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3,4,3-LI(1,2-HOPO): In Vitro Formation of Highly Stable Lanthanide Complexes Translates into Efficacious In Vivo Europium Decorporation
The spermine-based hydroxypyridonate octadentate chelator 3,4,3-LI(1,2-HOPO) was investigated for its ability to act as an antennae that sensitizes the emission of Sm{sup III}, Eu{sup III}, and Tb{sup III} in the Visible range (Φ{sub tot} = 0.2 - 7%) and the emission of Pr{sup III}, Nd{sup III}, Sm{sup III}, and Yb{sup III} in the Near Infra-Red range, with decay times varying from 1.78 μs to 805 μs at room temperature. The particular luminescence spectroscopic properties of these lanthanide complexes formed with 3,4,3-LI(1,2-HOPO) were used to characterize their respective solution thermodynamic stabilities as well as those of the corresponding La{sup III}, Gd{sup III}, Dy{sup III}, Ho{sup III}, Er{sup III}, Tm{sup III}, and Lu{sup III} complexes. The remarkably high affinity of 3,4,3-LI(1,2-HOPO) for lanthanide metal ions and the resulting high complex stabilities (pM values ranging from 17.2 for La{sup III} to 23.1 for Yb{sup III}) constitute a necessary but not sufficient criteria to consider this octadentate ligand an optimal candidate for in vivo metal decorporation. The in vivo lanthanide complex stability and decorporation capacity of the ligand were assessed, using the radioactive isotope {sup 152}Eu as a tracer in a rodent model, which provided a direct comparison with the in vitro thermodynamic results …
Date:
July 13, 2011
Creator:
Sturzbecher-Hoehne, Manuel; Ng Pak Leung, Clara; Daleo, Anthony; Kullgren, Birgitta; Prigent, Anne-Laure; Shuh, David K. et al.
Object Type:
Article
System:
The UNT Digital Library
E-18 (9-13-17)
None
Date:
September 13, 2017
Creator:
unknown
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[24-Hour Film Feast in memory of Esther Rolle dialogue with actor Antonio Fargas]
Video recording from The Black Academy of Arts and Letters recorded during the 2010 annual 24-Hour Film Feast in memory of actress Esther Rolle. The footage was shot during actor Antonio Fargas' dialogue on Rolle's pivotal work in American film and television held on Saturday, February 13th, 2010. The tape fades to black and then picks up with unrelated content around the 1:15:00 minute mark.
Date:
February 13, 2010
Creator:
King, Curtis & Fargas, Antonio
Object Type:
Video
System:
The UNT Digital Library
E-904 (7-13-19)
Photograph of Hickory Hills Engine 904.
Date:
July 13, 2019
Creator:
unknown
Object Type:
Photograph
System:
The Gateway to Oklahoma History
E-924 (7-13-19)
Photograph of Hickory Hills Engine 924.
Date:
July 13, 2019
Creator:
unknown
Object Type:
Photograph
System:
The Gateway to Oklahoma History
[2005 Sisson Golden Sledgehammer Award]
Photograph of the 2005 Sisson Golden Sledgehammer Award at the January 13, 2018 Dallas Chapter TXSSAR meeting. The award consists of photographs of the recipient, E. Thomas Smith, in a large frame. Each photograph has a caption above it. The phrase, "2005 Recipient of the Sisson Golden Sledgehammer Award -- Dallas Chapter's Hardest Worker: E. Thomas Smith," has been placed in the center top portion of the collage.
Date:
January 13, 2018
Creator:
Texas Society Sons of the American Revolution, Dallas Chapter 2
Object Type:
Photograph
System:
The UNT Digital Library
[2009 Sisson Golden Sledgehammer Award]
Photograph of the 2009 Sisson Golden Sledgehammer Award at the January 13, 2018 Dallas Chapter TXSSAR meeting. The award consists of photographs of the recipient, David Temple, in a frame. Each photograph has a caption underneath it. In the center of the collage is the phrase, "2009 Recipient of the Gary Sisson 'Golden' Sledgehammer Award -- Dallas Chapter's Hardest Worker: David J. Temple." To the right of the award is a photograph of the 2006 and 2007 award recipients, James Templin and Allen Christian, shaking hands. Part of the 2005 award can be seen on the far right side of the photograph.
Date:
January 13, 2018
Creator:
Texas Society Sons of the American Revolution, Dallas Chapter 2
Object Type:
Photograph
System:
The UNT Digital Library
2010 Water & Aqueous Solutions
Water covers more than two thirds of the surface of the Earth and about the same fraction of water forms the total mass of a human body. Since the early days of our civilization water has also been in the focus of technological developments, starting from converting it to wine to more modern achievements. The meeting will focus on recent advances in experimental, theoretical, and computational understanding of the behavior of the most important and fascinating liquid in a variety of situations and applications. The emphasis will be less on water properties per se than on water as a medium in which fundamental dynamic and reactive processes take place. In the following sessions, speakers will discuss the latest breakthroughs in unraveling these processes at the molecular level: Water in Solutions; Water in Motion I and II; Water in Biology I and II; Water in the Environment I and II; Water in Confined Geometries and Water in Discussion (keynote lecture and poster winners presentations).
Date:
August 13, 2010
Creator:
Ben-Amotz, Dor
Object Type:
Article
System:
The UNT Digital Library
2012 ORGANOMETALLIC CHEMISTRY GRC/GRS, JULY 7-13, 2012
The 2012 Organometallic Chemistry Gordon Research Conference will highlight new basic science and fundamental applications of organometallic chemistry in industrial, academic, and national lab settings. Scientific themes of the conference will include chemical synthesis, reactivity, catalysis, polymer chemistry, bonding, and theory that involve transition-metal (and main-group) interactions with organic moieties.
Date:
July 13, 2012
Creator:
Hillhouse, Gregory
Object Type:
Article
System:
The UNT Digital Library
2012 PHOTOSYNTHESIS GORDON RESEARCH CONFERENCE AND SEMINAR, JUL 7-13, 2012
The Gordon Research Conference on PHOTOSYNTHESIS was held at Davidson College, Davidson, North Carolina, July 8 ? 13, 2012. The Conference was well-attended with 150 participants (attendees list attached). The attendees represented the spectrum of endeavor in this field coming from academia, industry, and government laboratories, both U.S. and foreign scientists, senior researchers, young investigators, and students. Of the 150 attendees, 65 voluntarily responded to a general inquiry regarding ethnicity which appears on our registration forms. Of the 65 respondents, 20% were Minorities ? 5% Hispanic, 15% Asian and 0% African American. Approximately 28% of the participants at the 2012 meeting were women. The Gordon Research Seminar on PHOTOSYNTHESIS held at Davidson College, Davidson, North Carolina, July 7-8, 2012.. The Conference was well-attended with 51 participants (attendees list attached). The attendees represented the spectrum of endeavor in this field coming from academia, industry, and government laboratories, both U.S. and foreign scientists, senior researchers, young investigators, and students. Of the 51 attendees, 22 voluntarily responded to a general inquiry regarding ethnicity which appears on our registration forms. Of the 22 respondents, 14% were Minorities ? 0% Hispanic, 14% Asian and 0% African American. Approximately 35% of the participants at the 2012 …
Date:
July 13, 2012
Creator:
Debus, Richard
Object Type:
Article
System:
The UNT Digital Library
[2013 Summer Youth Arts Institute Behind the Scenes video]
Video of behind-the-scenes footage from the 2013 TBAAL Summer Youth Arts Institute. The video includes a student orchestra performance and awards ceremony, as well as footage of the lighting crew, auditions, and skit takes from the making of "Motown Motown: The Musical."
Date:
June 13, 2013
Creator:
unknown
Object Type:
Video
System:
The UNT Digital Library
[2016 Sisson Golden Sledgehammer Award]
Photograph of the 2016 Sisson Golden Sledgehammer Award at the January 13, 2018 Dallas Chapter TXSSAR meeting. The award consists of photographs of the recipient, Jerry Pinkerton, in interconnected frames. Pinkerton's last name has been placed in the center frame. The phrase, "Recipient of the Dr. Gary Sisson Golden Sledgehammer Award -- Dallas Chapter's 2016 Hardest Worker: Jerry W. Pinkerton," has been placed in the frame above his name. A list of Golden Sledgehammer winners from 2001-2016 can be seen on the table behind the award.
Date:
January 13, 2018
Creator:
Texas Society Sons of the American Revolution, Dallas Chapter 2
Object Type:
Photograph
System:
The UNT Digital Library
21st Century Flood Reform Act (H.R. 2874): Reforming the National Flood Insurance Program
This report discusses the National Flood Insurance Act and the proposed 21st Century Flood Reform Act in the House. House leaders submitted an Amendment in the Nature of a Substitute (H.R. 2874ANS) on November 6, 2017, that would modify H.R. 2874, the 21st Century Flood Reform Act, to add provisions from the six other bills approved by the House Financial Services Committee. H.R. 2874 would authorize the NFIP until September 30, 2022. This report summarizes selected provisions of the bill, concentrating on changes related to premiums and surcharges, affordability, increasing participation, the role of private insurance, treatment of multiple loss properties, and some provisions related to floodplain mapping and mitigation.
Date:
November 13, 2017
Creator:
Horne, Diane P.
Object Type:
Report
System:
The UNT Digital Library
[22nd annual Christmas Kwanzaa concert]
Video of the 22nd annual Kwanzaa concert at The Black Academy of Arts and Letters. The video includes performances by choirs from Texas College, Emmett Conrad High School, Paul Laurence Dunbar High School, Justin Kimball High School, Lancaster High School, Life School of Dallas, Lincoln High School, and South Oak Cliff High School, accompanied by the Yvonne A. Ewell Townview Center Band.
Date:
December 13, 2014
Creator:
Latte Media Group
Object Type:
Video
System:
The UNT Digital Library
3D Pixels: Recent Results
None
Date:
June 13, 2013
Creator:
Rohne, O.; Bolle, E.; Borri, M.; Boscardin, M.; Dalla Betta, G. F.; Darbo, G. et al.
Object Type:
Article
System:
The UNT Digital Library
[50th Annual Meeting of the Oral History Association Photograph 1]
Digital photograph taken at the 50th Annual Meeting of the Oral History Association in Long Beach, California, held in conjunction with the 35th Annual Meeting of the Southwest Oral History Association. The theme of the conference was "OHA@50: Traditions, Transitions and Technologies From The Field."
Date:
October 13, 2016
Creator:
Caught in the Moment Photography
Object Type:
Photograph
System:
The UNT Digital Library
[50th Annual Meeting of the Oral History Association Photograph 2]
Digital photograph taken at the 50th Annual Meeting of the Oral History Association in Long Beach, California, held in conjunction with the 35th Annual Meeting of the Southwest Oral History Association. The theme of the conference was "OHA@50: Traditions, Transitions and Technologies From The Field."
Date:
October 13, 2016
Creator:
Caught in the Moment Photography
Object Type:
Photograph
System:
The UNT Digital Library
[50th Annual Meeting of the Oral History Association Photograph 3]
Digital photograph taken at the 50th Annual Meeting of the Oral History Association in Long Beach, California, held in conjunction with the 35th Annual Meeting of the Southwest Oral History Association. The theme of the conference was "OHA@50: Traditions, Transitions and Technologies From The Field."
Date:
October 13, 2016
Creator:
Caught in the Moment Photography
Object Type:
Photograph
System:
The UNT Digital Library
[50th Annual Meeting of the Oral History Association Photograph 4]
Digital photograph taken at the 50th Annual Meeting of the Oral History Association in Long Beach, California, held in conjunction with the 35th Annual Meeting of the Southwest Oral History Association. The theme of the conference was "OHA@50: Traditions, Transitions and Technologies From The Field."
Date:
October 13, 2016
Creator:
Caught in the Moment Photography
Object Type:
Photograph
System:
The UNT Digital Library
[50th Annual Meeting of the Oral History Association Photograph 5]
Digital photograph taken at the 50th Annual Meeting of the Oral History Association in Long Beach, California, held in conjunction with the 35th Annual Meeting of the Southwest Oral History Association. The theme of the conference was "OHA@50: Traditions, Transitions and Technologies From The Field."
Date:
October 13, 2016
Creator:
Caught in the Moment Photography
Object Type:
Photograph
System:
The UNT Digital Library
[50th Annual Meeting of the Oral History Association Photograph 6]
Digital photograph taken at the 50th Annual Meeting of the Oral History Association in Long Beach, California, held in conjunction with the 35th Annual Meeting of the Southwest Oral History Association. The theme of the conference was "OHA@50: Traditions, Transitions and Technologies From The Field."
Date:
October 13, 2016
Creator:
Caught in the Moment Photography
Object Type:
Photograph
System:
The UNT Digital Library
[50th Annual Meeting of the Oral History Association Photograph 7]
Digital photograph taken at the 50th Annual Meeting of the Oral History Association in Long Beach, California, held in conjunction with the 35th Annual Meeting of the Southwest Oral History Association. The theme of the conference was "OHA@50: Traditions, Transitions and Technologies From The Field."
Date:
October 13, 2016
Creator:
Caught in the Moment Photography
Object Type:
Photograph
System:
The UNT Digital Library
[50th Annual Meeting of the Oral History Association Photograph 8]
Digital photograph taken at the 50th Annual Meeting of the Oral History Association in Long Beach, California, held in conjunction with the 35th Annual Meeting of the Southwest Oral History Association. The theme of the conference was "OHA@50: Traditions, Transitions and Technologies From The Field."
Date:
October 13, 2016
Creator:
Caught in the Moment Photography
Object Type:
Photograph
System:
The UNT Digital Library
[50th Annual Meeting of the Oral History Association Photograph 9]
Digital photograph taken at the 50th Annual Meeting of the Oral History Association in Long Beach, California, held in conjunction with the 35th Annual Meeting of the Southwest Oral History Association. The theme of the conference was "OHA@50: Traditions, Transitions and Technologies From The Field."
Date:
October 13, 2016
Creator:
Caught in the Moment Photography
Object Type:
Photograph
System:
The UNT Digital Library