Technical Risk Rating of DOE Environmental Projects - 9153 (open access)

Technical Risk Rating of DOE Environmental Projects - 9153

The U.S. Department of Energy's Office of Environmental Management (DOE-EM) was established to achieve the safe and compliant disposition of legacy wastes and facilities from defense nuclear applications. The scope of work is diverse, with projects ranging from single acquisitions to collections of projects and operations that span several decades and costs from hundreds of millions to billions US$. The need to be able to manage and understand the technical risks from the project to senior management level has been recognized as an enabler to successfully completing the mission. In 2008, DOE-EM developed the Technical Risk Rating as a new method to assist in managing technical risk based on specific criteria. The Technical Risk Rating, and the criteria used to determine the rating, provides a mechanism to foster open, meaningful communication between the Federal Project Directors and DOE-EM management concerning project technical risks. Four indicators (technical maturity, risk urgency, handling difficulty and resolution path) are used to focus attention on the issues and key aspects related to the risks. Pressing risk issues are brought to the forefront, keeping DOE-EM management informed and engaged such that they fully understand risk impact. Use of the Technical Risk Rating and criteria during reviews …
Date: February 11, 2009
Creator: Cercy, Michael; Fayfich, Ronald & Schneider, Steven
System: The UNT Digital Library
Loss Factor of the PEP-II Rings (open access)

Loss Factor of the PEP-II Rings

An RF power balance method is used to measure the synchrotron radiation losses and the wake field losses. We present the history of the losses in the Low Energy Ring (LER) and the High Energy Ring (HER) during the last several runs of PEP-II.
Date: July 11, 2008
Creator: Novokhatski, A. & Sullivan, M.
System: The UNT Digital Library
Multiple Valley Couplings in Nanometer Si MOSFETs (open access)

Multiple Valley Couplings in Nanometer Si MOSFETs

We investigate the couplings between different energy band valleys in a MOSFET device using self-consistent calculations of million-atom Schroedinger-Poisson Equations. Atomistic empirical pseudopotentials are used to describe the device Hamiltonian and the underlying bulk band structure. The MOSFET device is under nonequilibrium condition with a source-drain bias up to 2V, and a gate potential close to the threshold potential. We find that all the intervalley couplings are small, with the coupling constants less than 3 meV. As a result, the system eigenstates derived from different bulk valleys can be calculated separately. This will significantly reduce the simulation time, because the diagonalization of the Hamiltonian matrix scales as the third power of the total number of basis functions.
Date: July 11, 2008
Creator: Wang, Lin-Wang; Deng, Hui-Xiong; Jiang, Xiang-Wei; Luo, Jun-Wei; Li, Shu-Shen; Xia, Jian-Bai et al.
System: The UNT Digital Library
Pathway confirmation and flux analysis of central metabolicpathways in Desulfovibrio vulgaris Hildenborough using gaschromatography-mass spectrometry and fourier transform-ion cyclotronresonance mass spectrometry (open access)

Pathway confirmation and flux analysis of central metabolicpathways in Desulfovibrio vulgaris Hildenborough using gaschromatography-mass spectrometry and fourier transform-ion cyclotronresonance mass spectrometry

It has been proposed that during growth under anaerobic oroxygen-limited conditions Shewanella oneidensis MR-1 uses theserine-isocitrate lyase pathway common to many methylotrophic anaerobes,in which formaldehyde produced from pyruvate is condensed with glycine toform serine. The serine is then transformed through hydroxypyruvate andglycerate to enter central metabolism at phosphoglycerate. To examine itsuse of the serine-isocitrate lyase pathway under anaerobic conditions, wegrew S. oneidensis MR-1 on [1-13C]lactate as the sole carbon source witheither trimethylamine N-oxide (TMAO) or fumarate as an electron acceptor.Analysis of cellular metabolites indicates that a large percentage(>75 percent) of lactate was partially oxidized to either acetate orpyruvate. The 13C isotope distributions in amino acids and other keymetabolites indicate that, under anaerobic conditions, a complete serinepathway is not present, and lactate is oxidized via a highly reversibleserine degradation pathway. The labeling data also suggest significantactivity in the anaplerotic (malic enzyme and phosphoenolpyruvatecarboxylase) and glyoxylate shunt (isocitrate lyase and malate synthase)reactions. Although the tricarboxylic acid (TCA) cycle is often observedto be incomplete in many other anaerobes (absence of 2-oxoglutaratedehydrogenase activity), isotopic labeling supports the existence of acomplete TCA cycle in S. oneidensis MR-1 under TMAO reductioncondition.
Date: July 11, 2006
Creator: Tang, Yinjie; Pingitore, Francesco; Mukhopadhyay, Aindrila; Phan,Richard; Hazen, Terry C. & Keasling, Jay D.
System: The UNT Digital Library
MODEL-BASED HYDROACOUSTIC BLOCKAGE ASSESSMENT AND DEVELOPMENT OF AN EXPLOSIVE SOURCE DATABASE (open access)

MODEL-BASED HYDROACOUSTIC BLOCKAGE ASSESSMENT AND DEVELOPMENT OF AN EXPLOSIVE SOURCE DATABASE

We are continuing the development of the Hydroacoustic Blockage Assessment Tool (HABAT) which is designed for use by analysts to predict which hydroacoustic monitoring stations can be used in discrimination analysis for any particular event. The research involves two approaches (1) model-based assessment of blockage, and (2) ground-truth data-based assessment of blockage. The tool presents the analyst with a map of the world, and plots raypath blockages from stations to sources. The analyst inputs source locations and blockage criteria, and the tool returns a list of blockage status from all source locations to all hydroacoustic stations. We are currently using the tool in an assessment of blockage criteria for simple direct-path arrivals. Hydroacoustic data, predominantly from earthquake sources, are read in and assessed for blockage at all available stations. Several measures are taken. First, can the event be observed at a station above background noise? Second, can we establish backazimuth from the station to the source. Third, how large is the decibel drop at one station relative to other stations. These observational results are then compared with model estimates to identify the best set of blockage criteria and used to create a set of blockage maps for each station. The …
Date: July 11, 2005
Creator: Matzel, E; Ramirez, A & Harben, P
System: The UNT Digital Library
The Surface Wave Magnitude for the 9 October 2006 North Korean Nuclear Explosion (open access)

The Surface Wave Magnitude for the 9 October 2006 North Korean Nuclear Explosion

Surface waves were generated by the North Korean nuclear explosion of 9 October 2006 and recorded at epicentral distances up to 34 degrees, from which we estimated a surface wave magnitude (M{sub s}) of 2.94 with an interstation standard deviation of 0.17 magnitude units. The International Data Centre estimated a body wave magnitude (m{sub b}) of 4.1. This is the only explosion we have analyzed that was not easily screened as an explosion based on the differences between the M{sub s} and m{sub b} estimates. Additionally, this M{sub s} predicts a yield, based on empirical M{sub s}/Yield relationships, that is almost an order of magnitude larger then the 0.5 to 1 kiloton reported for this explosion. We investigate how emplacement medium effects on surface wave moment and magnitude may have contributed to the yield discrepancy.
Date: March 11, 2008
Creator: Bonner, J; Herrmann, R; Harkrider, D & Pasyanos, M
System: The UNT Digital Library
Dark Matter and Baryons in the Most X-ray Luminous and Merging Galaxy Cluster RX (open access)

Dark Matter and Baryons in the Most X-ray Luminous and Merging Galaxy Cluster RX

None
Date: April 11, 2008
Creator: Bradac, Marusa; Schrabback, Tim; Erben, Thomas; McCourt, Michael; Million, Evan; Mantz, Adam et al.
System: The UNT Digital Library
Search for CPT Violation in B0-B0bar Oscillations with BABAR (open access)

Search for CPT Violation in B0-B0bar Oscillations with BABAR

None
Date: April 11, 2008
Creator: Stoker, D. P. & /UC, Irvine
System: The UNT Digital Library
Electronic structure of multiferroic BiFeO3 by resonant soft-x-ray emission spectroscopy (open access)

Electronic structure of multiferroic BiFeO3 by resonant soft-x-ray emission spectroscopy

The electronic structure of multiferroic BiFeO{sub 3} has been studied using soft-X-ray emission spectroscopy. The fluorescence spectra exhibit that the valence band is mainly composed of O 2p state hybridized with Fe 3d state. The band gap corresponding to the energy separation between the top of the O 2p valence band and the bottom of the Fe 3d conduction band is 1.3 eV. The soft-X-ray Raman scattering reflects the features due to charge transfer transition from O 2p valence band to Fe 3d conduction band. These findings are similar to the result of electronic structure calculation by density functional theory within the local spin-density approximation that included the effect of Coulomb repulsion between localized d states.
Date: July 11, 2008
Creator: Higuchi, Tohru; Higuchi, T.; Liu, Y.-S.; Yao, P.; Glans, P.-A.; Guo, Jinghua et al.
System: The UNT Digital Library
SUSY Without Prejudice at Linear Colliders (open access)

SUSY Without Prejudice at Linear Colliders

We explore the physics of the general CP-conserving MSSM with Minimal Flavor Violation, the pMSSM. The 19 soft SUSY breaking parameters are chosen so to satisfy all existing experimental and theoretical constraints assuming that the WIMP is the lightest neutralino. We scan this parameter space twice using both flat and log priors and compare the results which yield similar conclusions. Constraints from both LEP and the Tevatron play an important role in obtaining our final model samples. Implications for future TeV-scale e{sup +}e{sup -} linear colliders (LC) are discussed.
Date: December 11, 2008
Creator: Rizzo, Thomas G.
System: The UNT Digital Library
CLOMP: Accurately Characterizing OpenMP Application Overheads (open access)

CLOMP: Accurately Characterizing OpenMP Application Overheads

Despite its ease of use, OpenMP has failed to gain widespread use on large scale systems, largely due to its failure to deliver sufficient performance. Our experience indicates that the cost of initiating OpenMP regions is simply too high for the desired OpenMP usage scenario of many applications. In this paper, we introduce CLOMP, a new benchmark to characterize this aspect of OpenMP implementations accurately. CLOMP complements the existing EPCC benchmark suite to provide simple, easy to understand measurements of OpenMP overheads in the context of application usage scenarios. Our results for several OpenMP implementations demonstrate that CLOMP identifies the amount of work required to compensate for the overheads observed with EPCC. Further, we show that CLOMP also captures limitations for OpenMP parallelization on NUMA systems.
Date: February 11, 2008
Creator: Bronevetsky, G; Gyllenhaal, J & de Supinski, B
System: The UNT Digital Library
The influence of projectile neutron number in the 208Pb(48Ti, n)255Rf and 208Pb(50Ti, n)257Rf reactions (open access)

The influence of projectile neutron number in the 208Pb(48Ti, n)255Rf and 208Pb(50Ti, n)257Rf reactions

Four isotopes of rutherfordium,254-257Rf, were produced by the 208Pb(48Ti, xn)256-xRf and 208Pb(50Ti, xn)258-xRf reactions (x = 1, 2) at the Lawrence Berkeley National Laboratory 88-Inch Cyclotron. Excitation functions were measured for the 1n and 2n exit channels. A maximum likelihood technique, which correctly accounts for the changing cross section at all energies subtended by the targets, was used to fit the 1n data to allow a more direct comparison between excitation functions obtained under different experimental conditions. The maximum 1n crosssections of the 208Pb(48Ti, n)255Rf and 208Pb(50Ti, n)257Rf reactions obtained from fits to the experimental data are 0.38 +/- 0.07 nb and 40 +/-5 nb, respectively. Excitation functions for the 2n exit channel were also measured, with maximum cross sections of nb for the 48Ti induced reaction, and 15.7 +/- 0.2 nb for the 50Ti induced reaction. The impact of the two neutron difference in the projectile on the 1n cross section is discussed. The results are compared to the Fusion by Diffusion model developed by Swiatecki, Wilczynska, and Wilczynski.
Date: July 11, 2008
Creator: Dragojevic, Irena; Dragojevic, I.; Gregorich, K. E.; Dullmann, Ch. E.; Garcia, M. A.; Gates, J. M. et al.
System: The UNT Digital Library
On the Suitability of Lanthanides as Actinide Analogs (open access)

On the Suitability of Lanthanides as Actinide Analogs

With the current level of actinide materials used in civilian power generation and the need for safe and efficient methods for the chemical separation of these species from their daughter products and for long-term storage requirements, a detailed understanding of actinide chemistry is of great importance. Due to the unique bonding properties of the f-elements, the lanthanides are commonly used as structural and chemical models for the actinides, but differences in the bonding between these 4f and 5f elements has become a question of immediate applicability to separations technology. This brief overview of actinide coordination chemistry in the Raymond group at UC Berkeley/LBNL examines the validity of using lanthanide analogs as structural models for the actinides, with particular attention paid to single crystal X-ray diffraction structures. Although lanthanides are commonly accepted as reasonable analogs for the actinides, these comparisons suggest the careful study of actinide materials independent of their lanthanide analogs to be of utmost importance to present and future efforts in nuclear industries.
Date: April 11, 2008
Creator: Szigethy, Geza & Raymond, Kenneth N.
System: The UNT Digital Library
Fluidized Bed Steam Reforming Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership (open access)

Fluidized Bed Steam Reforming Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership

Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NO{sub x} in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to …
Date: January 11, 2008
Creator: Jantzen, Carol M. & Williams, M. R.
System: The UNT Digital Library
Syntheses, Structure, Magnetism, and Optical Properties of the Interlanthanide Sulfides delta-Ln2-xLuxS3 (Ln = Ce, Pr, Nd) (open access)

Syntheses, Structure, Magnetism, and Optical Properties of the Interlanthanide Sulfides delta-Ln2-xLuxS3 (Ln = Ce, Pr, Nd)

{delta}-Ln{sub 2-x}LuxS{sub 3} (Ln = Ce, Pr, Nd; x = 0.67-0.71) compounds have been synthesized through the reaction of elemental rare earth metals and S using Sb{sub 2}S{sub 3} flux at 1000 C. These compounds are isotypic with CeTmS{sub 3}, which has a complex three-dimensional structure. It includes four larger Ln{sup 3+} sites in eight- and nine-coordinate environments, two disordered seven-coordinate Ln{sup 3+}/Lu{sup 3+} positions, and two six-coordinate Lu{sup 3+} ions. The structure is constructed from one-dimensional chains of LnSn (n = 6-9) polyhedra that extend along the b axis. These polyhedra share faces or edges with two neighbors within the chains, while in the [ac] plane they share edges and corners with other chains. Least square refinements gave rise to the formulas of {delta}-Ce{sub 1.30}Lu{sub 0.70}S{sub 3}, {delta}-Pr{sub 1.29}Lu{sub 0.71}S{sub 3} and {delta}-Nd{sub 1.33}Lu{sub 0.67}S{sub 3}, which are consistent with the EDX analysis and magnetic susceptibility data. {delta}-Ln{sub 2-x}LuxS{sub 3} (Ln = Ce, Pr, Nd; x = 0.67-0.71) show no evidence of magnetic ordering down to 5 K. Optical properties measurements show that the band gaps for {delta}-Ce{sub 1.30}Lu{sub 0.70}S{sub 3}, {delta}-Pr{sub 1.29}Lu{sub 0.71}S{sub 3}, and {delta}-Nd{sub 1.33}Lu{sub 0.67}S{sub 3} are 1.25 eV, 1.38 eV, and 1.50 eV, respectively. …
Date: January 11, 2008
Creator: Booth, Corwin H; Jin, Geng Bang; Choi, Eun Sang; Guertin, Robert P.; Brooks, James S.; Bray, Travis H. et al.
System: The UNT Digital Library
Hadronic B decays at BaBar and Belle (open access)

Hadronic B decays at BaBar and Belle

The authors review recent results of the BABAR and Belle Collaborations on the {alpha} and {gamma} angles of the unitarity triangle, on the B {yields} K{pi}{pi} Dalitz-plot analyses, and on the searches for baryonic B decays and for B {yields} D{bar D} decays.
Date: August 11, 2008
Creator: Lombardo, Vincenzo
System: The UNT Digital Library
Requirements for Reactor Physics Design (open access)

Requirements for Reactor Physics Design

It has been recognized that there is a need for requirements and guidance for design and operation of nuclear power plants. This is becoming more important as more reactors are being proposed to be built. In parallel with activities in individual countries are norms established by international organizations. This paper discusses requirements/guidance for neutronic design and operation as promulgated by the U.S. Nuclear Regulatory Commission (NRC). As an example, details are given for one reactor physics parameter, namely, the moderator temperature reactivity coefficient. The requirements/guidance from the NRC are discussed in the context of those generated for the International Atomic Energy Agency. The requirements/guidance are not identical from the two sources although they are compatible.
Date: April 11, 2008
Creator: Diamond, D. J.
System: The UNT Digital Library
ON THE IMPACT OF SUPER RESOLUTION WSR-88D DOPPLER RADAR DATA ASSIMILATION ON HIGH RESOLUTION NUMERICAL MODEL FORECASTS (open access)

ON THE IMPACT OF SUPER RESOLUTION WSR-88D DOPPLER RADAR DATA ASSIMILATION ON HIGH RESOLUTION NUMERICAL MODEL FORECASTS

Assimilation of radar velocity and precipitation fields into high-resolution model simulations can improve precipitation forecasts with decreased 'spin-up' time and improve short-term simulation of boundary layer winds (Benjamin, 2004 & 2007; Xiao, 2008) which is critical to improving plume transport forecasts. Accurate description of wind and turbulence fields is essential to useful atmospheric transport and dispersion results, and any improvement in the accuracy of these fields will make consequence assessment more valuable during both routine operation as well as potential emergency situations. During 2008, the United States National Weather Service (NWS) radars implemented a significant upgrade which increased the real-time level II data resolution to 8 times their previous 'legacy' resolution, from 1 km range gate and 1.0 degree azimuthal resolution to 'super resolution' 250 m range gate and 0.5 degree azimuthal resolution (Fig 1). These radar observations provide reflectivity, velocity and returned power spectra measurements at a range of up to 300 km (460 km for reflectivity) at a frequency of 4-5 minutes and yield up to 13.5 million point observations per level in super-resolution mode. The migration of National Weather Service (NWS) WSR-88D radars to super resolution is expected to improve warning lead times by detecting small scale …
Date: January 11, 2009
Creator: Chiswell, S
System: The UNT Digital Library
Discretizing gravity in warped spacetime (open access)

Discretizing gravity in warped spacetime

We investigate the discretized version of the compact Randall-Sundrum model. By studying the mass eigenstates of the lattice theory, we demonstrate that for warped space, unlike for flat space, the strong coupling scale does not depend on the IR scale and lattice size. However, strong coupling does prevent us from taking the continuum limit of the lattice theory. Nonetheless, the lattice theory works in the manifestly holographic regime and successfully reproduces the most significant features of the warped theory. It is even in some respects better than the KK theory, which must be carefully regulated to obtain the correct physical results. Because it is easier to construct lattice theories than to find exact solutions to GR, we expect lattice gravity to be a useful tool for exploring field theory in curved space.
Date: July 11, 2005
Creator: Schwartz, Matthew; Randall, Lisa; Schwartz, Matthew D. & Thambyahpillai, Shiyamala
System: The UNT Digital Library
Demonstartion of density dependence of x-ray flux in a laser-driven hohlraum (open access)

Demonstartion of density dependence of x-ray flux in a laser-driven hohlraum

Experiments have been conducted using laser-driven cylindrical hohlraums whose walls are machined from Ta{sub 2}O{sub 5} foams of 100 mg/cc and 4 g/cc densities. Measurements of the radiation temperature demonstrate that the lower density walls produce higher radiation temperatures than the high density walls. This is the first experimental demonstration of the prediction that this would occur [M. D. Rosen and J. H. Hammer, Phys. Rev. E 72, 056403 (2005)]. For high density walls, the radiation front propagates subsonically, and part of the absorbed energy is wasted by the flow kinetic energy. For the lower wall density, the front velocity is supersonic and can devote almost all of the absorbed energy to heating the wall.
Date: February 11, 2008
Creator: Young, P E; Rosen, M D; Hammer, J H; Hsing, W S; Glendinning, S G; Turner, R E et al.
System: The UNT Digital Library
Time-resolved soft-x-ray spectroscopy of a magnetic octupole transition in nickel-like xenon, cesium, and barium ions (open access)

Time-resolved soft-x-ray spectroscopy of a magnetic octupole transition in nickel-like xenon, cesium, and barium ions

A microcalorimeter with event mode capability for time-resolved soft-x-ray spectroscopy, and a high-resolution flat-field EUV spectrometer have been employed at the Livermore EBIT-I electron beam ion trap for observations and wavelength measurements of M1, E2, and M3 decays of long-lived levels in the Ni-like ions Xe{sup 26+}, Cs{sup 27+}, and Ba{sup 28+}. Of particular interest is the lowest excited level, 3d{sup 9}4s {sup 3}D{sub 3}, which can only decay via a magnetic octupole (M3) transition. For this level in Xe an excitation energy of (590.40 {+-} 0.03eV) and a level lifetime of (11.5 {+-} 0.5 ms) have been determined.
Date: November 11, 2005
Creator: Trabert, E; Beiersdorfer, P; Brown, G V; Boyce, K; Kelley, R L; Kilbourne, C A et al.
System: The UNT Digital Library
Global paths of time-periodic solutions of the Benjamin-Ono equation connecting arbitrary traveling waves (open access)

Global paths of time-periodic solutions of the Benjamin-Ono equation connecting arbitrary traveling waves

We classify all bifurcations from traveling waves to non-trivial time-periodic solutions of the Benjamin-Ono equation that are predicted by linearization. We use a spectrally accurate numerical continuation method to study several paths of non-trivial solutions beyond the realm of linear theory. These paths are found to either re-connect with a different traveling wave or to blow up. In the latter case, as the bifurcation parameter approaches a critical value, the amplitude of the initial condition grows without bound and the period approaches zero. We propose a conjecture that gives the mapping from one bifurcation to its counterpart on the other side of the path of non-trivial solutions. By experimentation with data fitting, we identify the form of the exact solutions on the path connecting two traveling waves, which represents the Fourier coefficients of the solution as power sums of a finite number of particle positions whose elementary symmetric functions execute simple orbits in the complex plane (circles or epicycles). We then solve a system of algebraic equations to express the unknown constants in the new representation in terms of the mean, a spatial phase, a temporal phase, four integers (enumerating the bifurcation at each end of the path) and one …
Date: December 11, 2008
Creator: Ambrose, David M. & Wilkening, Jon
System: The UNT Digital Library
Hybrid MOSFET/Driver for Ultra-Fast Switching (open access)

Hybrid MOSFET/Driver for Ultra-Fast Switching

The ultra-fast switching of power MOSFETs, in {approx}1ns, is very challenging. This is largely due to the parasitic inductance that is intrinsic to commercial packages used for both MOSFETs and drivers. Parasitic gate and source inductance not only limit the voltage rise time on the MOSFET internal gate structure but can also cause the gate voltage to oscillate. This paper describes a hybrid approach that substantially reduces the parasitic inductance between the driver and MOSFET gate as well as between the MOSFET source and its external connection. A flip chip assembly is used to directly attach the die-form power MOSFET and driver on a PCB. The parasitic inductances are significantly reduced by eliminating bond wires and minimizing lead length. The experimental results demonstrate ultra-fast switching of the power MOSFET with excellent control of the gate-source voltage.
Date: July 11, 2008
Creator: Tang, T. & Burkhart, C.
System: The UNT Digital Library
HYDROGEN EFFECTS ON STRAIN-INDUCED MARTENSITE FORMATION IN TYPE 304L STAINLESS STEEL (open access)

HYDROGEN EFFECTS ON STRAIN-INDUCED MARTENSITE FORMATION IN TYPE 304L STAINLESS STEEL

Unstable austenitic stainless steels undergo a strain-induced martensite transformation. The effect of hydrogen on this transformation is not well understood. Some researchers believe that hydrogen makes the transformation to martensite more difficult because hydrogen is an austenite stabilizer. Others believe that hydrogen has little or no effect at all on the transformation and claim that the transformation is simply a function of strain and temperature. Still other researchers believe that hydrogen should increase the ability of the metal to transform due to hydrogen-enhanced dislocation mobility and slip planarity. While the role of hydrogen on the martensite transformation is still debated, it has been experimentally verified that this transformation does occur in hydrogen-charged materials. What is the effect of strain-induced martensite on hydrogen embrittlement? Martensite near crack-tips or other highly strained regions could provide much higher hydrogen diffusivity and allow for quicker hydrogen concentration. Martensite may be more intrinsically brittle than austenite and has been shown to be severely embrittled by hydrogen. However, it does not appear to be a necessary condition for embrittlement since Type 21-6-9 stainless steel is more stable than Type 304L stainless steel but susceptible to hydrogen embrittlement. In this study, the effect of hydrogen on strain-induced …
Date: December 11, 2008
Creator: Morgan, M & Ps Lam, P
System: The UNT Digital Library