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Baeyer-Villiger Oxidation of 1,7- & 1,9-dibromopentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione

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Baeyer-Villiger oxidation of 1,9-dibromopentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione (1,9-dibromo-PCU-8,11-dione) was performed by using an excess amount of m-chloroperbenzoic acid (3 equivalents) and resulted in the formation of the corresponding monolactone. The reaction would not proceed to the dilactone stage. The structure of the reaction product was established unequivocally via single crystal X-ray diffraction. Baeyer-Villiger oxidation of 1,9-dibromo-PCU-8,11-dione using ceric ammonium nitrate (CAN) was also performed and afforded a mixture of lactones. Only one of these lactones, which also contained an alkene functionality, could be isolated and characterized. 1,7-dibromo-PCU-8,11-dione was also reacted with CAN, yielding the mono-lactone, which has also been characterized.
Date: May 2004
Creator: Akinola, Adeniyi O.
System: The UNT Digital Library

Utilization of Corridor Habitat by White-tailed Deer (Odocoileus virginianus) in Denton County, Texas

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White-tailed deer (Odocoileus virginianus) (N=15) movements were determined with use of radio telemetry techniques to determine the utilization of corridor habitat on the Lake Ray Roberts Greenbelt Corridor (RRGC) in north central Texas. Home ranges were calculated using three estimation types. Male white-tailed deer tend to have home ranges twice that of female home ranges. Seasonal home ranges were largest during spring (Feb. - April) and fall (Aug. - Oct.) seasons. Males had greater seasonal variation in utilization than females. No statistically significant difference (p=0.24) between white-tailed deer locations when the RRGC experiences heavy human traffic compared to days when there is light human traffic. Linearity indices indicated home ranges less linear than expected (LI = 3.02). The RRGC should be maintained at its current status to provide a variety of vegetational types and protective cover for white-tailed deer and other wildlife of Denton County.
Date: May 2004
Creator: Bruce, Troy Kenneth
System: The UNT Digital Library

Effects of Thickness and Indenter Tip Geometry in Nanoindentation of Nickel Films

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Nanoindentation has become a widely used technique to measure the mechanical properties of materials. Due to its capability to deform materials in micro- and nano-scale, nanoindentation has found more applications in characterizing the deformation behavior and determining the mechanical properties of thin films and coatings. This research deals with the characterization of samples received from Center for Advanced Microstructures and Devices (CAMD) and Integran Technologies Inc., Toronto, Canada and the objective of this investigation was to utilize the experimental data obtained from nanoindentation to determine the deformation behavior, mechanical properties of thin films on substrates and bulk materials, and the effect of geometrically different indenters (Berkovich, cubecorner, and conical). X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscopy (SEM), and atomic force microscopy (AFM) analysis were performed on these materials to determine the crystal orientation, grain size of the material, and also to measure any substrate effects like pile-up or sin-in respectively. The results indicate that indentation size effect (ISE) strongly depends on shape of the indenter and less sensitive to penetration depth where as the hardness measurements depends on shape of indenter and depth of penetration. There is a negligible strain rate dependency of hardness at deeper depths …
Date: May 2004
Creator: Parakala, Padma
System: The UNT Digital Library

The Relationship of Acculturation Stress and Leisure Satisfaction of Hispanic College Students

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Hispanics are the fastest growing minority group in the U.S. and signs indicate a similar trend in their college enrollment. Leisure activities are known to have a moderating effect on individuals experiencing stress in their lives. Hispanic organizations registered with a major 4-year metropolitan university were targeted. The hypothesis for this study was there is no relationship between acculturation stress and leisure satisfaction. Results indicate no relationship between acculturation stress and leisure satisfaction. One explanation for this lack of a significant relationship between these two measures might be that these college students had obtained a high level of acculturation, which would explain the relatively low level of acculturation stress reported.
Date: May 2004
Creator: Pacleb, Selverio V.
System: The UNT Digital Library

Design of Power Amplifier Test Signals with a User-Defined Multisine

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Cellular radio communication involves wireless transmission and reception of signals at radio frequencies (RF). Base stations house equipment critical to the transmission and reception of signals. Power amplifier (PA) is a crucial element in base station assembly. PAs are expensive, take up space and dissipate heat. Of all the elements in the base station, it is difficult to design and operate a power amplifier. New designs of power amplifiers are constantly tested. One of the most important components required to perform this test successfully is a circuit simulator model of an entire communication system that generates a standard test signal. Standard test signals 524,288 data points in length require 1080 hours to complete one test of a PA model. In order to reduce the time taken to complete one test, a 'simulated test signal,' was generated. The objective of this study is to develop an algorithm to generate this 'simulated' test signal such that its characteristics match that of the 'standard' test signal.
Date: May 2004
Creator: Nagarajan, Preeti
System: The UNT Digital Library

Polymorphous

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The first section explores how far I could stretch dichotomy in formal terms, while maintaining a visually resonant image. I wanted to manipulate a superficial surface filtered through "natural forms" as seen in scientific imagery. By this I wanted to create access to a place where forms could play and imagination could wander. I was seeking to find a confluence in seemingly opposing forces that would coexist in the same work. The second section answers questions I had established for myself. The most important discovery I made was about the true nature of what I called a dichotomy in my work. The last section discusses the conclusions drawn from mounting the Master of Fine Arts Exhibition. I found that my interests resided more in investigating an already confluent dualism, as opposed to reconciling a conflicting dichotomy.
Date: May 2004
Creator: Maxwell, Sarah
System: The UNT Digital Library

A Wet Etch Release Method for Silicon Microelectromechanical Systems (MEMS) Using Polystyrene Microspheres for Improved Yield

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One of the final steps in fabricating microelectromechanical devices often involves a liquid etch release process. Capillary forces during the liquid evaporation stage after the wet etch process can pull two surfaces together resulting in adhesion of suspended microstructures to the supporting substrate. This release related adhesion can greatly reduce yields. In this report, a wet etch release method that uses polystyrene microspheres in the final rinse liquid is investigated. The polystyrene microspheres act as physical barriers between the substrate and suspended microstructures during the final liquid evaporation phase. A plasma ashing process is utilized to completely remove the polystyrene microspheres from the microstructure surfaces. Using this process, release yields > 90% were achieved. It is found that the surface roughness of gold surfaces increases while that of the silicon is reduced due to a thin oxide that grows on the silicon surface during the plasma process.
Date: May 2004
Creator: Mantiziba, Fadziso
System: The UNT Digital Library

Space Vessels

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The submarine and the spaceship fit in perfectly with the ideas of permanence and protection on which my work has been focusing. It is not coincidental that I have long been fascinated with the shapes and mechanisms of these vehicles. They are complex machines designed for a complex function; I find the precision of this to be appealing. I have used their shapes and mechanisms as design aspect in my thesis work. Also, in the studio, I have developed a type of Damascus steel bowl by modifying a technique once used for making gun barrels. I have made three small vessels inspired by spaceships and submarines using this modified technique.
Date: May 2004
Creator: Herndon, Mark
System: The UNT Digital Library

Ethics Naturally: An Environmental Ethic Based on Naturalness

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In this thesis I attempt to base an environmental ethic on a quality called naturalness. I examine it in terms of quantification, namely, as to whether it can quantified? I then apply the concept to specific areas such as restoration and conservation to create an environmental ethic and to show how such an ethic would be beneficial in general, and especially to policy issues concerning the environment. The thesis consists of three chapters: (1) the definition of nature and natural by way of a historical approach; (2) the place of humans in this scheme; and (3) the place of value and the discussion concerning quantification.
Date: May 2004
Creator: Leard, Jason
System: The UNT Digital Library

The Rise, Fall, and Redemption of Oran M. Roberts

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This thesis analyzes the political career of Oran M. Roberts during the critical period from 1850 to 1873. Through a reassessment of Roberts's extensive personal papers in the context of modern historical scholarship, the author explains how Roberts's political philosophy reflected the biases and prejudices typical of his era, as well as his own material interests and ambitions. Topic areas covered include Roberts's position on the Compromise of 1850, his constitutional philosophy, his involvement in the secession movement in Texas (including his service as president of the state secession convention), his military career during the Civil War, his participation in Presidential Reconstruction, his views on Congressional Reconstruction, and his role in the process of "redemption" in Texas.
Date: May 2004
Creator: Klemme, A. Christian
System: The UNT Digital Library

A Country With No Name

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A Country With No Name is a collection of thirty-four poems with a preface explaining the style and influences of the author. The preface defends plain-language techniques in poetry, using W.H. Auden, Wislawa Szymborska, and Paul Simon as examples of poets who take a similar approach. The poems range in topic from personal and familial to societal and abstract. The main subjects encompass interpersonal relationships, romantic and otherwise, and larger concerns, such as the effects of war and modern lifestyles.
Date: May 2004
Creator: Hunziker, April
System: The UNT Digital Library

Use of Fading Procedures and Positive Reinforcement to Increase Consumption of Non-Preferred Food in a Child with Autism

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Traditionally children with developmental disabilities who develop feeding issues can be at great risk for malnutrition. Failure to eat adequate amounts of food and/or insistence on eating a limited range of foods can be detrimental to a child's health and can lead to other behavioral difficulties. Feeding problems are difficult to treat because high levels of physical prompting can quickly create an aversion to eating as well as cause stress for both parents and children. Behavioral problems that range from moderate to extremely maladaptive can ensue. The question the present study addressed was whether or not a treatment package including only positive reinforcement and fading for a non-preferred food would result in independent eating of the targeted non-preferred food.
Date: May 2004
Creator: Vorpahl, Cresse Merchant
System: The UNT Digital Library

The Effects of Parent Training on the Amount and Variety of Food Consumed By a Child with Autism.

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The current study assessed the effectiveness of a training package, delivered in the form of a manual, to teach a parent to increase the variety and amount of food consumed by her son. The participant was a 5-year-old boy with Pervasive Developmental Disorder and limited food consumption. A changing criterion design across two variables, variety of food and quantity of food, was used. Results were that the parent who used the manual, with limited assistance from the experimenter, did succeed in increasing food variety and quantity of target foods.
Date: May 2004
Creator: VanKirk, Tessa Schreiber
System: The UNT Digital Library

Culturing Vallisneria americana for Restoration Efforts

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Robust Vallisneria americana was cultured for restoration purposes. Preliminary studies, with various iron treatments, were conducted to ascertain the amount of phosphorous release into the water column from sediments. There was a significant difference in the amount of phosphorous released if commercial sediment was used with a low iron amendment or without an iron amendment. The second study consisted of planting V. americana on two different sediment types while supplying half of the plants with additional CO2. Plants grown on pond sediment with additional CO2 had significantly more biomass. In the third study all plants were grown on pond sediment, and half were treated with CO2. All plants that were treated with additional CO2 had significantly more biomass than those that were aerated.
Date: May 2004
Creator: Tanski, Erin M.
System: The UNT Digital Library

Key Components of a Comprehensive Visual Information System for College-Level Design Education Curriculum Analysis

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Electronic and computer technology have advanced and transformed graphic design. New technologies are forcing design educators to constantly monitor and update their programs, creating a need for a system to be adopted by college-level institutions to better investigate, evaluate and plan art and design curriculum. The author identifies metaphorical approaches to designing a two-part solution, which includes a Comprehensive Visual Information System (CVIS) and Three-Dimensional Virtual Database (3DVDb), which assign volumetric form to education components based on the form, structure and content of a discipline. Research and development of the conceptual design for the CVIS and 3DVDb are intended to aid in the development of an electronic media solution to be made accessible to students, faculty and administrators.
Date: May 2004
Creator: Short, Scott Allen
System: The UNT Digital Library

Preparation and characterization of praseodymium oxide films and powders.

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Nanocrystalline praseodymium oxide films have been successfully generated on stainless steel substrates. The electrochemical deposition was performed in the cathode compartment of a divided electrochemical cell with a regular three-electrode configuration. The green films obtained by electrodeposition were then annealed at high temperatures for 1-3 hours. X-ray diffraction revealed the fluorite structure of Pr6O11 and the crystallite size was calculated. X-ray photoelectron spectroscopy was employed to study the composition of the oxide films and also the oxidation state of Pr. Scanning electron microscopy was utilized to study the surface texture and microstructure of deposits. Fourier transform infrared spectrometery was used to investigate the composition of the films. The effects of different conditions on the green films were also studied such as different pH values of the electrolyte solution, different deposition modes, different supporting electrolytes and different applied current densities. Sintering experiments were conducted to investigate the properties of the green films. Praseodymium oxide powders were also successfully prepared by combining electrochemical methods with sintering processes. The praseodymium oxide powders were characterized by X-ray diffraction and Fourier transform infrared spectroscopy. The crystallite sizes of the powders were evaluated.
Date: May 2004
Creator: Shang, Yajuan
System: The UNT Digital Library

Instigating a Necessary Epiphany in Visual Message-Making for Design Educators and Future Communication Designers

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Man has used graphic signs and symbols to express a variety of thoughts and feelings since before the invention of writing; they have helped him to preserve the ideologies that have enabled him to articulate his conception of the world. Every culture in every historical era has invested the objects, animals and plants around it with a multitude of different psychological meanings to communicate its essential belief systems and social aspirations. In my document, I chose to shed light on the responsibility I believe design educators must assume regarding their ability to understand and teach the importance of how similar graphic signs, symbols, ideograms and icons are perceived differently by different cultures in the hyper-connected, inter-global economy of 21st century. It is very crucial not to discount the influence and correlation of symbolic, fundamental building blocks of design with the basic psychological functions that inform our subconscious, and are also informed by our individual social and cultural upbringings. People from different cultures may cognate these shapes similarly, but they perceive and encode their meanings based on their particular social and cultural influences. One-size-fits-all communication design solutions rarely work, especially when they are distributed to culturally diverse audiences, because various ethnic …
Date: May 2004
Creator: Sarkaria, Gagandeep
System: The UNT Digital Library

Selected Lute Music from Paris, Rés. Vmd. Ms. 27 from the Bibliothèque Nationale: Reconstruction, Edition, and Commentary

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Paris . Rés. Vmd. Ms. 27, known as Tl.1, or the Thibault Manuscript, is one of the earliest extant sources of lute music, containing twenty-four solos and eighty-six accompaniments for vocal compositions. The manuscript was copied in Italian lute tablature lacking rhythm signs, which makes it inaccessible for modern performance. Each selection contains a full score of the four-part vocal concordance, and the reconstructed lute part in both the original notation and keyboard transcription. The introductory study elaborates upon the creation dates for Tl.1 (ca. 1502-1512) through its relationship with the sources of the time and with the older unwritten tradition of Italian secular music that is apparent in the formal treatment of the music.
Date: December 2004
Creator: Sequera, Héctor J.
System: The UNT Digital Library

The impact of leisure travelers' characteristics on hotel Website attributes preference.

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Travel is now the largest online business-to-consumer product in the United States. Online hotel bookings are the second largest segment of online travel. Leisure travelers online spending will increase dramatically from 2002 to 2007. However, a majority of hospitality companies do not currently take advantage of the Internet as the cheapest and most efficient distribution medium. The purpose of this study examined leisure travelers' demographic and psychographic characteristics, online booking and travel frequency that influence travelers' desired hotel Website features and functions. The results found out that demographics (gender, occupation, and ethnicity), and psychographics (travel benefit sought), number of leisure travel trips per year, and number of online hotel bookings per year have impact on hotel Website attribute preferences.
Date: December 2004
Creator: Zhang, Li
System: The UNT Digital Library

Peptide-based hidden Markov model for peptide fingerprint mapping.

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Peptide mass fingerprinting (PMF) was the first automated method for protein identification in proteomics, and it remains in common usage today because of its simplicity and the low equipment costs for generating fingerprints. However, one of the problems with PMF is its limited specificity and sensitivity in protein identification. Here I present a method that shows potential to significantly enhance the accuracy of peptide mass fingerprinting, using a machine learning approach based on a hidden Markov model (HMM). This method is applied to improve differentiation of real protein matches from those that occur by chance. The system was trained using 300 examples of combined real and false-positive protein identification results, and 10-fold cross-validation applied to assess model discrimination. The model can achieve 93% accuracy in distinguishing correct and real protein identification results versus false-positive matches. The receiver operating characteristic (ROC) curve area for the best model was 0.833.
Date: December 2004
Creator: Yang, Dongmei
System: The UNT Digital Library

Police Officer Burnout: An Examination of Officer Stress, the Policing Subculture and the Advantages of Family Counseling

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The work of a police officer is stressful and could potentially lead to burnout. As a result, a variety of reactions may occur which include, cynicism, abuse of authority, and in extreme cases suicide. One method which has been proven to be effective in treating officer stress is counseling; however, because of the policing subculture the opportunity to seek counseling has been ignored. In order to successfully manage officer stress, the subculture must be dealt with. Additionally, the officers' family must also be acknowledged as being affected by officer burnout. Counseling services must be made available to the officer's family and through training they can become a source of support instead of an added source of stress to the officer.
Date: December 2004
Creator: Yanez, Luiz
System: The UNT Digital Library

Voting Operating System (VOS)

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The electronic voting machine (EVM) plays a very important role in a country where government officials are elected into office. Throughout the world, a specific operating system that tends to the specific requirement of the EVM does not exist. Existing EVM technology depends upon the various operating systems currently available, thus ignoring the basic needs of the system. There is a compromise over the basic requirements in order to develop the systems on the basis on an already available operating system, thus having a lot of scope for error. It is necessary to know the specific details of the particular device for which the operating system is being developed. In this document, I evaluate existing EVMs and identify flaws and shortcomings. I propose a solution for a new operating system that meets the specific requirements of the EVM, calling it Voting Operating System (VOS, pronounced 'voice'). The identification technique can be simplified by using the fingerprint technology that determines the identity of a person based on two fingerprints. I also discuss the various parts of the operating system that have to be implemented that can tend to all the basic requirements of an EVM, including implementation of the memory manager, …
Date: December 2004
Creator: Venkatadusumelli, Kiran
System: The UNT Digital Library

Solid phase microextraction of amino-dinitrotoluenes in tissue.

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TNT (2,4,6-trinitrotoluene) readily and predominantly transforms to 2ADNT (2-amino-4,6-dinitrotoluene) and 4ADNT (4-amino-2,6-dinitrotoluene) in environmental matrixes and tissues. Solid phase microextraction (SPME) was used to extract ADNTs (amino-dinitrotoluenes) from tissue as a potential method to investigate the recalcitrance of metabolically-generated ADNTs versus absorbed ADNTs. Tubifex tubifex was allowed to metabolize TNT into ADNTs in 24-hr static non-renewal exposure test followed by 24-hr depuration in clean reconstituted hard water. Polyacrylate-coated (PA) SPME fibers were then deployed and agitated in tissue homogenates containing metabolically-generated ADNTs for 48 hr to provide a measure of available ADNTs. Extractability of ADNTs from T. tubifex tissue containing metabolically-generated ADNTs was significantly less than extractability of ADNTs from T. tubifex tissue containing absorbed ADNTs: 50-60% and 81-90% of expected extractability based on fiber-water partition ratio. The lower SPME extractability of metabolically-generated ADNTs may stem from the unavailability of metabolically-generated ADNTs sequestered in tissue or bound to tissue macromolecules during metabolism of TNT to ADNT. Tissue extractions using SPMEs may be able to estimate such bound organic residues in tissue and serve as potential indicators of toxicological bioavailability and biomagnification potential of tissue-associated organic compounds.
Date: December 2004
Creator: Tsui-Bowen, Alethea
System: The UNT Digital Library

The Role of Violence in Hunt County, Texas, during Reconstruction

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The post Civil War period known as Reconstruction remains a topic of interest for historians. Having avoided the experience of invasion by Northern troops during the Civil War, the people living in the interior of the state of Texas accepted Confederate defeat at first. However, with the instituting of Northern efforts at Reconstruction, such as the installation of Republican interim government officials, the arrival of Freedmen's Bureau agents, and in some parts the stationing of federal troops, conservative whites throughout the state became defiant toward the federal government and its policies. Some white southerners even went so far as to take up arms and become embroiled in open conflict with the federal government and its local institutions. As a result, Unionist whites and freedmen found themselves to be the targets of groups of desperados committed to upholding the Southern Cause and ensuring the return of the conservative Democratic party to power in Texas politics. This study focuses on Hunt County from the years 1860 - 1873 to determine to what extent violence played a role in the era of Reconstruction. An analysis of data primarily from county, state, and federal records forms the basis of this study. The information obtained …
Date: December 2004
Creator: Hathcock, James A.
System: The UNT Digital Library