A systematic development of 2D alloy catalyst with synergistic performance of high lithium polysulfide (LiPS) binding energy and efficient Li+ ion/electron conduction is presented. The first section of work found that Li+ ions can flow through the percolated ion transport pathway in polycrystalline MoS2, while Na+ and K+ ions can easily flow through the percolated 1D ion channel near the grain boundaries. An unusually high ionic conductivity of extrinsic Li+, Na+, and K+ ions in 2D MoS2 film exceeding 1 S/cm was measured that is more than two orders of magnitude higher than those of conventional solid ionic materials, including 2D ionic materials. The second section of this dissertation focus on catalyzing the transformation of LiPSs to prevent the shuttle effect during the battery cycling by synthesizing 2H (semiconducting) – 1T (metallic) mixed phase 2D Mo0.5W0.5S2 alloy on CNF paper, using two step sputtering and sulfurization method. The lithium sulfur (Li-S) battery cell assembled with the 2D Mo0.5W0.5S2/CNF/S cathode shows a high specific capacity of 1228 mAh g-1 at 0.1C and much higher cyclic stability over 4 times as compared to the pristine cathodes. The high LiPSs binding energy of catalyst efficiently prevents the shuttling effect and corrosion of Li …

The present study systematically reviewed and statistically summarized the current body of literature on the relationship between maternal health literacy and maternal sensitivity, and the effect of these two variables on mothers' care and decision making on distal attachment outcomes. In so doing, a systematic review of the extant peer-reviewed, published literature examining the effectiveness of interventions in effort to improve health literacy and maternal sensitivity, with a focus on increasing the quality of mother-preterm infant attachment outcomes, was undergone. This was followed by four multilevel random effects meta-analyses. Results indicated that mothers who participated in health literacy (maternal sensitivity) interventions had, on average, higher attachment quality, in comparison to those who did not participate. Additionally, maternal age was found to be a statistically significant predictor of the overall average effect size. This suggests that maternal health literacy may be a yet unexplored correlate of mother-preterm infant attachment outcomes.

Preadolescence is a time of emotional, physical, social, and relational changes, which can lead to mental health concerns. Parents of preadolescents also experience changes within their roles as parents, and both parents and preadolescents experienced a wide range of changes and challenges during the COVID-19 pandemic. A mental health intervention focused on enhancing the parent-child relationship among parents of preadolescents is important for overall family functioning. This phenomenological study explored the experiences of parents of preadolescents after participating in a virtual child-parent relationship therapy (CPRT) intervention. Participants were seven parents ages 35 to 56 years-old with preadolescent children between the ages of 9 to 12 years-old. Semi-structured interviews were conducted following the CPRT intervention and analyzed. Six themes were found, including impact of group on learning, child's engagement with parent, child qualities, parent's understanding of self, importance of parent-child relationship, and integration of CPRT skills. The emerging themes indicated that the seven participants experienced changes in themselves, in their child, and in their parent-child relationships. Participants discussed their experiences with the virtual format and their integration of CPRT skills. The participants also reported feeling closeness and support from other group members, even with the virtual format. Findings from this study …

Mechanical pressure offers unique control over the energy landscape of chemical reactions, opening up pathways that are inaccessible through conventional thermochemistry. We hypothesize that the reduced dimensionality defines the conformational space of the high-pressure reaction, giving rise to new selectivity that is unavailable in 3D systems. Here, we demonstrate this concept through the pressure-controlled topochemical polymerization of the diacetylene molecule deca‐3,5‐diyn‐1‐amine (DDA) incorporated in the two-dimensional (2D) perovskite [DDA]2PbBr4. Compression at 3 GPa drives the first topochemical polymerization through 1,2 addition, forming a polyene product at room temperature. The reaction is initiated by the mechanical bending of the linear DDA molecule, a mechanism fundamentally different from the 1,4-addition in 3D solids. Importantly, pressure hinders the second 1,2-addition by disfavoring the gauche conformation between the remaining acetylene groups, allowing for the selective formation of polyene versus polyacene products. We characterize the reaction mechanisms and products using spectroscopies (Raman, X-ray photoelectron, ultraviolet-visible), X-ray diffraction and density-functional theory simulations. These results highlight the important role of dimensionality in high-pressure chemistry, and offers a new paradigm for creating low-dimensional functional materials.

This thesis targets at providing an algebraic method to indicate network behaviors. Furthermore, for a signed-average consensus problem of the system behaviors, event-triggering signed-average algorithms are designed to reduce the communication overheads. In Chapter 1, the background is introduced, and the problem is formulated. In Chapter 2, notations and basics of graph theory are presented. It is known that the terminal value of the system state is determined by the initial state, left eigenvector and right eigenvector associated with zero eigenvalue of the Laplacian matrix. Since there is no mathematical expression of right eigenvector, in Chapter 3, mathematical expression of right eigenvector is given. In Chapter 4, algebraic trait for structurally balanced property of a node is proposed. In Chapter 5, a method for characterization of collective behaviors under directed signed networks is developed. In Chapter 6, dynamic event-triggering signed-average algorithms are proposed and proved for the purpose of relieving the communication burden between agents. Chapter 7 summarizes the thesis and gives future directions.

The interest toward Mars exploration has been considerably increasing due to also the successful deployment of the Perseverance rover and the continuous tests developed by SpaceX's launch vehicle, Starship. While the Mars 2020 mission is currently in progress, the first controlled flight on another planet have been proven in April 2021 with the vertical take-off and landing of the Ingenuity rotorcraft on Mars. In addition, the rotorcraft Dragonfly is expected to achieve the same endeavor in Titan, the largest moon of Saturn, by 2036. Continuous efforts have been oriented toward the development of new technologies and aircraft configurations to improve the performance of current proposed designs to achieve powered flight in different planetary bodies. This thesis work is a preliminary study to develop a comprehensive analysis over the generation of optimum airfoil geometries to achieve vertical flight in environments where low Reynolds numbers and Mach number equal to 0.2 and 0.5.

This dissertation tested the hypothesis that energy transferred from a plasma or plume can be used to optimize the structure, chemistry, topography, optical and electrical properties of pulsed laser deposited and sputtered thin-films of ZnO, a-BOxNy, and few layer 2H-WS2 for transparent electronics devices fabricated without substrate heating or with low substrate heating. Thus, the approach would be compatible with low-temperature, flexible/bendable substrates. Proof of this concept was demonstrated by first optimizing the processing-structure-properties correlations then showing switching from accumulation to inversion in ITO/a-BOxNy/ZnO and ITO/a-BOxNy/2H-WS2 transparent MIS capacitors fabricated using the stated processes. The growth processes involved the optimization of the individual materials followed by growing the multilayer stacks to form MIS structures. ZnO was selected because of its wide bandgap that is transparent over the visible range, WS2 was selected because in few-layer form it is transparent, and a-BOxNy was used as the gate insulator because of its reported atomic smoothness and low dangling bond concentration. The measured semiconductor-insulator interfacial trap properties fall in the range reported in the literature for SiO2/Si MOS structures. X-ray photoelectron spectroscopy (XPS), Hall, photoluminescence, UV-Vis absorption, and X-ray diffraction (XRD) measurements investigated the low-temperature synthesis of ZnO. All films are nanocrystalline with …

Many academic institutions are tasked with trying to improve the usability of their online educational support technologies such as ePortfolios, intelligent websites, and other interface technology to make them as efficient as possible to meet the requirements of their end users. This is particularly important for the academic institutions during times and situations when they may not have a live human presence available to respond to various inquiries from their end users about the technology. The challenges of an academic institution in making its ePortfolios viable can cost itself, its end users, as well as its other stakeholders, money, time, and confidence in the technology. This study is about usability testing for improving the user-interface for ePortfolios. This is a qualitative study using the think-aloud protocol (TAP) for data collection and failure modes and effects analysis (FMEA) for data analysis.

A collection of poetry concerned with loss and the act of creation.

Behavior analysts often work with families from diverse cultural backgrounds. Ideally, behavior analysts and families interact in ways that are responsive to the family's culture and valued outcomes. The data indicate that most behavior analysts, however, come from one dominant cultural group. This is a proposal for training program and evaluation method to support culturally responsive professional-family interactions. This proposed study is designed to be conducted via Zoom-- a cloud-based video conferencing service. A pre-post treatment design is proposed to assess the effects of the training. Hypothetical data were generated to consider the range of effects such a program might have on trainee responses to written/live scenarios. Responses in the observation protocol included written descriptions, empathetic statements, perspective taking statements, and non-verbal behaviors. Overall, the program was designed using evidence-based procedures and is likely to support behavior analysts in training and in practice to improve their interactions with families and become more culturally responsive to groups of people that are from the non-dominant culture.

In order to better understand the changes occurring in the internal environment of the pyrolysis process a method of monitoring the internal environment in real time is the key objective of this study. To accomplish this objective four tasks were laid out in order to develop an effective way of monitoring the changes in gases present as pyrolysis is occurring as well as in material activation processing. For all processing the self-activation process was used which combines pyrolysis and thermal activation into a single step process. In the first task 10 hard wood species were activated and the resulting properties were compared to see the impact of wood species on the resulting carbon structures. In order to understand the impact of gas concentration on the resulting carbons the second task developed a gas sensor array which effectiveness was corroborated using GC-MS and then comparisons of the changes in the resulting were made. For the third task the gas sensor array was used to analyze the production of CO2 gas and a triple Gaussian model was developed to model the changes in gas production throughout processing. H2 gas production was modeled in the fourth task using the same Gaussian model as …

This dissertation examines the role of third parties in civil war mediation and peacekeeping efforts. The dissertation makes two primary contributions to the literature. First, it builds upon existing literature by applying state-level arguments of third party involvement in mediation and peacekeeping efforts to the United Nations Security Council and regional IGOs. Second, it investigates the role of communication and coordination between third parties in their conflict management efforts.

The purpose of this study was to investigate the effects of Pb and hypoxia co-exposure on Pb toxicity and Ca homeostasis in early life stage (ELS) zebrafish (Danio rerio). Previous evidence indicates that exposure of ELS zebrafish to hypoxia (~20% air saturation) reduces Ca uptake, likely through down-regulation of the apical epithelial Ca channel (ECaC). Considering that Pb and Ca are known antagonists and compete for uptake pathways, it was hypothesized that co-exposure of Pb with hypoxia would decrease Pb toxicity by reducing Pb uptake (likely mediated through a reduced number of ECaCs). However, it was shown that at 96 hpf, whole body accumulation of both Pb and Ca was lower at 40% air saturation compared to 100% and 20% air saturation. This result closely aligned with the 96h LC50 results which showed the highest mortality of zebrafish at 40% compared to the other air saturation levels. This suggests that toxicity is likely the result of exacerbated hypocalcemia at 40% air saturation due to both Pb competition for Ca binding to Ca uptake channels/transporters, such as ECaC, and potentially reduced expression of such channels/transporters in response to this level of hypoxia. Overall, it appears that ELS zebrafish respond differentially to …

Recently, 3D printing has received increasing attention for the fabrication and assembly of electrodes for batteries due to the freedom of creating structures in any shape or size, porosity, flexibility, stretchability, and chemistry. Particularly, zinc ion batteries (ZIBs) are favored due to high safety, cheap materials cost, and high volumetric capacity (5,849 mAh/cm3), however, rapid evaporation of Zn due to low melting temperature has limited its 3D printability via conventional laser-based additive manufacturing technique. Here, we develop a printable ink for the fabrication of flexible and 3D printed Zn anode with varied surface areas using the direct ink writing (DIW) method. Our 3D printed porous and high surface area Zn anode structures effectively suppressed the dendrite growth while providing high Zn ion diffusion towards the cathode to significantly enhance the performance of ZIB. By varying filament distancing and path, we 3D printed zinc anode structures with different active surface areas, surface area to volume ratio, porosity, flexible and multiple layer structures that can be incorporated on any device. Carbon in the composite improved conductivity, and mechanical stability of 3D printed zinc anode. Our 3D printed composite anodes allowed flexible designing of batteries surpassing conventional battery designs such as coin cells …

Due to inadequate long-term and large-scale observation approach for observation of soil moisture across the globe, this study intends to unveil the importance of using simulated soil moisture fields from land surface models, forced with observed precipitation and near-surface meteorology in monitoring drought and formulating effective water management practices for continued production irrigation applications. This study shows that socio-economic and ecosystem effects can be determined by evaluating spatial-temporal changes in irrigation applications. Thus, it facilitates understanding of the importance of water management and how water, energy, and carbon flows protect our climate and environment. By using Soil Moisture Active Passive (SMAP) in monitoring soil moisture, the information obtained is critical in providing early drought warnings, particularly in those parts of the United States that experience flash agricultural droughts. Further, this study highlights that frequent and reliable soil moisture measurements from SMAP helped improve the predictive capability of weather and climate models.

This multi-case study sought to better understand how students with intellectual disability (ID) are forging pathways to higher education via the community college. Five individuals with ID who accessed higher education via the community college and their parents/guardians were interviewed. Each case provided insight into personal pathways with results given in case descriptions and individual case themes. Cross-case analysis revealed four themes positively impacting the college-going pathway for students with ID: value-driven grit, pathway knowledge, community support, and accessibility. Based on findings from this study, families appear to be the primary systems forging pathways to the community college for individuals with ID. Local education agencies and community colleges can assist these families by engaging in interagency collaboration, evaluating their systems, and aligning practices to the goal of students with ID accessing and engaging in higher education.

We investigated the hypothesis that exposure to inhaled diesel exhaust PM can alter the gut microbiome and intestinal integrity, thereby promoting systemic inflammatory response and early CVD risk, which are exacerbated by HF diet. Furthermore, we investigated whether the observed exposure and diet-mediated outcomes could be mitigated through probiotic treatment. We performed an exposure study on C57Bl/6 male mice, placed on either a low fat (LF) diet or a high-fat (HF) diet, and exposed via oropharyngeal aspiration to 35 μg diesel exhaust particles (DEP) suspended in 35 μl of sterile saline or sterile saline controls (CON) twice a week for four weeks. A subset of mice on HF diet were dosed with 0.3 g/day (PRO, ~7.5x108 CFU/day) of probiotic Ecologic® Barrier 849 (Winclove Probiotics) in drinking water during the course of the study. For our first aim, we investigated the alterations in the gut microbiome, measured circulating cytokines and lipopolysaccharide (LPS), and measured CVD biomarkers in the heart. Our results revealed that exposure to inhaled DEP results in gut dysbiosis characterized by expansion of the phyla Verrucomicrobia and Proteobacteria and reduction in Actinobacteria, which was exacerbated by HF diet. Probiotics mitigated the DEP-mediated expansion of Proteobacteria and re-established Actinobacteria in …

NAND flash-based solid state drives (SSDs) have been widely adopted in data centers and high performance computing (HPC) systems due to their better performance compared with hard disk drives. However, little is known about the reliability characteristics of SSDs in production systems. Existing works that study the statistical distributions of SSD failures in the field lack insights into distinct characteristics of SSDs. In this dissertation, I explore the SSD-specific SMART (Self-Monitoring, Analysis, and Reporting Technology) attributes and conduct in-depth analysis of SSD reliability in a production environment with a focus on the unique error types and health dynamics. QLC SSD delivers better performance in a cost-effective way. I study QLC SSDs in terms of their architecture and performance. In addition, I apply thermal stress tests to QLC SSDs and quantify their performance degradation processes. Various types of big data and machine learning workloads have been executed on SSDs under varying temperatures. The SSD throughput and application performance are analyzed and characterized.

Motivated by previous relevant research on phononics including both active and passive phononics, the interest of faster turnability and more functions of the active phononics of further study led to this proposing research topic: magnetic field tunable active functional phononics. The first design of magnetic field tunable reciprocal--non-reciprocal transmission acoustic device was established, material was characterized, and numerical simulation has been performed. The simulation results show clear T-symmetric breaking non-reciprocity due to energy level splitting effect with Doppler effect – an acoustic Zeeman effect. Inspired by this preliminary work, further experiments were planned to demonstrate this effective Zeeman effect in phononics and effectively charged phonons in water based ferro-fluid. The objectives of this work as the next series of tasks were to illustrate acoustic Zeeman effect and acoustic Landau levels in various strength of magnetic field to investigate a design non-reciprocal sound device with magnetic field switching, which could be controlled on the amount of non-reciprocity with the strength of magnetic field. Once this new field first discovered by the proposed study tasks, more active tunable magnetic field phononics devices could be designed and exemplified in terms of both simulations and experiments. Faster and more controllable active phononic devices could …

Probiotics/prebiotic supplementation represents a viable option for addressing systemic inflammation and chronic disease risk resulting from excessive body weight. The purpose of this feasibility study was to determine if 90-d of supplementation with prebiotic and probiotic could alter mRNA responsible for inflammation and subsequently metabolic health in weight stable overweight adults. Participants were advised to not change their diet or exercise habits during the study. All protocols were approved by the University IRB and participants gave written informed consent. Participants were randomly assigned to either placebo (N=7; rice flour) or combined (N=8) prebiotic (PreticX® Xylooligosaccharide; 0.8 g/d; ADIP) and probiotic (MegaDuo® Bacillus subtilis HU58 and Bacillus coagulans SC-208; 3 Billion CFU/d) and measurements were made at baseline, 30, 60, and 90-d. Whole body DXA scans (GE iDXA®) and blood 574-plex mRNA analysis (Nanostring®) were used to generate primary outcomes. Compared to placebo, supplementation was associated with a 36% reduction in visceral adipose tissue (p = 0.001). Supplement resulted in significant, differential expression of 15 mRNA associated with adipose tissue inflammation, systemic inflammation, and/or chronic disease risk. The key findings support that 90-d prebiotic/probiotic supplementation may be associated with an improved metabolic health, reduced adipose tissue inflammation, reduced systemic inflammation, and …