Recently, 3D printing has received increasing attention for the fabrication and assembly of electrodes for batteries due to the freedom of creating structures in any shape or size, porosity, flexibility, stretchability, and chemistry. Particularly, zinc ion batteries (ZIBs) are favored due to high safety, cheap materials cost, and high volumetric capacity (5,849 mAh/cm3), however, rapid evaporation of Zn due to low melting temperature has limited its 3D printability via conventional laser-based additive manufacturing technique. Here, we develop a printable ink for the fabrication of flexible and 3D printed Zn anode with varied surface areas using the direct ink writing (DIW) method. Our 3D printed porous and high surface area Zn anode structures effectively suppressed the dendrite growth while providing high Zn ion diffusion towards the cathode to significantly enhance the performance of ZIB. By varying filament distancing and path, we 3D printed zinc anode structures with different active surface areas, surface area to volume ratio, porosity, flexible and multiple layer structures that can be incorporated on any device. Carbon in the composite improved conductivity, and mechanical stability of 3D printed zinc anode. Our 3D printed composite anodes allowed flexible designing of batteries surpassing conventional battery designs such as coin cells …

The Abraham solvation model (ABSM) is an experimentally derived predictive model used to help predict various solute properties. This work covers various uses for the ABSM including predicting molar enthalpies of vaporization, predicting solvent coefficients for two new solvents (2,2,5,5-tetramethyloxolane and diethyl carbonate), predicting values for multiple new ionic liquids (ILs). This work also introduces a novel method for updating IL ABSM parameters by updating cation- and anion-specific values using linear algebra and binary matrices.

Children with disabilities are three to four times more likely to be abused than their non-disabled peers due to the impact of challenges related to behavior, cognition, language, social skills, and communication skills. In September of 2018, the Council for Exceptional Children (CEC) specifically noted the need to establish maltreatment prevention and response curricula and promote research and advocacy surrounding maltreatment of children with disabilities. One common curriculum recommended is Kidpower®. While Kidpower® shows promise in increasing people safety skills and offers some basic accommodations for use with disabled populations, a complete accommodation plan for deaf or hard of hearing students has not been developed. The purpose of this study was to explore how Kidpower® curriculum could be accommodated to meet the unique needs of deaf and hard of hearing students from the perspective of the deaf education community, including deaf adults, deaf education teachers, deaf education teacher preparation faculty, and parents with deaf or hard of hearing children. A combination of focus groups and interviews were utilized to review lessons and homework from the Kidpower® curriculum. Participants gave feedback on obstacles and ideas for accommodations and modifications that would mediate the challenges. Data were inductively coded and analyzed for …

This document examines current practices and opportunities in the music performance field related to artistic citizenship, community engagement, and the field of teaching artistry. The relationship of musicians to their audiences and communities has shifted significantly in the twenty-first century, and there is an increasing need to redefine the essential skills of the professional musician. Derived from the field of teaching artistry, the concept of "activating artistry" suggests that our greatest strength and power as artists lies in drawing out individual artistic expression in other people, and it is with this power that artists as a workforce can create meaningful change in society. This intention could be manifested in many different contexts during the course of a given music career, however, developing the tool kit necessary for engaging in such work is not widely emphasized in the training of musicians. What tools can be provided for students and professionals to help them navigate both traditional and evolving career paths in music? How are bassoonists doing as a field in addressing the imperative of community engagement and artistic citizenship? How might we explore more collaborative ways to engage with our diverse communities – ways that value their perspectives? These questions guide …

Additive friction stir deposition (AFSD) of AZ31B magnesium alloy was conducted to examine evolution of grain structure, phases, and crystallographic texture. AFSD was carried out using a hollow tool made from tool steel at a constant rotational velocity of 400 rpm on the AZ31B base plate. Bar stock of AZ31B was utilized as a feed material. The linear velocity of the tool was varied in the range of 4.2-6.3 mm/s. The feed rate of the material had to be maintained at a half value compared to the corresponding linear velocity for the successful deposition. The layer thickness and length of the deposits were kept constant at 1 mm and 50 mm respectively. The tool torque and actuator force values were recorded during the process and for calculation of the average input energy for each processing condition. Temperature during the AFSD experiments was monitored using a type k thermocouple located 4 mm beneath the deposition surface at the center of the deposition track. The average input energy values showed a decreasing trend with increasing tool linear velocity. The temperature values during deposition were ∼0.7 times the liquidus of the alloy. The deposited material then was examined by laser microscope and profilometer, …

Seminaries in the United States have for more than two centuries sought to equip ministerial leaders for service within the community of faith. And yet these institutions have traditionally been the focus of very little quantitative research. This lack of data is particularly noteworthy given the existential crises many seminaries currently face, especially regarding their flagship Master of Divinity (MDiv) programs. Among seminary leadership, a common response to declining MDiv enrollment has been to decrease the length of the program, which historically required at least 90 credit hours. The purpose of this quantitative study was to explore change at the Association of Theological Schools member institutions (AMIs) between 2000–2019 through the lens of these credit-hour reductions. Longitudinal data from 113 AMIs were analyzed to examine the relationship between a variety of financial, enrollment, and institutional characteristics and the likelihood that an AMI would reduce its required MDiv credit hours. Results from an event history analysis revealed that, all else being equal, experiencing an increase in total revenues reduced an AMI's likelihood of making a reduction, while being a middle-age institution (founded 1870–1959) and having a higher percentage of peer institutions that made a change increased the likelihood of making a …

Adult attachment has been found to play an important role for romantic relationship satisfaction. Specifically, the existent literature generally suggests that attachment anxiety is negatively related to relationship satisfaction. However, the underlying mechanism for this link still needs further exploration. The present study examined the direct and indirect effect of attachment anxiety on relationship satisfaction via two distinct relationship commitment variables: constraint commitment and dedication commitment. The final sample included 146 unmarried participants who were in a romantic relationship for at least three months. Results of multiple regression analyses on the indirect effect model indicated that attachment anxiety had a significant direct effect on relationship satisfaction as well as a significant indirect effect on relationship satisfaction via constraint commitment. However, the hypothesized indirect effect through dedication commitment was not supported. Findings are discussed from the adult attachment perspective. Counseling implications, limitations, and future research directions are outlined.

A systematic development of 2D alloy catalyst with synergistic performance of high lithium polysulfide (LiPS) binding energy and efficient Li+ ion/electron conduction is presented. The first section of work found that Li+ ions can flow through the percolated ion transport pathway in polycrystalline MoS2, while Na+ and K+ ions can easily flow through the percolated 1D ion channel near the grain boundaries. An unusually high ionic conductivity of extrinsic Li+, Na+, and K+ ions in 2D MoS2 film exceeding 1 S/cm was measured that is more than two orders of magnitude higher than those of conventional solid ionic materials, including 2D ionic materials. The second section of this dissertation focus on catalyzing the transformation of LiPSs to prevent the shuttle effect during the battery cycling by synthesizing 2H (semiconducting) – 1T (metallic) mixed phase 2D Mo0.5W0.5S2 alloy on CNF paper, using two step sputtering and sulfurization method. The lithium sulfur (Li-S) battery cell assembled with the 2D Mo0.5W0.5S2/CNF/S cathode shows a high specific capacity of 1228 mAh g-1 at 0.1C and much higher cyclic stability over 4 times as compared to the pristine cathodes. The high LiPSs binding energy of catalyst efficiently prevents the shuttling effect and corrosion of Li …

The interest toward Mars exploration has been considerably increasing due to also the successful deployment of the Perseverance rover and the continuous tests developed by SpaceX's launch vehicle, Starship. While the Mars 2020 mission is currently in progress, the first controlled flight on another planet have been proven in April 2021 with the vertical take-off and landing of the Ingenuity rotorcraft on Mars. In addition, the rotorcraft Dragonfly is expected to achieve the same endeavor in Titan, the largest moon of Saturn, by 2036. Continuous efforts have been oriented toward the development of new technologies and aircraft configurations to improve the performance of current proposed designs to achieve powered flight in different planetary bodies. This thesis work is a preliminary study to develop a comprehensive analysis over the generation of optimum airfoil geometries to achieve vertical flight in environments where low Reynolds numbers and Mach number equal to 0.2 and 0.5.

Air corridors are an integral part of the advanced air mobility infrastructure. They are the virtual highways in the sky for transportation of people and cargo in the controlled airspace at an altitude of around 1000 ft. to 2000 ft. above the ground level. This paper presents fundamental insights into the design of air corridors with high operational efficiency as well as zero collisions. It begins with the definitions of air cube, skylane or track, intersection, vertiport, gate, and air corridor. Then, a multi-layered air corridor model is proposed. Traffic at intersections is analyzed in detail with examples of vehicles turning in different directions. The concept of capacity of an air corridor is introduced along with the nature of distribution of locations of vehicles in the air corridor and collision probability inside the corridor are discussed. Finally, the results of simulations of traffic flows are presented.

This thesis targets at providing an algebraic method to indicate network behaviors. Furthermore, for a signed-average consensus problem of the system behaviors, event-triggering signed-average algorithms are designed to reduce the communication overheads. In Chapter 1, the background is introduced, and the problem is formulated. In Chapter 2, notations and basics of graph theory are presented. It is known that the terminal value of the system state is determined by the initial state, left eigenvector and right eigenvector associated with zero eigenvalue of the Laplacian matrix. Since there is no mathematical expression of right eigenvector, in Chapter 3, mathematical expression of right eigenvector is given. In Chapter 4, algebraic trait for structurally balanced property of a node is proposed. In Chapter 5, a method for characterization of collective behaviors under directed signed networks is developed. In Chapter 6, dynamic event-triggering signed-average algorithms are proposed and proved for the purpose of relieving the communication burden between agents. Chapter 7 summarizes the thesis and gives future directions.

This dissertation presents an assortment of research aimed at understanding the composition-dependence of deformation behavior and the response to thermomechanical processing, to enable efficient design and processing of low stacking fault energy (SFE) high entropy alloy (HEAs). The deformation behavior and SFE of four low SFE HEAs were predicted and experimentally verified using electron microscopy and in-situ neutron diffraction. A new approach of employing a minimization function to refine and improve the accuracy of a semi-empirically derived expression relating composition with SFE is demonstrated. Ultimately, by employing the minimization function, the average difference between experimental and predicted SFE was found to be 2.64 mJ m-2. Benchmarking with currently available approaches suggests that integrating minimization functions can substantially improve prediction accuracy and promote efficient HEA design with expansion of databases. Additionally, in-situ neutron diffraction was used to present the first in-situ measurement of the interspacing between stacking faults (SFs) which were correlated with work hardening behavior. Electron transparent specimens (< ~100 nm thick) were used in order to resolve nanoscale planar faults instead of the thicker sub-sized specimens (on the order of millimeters in thickness) which exhibit the classical stages III work hardening behavior characteristic of low SFE metals and alloys. …

The dissertation seeks to rediscover Julius Schloss, a German Jewish composer victimized by the Nazis. Except for the promising start of his career in his early years, Schloss suffered a hard life as an exiled refugee. However, his unusual experiences inspired him to compose two Chinese Rhapsodies during his last years of exile in Shanghai, in which he synthesized Western composition techniques and Chinese folk materials, amalgamating influences from both Western and Eastern music cultures. Focusing on Schloss's First Chinese Rhapsody, the dissertation explores how Schloss links the new to the old, the West to the East, through an analysis of the way he employs Chinese folk song material and serial polyphonic voice-leading in his post-tonal musical language. Since the Rhapsody has both serial and polyphonic voice-leading aspects, both are analyzed, showing how they are integrated in the form.

In this work, we have performed comparative evolutionary analysis, functional genomics analysis, and machine learning analysis to identify the molecular factors that discriminate between multipartite and unipartite bacteria, with the goal to decipher taxon-specific factors and those that are prevalent across the taxa underlying the these traits. We assessed the roles of evolutionary mechanisms, namely, horizontal gene transfer and gene gain, in driving the divergence of bacteria with single and multiple chromosomes. In addition, we performed functional genomic analysis to garner support for our findings from comparative evolutionary analysis. We found genes such as those encoding conserved hypothetical protein DR_A0179 and hypothetical protein DR_A0109 in Deinococcus radiodurans R1, and Putative phage phi-C31 gp36 major capsid-like protein and hypothetical protein RSP_3729 in Rhodobacter sphaeroides 2.4.1, which are located on accessory chromosomes in both bacteria and were not found in the inferred ancestral sequences, and on the primary chromosomes, as well as were not found in their closest relatives with single chromosome within the same clade. These genes emphasize the important potential roles of the secondary chromosomes in helping multipartite bacteria to adapt to specialized environments or conditions. In addition, we applied machine learning algorithms to predict multipartite genomes based on gene …

The present studies determine the accumulation of persistent organic pollutants (POPs) in three pinniped species, evaluate the relationship with relevant biomarkers of exposure, and calculate toxic effect thresholds. Stranded harp and hooded seals were found to be accumulating PBDEs at levels which could pose a based on threshold levels determined in this study. Northern fur seals are accumulating all three classes of POPs (PCBs, PBDEs, and OCPs) with significant relationships being seen with blubber percent lipid. Correlations between contaminant concentrations and expression levels of relevant biomarkers were seen potentially indicating an effect on multiple pathways. Overall risk can be hard to determine due to factors such as sex and age. Broad threshold response values and hazard quotients were calculated for toxic effect endpoints in pinnipeds. Overall these results suggest that certain populations of pinnipeds are at high risk of experiencing toxic effects due to POP exposure, but it is important to understand effects even at lower concentrations. The relationship between exposure, toxic effects, and other stressors, both environmental and physiological, can impact the overall fitness and survival of pinnipeds.

Low Earth orbit (LEO) satellite systems have been proposed as a resource for combating the challenges in 5G network coverage and expanding connectivity to a global realm. This research focuses on the current architecture of LEO satellite constellations, with an emphasis on satellite coverage, visibility patterns and coordination schemes. Key-elements of integrating LEO satellites into the eMBB component of 5G are presented and a breakdown of potential link channel characteristics and physical layer performance metrics are described. The produced information allows for a justified analysis on the conceptualized integration.

As technologies for learning become increasingly available in K-12 schools, the role and responsibilities of campus principals continue to evolve. Incorporating technologies in schools requires shifts in practices, the development of new skills, and in some cases, changes in the mindset of stakeholders. Schools should be capable of absorbing the knowledge and creating the systemic structures required for the implementation ICTs. The purpose of this study was to research the principals' perspective to lead the implementation of ICTs for learning in public schools. As campus leaders, principals are increasingly required to support the utilization of ICTs for classroom instruction. It is of particular importance, therefore, to study and explore the needs school principals identify to lead the implementation of technologies for learning. More specifically, the goal was to gather relevant data to analyze topics that campus principals believe positively and negatively influence the implementation of ICTs in schools.

This research explores the relationship between narrative, empathy and anxiety in art museum education. The study begins from my personal experience with anxiety and is methodologically rooted in narrative inquiry and friendship as method. In this study, I propose a creative method of narrative postcard writing called (fe)mail – rooted in a feminist ethic of care that seeks to understand and empathize with the experience of others through correspondence. This research asks relevant questions about the future of art museum programming for mental illness and the act of writing (fe)mail as a reflective practice for academics and educators in the field of social science. In my narrative analysis of the program and the data, I also problematizes my role as researcher, educator and friend throughout the study by considering my own biases, expectations and personal educator agenda. The study is divided into two parts. The first comprises correspondence and analysis of (fe)mail between myself and my best friend/co-participant, Atleigh. In Part I, I conduct a narrative analysis of the (fe)mail data produced between us in order to answer the following questions: What qualities of (fe)mail will appear in the exchange? Can (fe)mail be used as a tool for self-care during …

This thesis demonstrates a queer perspective stemming from a qualitative analysis of data gathered in interviews with LGBTQ+ people to analyze a transforming ethos of gayborhoods and queer desires. In particular, the research focuses on the interactive relationship between self-identified lesbian, gay, bisexual, transgender, and queer (LGBTQ+) participants; the cyberspace(s) of LGBTQ+ mobile-dating applications (apps); and tangible urban places. The topic of gayborhood demise and whether such places are worth saving has been debated by scholars and journalists for the last decade. The demise of gayborhoods is often thought to be a symptom of neoliberal urban processes such as gentrification within the context of the post-gay era and broader societal acceptance of homosexuality. This means the question of "if the gayborhood is worth saving" is inherently imbedded in an assumption that homosexuality is not viewed or treated as different or lesser than heterosexuality. In this imagined post-gay era, gayborhoods are declining because the dangers posed to the LGBTQ+ population are purported to no longer exist, so there is no longer a need for designated queer and/or safe places. This research destabilizes the assumptions embedded within the conception of the post-gay era by asking whether the gayborhood meets the needs and …

This research looks thoughtfully and deeply at the relationship between art education and signs, as defined by the French philosopher Gilles Deleuze (1964/1998). Signs, as articulated by Deleuze (1964/1998), are violent disruptions to our way of understanding the world, causing us to think again and/or re-consider what we once knew (or thought we knew). This study looks generatively at how these kinds of disruptive and disorienting moments might be mined for possibilities in art education and remind us of our own relationality. As a post-qualitative lived inquiry, it asks how might art education be-with apprenticeship to signs and what might art education do-with sign-encounters? Using the theoretical lens of transcendental empiricism and new materialism, this study considers how art educators might hold open the space of sign-encounters for oneself and one's students by turning towards the rhizomatic cut and staying with uncertainty. It is focused on the doing-with, making-with, and thinking-with of art, pedagogy, and philosophy/theory, investigating their deep entanglements in spaces of disruption and ultimately developing frame-works for engaging in this kind of work in the classroom. Drawing from Erin Manning and Brian Massumi's theory of research-creation, this research was experienced in an emergent, layered, and complex way over …

With the advent of autonomous systems and deep learning systems, safety pertaining to these systems has become a major concern. The existing failure analysis techniques are not enough to thoroughly analyze the safety in these systems. Moreover, because these systems are created to operate in various conditions, they are susceptible to unknown safety issues. Hence, we need mechanisms which can take into account the complexity of operational design domains, identify safety issues other than failures, and expose unknown safety issues. Moreover, existing safety analysis approaches require a lot of effort and time for analysis and do not consider machine learning (ML) safety. To address these limitations, in this dissertation, we discuss an artificial-intelligence driven model-based methodology that aids in identifying unknown safety issues and analyzing ML safety. Our methodology consists of 4 major tasks: 1) automated model generation, 2) automated analysis of component state transition model specification, 3) undesired states analysis, and 4) causal factor analysis. In our methodology we identify unknown safety issues by finding undesired combinations of components' states and environmental entities' states as well as causes resulting in these undesired combinations. In our methodology, we refer to the behaviors that occur because of undesired combinations as off-nominal …

The purpose of this study was to collect design requirements from women engineers on artificial intelligence teammates such as Microsoft Teams, Slack, and Trello. A mixed methods research design was used for this study with an online survey and semi-structure interviews. The study results revealed design requirements from women engineers including solutions to sociotechnical issues that could arise from artificial intelligence teammates in the workplace. The results showed various ways women engineers collaborate in the workplace with and without artificial intelligence. Additionally, women engineers' attitude towards artificial intelligence was examined to identify if there was a correlation to self-efficacy. This research study fills a previous study gap that solicited design requirements from research scientists, by soliciting practitioners. Practitioners such as women engineers are underrepresented in the workplace, and they could benefit from an artificial intelligence teammate with their design requirements. Finally, this study contributes to the information science literature on collaborative information seeking, artificial intelligence design, and engineers' information seeking behaviors.

In his Art of Piano Playing, the renowned Russian pianist and teacher Heinrich Neuhaus asserts that the concept of an "artistic image" can give musical meaning to the score, help pianists to understand the musical content of a composition, and help students to find pianistic expression in the details. The concept of artistic image can be applied in pedagogy, guiding young pianists to learn content and organize their practice. The artistic image is the picture of a musical idea and the musical language, which comes from melody, phrasing, musical structure, and the emotional and poetic content. Twelve Children's Pieces of Medium Difficulty, Op. 31, is one of the important works for young pianists by Reinhold Glière (1875–1956). The set has emotional characteristics that allow intermediate young pianists to grasp its rich content and then develop technically. His piano works have been little studied by scholars as part of a pedagogical approach. This pedagogical guide uses the concept of artistic image in Glière's work to help young pianists, or their teachers, prepare this work thoroughly and perform it successfully on the stage.

This study aimed to gain insight into the clinical practices and attitudes of currently practicing play therapists working with children with a parent with a substance use disorder. Participants in the study were play therapists credentialed by the Association for Play Therapy, either as a Registered Play Therapist™ or Registered Play Therapist-Supervisor™. A total of 198 play therapists participated in the study. Results demonstrated that variables including prior education, caseload of children affected by parental substance use, and the number of years since obtaining a mental health licensure explained 16% of the variance in participant attitude scores on the Drug and Drug Problems Perceptions Questionnaire (DDPPQ). Specifically, education (β = -.335, rs2 = .884, p < .001) was found to be a significant predictor of play therapist attitudes towards substance users as it explained 88% of the variance accounted for in the effect. Additionally, although not found to be significant, caseload (β = -.134, rs2 = .325, p = .058) was found to explain 33% of the variance accounted for in the effect. This initial exploration of play therapists' attitudes towards substance users provides strong evidence towards the importance of education and training in substance use disorders. Further exploration of …