Concerns about climate change have encouraged significant interest in concepts for ultra-low or ''zero''-emissions power generation systems. In some proposed concepts, nitrogen is removed from the combustion air and replaced with another diluent such as carbon dioxide or steam. In this way, formation of nitrogen oxides is prevented, and the exhaust stream can be separated into concentrated CO{sub 2} and steam or water streams. The concentrated CO{sub 2} stream could then serve as input to a CO{sub 2} sequestration process or utilized in some other way. Some of these concepts are illustrated in Figure 1. This project is an investigation of one approach to ''zero'' emission power generation. Oxy-fuel combustion is used with steam as diluent in a power cycle proposed by Clean Energy Systems, Inc. (CES) [1,2]. In oxy-fuel combustion, air separation is used to produce nearly pure oxygen for combustion. In this particular concept, the combustion temperatures are moderated by steam as a diluent. An advantage of this technique is that water in the product stream can be condensed with relative ease, leaving a pure CO{sub 2} stream suitable for sequestration. Because most of the atmospheric nitrogen has been separated from the oxidant, the potential to form any …

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A mathematical model is formulated to describe the dynamics of a rigid barrier filter system. Complete with filtration, regeneration and particle re-deposition, this model provides sizing information for new filter systems and diagnostic information for operating filter systems. To turn this model into a practical and smart filter system predictive model, monitoring devices for variables such as real-time particle concentration and size distribution are currently under laboratory development. The program goal is to introduce a smart filter system to supervise its operation and to assure its system reliability. Primarily, a smart filter system will update operating information, sound up malfunction alarms, and provide self-activated measures such as adjusting the cleaning frequency, intensity and back-pulse duration.

This report examines the major, foreign conventional weapon systems that China has acquired or has committed to acquire since 1990, with particular attention to implications for U.S. security concerns. It is not the assumption of this report that China’s military, the People’s Liberation Army (PLA), will engage in conflict with other forces in Asia. Nonetheless, since the mid-1990s, there has been increasing concern about China’s assertiveness in Asia and greater threats against Taiwan.

Circulating fluid bed technology offers the advantages of a plug flow, yet well-mixed, and high throughput reactor for power plant applications. The ability to effectively scale these systems in size, geometry, and operating conditions is limited because of the extensive deviation from ideal dilute gas-solids flow behavior (Monazam et al., 2001; Li, 1994). Two fluid computations show promise of accurately simulating the hydrodynamics in the riser circulating fluid bed; however, validation tests for large vessels with materials of interest to the power industry are lacking (Guenther et al., 2002). There is little available data in reactors large enough so that geometry (i.e. entrance, exit, and wall) effects do not dominate the hydrodynamics, yet with sufficiently large particle sizes to allow sufficiently large grid sizes to allow accurate and timely hydrodynamic simulations. To meet this need experimental tests were undertaken with relatively large particles of narrow size distribution in a large enough unit to reduce the contributions of wall effects and light enough to avoid geometry effects. While computational fluid dynamic calculations are capable of generating detailed velocity and density profiles, it is believed that the validation and model development begins with the ability to simulate the global flow regime transitions. …

In the current fiscal year FY01, several CFD simulations were conducted to investigate the effects of moisture in biomass/coal, particle injection locations, and flow parameters on carbon burnout and NO{sub x} inside a 150 MW GEEZER industrial boiler. Various simulations were designed to predict the suitability of biomass cofiring in coal combustors, and to explore the possibility of using biomass as a reburning fuel to reduce NO{sub x}. Some additional CFD simulations were also conducted on CERF combustor to examine the combustion characteristics of pulverized coal in enriched O{sub 2}/CO{sub 2} environments. Most of the CFD models available in the literature treat particles to be point masses with uniform temperature inside the particles. This isothermal condition may not be suitable for larger biomass particles. To this end, a stand alone program was developed from the first principles to account for heat conduction from the surface of the particle to its center. It is envisaged that the recently developed non-isothermal stand alone module will be integrated with the Fluent solver during next fiscal year to accurately predict the carbon burnout from larger biomass particles. Anisotropy in heat transfer in radial and axial will be explored using different conductivities in radial and …

In this paper we describe our progress toward creating a computational workbench for performing virtual simulations of Vision 21 power plants. The workbench provides a framework for incorporating a full complement of models, ranging from simple heat/mass balance reactor models that run in minutes to detailed models that can require several hours to execute. The workbench is being developed using the SCIRun software system. To leverage a broad range of visualization tools the OpenDX visualization package has been interfaced to the workbench. In Year One our efforts have focused on developing a prototype workbench for a conventional pulverized coal fired power plant. The prototype workbench uses a CFD model for the radiant furnace box and reactor models for downstream equipment. In Year Two and Year Three, the focus of the project will be on creating models for gasifier based systems and implementing these models into an improved workbench. In this paper we describe our work effort for Year One and outline our plans for future work. We discuss the models included in the prototype workbench and the software design issues that have been addressed to incorporate such a diverse range of models into a single software environment. In addition, we …

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The US Department of Energy (DOE) has awarded Foster Wheeler Development Corporation a contract to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% while producing near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The unique aspect of the process is that it utilizes a pressurized circulating fluidized bed partial gasifier and does not attempt to consume the coal in a single step. To convert all the coal to syngas in a single step requires extremely high temperatures ({approx} 2500 to 2800F) that melt and vaporize the coal and essentially drive all coal ash contaminants into the syngas. …

This report provides a brief summary of the existing drug certification requirements for drug producing and drug-transit countries, background on the experience, criticisms, and reform efforts under these provisions; a summary of early congressional options and proposals advanced in 2001, with possible advantages and disadvantages; a summary of later initiatives with legislative activity; and (5) a tracking of legislative action on the major initiatives.

A fixed-bed regenerable desulfurization sorbent, identified as RVS-land developed by researchers at the U.S. Department of Energy's National Energy Technology Laboratory, was awarded the R&D 100 award in 2000 and is currently offered as a commercial product by Sued-Chemie Inc. An extensive testing program for this sorbent was undertaken which included tests at a wide range of temperatures, pressures and gas compositions both simulated and generated in an actual gasifier for sulfidation and regeneration. This testing has demonstrated that during these desulfurization tests, the RVS-1 sorbent maintained an effluent H2S concentration of <5 ppmv at temperatures from 260 to 600 C (500-1100 F) and pressures of 203-2026 kPa(2 to 20 atm) with a feed containing 1.2 vol% H{sub 2}S. The types of syngas tested ranged from an oxygen-blown Texaco gasifier to biomass-generated syngas. The RVS-1 sorbent has high crush strength and attrition resistance, which, unlike past sorbent formulations, does not decrease with extended testing at actual at operating conditions. The sulfur capacity of the sorbent is roughly 17 to 20 wt.% and also remains constant during extended testing (>25 cycles). In addition to H{sub 2}S, the RVS-1 sorbent has also demonstrated the ability to remove dimethyl sulfide and carbonyl sulfide …

In hadronic physics, the nucleon structure and the quarks confinement are still topical issues. The neutral pion electroproduction and virtual Compton scattering (VCS) reactions allow us to access new observables that describe this structure. This work is focused on the VCS experiment performed at Jefferson Lab in 1998.

Ensemble Performance at the UNT College of Music Recital Hall.

Ensemble performance at the UNT College of Music Stan Kenton Hall.

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This is the final report for the interagency agreement between the Department of Energy and NASA, 94ER75989, titled U.S. DOE-FCCSET-Summer Teaching Enhancement Program. Our goal to enhance the classroom Instruction in the earth and environmental science programs in the secondary schools of the state of Maryland. The participation of 72 teachers of secondary school students were collaborative partners with the 24 local Maryland School System, the Maryland State Department of Education, the University of Maryland, and the Goddard Space Flight Center. The program enabled these teachers the opportunity to attend a four-week program to enhance the teaching of the earth and environmental sciences in the secondary schools of Maryland. Participants learned how earth systems are studied both from the ground station earth monitoring project and continued it during the school year with their students. Each teacher served as an ambassador for earth science teaching enhancement in their respective school and school system.

FuelCell Energy, INC. (FCE) is currently involved in the design of ultra high efficiency power plants under a cooperative agreement (DE-FC26-00NT40) managed by the National Energy Technology Laboratory (NETL) as part of the DOE's Vision 21 program. Under this project, FCE is developing a fuel cell/turbine hybrid system that integrates the atmospheric pressure Direct FuelCell{reg_sign} (DFC{reg_sign}) with an unfired Brayton cycle utilizing indirect heat recovery from the power plant. Features of the DFC/T{trademark} system include: high efficiency, minimal emissions, simplicity in design, direct reforming internal to the fuel cell, no pressurization of the fuel cell, independent operating pressure of the fuel cell and turbine, and potential cost competitiveness with existing combined cycle power plants at much smaller sizes. Objectives of the Vision 21 Program include developing power plants that will generate electricity with net efficiencies approaching 75 percent (with natural gas), while producing sulfur and nitrogen oxide emissions of less than 0.01 lb/million BTU. These goals are significant improvements over conventional power plants, which are 35-60 percent efficient and produce emissions of 0.07 to 0.3 lb/million BTU of sulfur and nitrogen oxides. The nitrogen oxide and sulfur emissions from the DFC/T system are anticipated to be better than the Vision …

In order to increase efficiencies of carbonizers, operation at high pressures is needed. In addition, waste biomass fuels of opportunity can be used to offset fossil fuel use. The National Energy Technology Laboratory (NETL) Fluidized Bed Gasifier/Combustor (FBG/C) was used to gasify coal and mixtures of coal and biomass (sawdust) at 425 psig. The purpose of the testing program was to generate steady state operating data for modeling efforts of carbonizers. A test program was completed with a matrix of parameters varied one at a time in order to avoid second order interactions. Variables were: coal feed rate, pressure, and varying mixtures of sawdust and coal types. Coal types were Montana Rosebud subbituminous and Pittsburgh No. 8 bituminous. The sawdust was sanding waste from a furniture manufacturer in upstate New York. Coal was sieved from -14 to +60 mesh and sawdust was sieved to -14 mesh. The FBG/C operates at a nominal 425 psig, but pressures can be lowered. For the tests reported it was operated as a jetting, fluidized bed, ash-agglomerating gasifier. Preheated air and steam are injected into the center of the bottom along with the solid feed that is conveyed with cool air. Fairly stable reactor internal …

Electricity produced from hydrogen in fuel cells can be highly efficient relative to competing technologies and has the potential to be virtually pollution free. Thus, fuel cells may become an ideal solution to this nation's energy needs if one has a satisfactory process for producing hydrogen from available energy resources such as coal, and low-cost alternative feedstocks such as biomass. GE EER is developing an innovative fuel-flexible advanced gasification-combustion (AGC) technology for production of hydrogen for fuel cells or combustion turbines, and a separate stream of sequestration-ready CO2. The AGC module can be integrated into a number of Vision- 21 power systems. It offers increased energy efficiency relative to conventional gasification and combustion systems and near-zero pollution. The R&D on the AGC technology is being conducted under a Vision-21 award from the U.S. DOE NETL with co-funding from GE EER, Southern Illinois University at Carbondale (SIU-C), and the California Energy Commission (CEC). The AGC technology converts coal and air into three separate streams of pure hydrogen, sequestration-ready CO2, and high temperature/pressure oxygen-depleted air to produce electricity in a gas turbine. The three-year program integrates lab-, bench- and pilot-scale studies to demonstrate the AGC concept. Process and kinetic modeling studies as …

Vision 21 is the U. S. Department of Energy's initiative to deploy high efficiency, ultraclean co-production coal conversion power plants in the twenty-first century. These plants will consist of power and co-production modules, which are integrated to meet specific power and chemical markets. A variety of fuel gas processing technology issues involving gas separations, cleanup, gas-to-liquid fuels production and chemical synthesis, to mention a few, will be addressed by the program. The overall goal is to effectively eliminate, at competitive costs, environmental concerns associated with the use of fossil fuels for producing electricity and transportation fuels. The Fuel Processing Research Facility (FPRF) was developed as a fuel-flexible platform to address many of these technology needs. The facility utilizes a simplified syngas generator that is capable of producing 2,000 standard cubic feet per hour of 900 degree Celsius and 30 atmosphere synthesis gas that can be tailored to the gas composition of interest. It was built on a ''mid-scale'' level in an attempt to successfully branch the traditionally difficult scale-up from laboratory to pilot scale. When completed, the facility will provide a multi-faceted R&D area for the testing of fuel cells, gas separation technologies, and other gas processing unit operations.

This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. …