This report chronicles the process of remediation of the flammable gas hazard in Tank 241-SY-101 (SY-101) by waste transfer and back-dilution from December 18, 1999 through April 2, 2000. A brief history is given of the development of the flammable gas retention and release hazard in this tank, and the transfer and dilution systems are outlined. A detailed narrative of each of the three transfer and dilution campaigns is given to provide structure for the balance of the report. Details of the behavior of specific data are then described, including the effect of transfer and dilution on the waste levels in Tanks SY-101 and SY-102, data from strain gauges on equipment suspended from the tank dome, changes in waste configuration as inferred from neutron and gamma logs, headspace gas concentrations, waste temperatures, and the mixerpump operating performance. Operating data and performance of the transfer pump in SY-101 are also discussed.

The authors compare frequency doubling of broadband light in a single nonlinear crystal with doubling in five crystals with intercrystal temporal walk off compensation, and with doubling in five crystals adjusted for offset phase matching frequencies. Using a plane-wave, dispersive numerical model of frequency doubling they study the bandwidth of the second harmonic and the conversion efficiency as functions of crystal length and fundamental irradiance. For low irradiance the offset phase matching arrangement has lower efficiency than a single crystal of the same total length but gives a broader second harmonic bandwidth. The walk off compensated arrangement gives both higher conversion efficiency and broader bandwidth than a single crystal. At high irradiance, both multicrystal arrangements improve on the single crystal efficiency while maintaining broad bandwidth.

Information technology is being used to provide interactive access to data collected from the electro-metallurgical treatment of spent fuel. The data are results from many hundreds of experiments performed to better characterize the processes by which uranium is separated from the waste products. Web-based display and relational database query capabilities facilitate the identification of trends in the data and the relating of these trends to the underlying electrochemistry. The objectives are to ensure that the process behavior is well understood, to make readily accessible the necessary data for development and validation of models, and to identify unexpected trends in the data as indications of phenomena not yet represented in the models.

The total inventory of fourteen radionuclides, three metals, and volatile organic compounds (VOCs) has been calculated for the twenty-two Old Solvent Tanks (OSTs). The inventory calculations are based upon extensive characterization data of the multiple liquid and sludge samples taken from the OSTs. In addition, the total inventory of sixteen actinides (including error) has been calculated. The actinide inventory will be useful for criticality safety considerations.

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The entire history of the discoveries of K{sub L}{sup o} and violations of T and CP began at Brookhaven. It is most appropriate for us to hold today's special seminar on CP Violation in K decay in this laboratory. Forty-five years ago, in the same paper on parity nonconservation, it was also pointed out that there is no proof of T symmetry in the weak interaction, nor of C invariance. That paper was submitted to the Physical Review (then, also located at BNL) on June 22, 1956. A month later, Lederman and his collaborators discovered a long-lived neutral V particle (now called K{sub L}{sup o}) at the Cosmotron using the cloud chamber. This discovery was presented as a rigorous proof of C symmetry. In the same summer at Brookhaven, in collaboration with Oehme and Yang, I did the analysis on the neutral kaon system, assuming T, C and CP violations (but based on CPT symmetry). In that work, the two non-orthogonal eigen-states {psi}{sub +} and {psi}{sub -} (now K{sub S}{sup o} and K{sub L}{sup o}) were characterized by a non-orthogonality parameter {alpha} ({approx_equal} 2 Re{epsilon} in today's notation), which was shown to be small, because of unitarity. We then went …

Phase-space analysis of neutron optics has revealed that neutron imaging by Bragg reflection from thick bent perfect crystals can be non-dispersive (independent of the neutron wavelength), like with an optical mirror. The corresponding devices, called Bragg mirrors (BM), can be used for neutron imaging at pulsed neutron sources. Using a position sensitive detector (PSD) and time-of-flight analysis (TOF), a BM imaging system will make it possible to collect both real space mapping data and scattering space data simultaneously. Each pixel of PSD will correspond to a point in the sample and will contain a segment of the diffraction pattern (useful for strain, texture or phase analysis), or of an inelastic spectrum. In this paper the resolution and efficiency of BM in TOF diffraction experiments are calculated and compared with the usual sequential method of mapping. Experimental tests performed at steady state neutron sources showed sub-millimeter spatial resolution in the one-dimensional case.

This report summarizes results obtained from the environmental monitoring program at the Savannah River Plant during 1973. A brief discussion of plant releases to the environment and radioactivity detected in the environment is presented in the text and tables. The appendix contains tables of results from environmental sample analyses, sensitivities of laboratory analyses, and maps of sampling locations.

A design goal for VULCAN, the SNS engineering diffractometer, is to enable spatial mapping with 0.1 mm resolution. Because the targeted applications often involve the use of large samples or special environment, slits cannot be used for this purpose. In this paper, methods to achieve 0.1 mm spatial resolution are outlined. For the incident beam, a new compact focusing device is proposed. The device is made of a stack of bent silicon wafers, each having a reflective multilayer (supermirror) deposited on one side and a neutron-absorbing layer on the other side. The optimal design to minimize the optical spatial aberrations is discussed and Monte-Carlo simulation results are presented. For the diffracted beam, imaging devices made from thick packets of diffracting bent silicon wafers (known as the Bragg Mirrors) could be used. The requirements to achieve a sharp imaging together with a large phase-space acceptance window are discussed and preliminary testing results are presented.

This report addresses Milestone M4900, ''Simulant Mixing Sample Analysis Results,'' and contains the data generated during the ''Mixing of Process Heels, Process Solutions, and Recycle Streams: Small-Scale Simulant'' task. The Task Technical and Quality Assurance Plan for this task is BNF-003-98-0079A. A report with a narrative description and discussion of the data will be issued separately.

The development of nonradioactive waste simulants to support the River Protection Project - Waste Treatment Plant bench and pilot-scale testing is crucial to the design of the facility. The report documents the simulants development to support the SRTC programs and the strategies used to produce the simulants.

A method for treatment and disposal of the Hanford High Level Waste has been proposed for BNFL, Inc. In this process, a portion of the Hanford High Level Waste will be pretreated to concentrate radionuclides prior to vitrification. This task examines the stability of one of the ion exchange resins, SuperLig (TM) 639, toward irradiation. These tests were conducted using simulated Hanford High Level Waste containing pertechnetate ion as a stand-in for pertechnetate.

A study was funded by High Level Waste Management to determine the effect of increasing the wind speed threshold for High-Level Waste projects using windbreaks. It was also requested to determine the conditions enabling particles to be transported up and over a windbreak and to include the effect of forced ventilation up to 300 cfm.

Organisms living on the earth are exposed to solar radiation, including its ultraviolet (UV) components (for general reviews, the reader is referred to Smith [1] and Young et al. [2]). UV wavelength regions present in sunlight are frequently designated as UVB (290-320 nm) and UVA (320-400 nm). In today's solar spectrum, UVA is the principal UV component, with UVB present at much lower levels. Ozone depletion will increase the levels of UVB reaching the biosphere, but the levels of UVA will not be changed significantly [3]. Because of the high efficiency of UVB in producing damage in biological organisms in the laboratory experiments, it has sometimes been assumed that UVA has little or no adverse biological effects. However, accumulating data [4, 5], including action spectra (efficiency of biological damage as a function of wavelength of radiation; see Section 5) for DNA damage in alfalfa seedlings [6], in human skin [7], and for a variety of plant damages (Caldwell, this volume) indicate that UVA can induce damage in DNA in higher organisms. Thus, understanding the differential effects of UVA and UVB wavebands is essential for estimating the biological consequences of stratospheric ozone depletion.

Radiation can damage cellular components, including DNA. Organisms have developed a panoply of means of dealing with DNA damage. Some repair paths have rather narrow substrate specificity (e.g. photolyases), which act on specific pyrimidine photoproducts in a specific type (e.g., DNA) and conformation (double-stranded B conformation) of nucleic acid. Others, for example, nucleotide excision repair, deal with larger classes of damages, in this case bulky adducts in DNA. A detailed discussion of DNA repair mechanisms is beyond the scope of this article, but one can be found in the excellent book of Friedberg et al. [1] for further detail. However, some DNA damages and paths for repair of those damages important for photobiology will be outlined below as a basis for the specific examples of genetic and molecular analysis that will be presented below.

An environmental monitoring program has been in existence at SRP since 1951. The original preoperational surveys have evolved into an extensive environmental monitoring program in which sample types from approximately 500 locations are analyzed for radiological and/or nonradiological parameters. The results of these analyses for 1981 are presented in this report.

The recently discovered dynamical diffraction effect ''neutron camel'' was used for the residual stress measurements in a thick Si(111) crystal coated with a 2000 {angstrom} thick Ni film. The observed asymmetry of the back-face rocking curve corresponds to the bending radius of {approx} 19 km and the tension force applied to the Ni film is {approx} 90 N/m. Relative deformation of the Si crystallographic cells in the vicinity of diffractive surfaces is |{partial_derivative}u{sub z}/{partial_derivative}z| {approx} 1.6 x 10{sup -6}.

Understanding the exchanges of carbon between the atmosphere and ocean and the fate of carbon delivered to the deep sea is fundamental to the evaluation of ocean carbon sequestration options. An additional key requirement is that sequestration must be verifiable and that environmental effects be monitored and minimized. These needs can be addressed by carbon system observations made from low-cost autonomous ocean-profiling floats and gliders. We have developed a prototype ocean carbon system profiler based on the Sounding Oceanographic Lagrangian Observer (SOLO; Davis et al., 1999). The SOLO/ carbon profiler will measure the two biomass components of the carbon system and their relationship to physical variables, such as upper ocean stratification and mixing. The autonomous observations within the upper 1500 m will be made on daily time scales for periods of months to seasons and will be carried out in biologically dynamic locations in the world's oceans that are difficult to access with ships (due to weather) or observe using remote sensing satellites (due to cloud cover). Such an observational capability not only will serve an important role in carbon sequestration research but will provide key observations of the global ocean's natural carbon cycle.

The overall objective of this small-scale simulant mixing study was to identify the processes within the Hanford Site River Protection Project-Waste Treatment Plant (RPP-WTP) that may generate precipitates and to identify the types of precipitates formed. This information can be used to identify where mixtures of various solutions will cause precipitation of solids, potentially causing operational problems such as fouling equipment or increasing the amount of High Level Waste glass produced. Having this information will help guide protocols for flushing or draining tanks, mixing internal recycle streams, and mixing waste tank supernates. This report contains the discussion and thermodynamic chemical speciation modeling of the raw data.

This report examines significant contributions to inelastic behavior of common building systems and develops frequency dependent force reduction factors that may be used with the results from linear elastic analyses models.

A moving diffractor changes the energy of elastically diffracted neutrons by the Doppler effect. Depth-graded multilayers can diffract neutrons over a large band of energy. Using a pulsed neutron source, such a depth-graded multilayer, decelerating synchronously with the incident neutron pulse, can shift the reflected neutrons into a compressed energy window. This focusing in energy is associated with a broadening of the pulse in time, but the process does not involve a significant decrease in the neutron phase-space density. The proposed method can be used to design long pulse or quasi-continuous sources of cold, very cold or ultra cold neutrons (UCN). The analysis concentrates on enhanced production of UCN at pulsed neutron sources.

The U.S. has generally lacked the capability for an iterative process of detailed structural design, manufacturing, and testing at the full blade level to achieve specific structural performance, cost, and weight targets. This project examined the effects that different composites processing methods had on the performance of representative blade substructures. In addition, the results of the testing of these substructures was used to validate NuMAD, the design tool developed at Sandia National Laboratories.

The Gordon Research Conference on Applied and Environmental Microbiology was held at Connecticut College, New London, Connecticut, July 22-27, 2001. The conference was attended by 121 participants. The attendees represented the spectrum of endeavor in this field, coming from academia, industry, and government laboratories, and included US and foreign scientists, senior researchers, young investigators, and students. Emphasis was placed on current unpublished research and discussion of the future target areas in this field. There was a conscious effort to stimulate discussion about the key issues in the field today. Session topics included the following: Environmental and applied genomics, Cell-to-cell signaling and multicellular behavior, Emerging technologies and methods, Novel metabolisms and ecosystems, Directed evolution of enzymes and pathways, Symbiotic and trophic relationships, Synthesis and application of novel biopolymers, and Microbes at the oxic-anoxic interface. There was also a special lecture titled ''Under the umbrella of the big tree: microbial biology into the 21st century.''

This report identifies an appropriate thermal stabilization temperature for {sup 233}U oxides. The temperature is chosen principally on the basis of eliminating moisture and other residual volatiles. This report supports the U. S. Department of Energy (DOE) Standard for safe storage of {sup 233}U (DOE 2000), written as part of the response to Recommendation 97-1 of the Defense Nuclear Facilities Safety Board (DNFSB), addressing safe storage of {sup 233}U. The primary goals in choosing a stabilization temperature are (1) to ensure that the residual volatiles content is less than 0.5 wt % including moisture, which might produce pressurizing gases via radiolysis during long-term sealed storage; (2) to minimize potential for water readsorption above the 0.5 wt % threshold; and (3) to eliminate reactive uranium species. The secondary goals are (1) to reduce potential future chemical reactivity and (2) to increase the particle size thereby reducing the potential airborne release fraction (ARF) under postulated accident scenarios. The prevalent species of uranium oxide are the chemical forms UO{sub 2}, UO{sub 3}, and U{sub 3}O{sub 8}. Conversion to U{sub 3}O{sub 8} is sufficient to accomplish all of the desired goals. The preferred storage form is U{sub 3}O{sub 8} because it is more stable …