Factors Affecting Household Disaster Preparedness: A Study of the Canadian Context

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This study addresses the issue of household disaster preparedness. This work contributes two elements to disaster research. The first contribution improve the knowledge of the factors that affect household disaster preparedness. The review of literature yielded three categories of variables that can jointly explain household disaster preparedness: household structure, demographics, and risk-perception factors. In this study 19 variables compose these factors. A second contribution constitutes a theoretical exploration of the concept of disaster preparedness. In this work, four different constructs of disaster preparedness were tested. These constructs include material preparedness, preparedness activities, a combined index, and a weighted and combined index. The study presents the logic and methodology of the index construction and validation. The data used in this study came from households in the Montreal Urban Community (MUC) in Canada. A random sample of 1,003 English- and French-speaking heads of households adequately represents the 1.8 million persons within the MUC. An independent survey firm conducted the interviews in 1996. Results show that the weighted combined household disaster preparedness index constitutes the best construct to represent the concepts under study. Study results also reveal that risk-perception variables (attitudinal factors) offered the strongest explanatory power. Household structure and demographic variables collectively …
Date: December 2000
Creator: Doré, Michel C
System: The UNT Digital Library
Comparison of Computer Testing versus Traditional Paper and Pencil Testing (open access)

Comparison of Computer Testing versus Traditional Paper and Pencil Testing

This study evaluated 227 students attending 12 classes of the Apprentice Medical Services Specialist Resident Course. Six classes containing a total of 109 students took the Block One Tests in the traditional paper and pencil form. Another six classes containing a total of 118 students took the same Block One Tests on computers. A confidence level of .99 and level of signifi­cance of .01 was established. An independent samples t-test was conducted on the sample. Additionally, a one-way analysis of variance was performed between the classes administered the Block One Tests on computers. Several other frequencies and comparisons of Block One Test scores and other variables were accomplished. The variables examined included test versions, shifts, student age, student source, and education levels. The study found no significant difference between test administration modes. This study concluded that computer-administering tests identical to those typically administered in the traditional paper and pencil manner had no significant effect on achievement. It is important to note, however, that the conclusion may only be valid if the computer-administered test contains exactly the same test items, in the same order and format, with the same layout, structure, and choices as the traditional paper and pencil test. In …
Date: August 2000
Creator: Millsap, Claudette M.
System: The UNT Digital Library
Child-Centered Group Play Therapy with Children Experiencing Adjustment Difficulties (open access)

Child-Centered Group Play Therapy with Children Experiencing Adjustment Difficulties

This research study investigated the effectiveness of child-centered group play therapy with children experiencing adjustment difficulties. Specifically, this study determined the effectiveness of child-centered group play therapy in: (a) improving self-concept, (b) reducing externalizing, internalizing, and overall behavior problems, (c) enhancing emotional and behavioral adjustment to the school environment, and (d) increasing self-control of kindergarten children experiencing adjustment difficulties. Also investigated were child-centered group play therapy effects on reducing parenting stress of the parents of kindergarten children experiencing adjustment difficulties. The experimental group consisted of 15 kindergarten children who received one 40-minute child-centered group play therapy session per week, for twelve weeks. Group facilitators were play therapists who were doctoral students at the University of North Texas. The control group consisted of the 14 kindergarten students that had been assigned to the control group in Baggerly's (1999) study. Before the group play therapy sessions began and after termination of the sessions: the researchers administered the Joseph Pre-School and Primary Self-Concept Screening Test; parents completed the Child Behavior Checklist-Parent Report, Self-Control Rating Scale, Filial Problem Checklist, and Parenting Stress Index; and teachers completed the Child Behavior Checklist-Teacher Report, Early Childhood Behavior Scale, and Self-Control Rating Scale. Although the general results of …
Date: August 2000
Creator: McGuire, Donald E.
System: The UNT Digital Library
Students' Criteria for Course Selection: Towards a Metadata Standard for Distributed Higher Education (open access)

Students' Criteria for Course Selection: Towards a Metadata Standard for Distributed Higher Education

By 2007, one half of higher education students are expected to enroll in distributed learning courses. Higher education institutions need to attract students searching the Internet for courses and need to provide students with enough information to select courses. Internet resource discovery tools are readily available, however, users have difficulty selecting relevant resources. In part this is due to the lack of a standard for representation of Internet resources. An emerging solution is metadata. In the educational domain, the IEEE Learning Technology Standards Committee (LTSC) has specified a Learning Object Metadata (LOM) standard. This exploratory study (a) determined criteria students think are important for selecting higher education courses, (b) discovered relationships between these criteria and students' demographic characteristics, educational status, and Internet experience, and (c) evaluated these criteria vis-à-vis the IEEE LTSC LOM standard. Web-based questionnaires (N=209) measured (a) the criteria students think are important in the selection of higher education courses and (b) three factors that might influence students' selections. Respondents were principally female (66%), employed full time (57%), and located in the U.S. (89%). The chi square goodness-of-fit test determined 40 criteria students think are important and exploratory factor analysis determined five common factors among the top 21 …
Date: August 2000
Creator: Murray, Kathleen R.
System: The UNT Digital Library
Cowboys, Postmodern Heroes, and Anti-heroes: The Many Faces of the Alterized White Man (open access)

Cowboys, Postmodern Heroes, and Anti-heroes: The Many Faces of the Alterized White Man

This thesis investigates how hegemonic white masculinity adopts a new mode of material accumulation by entering into an ambivalent existence as a historical agent and metahistory at the same time and continues to function as a performative identity that offers a point of identification for the working class white man suggesting that bourgeois identity is obtainable through the performance of bourgeois ethics. The thesis postulates that the phenomenal transitions brought on by industrialization and deindustrialization of 50's through 90's coincide with the representational changes of white masculinity from paradigmatic cowboy incarnations to the postmodern action heroes, specifically as embodied by Bruce Willis. The thesis also examines how postmodern heroes' "intero-alterity" is further problematized by antiheroes in Tim Burton's films.
Date: August 2000
Creator: Murphree, Hyon Joo Yoo
System: The UNT Digital Library
Family Rituals and Resilience: Relationship Among Measures of Religiosity, Openness to Experience, and Trait Anxiety (open access)

Family Rituals and Resilience: Relationship Among Measures of Religiosity, Openness to Experience, and Trait Anxiety

Rituals are an integral part of society. The focus of research on rituals has been shifting to highlight the effect rituals may produce on individual resilience and ability to function. This study examined the relationships between participation in family rituals and several conceptually related facets of the human experience, including religiosity, openness to experience, and anxiety. Participants responded to questions on an assessment instrument (Family Ritual Questionnaire) designed to measure participation in a broad variety of identified family rituals; they were grouped according to responses on that questionnaire, and the resulting groups were compared on their responses to questionnaires addressing religiosity (Religious Background and Behavior Questionnaire), openness to experience (Revised NEO Personality Inventory Openness to Experiences scale), and anxiety (State-Trait Anxiety Inventory). The four-group classification system did not produce significant differences on measures of religiosity, openness to experience, or trait anxiety. Nor were there any significant differences noted when the groups were examined on the basis of the demographic characteristics of age, gender, separation time from family of origin, or academic status. The demographic descriptive which was associated with specific group differences related to adult composition of family of origin: participants described the adults present in their families of origin, …
Date: August 2000
Creator: Emmett, Gloria J.
System: The UNT Digital Library
Carbachol- and ACPD-Induced Phosphoinositide Responses in the Developing Rat Neocortex (open access)

Carbachol- and ACPD-Induced Phosphoinositide Responses in the Developing Rat Neocortex

Signal transduction via the phosphoinositide (PI) second messenger system has key roles in the development and plasticity of the neocortex. The present study localized PI responses to individual cortical layers in slices of developing rat somatosensory cortex. The acetylcholine agonist carbachol and the glutamate agonist trans-1-amino-1,3-cyclopentanedicarboxylic acid (ACPD) were used to stimulate PI turnover. The PI responses were compared to the distribution of the corresponding PI-linked receptors in order to investigate the regional ontogeny of PI coupling to receptors in relation to neural development. The method for assessing PI turnover was modified from Hwang et al. (1990). This method images the PI response autoradiographically through the localizaton of [3H]cytidine that has been incorporated into the membrane-bound intermediate, cytidine diphosphate diacylglycerol. In each age group (postnatal days 4-30), carbachol resulted in more overall labeling than ACPD. For both agonists, the response peaked on postnatal day 10 (P10) and was lowest in the oldest age group. The laminar distribution of the carbachol PI response from P4-P16 corresponded fairly well with the laminar distribution of [3H]quinuclidinyl benzilate binding (Fuchs, 1995). However, in the subplate layer the carbachol response was strong while receptor binding was minimal. The carbachol response decreased after postnatal day 10, …
Date: August 2000
Creator: Hartgraves, Morri D.
System: The UNT Digital Library
Strategic Alliance Between a Bed & Breakfast Inn and a Restaurateur: Impact on Net Income of the Bed & Breakfast Inn (open access)

Strategic Alliance Between a Bed & Breakfast Inn and a Restaurateur: Impact on Net Income of the Bed & Breakfast Inn

This study was conducted to investigate the impact of restaurant facilities, belonging to a B&B and leased to a professional restaurateur, upon the revenue of the B&B. This study assessed the physical demands placed on the B&B operator by an on-premises restaurant. Lack of sufficient data precluded proving the premise that an on-premises restaurant leased to a restaurateur would increase the income of the B&B without placing undue physical demands on the B&B operator. However, many contributing factors support the importance of a B&B having an on-premises restaurant that is leased to a professional restaurateur.
Date: August 2000
Creator: Filler, Eunice Jeraldine
System: The UNT Digital Library
David Lefkowitz of Dallas: A Rabbi for all Seasons (open access)

David Lefkowitz of Dallas: A Rabbi for all Seasons

This dissertation discusses the impact David Lefkowitz and his ministry had on Dallas during the years of his ministry (1920-1949) at Temple Emanu-El in Dallas Texas, and the years following his death in 1955. The focus is on his involvement in civic activities, although his pastoral activities are also discussed. Sources include interviews with family members, friends and acquaintances, newspaper articles, journals, internet sources, unpublished theses and dissertations about Dallas and related subjects, minutes of the Temple's Board of Directors' meetings, minutes of the Central Conference of American Rabbis, minutes of the Board of Directors' Meetings of the Dallas Jewish Welfare Federation, the Temple Emanu-El Bulletins, and selected sermons, speeches and letters of David Lefkowitz. David Lefkowitz was an important figure in the history of Dallas. He taught, by precept and example, that Jews could participate fully in the civic life of Dallas. Because of his teachings, Jews made a positive difference in the development of Dallas. He has left a lasting impression on Dallas, and through his ministry and hard work, he made Dallas a better place for all its citizens.
Date: August 2000
Creator: Guzman, Jane Bock
System: The UNT Digital Library

Bird Bones and a Hatched Egg

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A fifty page manuscript of poetry and a critical introduction detailing the poet's aesthetics. Using the idea of the double-image and eroticism, the poet places her work in the category of the surreal. She describes the process of writing poetry born of fragmentary elements as a feminist emergence of agency. The manuscript is composed of four sections, each an element in the inevitable breakdown of a love relationship: meeting, love-making, birth of a child, death. Quotes from various authors of anthropological and fictional texts begin each section to reinforce thematic structure in a process of unveiling the agency of the narrator. The poems are organized as a series, beginning and ending with sequence poems.
Date: December 2000
Creator: Skebe, Carolyn Alifair
System: The UNT Digital Library

The Effect of Attachment on Preschooler's Emotion Understanding

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The purpose of this study was to identify the relationship between attachment and emotion understanding in preschoolers. Data was collected from 16 preschool children and their mothers recruited from a private learning center in a downtown metropolitan area. Attachment was measured by use of the Attachment Q-sort, 3.0 (Waters, 1995), while emotion understanding was assessed through use of Denham's (1986) affective perspective-taking task and interviews of children concerning naturally occurring emotions and emotion causes (Fabes et al., 1991). Results included a significant correlation (p < .05) between secure attachment and preschooler's ability to decipher the cause of another's emotion; however, a significant correlation was not found between secure attachment and preschooler's perspective-taking ability or ability to name other's emotions. Thus, conclusions about the impact of attachment upon emotion understanding were mixed, and more research on the subject was implicated.
Date: December 2000
Creator: Hernandez, Jennie R.
System: The UNT Digital Library

Logic Programming Tools for Dynamic Content Generation and Internet Data Mining

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The phenomenal growth of Information Technology requires us to elicit, store and maintain huge volumes of data. Analyzing this data for various purposes is becoming increasingly important. Data mining consists of applying data analysis and discovery algorithms that under acceptable computational efficiency limitations, produce a particular enumeration of patterns over the data. We present two techniques based on using Logic programming tools for data mining. Data mining analyzes data by extracting patterns which describe its structure and discovers co-relations in the form of rules. We distinguish analysis methods as visual and non-visual and present one application of each. We explain that our focus on the field of Logic Programming makes some of the very complex tasks related to Web based data mining and dynamic content generation, simple and easy to implement in a uniform framework.
Date: December 2000
Creator: Gupta, Anima
System: The UNT Digital Library
The Effects of Media Exposure on Body Satisfaction, Beliefs About Attractiveness, Mood and Bulimic Symptomatology Among College Women (open access)

The Effects of Media Exposure on Body Satisfaction, Beliefs About Attractiveness, Mood and Bulimic Symptomatology Among College Women

The research of Stice et al. (1994) and Stice and Shaw (1994) proposed several mechanisms that may mediate the adverse effects of media exposure to the thin ideal including internalization of the thin-ideal, negative affect, and body dissatisfaction. The purpose of this study was to extend initial research of Stice and Shaw (1994) by incorporating two forms of media (e.g., TV and Magazines) to assess the effects of exposure to the media portrayal of ideal body shape on women's mood, body satisfaction, and internalization of societal values concerning attractiveness. The relation of these variables to bulimic symptomatology was examined. The current study improved upon Stice and Shaw's study (1994) by matching participants' scores on BMI, level of negative affect, and level of body satisfaction before random assignment to the experimental conditions. Female undergraduates aged 18 to 25 years participated in premeasure (N = 198) and post measure (N = 164) conditions. Results from repeated mulitvariate analysis indicated media exposure to ideal-body images demonstrated no significant changes in women's affect, body satisfaction or endorsement of the thin ideal. Indirect support for the sociocultural theory of eating disorders was provided by multiple regression analyses that demonstrated lower levels of satisfaction with size …
Date: December 2000
Creator: Varnado, Jessica Lea
System: The UNT Digital Library
Themes of Exodus and Revolution in Ellison's Invisible Man, Morrison's Beloved, and Doctorow's Ragtime (open access)

Themes of Exodus and Revolution in Ellison's Invisible Man, Morrison's Beloved, and Doctorow's Ragtime

In my dissertation I examine the steps in and performance of revolution through the writings of three Postmodern authors, Ralph Ellison, Toni Morrison, and E. L. Doctorow, in light of the model of the biblical Exodus journey and the revolution which precipitated that movement. I suggest that the revolution which began with the Israelites' bondage in Egypt has provided the foundation for American literature. I show that Invisible Man, Beloved, and Ragtime not only employ the motif of the Exodus journey; they also perpetuate the silent revolution begun by the Israelites while held captive in Egypt. This dissertation consists of six chapters. Chapter One provides the introduction to the project. Chapter Two provides the model for this study by defining the characteristics of the Exodus journey, Moses as the leader of the Israelites, and the pattern of revolution established by Michael Walzer in Exodus and Revolution. In Chapters Three, Four, and Five, I apply the model established in Chapter Two to the individual texts. In Chapter Six, I draw three conclusions which arise from my study. My first conclusion is that the master story of the Exodus journey and the Israelites' liberation from Egypt informs all Western literaturewhether the literature …
Date: December 2000
Creator: Turner, Tracy Peterson
System: The UNT Digital Library
Public School Educators' Use of Computer-Mediated Communication (open access)

Public School Educators' Use of Computer-Mediated Communication

This study examined the uses of computer-mediated communication (CMC) by educators in selected public schools. It used Rogers' Diffusion of Innovation Theory as the underpinnings of the study. CMC refers to any exchange of information that involves the use of computers for communication between individuals or individuals and a machine. This study was an exploration of difficulties users confront, what services they access, and the tasks they accomplish when using CMC. It investigated the factors that affect the use of CMC. The sample population was drawn from registered users on TENET, the Texas Education Network as of December 1997. The educators were described with frequency and percentages analyzing the demographic data. For the research, eight indices were selected to test how strongly these user and environmental attributes were associated with the use of CMC. These variables were (1) education, (2) position, (3) place of employment, (4) geographic location, (5) district size, (6) organization vitality, (7) adopter resources, and (8) instrumentality Two dependent variables were used to test for usage: (1) depth or frequency of CMC usage and amount of time spent online and (2) breadth or variety of Internet utilities used. Additionally, the users' perception of network benefits was measured. …
Date: December 2000
Creator: Urias-Barker, Zelina
System: The UNT Digital Library
Effects of a Surface Engineered Metallic Coating on Elastomeric Valve Stem Seal Leakage (open access)

Effects of a Surface Engineered Metallic Coating on Elastomeric Valve Stem Seal Leakage

Valve stem seal leakage is a major source of fugitive emissions, and controlling these emissions can result in added expense in leak detection and repair programs. Elastomeric O-rings can be used as valve stem seals, and O-ring manufacturers recommend lubrication of elastomeric seals to prevent damage and to assure proper sealing. In this research, a metallic coating was applied as a lubricant using a vacuum vapor deposition process to the surface of elastomeric valve stem seals. Valve stem leak measurements were taken to determine if the coated O-rings, alone or with the recommended lubrication, reduced valve stem seal leakage. This research determined that the metallic coating did not reduce valve stem leakage.
Date: December 2000
Creator: Taylor, John Abner
System: The UNT Digital Library
Effects of Self-Monitoring and Monetary Reward on Fluid Adherence among Adult Hemodialysis Patients (open access)

Effects of Self-Monitoring and Monetary Reward on Fluid Adherence among Adult Hemodialysis Patients

The effects of a monetary reward and self-monitoring on reducing interdialytic weight gain (IWG) were compared for 6 hemodialysis patients in an outpatient setting. A single-subject experimental design (A-B-BC-B-BC) was used to examine each variable individually and in combination, with alternating phases to control for possible sequencing effects. Monetary reward (50 cents - $3) was administered in a titrated manner according to standardized criteria, ranging from 3 % and 4% of patients' dry weight on weekdays and weekends, respectively, to 3.5% and 4.5% for weekdays and weekends. Self-monitoring involved recording daily fluid and diet intake. Results indicated that by the end of the treatment program, the 6 participants averaged a 14% reduction in weekday IWG and a 15.45% reduction in weekend IWG; however, due to significant variability, it cannot be concluded that the reductions are treatment effects. Four out of 6 participants reduced their average IWG for both weekends and weekdays by .75 kg (1.65 lb.). The average weekend reduction for these 4 participants was .85 kg (1.87 lbs.) while the average weekday reduction was .65 kg (1.43 lb.). All 6 participants showed reductions in weekday IWG that averaged .53 kg (1.17 lb.). However, only 2 participants demonstrated IWG reductions …
Date: December 2000
Creator: Sonnier, Bridget L.
System: The UNT Digital Library

Burnout Among Student Affairs Professionals at Metropolitan Universities

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The purpose of this study was to determine the level of burnout among student affairs professionals at the 52 U.S. member institutions of the Coalition of Urban and Metropolitan Universities. Packets containing the Maslach Burnout Inventory (MBI), the Moos Work Environment Scale (WES), and a demographic survey were mailed to 371 senior student affairs administrators at the member institutions, with a completed response rate of 58.22%. The senior student affairs administrators surveyed included the chief student affairs officers and the professional staff who reported to them. The research design employed t-tests, analyses of variance, and Pearson's Product Moment correlations. The scores obtained from the MBI and WES subscales were compared overall and along 9 independent variablestitle of position, size of institution, appointment, salary, years in current position, years in profession, age, gender, and highest degree attained. Average levels of burnout were found on each of the MBI subscores. Contrary to earlier studies, women did not suffer from statistically significant higher levels of burnout than men, and burnout levels decreased with age and years in the profession for both sexes. Lower scores on the MBI depersonalization subscale were found in employees in mid-career and in professionals from smaller schools. Emotional exhaustion …
Date: August 2001
Creator: Murphy, Lynda
System: The UNT Digital Library

Thermal, Electrical, and Structural Analysis of Graphite Foam

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A graphite foam was developed at Oak Ridge National Laboratory (ORNL) by Dr. James Klett and license was granted to POCO Graphite, Inc. to manufacture and market the product as PocoFoam™. Unlike many processes currently used to manufacture carbon foams, this process yields a highly graphitic structure and overcomes many limitations, such as oxidation stabilization, that are routinely encountered in the development of carbon foam materials. The structure, thermal properties, electrical resistivity, isotropy, and density uniformity of PocoFoam™ were evaluated. These properties and characteristics of PocoFoam™ are compared with natural and synthetic graphite in order to show that, albeit similar, it is unique. Thermal diffusivity and thermal conductivity were derived from Fourier's energy equation. It was determined that PocoFoam™ has the equivalent thermal conductivity of metals routinely used as heat sinks and that thermal diffusivity is as much as four times greater than pure copper and pure aluminum. SEM and XRD results indicate that PocoFoam™ has a high degree of crystalline alignment and near theoretical d spacing that is more typical of natural flake graphite than synthetic graphite. PocoFoam™ is anisotropic, indicating an isotropy factor of 0.5, and may yield higher thermal conductivity at cryogenic temperatures than is observed in …
Date: August 2001
Creator: Morgan, Dwayne Russell
System: The UNT Digital Library

The Pettis Integral and Operator Theory

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Let (Ω, Σ, µ) be a finite measure space and X, a Banach space with continuous dual X*. A scalarly measurable function f: Ω→X is Dunford integrable if for each x* X*, x*f L1(µ). Define the operator Tf. X* → L1(µ) by T(x*) = x*f. Then f is Pettis integrable if and only if this operator is weak*-to-weak continuous. This paper begins with an overview of this function. Work by Robert Huff and Gunnar Stefansson on the operator Tf motivates much of this paper. Conditions that make Tf weak*-to-weak continuous are generalized to weak*-to­weak continuous operators on dual spaces. For instance, if Tf is weakly compact and if there exists a separable subspace D X such that for each x* X*, x*f = x*fχDµ-a.e, then f is Pettis integrable. This nation is generalized to bounded operators T: X* → Y. To say that T is determined by D means that if x*| D = 0, then T (x*) = 0. Determining subspaces are used to help prove certain facts about operators on dual spaces. Attention is given to finding determining subspaces far a given T: X* → Y. The kernel of T and the adjoint T* of T are used …
Date: August 2001
Creator: Huettenmueller, Rhonda
System: The UNT Digital Library

Submerged wood inhabiting macoinvertebrates of the Elm Fork of the Trinity River, Texas: Assemblage analyses, comparisons to the benthic fauna, and a study of Cyrnellus fraternus (Trichoptera: Polycentropodidae)

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Taxonomic composition and spatio-temporal variability of macroinvertebrates inhabiting snags were examined from an 8-km segment of the Elm Fork of the Trinity River. Seventy-seven macroinvertebrate taxa were collected from submerged wood during the study. Assemblages were highly variable spatially and temporally, especially among seasons. An ordination of species and environment did not find snag taxa to have striking correlations with many of the selected environmental variables, although there were some trends in flow-mediated species distributions. There were significant seasonal differences in the abundances of some taxa, particularly among the Chironomidae (Diptera). The Tribe Orthocladiini was numerically abundant during the winter, while the Tribes Chironomini and Tanytarsini dominated the summer and autumn. Additionally, this study included a secondary production and microdistribution analysis of a population of the caddisfly Cyrnellus fraternus. Distributions of C. fraternus were restricted to snags, the most stable substratum for retreat building and for resisting periodic high waters. Larvae were not found in the soft sand and mud benthic habitats near submerged wood. The insects were multivoltine with a minimum of three generations per year. Pupae were collected July through September and adults emerged from May through October. The population overwintered as larvae. Estimated annual production was 1,015.4 …
Date: August 2001
Creator: Johnson, Zane B.
System: The UNT Digital Library

Comparison of GPS Point Selection Methods for GIS Area Measurement of Small Jurisdictional Wetlands

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U.S. Army Corps of Engineers (USACE) regulates fill of jurisdictional waters of the United States including wetlands. Recent USACE regulations set a threshold of impacts to wetlands at one-half acre. Impact area can be determined by Global Positioning System (GPS) measurement of wetland boundary and Geographic Information System (GIS) calculation of impact area. GPS point selection methods include (1) equal time interval, (2) transect and (3) intuition. Four two-acre shapes were measured with each GPS method and brought into GIS for area calculation. Analysis of variance and Root Mean Square Error analyses determine that the transect method is an inferior point selection method in terms of accuracy and efficiency.
Date: August 2001
Creator: Shelton, Michael
System: The UNT Digital Library
Thermochemical investigations of crystalline solutes in non-electrolyte solutions: Mathematical representation of solubility data and the development of predictive solubility equations in systems with specific and non-specific interactions. (open access)

Thermochemical investigations of crystalline solutes in non-electrolyte solutions: Mathematical representation of solubility data and the development of predictive solubility equations in systems with specific and non-specific interactions.

Understanding the thermodynamic properties of multicomponent mixtures is of critical importance in many chemical and industrial applications. Experimental measurements become progressively difficult as the number of solution components increases -- producing the need for predictive models. Problems in development of predictive models arise if the mixture has one or more components that interact through molecular complexation or association. Experimental solubilities of anthracene and pyrene dissolved in binary systems containing one or more alcohols were measured in order to address this problem. Alcohols examined in this study were: 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-1-propanol, 3-methyl-1-butanol, and 1-octanol. In binary solvent mixtures containing only a single self-associating alcoholic solvent, the alkane cosolvents studied were: n-hexane, n-heptane, n-octane, 2,2,4-trimethylpentane, cyclohexane, methylcyclohexane, tert-butylcyclohexane. Predictive solubility equations were developed using mobile order theory. This approach differs from classical solution models by representing hydrogen bonding with a probability term rather than with expressions derived from stepwise equilibria or expressions to represent hypothetical solution aggregates. Results were compared with the predicted solubilities found from using expressions developed using the Kretschmer-Wiebe and Mecke-Kempter approaches for modeling associated solutions. It was found that the mobile order approach provided reasonably accurate predictions for the solute solubilities in the systems studied. The …
Date: May 2008
Creator: Zvaigzne, Anita Ilze
System: The UNT Digital Library

A study of freshman interest groups and leadership practices at Texas Woman's University

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This study investigated the level of leadership practices and retention rates of freshman students at Texas Woman's University. The data for the study were collected using the Leadership Practices Inventory, Student Version. The sample for the study consisted of 151 freshman students. The students were each placed in one of three control groups. Group A students (the treatment group) were in the Neighbors Educated Together Program (NET). Group B students (control group) were in one of two university-sponsored programs (COLORS or University 1000), and Group C students (control group) were the residual group of first-time college freshmen. These three groups were surveyed prior to their participation in the NET program or a university-sponsored program and again at the end of 14 weeks. In addition, retention rates were examined on the 12 class day of the spring semester. The study found statistically significant differences (p <. 05) on the pretests and posttests between Group C, residual students, and the other two groups on the Enabling the Followers to Act subscale, the Inspiring a Shared Vision subscale, and Encouraging the Heart subscale. Group A, NET students, and Group B, COLORS/University 1000 students, showed no statistically significant differences between groups. The difference from …
Date: August 2001
Creator: Mendez-Grant, Monica S
System: The UNT Digital Library