Past studies demonstrate that complexation will limit abiotic and biotic U(VI) reduction rates and the overall extent of reduction. However, the underlying basis for this behavior is not understood and presently unpredictable across species and ligand structure. The central tenets of these investigations are: (1) reduction of U(VI) follows the electron-transfer (ET) mechanism developed by Marcus; (2) the ET rate is the rate-limiting step in U(VI) reduction and is the step that is most affected by complexation; and (3) Marcus theory can be used to unify the apparently disparate U(VI) reduction rate data and as a computational tool to construct a predictive relationship.

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Presentation by Dr. Dan Arvizu of NREL given at the Colorado New Energy Summit held March 24, 2007 in Denver, Colorado.

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The summary of this report is: (1) biogenic flux increases as hydrologic residence time decreases; (2) reaction-based reactive transport modeling can capture this effect; (3) solid-phase Fe(III) bioreduction can be sustained at long residence times in natural sediments; and (4) long-term coupled Fe(III)/U(VI) bioreduction can be sustained in natural sediments.

This presentation on solar technologies and sustainability was given at the 17th Annual Rocky Mountain Land-Use Institute (RMLUI) Land-Use Conference.

Renewable portfolio standards (RPS) have rapidly developed momentum in certain sections of the United States and throughout the world, primarily in response to climate and energy security concerns. This presentation at the RPS Symposium, sponsored by the Electric Utility Consultants Inc., will discuss renewable energy financing and the economics of such policies.

The primary objective of this report is to evaluate the rates and mechanisms of U(VI) reduction by microbial populations.

Presentation on progress and possible scenarios towards meeting the 30x30 initiative proposed by President Bush

Cr alloys containing 0-30 weight % W were investigated for their high temperature strength and oxidation resistance. These experimental alloys are intended for use in elevated temperature applications. Alloys were melted in a water-cooled, copper-hearth arc furnace. Microstructure of the alloys was studied using X-ray diffraction, scanning electron microscopy, and light microscopy. Meyer and Vickers hardness tests were utilized for measuring room temperature strength. A hot hardness tester with a spherical ruby indenter was used to study the strength of these materials between 800ºC and 1200ºC. A parabolic relationship was observed between load and indent size at all temperatures. On the other hand, decrease in hardness of the alloys with temperature was linear up to 1200ºC.

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This research hypotheses is: (1) Indigenous microorganisms in the shallow aquifer at the FRC have the capability to reduce U(VI) and Tc(VII) but rates are limited by--Scarce electron donor, Low pH and potentially toxic metals, and High nitrate. (2) U(VI) and Tc(VII) reduction rates can be increased by--Successive donor additions, Raising pH to precipitate toxic metals, and Adding humics to complex toxic metals and serve as electron shuttles.

Analysis of the Genetic Potential and Gene Expression of Microbial Communities Involved in the In Situ Bioremediation of Uranium and Harvesting Electrical Energy from Organic Matter The primary goal of this research is to develop conceptual and computational models that can describe the functioning of complex microbial communities involved in microbial processes of interest to the Department of Energy. Microbial Communities to be Investigated: (1) Microbial community associated with the in situ bioremediation of uranium-contaminated groundwater; and (2) Microbial community that is capable of harvesting energy from waste organic matter in the form of electricity.

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Presentation for the European Wind Energy Conference held February 27--March 2, 2006, in Athens, Greece, showing grid impacts of wind power variability.

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Pyrgeometers are used to measure the atmospheric longwave irradiance throughout the ARM program sites. Previous calibrations of pyrgeometers using ARM/Eppley/NREL blackbody were consistent, but introduced a difference in the historical clear sky measured irradiance. This difference was believed to be in the order of 12 W/m2. In this poster we show the improvements to the blackbody and calibration methodology by comparing our results to the results of a group of pyrgeometers that were recently calibrated against the World Infrared Standard Group, in the World Radiation Center, Davos/Switzerland.