecofeminist Environmental Jurisprudence: Nature, Law, and Gender (open access)

Toward an Ecofeminist Environmental Jurisprudence: Nature, Law, and Gender

This thesis develops a legal theory reflecting the insights of feminism and environmental philosophy. I argue that human beings are not ontologically separate, but embedded in webs of relationality with natural others. My primary purposes are to 1) delineate ways in which institutions of modernity (such as law and science) have precipitated ecosocial crisis through the attempt to dialectically enforce mastery and control over nature and women; and 2) explore alternate political forms and ontologies which challenge the classical liberalist view of the (human) individual as a radically isolated, discrete, autonomous being. My overarching theme is that law functions as a narrative that can both hinder and enhance the promotion of ecological ideas, and how ecofeminism can contribute to transformative projects of environmental philosophy and feminist law.
Date: August 1999
Creator: Mallory, Chaone
Object Type: Thesis or Dissertation
System: The UNT Digital Library