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ENHANCEMENT OF EQUILIBRIUMSHIFT IN DEHYDROGENATION REACTIONS USING A NOVEL MEMBRANE REACTOR (open access)

ENHANCEMENT OF EQUILIBRIUMSHIFT IN DEHYDROGENATION REACTIONS USING A NOVEL MEMBRANE REACTOR

With the advances in new inorganic materials and processing techniques, there has been renewed interest in exploiting the benefits of membranes in many industrial applications. Inorganic and composite membranes are being considered as potential candidates for use in membrane-reactor configuration for effectively increasing reaction rate, selectivity and yield of equilibrium limited reactions. To investigate the usefulness of a palladium-ceramic composite membrane in a membrane reactor-separator configuration, we investigated the dehydrogenation of cyclohexane by equilibrium shift. A two-dimensional pseudo-homogeneous reactor model was developed to study the dehydrogenation of cyclohexane by equilibrium shift in a tubular membrane reactor. Radial diffusion was considered to account for the concentration gradient in the radial direction due to permeation through the membrane. For a dehydrogenation reaction, the feed stream to the reaction side contained cyclohexane and argon, while the separation side used argon as the sweep gas. Equilibrium conversion for dehydrogenation of cyclohexane is 18.7%. The present study showed that 100% conversion could be achieved by equilibrium shift using Pd-ceramic membrane reactor. For a feed containing cyclohexane and argon of 1.64 x 10{sup -6} and 1.0 x 10{sup -3} mol/s, over 98% conversion could be readily achieved. The dehydrogenation of cyclohexane was also experimentally investigated in …
Date: February 13, 2001
Creator: Ilias, Shamsuddin & King, Franklin G.
Object Type: Report
System: The UNT Digital Library
Laboratory Scale Antifoam Studies for the STTPB Process (open access)

Laboratory Scale Antifoam Studies for the STTPB Process

Three candidate antifoam/defoam agents were tested on a laboratory scale with simulated KTPB slurry using the proposed STTPB process precipitation, concentration, and washing steps. Conclusions are if air entrainment in the slurry is carefully avoided, little or no foam will be generated during normal operations during precipitation, concentration, and washing of the precipitate. Three candidate antifoam/defoam agents were tested on a laboratory scale with simulated KTPB slurry using the proposed STTPB process precipitation, concentration and washing steps. In all cases little or no foam formed during normal operations of precipitation, concentration and washing. Foam was produced by purposely-introducing gas sub-surface into the slurry. Once produced, the IIT B52 antifoam was effective in defoaming the slurry. In separate foam column tests, all antifoam/defoam agents were effective in mitigating foam formation and in defoaming a foamed 10 wt % insoluble solids slurry. Based on the results in this report as well as foam column studies at IIT, it is recommended that IIT B52 antifoam at the 1000 ppmV level be used in subsequent STTPB work where foaming is a concern. This study indicates that the addition of antifoam agent hinders the recovery of NaTPB during washing. Washing precipitate with no antifoam agent …
Date: February 13, 2001
Creator: Baich, M. A.
Object Type: Report
System: The UNT Digital Library
CST/Water Slurry Mixing and Resuspension (open access)

CST/Water Slurry Mixing and Resuspension

Crystalline Silicotitanate (CST) was selected as one of the alternatives to the In-Tank Precipitation Process (ITP) for removal of cesium from the salt waste at Savannah River Site. The proposed salt waste treatment process using CST would involve passing a filtered salt waste through a fixed bed of CST. The CST would remove the cesium from the salt waste by ion exchange and the decontaminated salt would be incorporated into the Saltstone Process. This report documents the results of investigations into the mixing and re-suspension characteristics of two 10 wt percent CST slurries.
Date: February 13, 2001
Creator: Baich, M. A.
Object Type: Report
System: The UNT Digital Library
Wet-Etch Figuring Optical Figuring by Controlled Application of Liquid Etchant (open access)

Wet-Etch Figuring Optical Figuring by Controlled Application of Liquid Etchant

WET-ETCH FIGURING (WEF) is an automated method of precisely figuring optical materials by the controlled application of aqueous etchant solution. This technology uses surface-tension-gradient-driven flow to confine and stabilize a wetted zone of an etchant solution or other aqueous processing fluid on the surface of an object. This wetted zone can be translated on the surface in a computer-controlled fashion for precise spatial control of the surface reactions occurring (e.g. chemical etching). WEF is particularly suitable for figuring very thin optical materials because it applies no thermal or mechanical stress to the material. Also, because the process is stress-free the workpiece can be monitored during figuring using interferometric metrology, and the measurements obtained can be used to control the figuring process in real-time--something that cannot be done with traditional figuring methods.
Date: February 13, 2001
Creator: Britten, J
Object Type: Report
System: The UNT Digital Library
Major Tax Issues in the 106th Congress: A Retrospective Summary (open access)

Major Tax Issues in the 106th Congress: A Retrospective Summary

None
Date: February 13, 2001
Creator: unknown
Object Type: Report
System: The UNT Digital Library
The Boerne Star (Boerne, Tex.), Vol. 96, No. 13, Ed. 1 Tuesday, February 13, 2001 (open access)

The Boerne Star (Boerne, Tex.), Vol. 96, No. 13, Ed. 1 Tuesday, February 13, 2001

Semiweekly newspaper from Boerne, Texas that includes local, state, and national news along with advertising.
Date: February 13, 2001
Creator: Keasling, Edna & Pritchett, Melissa
Object Type: Newspaper
System: The Portal to Texas History
Letter to Susan Bussey regarding Benito Bowie (open access)

Letter to Susan Bussey regarding Benito Bowie

Letter to the Pardon and Parole board advocating for Benito Bowie. Asking he be granted parole.
Date: February 13, 2001
Creator: Lemaster, Tony
Object Type: Letter
System: The Gateway to Oklahoma History
The Baytown Sun (Baytown, Tex.), Vol. 79, No. 79, Ed. 1 Tuesday, February 13, 2001 (open access)

The Baytown Sun (Baytown, Tex.), Vol. 79, No. 79, Ed. 1 Tuesday, February 13, 2001

Daily newspaper from Baytown, Texas that includes local, state, and national news along with advertising.
Date: February 13, 2001
Creator: Cash, Wanda Garner
Object Type: Newspaper
System: The Portal to Texas History
Altus Times (Altus, Okla.), Vol. 101, No. 287, Ed. 1 Tuesday, February 13, 2001 (open access)

Altus Times (Altus, Okla.), Vol. 101, No. 287, Ed. 1 Tuesday, February 13, 2001

Daily newspaper from Altus, Oklahoma that includes local, state, and national news along with advertising.
Date: February 13, 2001
Creator: Bush, Michael
Object Type: Newspaper
System: The Gateway to Oklahoma History
[Letter from Sue Lovell to many Texas Human Rights Foundation members, February 13, 2001] (open access)

[Letter from Sue Lovell to many Texas Human Rights Foundation members, February 13, 2001]

Letter from Sue Lovell to many different members of the Texas Human Rights Foundation discussing the Schwab Award ceremony details and changes to the date of the ceremony.
Date: February 13, 2001
Creator: Lovell, Sue
Object Type: Letter
System: The Portal to Texas History
Rains County Leader (Emory, Tex.), Vol. 113, No. 35, Ed. 1 Tuesday, February 13, 2001 (open access)

Rains County Leader (Emory, Tex.), Vol. 113, No. 35, Ed. 1 Tuesday, February 13, 2001

Weekly newspaper from Emory, Texas that includes local, state, and national news along with advertising.
Date: February 13, 2001
Creator: Hill, Earl Clyde, Jr.
Object Type: Newspaper
System: The Portal to Texas History
[News Clip: Hannibal] captions transcript

[News Clip: Hannibal]

Video footage from the KXAS-TV/NBC station in Fort Worth, Texas, to accompany a news story about a movie clip.
Date: February 13, 2001, 4:00 p.m.
Creator: KXAS-TV (Television station : Fort Worth, Tex.)
Object Type: Video
System: The UNT Digital Library
Sapulpa Daily Herald (Sapulpa, Okla.), Vol. 85, No. 130, Ed. 1 Tuesday, February 13, 2001 (open access)

Sapulpa Daily Herald (Sapulpa, Okla.), Vol. 85, No. 130, Ed. 1 Tuesday, February 13, 2001

Daily newspaper from Sapulpa, Oklahoma that includes local, state, and national news along with advertising.
Date: February 13, 2001
Creator: Quinnelly, Lorrie J.
Object Type: Newspaper
System: The Gateway to Oklahoma History
Data Summary Report for Savannah River Integrator Operable Unit Fish Tissue (open access)

Data Summary Report for Savannah River Integrator Operable Unit Fish Tissue

This report presents the results of the verification and validation of the analytical data for the Savannah River Fish (SRF) investigation. The data were validated to determine if the records conform to the technical criteria associated with definitive data.
Date: February 13, 2001
Creator: Craig, B.
Object Type: Report
System: The UNT Digital Library
Experimental Studies on Attenuation of Pressure Waves Induced by Thermal Shocks (open access)

Experimental Studies on Attenuation of Pressure Waves Induced by Thermal Shocks

High magnitude pressure waves are expected in the mercury-filled Spallation Neutron Source target system. An appropriate measure is needed to protect the target system from such high pressure waves. It has been known that inclusion of devices like scattering centers in the pressure field will attenuate pressure waves by scattering waves between scattering centers. A series of experiments have been conducted to test such a concept. After verifying the concept by performing simple scoping experiments, fives series of experiments were conducted with various configuration to measure changes in sound speed and pressure amplitude with inclusion of various scattering centers. Results indicate that for the conditions of our test, no significant change in sound speed was observed; however, substantial attenuation of pressure waves was detected with scattering centers in mercury.
Date: February 13, 2001
Creator: Kim, S. H.
Object Type: Article
System: The UNT Digital Library
Scientific Presentation. 7th Meeting of the Management Steering Committee of the RIKEN BNL Collaboration. (open access)

Scientific Presentation. 7th Meeting of the Management Steering Committee of the RIKEN BNL Collaboration.

The RIKEN BNL Research Center (RBRC) was established in April 1997 at Brookhaven National Laboratory. It is funded by the ''Rikagaku Kenkysho,'' (RIKEN) The Institute of Physical and Chemical Research, of Japan. The Center is dedicated to the study of strong interactions, including hard QCD/spin physics, lattice QCD and RHIC (Relativistic Heavy Ion Collider) physics through nurturing of a new generation of young physicists. The Director of RBRC is Professor T. D. Lee. The first years were dedicated to the establishment of a theory group. This has essentially been completed consisting of Fellows, Postdocs, and RHIC Physics/University Fellows, with an active group of consultants. The center also organizes an extensive series of workshops on specific topics in strong interactions with an accompanying series of published proceedings. In addition, a 0.6 teraflop parallel processor computer has been constructed and operational since August 1998. It was awarded the Supercomputer 1998 Gordon Bell Prize for price performance. An active experimental group centered around the spin physics program at RHIC has subsequently also been established at RBRC. It presently consists of five Fellows, one Postdoc and several scientific collaborators with more appointments being expected in the near future. Members and participants of RBRC on …
Date: February 13, 2001
Creator: Lee, T. D.
Object Type: Report
System: The UNT Digital Library
Site Characterization Work Plan for Gnome-Coach Site, New Mexico (open access)

Site Characterization Work Plan for Gnome-Coach Site, New Mexico

Project Gnome was the first nuclear experiment conducted under the U.S. Atomic Energy Commission (AEC), predecessor to the U.S. Department of Energy (DOE), Plowshare Program. Gnome was part of a joint government-industry experiment focused on developing nuclear devices exclusively for peaceful purposes. The intent of the Gnome experiment was to evaluate the effects of a nuclear detonation in a salt medium. Historically, Project Gnome consisted of a single detonation of a nuclear device on December 10, 1961. Since the Gnome detonation, the AEC/DOE has conducted surface restoration, site reconnaissance, and decontamination and decommissioning activities at the site. In addition, annual groundwater sampling is performed under a long-term hydrological monitoring program begun in 1980. Coach, an experiment to be located near the Gnome project, was initially scheduled for 1963. Although construction and rehabilitation were completed for Coach, the experiment was canceled and never executed. Known collectively as Project Gnome-Coach, the site is situated within the Salado Formation approximately 25 miles east of Carlsbad, New Mexico, in Eddy County, and is comprised of nearly 680 acres, of which 60 acres are disturbed from the combined AEC/DOE operations. The scope of this work plan is to document the environmental objectives and the proposed …
Date: February 13, 2001
Creator: United States. Department of Energy. Nevada Operations Office.
Object Type: Report
System: The UNT Digital Library
Scientific Presentation. 7th Meeting of the Management Steering Committee of the RIKEN BNL Collaboration. (open access)

Scientific Presentation. 7th Meeting of the Management Steering Committee of the RIKEN BNL Collaboration.

The RIKEN BNL Research Center (RBRC) was established in April 1997 at Brookhaven National Laboratory. It is funded by the ''Rikagaku Kenkysho,'' (RIKEN) The Institute of Physical and Chemical Research, of Japan. The Center is dedicated to the study of strong 'interactions, including hard QCD/spin physics, lattice QCD and RHIC (Relativistic Heavy Ion Collider) physics through nurturing of a new generation of young physicists. The Director of RBRC is Professor T. D. Lee. The first years were dedicated to the establishment of a theory group. This has essentially been completed consisting of Fellows, Postdocs, and RHIC Physics/University Fellows, with an active group of consultants. The center also organizes an extensive series of workshops on specific topics in strong interactions with an accompanying series of published proceedings. In addition, a 0.6 teraflop parallel processor computer has been constructed and operational since August 1998. It was awarded the Supercomputer 1998 Gordon Bell Prize for price performance. An active experimental group centered around the spin physics program at RHIC has subsequently also been established at RBRC. It presently consists of five Fellows, one Postdoc and several scientific collaborators with more appointments being expected in the near future. Members and participants of RBRC on …
Date: February 13, 2001
Creator: Lee, T. D.
Object Type: Report
System: The UNT Digital Library
Multiphase Flow and Cavern Abandonment in Salt (open access)

Multiphase Flow and Cavern Abandonment in Salt

This report will explore the hypothesis that an underground cavity in gassy salt will eventually be gas filled as is observed on a small scale in some naturally occurring salt inclusions. First, a summary is presented on what is known about gas occurrences, flow mechanisms, and cavern behavior after abandonment. Then, background information is synthesized into theory on how gas can fill a cavern and simultaneously displace cavern fluids into the surrounding salt. Lastly, two-phase (gas and brine) flow visualization experiments are presented that demonstrate some of the associated flow mechanisms and support the theory and hypothesis that a cavity in salt can become gas filled after plugging and abandonment
Date: February 13, 2001
Creator: Ehgartner, Brian & Tidwell, Vince
Object Type: Report
System: The UNT Digital Library
Fusion Materials Semiannual Progress Report for Period Ending June 30, 2000 (open access)

Fusion Materials Semiannual Progress Report for Period Ending June 30, 2000

This is the twenty-eighth in a series of semiannual technical progress reports on fusion materials. This report combines the full spectrum of research and development activities on both metallic and non-metallic materials with primary emphasis on the effects of the neutronic and chemical environment on the properties and performance of materials for in-vessel components. This effort forms one element of the materials program being conducted in support of the Fusion Energy Sciences Program of the U.S. Department of Energy. The other major element of the program is concerned with the interactions between reactor materials and the plasma and is reported separately.
Date: February 13, 2001
Creator: Berk, S.E.
Object Type: Report
System: The UNT Digital Library
Criteria for Determining Element Size and Time Step for Thermal Shock Simulation (open access)

Criteria for Determining Element Size and Time Step for Thermal Shock Simulation

Rapid energy deposition into spallation source targets can lead to their temperature rise at enormous rates, giving rise to dynamic thermoelastic stresses. Understanding and predicting the resulting stress waves are crucial for robust design and safe operation of such devices. To simulate the thermal shock phenomenon accurately, many factors should be carefully considered, such as geometry, surface condition, energy deposition profile, equation of state, possible cavitation, viscous damping, rate-dependent constitutive equation, element size, and time step. In this paper a closed form expression for the induced stress in slender bars with distributed energy deposition has been directly derived; it is then used to test the accuracy of computed results with FEA codes. It was found that significant errors can occur unless care is taken to restrict element size and time step depending on the boundary conditions, steepness of temperature profiles and rise rate. Criteria have been proposed for determining the above two parameters. Numerical simulation with the well-established ANSYS5.5 code system showed that excellent results could be achieved if the proposed criteria are met.
Date: February 13, 2001
Creator: Zheng, J.
Object Type: Article
System: The UNT Digital Library
Rubén Puente será teniente de la Policía de Tránsito (open access)

Rubén Puente será teniente de la Policía de Tránsito

News release about Ruben Puente joining DART Transit Police Department as a lieutenant.
Date: February 13, 2001
Creator: Lyons, Morgan
Object Type: Text
System: The Portal to Texas History
Ruben Puente becomes Lieutenant with DART Transit Police (open access)

Ruben Puente becomes Lieutenant with DART Transit Police

News release about Ruben Puente joining DART Transit Police Department as a lieutenant.
Date: February 13, 2001
Creator: Lyons, Morgan
Object Type: Text
System: The Portal to Texas History
The Oklahoma Daily (Norman, Okla.), Vol. 84, No. 101, Ed. 1 Tuesday, February 13, 2001 (open access)

The Oklahoma Daily (Norman, Okla.), Vol. 84, No. 101, Ed. 1 Tuesday, February 13, 2001

Student newspaper of the University of Oklahoma in Norman, Oklahoma that includes national, local, and campus news along with advertising.
Date: February 13, 2001
Creator: McFall, Amy
Object Type: Newspaper
System: The Gateway to Oklahoma History