This paper reports the use of GIS mapping software—ArcMap and ArcInfo Workstation—by the Idaho National Engineering and Environmental Laboratory (INEEL) as a non-intrusive method of locating and characterizing radioactive waste in a 97-acre landfill to aid in planning cleanup efforts. The fine-scale techniques and methods used offer potential application for other burial sites for which hazards indicate a non-intrusive approach. By converting many boxes of paper shipping records in multiple formats into a relational database linked to spatial data, the INEEL has related the paper history to our current GIS technologies and spatial data layers. The wide breadth of GIS techniques and tools quickly display areas in need of remediation as well as evaluate methods of remediation for specific areas as the site characterization is better understood and early assumptions are refined.

A mobile melt-dilute (MMD) module for the treatment of aluminum research reactor spent fuel is being developed jointly by the Savannah River National Laboratory and Argonne National Laboratory. The process uses a closed system approach to retain fission products/gases inside a sealed canister after treatment. The MMD process melts and dilutes spent fuel with depleted uranium to obtain an isotopic content of less than 20 percent. The final ingot is solidified inside the sealed canister and can be stored safely either wet or dry until final disposition or reprocessing. The MMD module can be staged at or near the research reactor fuel storage sites to facilitate the melt-dilute treatment of the spent fuel into a stable non-proliferable form.

The removal of cesium from aqueous waste solution was investigated in a column setup using SuperLig(R) 644 resin. The resin was significantly coarser in size than those used in previous studies because of hydraulic problems encountered during pilot-scale tests. The bed volume (BV = 140) at the onset of breakthrough surpassed the design requirement of 100 BV at 50 percent breakthrough. The percent of cesium removed by the resin at the onset of breakthrough was 99.96. The elution of cesium with 0.5 M HNO3 was satisfactory with a peak BV of 2.5. The elution BV for C/Co = 0.01 was 10, which is less than the target of 15 BV. The percent of sorbed cesium eluted from the resin was 99.88 percent. In addition, the BV of the various solutions used for the supporting process steps (feed displacement, post-feed displacement rinse, post-elution rinse, and regeneration) of the cesium ion exchange system was sufficient.

There are many accelerator applications for high intensity heavy ion sources, with recent needs including dc beams for RIA, and pulsed beams for injection into synchrotrons such as RHIC and LHC. The present status of sources producing high currents of high charge state heavy ions is reviewed. These sources include ECR, EBIS, and Laser ion sources. Benefits and limitations for these type sources are described. Possible future improvements in these sources are also mentioned.

Recent strong experimental evidence of a narrow exotic S = +1 baryon resonance, {Theta}{sup +}, suggests the existence of other exotic baryons. We discuss the prospects of confirming earlier experimental evidence of {Theta}{sup +} and the observation of additional hypothetical exotic baryons in e{sup +}e{sup -} annihilations and {gamma}{gamma} collisions at LEP and B Factories.

In this work, nanostructured composite materials have been synthesized using the mechanical alloying process. The new materials produced have been investigated by X-ray diffraction (XRD), transition electron microscope (TEM), scanning electron microscope (SEM) and electron energy dispersion spectrum (EDS) for their phase compositions, crystal structure, grain size, particle morphology and the distribution of catalyst element. Hydrogen storage capacities and the hydriding-dehydriding kinetics of the new materials have been measured at different temperatures using a Sieverts apparatus. It is observed that mechanical alloying accelerates the hydrogenation kinetics of the magnesium based materials at low temperature, but a high temperature must be provided to release the absorbed hydrogen from the hydrided magnesium based materials. It is believed that the dehydriding temperature is largely controlled by the thermodynamic configuration of magnesium hydride. Doping Mg-Ni nano/amorphous composite materials with lanthanum reduces the hydriding and dehydriding temperature. Although the stability of MgH2 can not be easily reduced by ball milling alone, the results suggest the thermodynamic properties of Mg-Ni nano/amorphous composite materials can be alternated by additives such as La or other effective elements. Further investigation toward understanding the mechanism of additives will be rewarded.

The electronic structure, crystalline feature and morphology of the tetrahydrofuran (THF) treated magnesium, along with its hydriding and dehydriding properties have been investigated. The THF treated magnesium absorbs 6.3 wt per cent hydrogen at 723K and 3.5 MPa. After hydrogenation, in addition to the expected MgH2, a new less-stable hydride phase appears at 673K, but not at a lower temperature. Desorption produces 5.5 wt per cent hydrogen at 723K against a back pressure of 1.3 Pa after 20 cycles of hydriding-dehydriding. The THF treatment improves the kinetics of hydrogen absorption and desorption significantly. From 723K to 623K, the THF treated Mg demonstrates acceptable reaction rates. XPS studies show that tetrahydrofuran treatment causes the electronic energy state of the magnesium surface atoms to change, but the XRD studies show the crystal structure remains unchanged. Metallographic observation of the bulk hydrides of THF treated magnesium reveal they are poly-crystalline wi th the wide-spreading slip bands and twins within the crystals, indicating the phase transformation upon hydriding causes serious stress and distortion. It appears this microstructural deformation explains the much higher energy requirements (higher pressure and temperature) for magnesium hydrogenation than the simple lattice expansion that accompany hydrogen uptake for LaNi5 and FeTi.

Measurements of the linear power spectrum of galaxies have placed tight constraints on neutrino masses. We extend the framework of the halo model of cosmological nonlinear matter clustering to include the effect of massive neutrino infall into cold dark matter (CDM) halos. The magnitude of the effect of neutrino clustering for three degenerate mass neutrinos with m{sub v{sub 1}} = 0.9 eV is of order {approx}1%, within the potential sensitivity of upcoming weak lensing surveys. In order to use these measurements to further constrain--or eventually detect--neutrino masses, accurate theoretical predictions of the nonlinear power spectrum in the presence of massive neutrinos will be needed, likely only possible through high-resolution multiple particle (neutrino, CDM and baryon) simulations.

The authors present a measurement of the cross section for Z production times the branching fraction to {tau} leptons, {sigma} {center_dot} Br(Z {yields} {tau}{sup +}{tau}{sup -}), in p{bar p} collisions at {radical}s = 1.96 TeV in the channel in which one {tau} decays into {mu}{nu}{sub {mu}}{nu}{sub {tau}}, and the other into hadrons + {nu}{sub {tau}} or e{nu}{sub e}{nu}{sub {tau}}. The data sample corresponds to an integrated luminosity of 226 pb{sup -1} collected with the D0 detector at the Fermilab Tevatron collider. The final sample contains 2008 candidate events with an estimated background of 55%. From this they obtain {sigma} {center_dot} Br(Z {yields} {tau}{sup +}{tau}{sup -}) = 237 {+-} 15(stat) {+-} 18(sys) {+-} 15(lum) pb, in agreement with the standard model prediction.

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The authors report on a search for pair production of first-generation scalar leptoquarks (LQ) in p{bar p} collisions at {radical}s = 1.96 TeV using an integrated luminosity of 252 pb{sup -1} collected at the Fermilab Tevatron collider by the D0 detector. They observe no evidence for LQ production in the topologies arising from LQ{ovr LQ} {yields} eqeq and LQ{ovr LQ} {yields} eqvq, and derive 95% C.L. lower limits on the LQ mass as a function of {beta}, where {beta} is the branching fraction for LQ {yields} eq. The limits are 241 and 218 GeV/c{sup 2} for {beta} = 1 and 0.5, respectively. These results are combined with those obtained by D0 at {radical}s = 1.8 TeV, which increases these LQ mass limits to 256 and 234 GeV/c{sup 2}.

In this paper we describe our approach to build a pipeline simulator for the future Large-scale Synoptic Survey Telescope (LSST). The simulated pipeline will be used to research and evaluate software architectures that are efficient and flexible. It will also be used to define the real-time software and hardware requirements needed to support the anticipated LSST data rates. The LSST data pipeline requirements are still being defined, however, previous surveys can provide a good source for data requirements. Our approach is to use the SuperMacho data pipeline as a prototyping tool to identify a framework for building Modular Data-Centric Pipeline (MDCP) architectures. The prototyping is done in a hierarchical fashion to help capture and define the general data attributes (schema) first. We then model other necessary components based on science and performance requirements. We use identified schemas or data attributes as a way to define a data model for LSST.

X-ray fluorescence spectroscopy is a widely used method for determining the electronic configuration and local structure of dilute species with high sensitivity. In the dilute limit, and for thin films, the X-ray fluorescence signal is directly proportional to the atomic sub-shell absorption coefficient. However, for concentrated samples, the well-documented self-absorption effect often leads to the severe suppression of XANES (X-ray Absorption Near-Edge Structure) and EXAFS (Extended X-ray Absorption Fine-Structure) amplitudes. Thus to recover the real value of the sub-shell absorption coefficient, it is important to apply correction procedures to the measured fluorescence spectra. In this paper, we describe a new straightforward method to correct for self-absorption effects (the difference in the measured fluorescence signal compared to that of the true sub-shell photoabsorption coefficient) in XANES and EXAFS fluorescence measurements. Using a variety of sample and detector configurations, this method is used to extract the sub-shell absorption coefficient on elemental nickel and thick single-crystals of Gd{sub 3}Ga{sub 5}O{sub 12} and LaAlO{sub 3}.

Yoffe's linear theory of dynamic brittle fracture suggests that crack motion will be unstable beyond {approx}70% of the Rayleigh speed, a prediction that is not supported by experiment. We show by atomistic simulations that hyperelasticity, the elasticity of large strains, plays a governing role in the instability dynamics of brittle fracture. A simple scaling model based on an effective elastic modulus, coupled with Yoffe's solution, gives successful predictions for the onset speed of the crack instability.

Article on the correlation and prediction of partition coefficients between the gas phase and water, and the solvents dodecane and undecane.

We have developed a model of the diesel fuel injection process for application to analysis of low temperature non-sooting combustion. The model uses a simplified mixing correlation and detailed chemical kinetics, and analyzes a parcel of fuel as it moves along the fuel jet, from injection into evaporation and ignition. The model predicts chemical composition and soot precursors, and is applied at conditions that result in low temperature non-sooting combustion. Production of soot precursors is the first step toward production of soot, and modeling precursor production is expected to give insight into the overall evolution of soot inside the engine. The results of the analysis show that the model has been successful in describing many of the observed characteristics of low temperature combustion. The model predicts results that are qualitatively similar to those obtained for soot formation experiments at conditions in which the EGR rate is increased from zero to very high values as the fueling rate is kept constant. The model also describes the two paths to achieve non-sooting combustion. The first is smokeless rich combustion and the second is modulated kinetics (MK). The importance of the temperature after ignition and the equivalence ratio at the time of ignition …

We have developed a methodology for analysis of PCCI engines that applies to conditions in which there is some stratification in the air-fuel distribution inside the cylinder at the time of combustion. Our analysis methodology consists of two stages: first, a fluid mechanics code is used to determine temperature and equivalence ratio distributions as a function of crank angle, assuming motored conditions. The distribution information is then used for grouping the mass in the cylinder into a two-dimensional (temperature-equivalence ratio) array of zones. The zone information is then handed on to a detailed chemical kinetics model that calculates combustion, emissions and engine efficiency information. The methodology applies to situations where chemistry and fluid mechanics are weakly linked. The results of the multi-zone model have been compared to the results obtained from a fully integrated code, in which a chemical kinetics code is directly linked into a fluid mechanics code to calculate chemistry in every cell of the grid. The results show that the multi-zone model predicts burn duration and peak cylinder pressure with good accuracy. However, ignition timing predicted by the multi-zone model is sensitive to the transition angle between the fluid mechanics code and the chemical kinetics code. The …

We have conducted a detailed numerical analysis of HCCI engine operation at low loads to investigate the sources of HC and CO emissions and the associated combustion inefficiencies. Engine performance and emissions are evaluated as fueling is reduced from typical HCCI conditions, with an equivalence ratio f = 0.26 to very low loads (f = 0.04). Calculations are conducted using a segregated multi-zone methodology and a detailed chemical kinetic mechanism for iso-octane with 859 chemical species. The computational results agree very well with recent experimental results. Pressure traces, heat release rates, burn duration, combustion efficiency and emissions of hydrocarbon, oxygenated hydrocarbon, and carbon monoxide are generally well predicted for the whole range of equivalence ratios. The computational model also shows where the pollutants originate within the combustion chamber, thereby explaining the changes in the HC and CO emissions as a function of equivalence ratio. The results of this paper contribute to the understanding of the high emission behavior of HCCI engines at low equivalence ratios and are important for characterizing this previously little explored, yet important range of operation.

This paper illustrates the applicability of a sequential fluid mechanics, multi-zone chemical kinetics model to analyze HCCI experimental data for two combustion chamber geometries with different levels of turbulence: a low turbulence disc geometry (flat top piston), and a high turbulence square geometry (piston with a square bowl). The model uses a fluid mechanics code to determine temperature histories in the engine as a function of crank angle. These temperature histories are then fed into a chemical kinetic solver, which determines combustion characteristics for a relatively small number of zones (40). The model makes the assumption that there is no direct linking between turbulence and combustion. The results show that the multi-zone model yields good results for both the disc and the square geometries. The model makes good predictions of pressure traces and heat release rates. The experimental results indicate that the high turbulence square geometry has longer burn duration than the low turbulence disc geometry. This difference can be explained by the sequential multi-zone model, which indicates that the cylinder with the square bowl has a thicker boundary layer that results in a broader temperature distribution. This broader temperature distribution tends to lengthen the combustion, as cold mass within …

This paper presents an evaluation of the applicability of Homogeneous Charge Compression Ignition Engines (HCCI) for small-scale cogeneration (less than 1 MWe) in comparison to five previously analyzed prime movers. The five comparator prime movers include stoichiometric spark-ignited (SI) engines, lean burn SI engines, diesel engines, microturbines and fuel cells. The investigated option, HCCI engines, is a relatively new type of engine that has some fundamental differences with respect to other prime movers. Here, the prime movers are compared by calculating electric and heating efficiency, fuel consumption, nitrogen oxide (NOx) emissions and capital and fuel cost. Two cases are analyzed. In Case 1, the cogeneration facility requires combined power and heating. In Case 2, the requirement is for power and chilling. The results show that the HCCI engines closely approach the very high fuel utilization efficiency of diesel engines without the high emissions of NOx and the expensive diesel fuel. HCCI engines offer a new alternative for cogeneration that provides a unique combination of low cost, high efficiency, low emissions and flexibility in operating temperatures that can be optimally tuned for cogeneration systems. HCCI engines are the most efficient technology that meets the oncoming 2007 CARB NOx standards for cogeneration …

Article on the co-localization of L-phenylalanine ammonia-lyase and cinnamate 4-hydroxylase for metabolic channeling in phenylpropanoid biosynthesis.

Some of the global warming effect of anthropogenic greenhouse gases is offset by increased solar reflection from clouds with smaller droplets that form on increased numbers of cloud condensation nuclei in polluted air. The global magnitude of the resulting indirect aerosol climate forcing is estimated to be comparable (and opposed) to the anthropogenic carbon dioxide forcing, but estimates are highly uncertain because of complexities in characterizing the physical process that determine global aerosol and cloud populations and their interactions. Beyond reflecting sunlight more effectively, smaller droplets are less efficient at producing precipitation, and decreased precipitation is expected to result in increased cloud water and cloud cover, further increasing the indirect forcing. Yet polluted marine boundary-layer clouds are not generally observed to hold more water. Here we use model simulations of stratocumulus clouds to show that suppression of precipitation from increased droplet concentrations leads to increased cloud water only when sufficient precipitation reaches the surface, a condition favored when the overlying air is moist. Otherwise, aerosol induced suppression of precipitation enhances entrainment of overlying dry air, thereby reducing cloud water and diminishing the indirect climate forcing.

The authors present a new measurement of the inclusive and differential production cross sections of J/{psi} mesons and b-hadrons in proton-antiproton collisions at {radical}s = 1960 GeV. The data correspond to an integrated luminosity of 39.7 pb{sup -1} collected by the CDF Run II detector. They find the integrated cross section for inclusive J/{psi} production for all transverse momenta from 0 to 20 GeV/c in the rapidity range |y| < 0.6 to be 4.08 {+-} 0.02(stat){sub -0.33}{sup +0.36}(syst) {mu}b. They separate the fraction of J/{psi} events from the decay of the long-lived b-hadrons using the lifetime distribution in all events with p{sub T}(J/{psi}) > 1.25 GeV/c. They find the total cross section for b-hadrons, including both hadrons and anti-hadrons, decaying to J/{psi} with transverse momenta greater than 1.25 GeV/c in the rapidity range |y(J/{psi})| < 0.6, is 0.330 {+-} 0.005(stat){sub -0.033}{sup +0.036}(syst) {mu}b. Using a Monte Carlo simulation of the decay kinematics of b-hadrons to all final states containing a J/{psi}, they extract the first measurement of the total single b-hadron cross section down to zero transverse momentum at {radical}s = 1960 GeV. They find the total single b-hadron cross section integrated over all transverse momenta for b-hadrons in the …

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