Benchmark Analysis of Subcritical Noise Measurements on a Nickel-Reflected Plutonium Metal Sphere (open access)

Benchmark Analysis of Subcritical Noise Measurements on a Nickel-Reflected Plutonium Metal Sphere

Subcritical experiments using californium source-driven noise analysis (CSDNA) and Feynman variance-to-mean methods were performed with an alpha-phase plutonium sphere reflected by nickel shells, up to a maximum thickness of 7.62 cm. Both methods provide means of determining the subcritical multiplication of a system containing nuclear material. A benchmark analysis of the experiments was performed for inclusion in the 2010 edition of the International Handbook of Evaluated Criticality Safety Benchmark Experiments. Benchmark models have been developed that represent these subcritical experiments. An analysis of the computed eigenvalues and the uncertainty in the experiment and methods was performed. The eigenvalues computed using the CSDNA method were very close to those calculated using MCNP5; however, computed eigenvalues are used in the analysis of the CSDNA method. Independent calculations using KENO-VI provided similar eigenvalues to those determined using the CSDNA method and MCNP5. A slight trend with increasing nickel-reflector thickness was seen when comparing MCNP5 and KENO-VI results. For the 1.27-cm-thick configuration the MCNP eigenvalue was approximately 300 pcm greater. The calculated KENO eigenvalue was about 300 pcm greater for the 7.62-cm-thick configuration. The calculated results were approximately the same for a 5-cm-thick shell. The eigenvalues determined using the Feynman method are up to …
Date: September 1, 2009
Creator: Bess, John D. & Hutchinson, Jesson
System: The UNT Digital Library
CCpi0 Event Reconstruction at MiniBooNE (open access)

CCpi0 Event Reconstruction at MiniBooNE

We describe the development of a fitter to reconstruct {nu}{sub {mu}} induced Charged-Current single {pi}{sup 0} (CC{pi}{sup 0}) events in an oil Cerenkov detector (CH{sub 2}). These events are fit using a generic muon and two photon extended track hypothesis from a common event vertex. The development of ring finding and particle identification are described. Comparisons between data and Monte Carlo are presented for a few kinematic distributions.
Date: September 1, 2009
Creator: Nelson, Robert H.
System: The UNT Digital Library
Changes in the chemistry of shallow groundwater related to the 2008 injection of CO2 at the ZERT Field Site, Bozeman, Montana (open access)

Changes in the chemistry of shallow groundwater related to the 2008 injection of CO2 at the ZERT Field Site, Bozeman, Montana

Approximately 300 kg/day of food-grade CO2 was injected through a perforated pipe placed horizontally 2-2.3 m deep during July 9-August 7, 2008 at the MSU-ZERT field test to evaluate atmospheric and near-surface monitoring and detection techniques applicable to the subsurface storage and potential leakage of CO2. As part of this multidisciplinary research project, 80 samples of water were collected from 10 shallow monitoring wells (1.5 or 3.0 m deep) installed 1-6 m from the injection pipe, at the southwestern end of the slotted section (zone VI), and from two distant monitoring wells. The samples were collected before, during and following CO2 injection. The main objective of study was to investigate changes in the concentrations of major, minor and trace inorganic and organic compounds during and following CO2 injection.
Date: September 1, 2009
Creator: Kharaka, Y. K.; Thordsen, T. T.; Kakouros, E.; Ambats, G.; Herkelrath, W. N.; Birkholzer, J. T. et al.
System: The UNT Digital Library
Charged Kaon Mass Measurement using the Cherenkov Effect (open access)

Charged Kaon Mass Measurement using the Cherenkov Effect

The two most recent and precise measurements of the charged kaon mass use X-rays from kaonic atoms and report uncertainties of 14 ppm and 22 ppm yet differ from each other by 122 ppm. We describe the possibility of an independent mass measurement using the measurement of Cherenkov light from a narrow-band beam of kaons, pions, and protons. This technique was demonstrated using data taken opportunistically by the Main Injector Particle Production experiment at Fermi National Accelerator Laboratory which recorded beams of protons, kaons, and pions ranging in momentum from +37 GeV/c to +63 GeV/c. The measured value is 491.3 {+-} 1.7 MeV/c{sup 2}, which is within 1.4{sigma} of the world average. An improvement of two orders of magnitude in precision would make this technique useful for resolving the ambiguity in the X-ray data and may be achievable in a dedicated experiment.
Date: September 1, 2009
Creator: Graf, N.; Lebedev, A.; Abrams, R. J.; Akgun, U.; Aydin, G.; Baker, W. et al.
System: The UNT Digital Library
Chitinase genes revealed and compared in bacterial isolates, DNA extracts and a metagenomic library from a phytopathogen suppressive soil (open access)

Chitinase genes revealed and compared in bacterial isolates, DNA extracts and a metagenomic library from a phytopathogen suppressive soil

Soil that is suppressive to disease caused by fungal pathogens is an interesting source to target for novel chitinases that might be contributing towards disease suppression. In this study we screened for chitinase genes, in a phytopathogen-suppressive soil in three ways: (1) from a metagenomic library constructed from microbial cells extracted from soil, (2) from directly extracted DNA and (3) from bacterial isolates with antifungal and chitinase activities. Terminal-restriction fragment length polymorphism (T-RFLP) of chitinase genes revealed differences in amplified chitinase genes from the metagenomic library and the directly extracted DNA, but approximately 40% of the identified chitinase terminal-restriction fragments (TRFs) were found in both sources. All of the chitinase TRFs from the isolates were matched to TRFs in the directly extracted DNA and the metagenomic library. The most abundant chitinase TRF in the soil DNA and the metagenomic library corresponded to the TRF{sup 103} of the isolate, Streptomyces mutomycini and/or Streptomyces clavifer. There were good matches between T-RFLP profiles of chitinase gene fragments obtained from different sources of DNA. However, there were also differences in both the chitinase and the 16S rRNA gene T-RFLP patterns depending on the source of DNA, emphasizing the lack of complete coverage of the …
Date: September 1, 2009
Creator: Hjort, K.; Bergstrom, M.; Adesina, M.F.; Jansson, J.K.; Smalla, K. & Sjoling, S.
System: The UNT Digital Library
CMS hadron calorimeter front-end upgrade for SLHC phase I (open access)

CMS hadron calorimeter front-end upgrade for SLHC phase I

We present an upgrade plan for the CMS HCAL detector. The HCAL upgrade is required for the increased luminosity (3 * 10E34) of SLHC Phase I which is targeted for 2014. A key aspect of the HCAL upgrade is to add longitudinal segmentation to improve background rejection, energy resolution, and electron isolation at the L1 trigger. The increased segmentation is achieved by replacing the hybrid photodiodes (HPDs) with silicon PMTs (SIPMs). We plan to instrument each fiber of the calorimeter with an SIPM (103,000 total). We will then electrically sum outputs from selected SIPMs to form the longitudinal readout segments. In addition to having more longitudinal information, the upgrade plans include a new custom ADC with matched sensitivity and timing information. The increased data volume requires higher speed transmitters and the additional power dissipation for the readout electronics requires better thermal design, since much of the on-detector infrastructure (front-end electronics crates, cooling pipes, optical fiber plant, etc.) will remain the same. We will report on the preliminary designs for these upgraded systems, along with performance requirements and initial design studies.
Date: September 1, 2009
Creator: Whitmore, Juliana
System: The UNT Digital Library
A comparison of global optimization algorithms with standard benchmark functions and real-world applications using Energy Plus (open access)

A comparison of global optimization algorithms with standard benchmark functions and real-world applications using Energy Plus

There is an increasing interest in the use of computer algorithms to identify combinations of parameters which optimise the energy performance of buildings. For such problems, the objective function can be multi-modal and needs to be approximated numerically using building energy simulation programs. As these programs contain iterative solution algorithms, they introduce discontinuities in the numerical approximation to the objective function. Metaheuristics often work well for such problems, but their convergence to a global optimum cannot be established formally. Moreover, different algorithms tend to be suited to particular classes of optimization problems. To shed light on this issue we compared the performance of two metaheuristics, the hybrid CMA-ES/HDE and the hybrid PSO/HJ, in minimizing standard benchmark functions and real-world building energy optimization problems of varying complexity. From this we find that the CMA-ES/HDE performs well on more complex objective functions, but that the PSO/HJ more consistently identifies the global minimum for simpler objective functions. Both identified similar values in the objective functions arising from energy simulations, but with different combinations of model parameters. This may suggest that the objective function is multi-modal. The algorithms also correctly identified some non-intuitive parameter combinations that were caused by a simplified control sequence of …
Date: September 1, 2009
Creator: Kamph, Jerome Henri; Robinson, Darren & Wetter, Michael
System: The UNT Digital Library
Deriving In-Use PHEV Fuel Economy Predictions from Standardized Test Cycle Results (open access)

Deriving In-Use PHEV Fuel Economy Predictions from Standardized Test Cycle Results

Plug-in hybrid electric vehicles (PHEVs) have potential to reduce or eliminate the U.S. dependence on foreign oil. Quantifying the amount of petroleum each uses, however, is challenging. To estimate in-use fuel economy for conventional vehicles the Environmental Protection Agency (EPA) conducts chassis dynamometer tests on standard historic drive cycles and then adjusts the resulting “raw” fuel economy measurements downward. Various publications, such as the forthcoming update to the SAE J1711 recommended practice for PHEV fuel economy testing, address the challenges of applying standard test procedures to PHEVs. This paper explores the issue of how to apply an adjustment method to such “raw” PHEV dynamometer test results in order to more closely estimate the in-use fuel and electricity consumption characteristics of these vehicles. The paper discusses two possible adjustment methods, and evaluates one method by applying it to dynamometer data and comparing the result to in-use fleet data (on an aftermarket conversion PHEV). The paper will also present the methodologies used to collect the data needed for this comparison.
Date: September 1, 2009
Creator: Smart, John; Carlson, Richard "Barney"; Gonder, Jeff & Brooker, Aaron
System: The UNT Digital Library
Design, fabrication and testing of single spoke resonators at Fermilab (open access)

Design, fabrication and testing of single spoke resonators at Fermilab

The Fermilab High Intensity Neutrino Source (HINS) linac R&D program is building a pulsed 30 MeV superconducting H- linac. The linac incorporates superconducting solenoids, high power RF vector modulators and superconducting spoke-type accelerating cavities starting at 10 MeV. This will be the first application and demonstration of any of these technologies in a low-energy, high-intensity proton/H- linac. The HINS effort is relevant to a high intensity, superconducting H- linac that might serve the next generation of neutrino physics and muon storage ring/collider experiments. In this paper we present the RF design, the mechanical design, the fabrication, the chemistry and testing of the first two SSR1 (Single Spoke Resonator type-1) prototype cavities that were built. These cavities operate at 325 MHz with {beta} = 0.21. The design and testing of the input coupler and the tuning mechanism are also discussed.
Date: September 1, 2009
Creator: Ristori, L.; Apollinari, G.; Borissov, E.; Gonin, I.V.; Khabiboulline, T.N.; Mukherjee, A. et al.
System: The UNT Digital Library
Diboson physics at CDF (open access)

Diboson physics at CDF

At the Fermilab Tevatron, the CDF detector is used to study diboson production in p{bar p} collisions at {radical}s = 1.96 TeV. We report recent diboson production measurements, limits on anomalous triple gauge couplings and latest results from semi-leptonic diboson searches.
Date: September 1, 2009
Creator: Annovi, Alberto
System: The UNT Digital Library
Direct measurement of the W boson width (open access)

Direct measurement of the W boson width

We present a direct measurement of the width of the W boson using the shape of the transverse mass distribution of W {yields} e{nu} candidates selected in 1 fb{sup -1} of data collected with the D0 detector at the Fermilab Tevatron collider in p{bar p} collisions at {radical}s = 1.96 TeV. We use the same methods and data sample that were used for our recently published W boson mass measurement, except for the modeling of the recoil, which is done with a new method based on a recoil library. Our result, 2.028 {+-} 0.072 GeV, is in agreement with the predictions of the standard model and is the most precise direct measurement result from a single experiment to date.
Date: September 1, 2009
Creator: Abazov, V. M.; Abbott, B.; Abolins, M.; Acharya, B. S.; Adams, M.; Adams, T. et al.
System: The UNT Digital Library
Drama: A Comparative Analysis of Individual Narratives (open access)

Drama: A Comparative Analysis of Individual Narratives

This article contains a narrative that explores how a selected group of educators made meaning of their experiences teaching college courses in prison.
Date: September 1, 2009
Creator: Spaulding, Susanna Belle; Banning, James; Harbour, Clifford P. & Davies, Timothy Gray
System: The UNT Digital Library
Dry Processing of Used Nuclear Fuel (open access)

Dry Processing of Used Nuclear Fuel

Dry (non-aqueous) separations technologies have been used for treatment of used nuclear fuel since the 1960s, and they are still being developed and demonstrated in many countries. Dry technologies offer potential advantages compared to traditional aqueous separations including: compactness, resistance to radiation effects, criticality control benefits, compatibility with advanced fuel types, and ability to produce low purity products. Within the Department of Energy’s Advanced Fuel Cycle Initiative, an electrochemical process employing molten salts is being developed for recycle of fast reactor fuel and treatment of light water reactor oxide fuel to produce a feed for fast reactors. Much of the development of this technology is based on treatment of used Experimental Breeder Reactor II (EBR-II) fuel, which is metallic. Electrochemical treatment of the EBR-II fuel has been ongoing in the Fuel Conditioning Facility, located at the Materials and Fuel Complex of Idaho National Laboratory since 1996. More than 3.8 metric tons of heavy metal of metallic fast reactor fuel have been treated using this technology. This paper will summarize the status of electrochemical development and demonstration activities with used nuclear fuel, including high-level waste work. A historic perspective on the background of dry processing will also be provided.
Date: September 1, 2009
Creator: Goff, K. M. & Simpson, M. F.
System: The UNT Digital Library
Dynamic Analysis of Fuel Cycle Transitioning (open access)

Dynamic Analysis of Fuel Cycle Transitioning

This paper examines the time-dependent dynamics of transitioning from a once-through fuel cycle to a closed fuel cycle. The once-through system involves only Light Water Reactors (LWRs) operating on uranium oxide fuel UOX), while the closed cycle includes both LWRs and fast spectrum reactors (FRs) in either a single-tier system or two-tier fuel system. The single-tier system includes full transuranic recycle in FRs while the two-tier system adds one pass of mixed oxide uranium-plutonium (MOX U-Pu) fuel in the LWR. While the analysis primarily focuses on burner fast reactors, transuranic conversion ratios up to 1.0 are assessed and many of the findings apply to any fuel cycle transitioning from a thermal once-through system to a synergistic thermal-fast recycle system. These findings include uranium requirements for a range of nuclear electricity growth rates, the importance of back end fuel cycle facility timing and magnitude, the impact of employing a range of fast reactor conversion ratios, system sensitivity to used fuel cooling time prior to recycle, impacts on a range of waste management indicators, and projected electricity cost ranges for once-through, single-tier and two-tier systems. The study confirmed that significant waste management benefits can be realized as soon as recycling is initiated, …
Date: September 1, 2009
Creator: Dixon, Brent; Piet, Steve; Shropshire, David & Matthern, Gretchen
System: The UNT Digital Library
Dynamic Complexity Study of Nuclear Reactor and Process Heat Application Integration (open access)

Dynamic Complexity Study of Nuclear Reactor and Process Heat Application Integration

Abstract This paper describes the key obstacles and challenges facing the integration of nuclear reactors with process heat applications as they relate to dynamic issues. The paper also presents capabilities of current modeling and analysis tools available to investigate these issues. A pragmatic approach to an analysis is developed with the ultimate objective of improving the viability of nuclear energy as a heat source for process industries. The extension of nuclear energy to process heat industries would improve energy security and aid in reduction of carbon emissions by reducing demands for foreign derived fossil fuels. The paper begins with an overview of nuclear reactors and process application for potential use in an integrated system. Reactors are evaluated against specific characteristics that determine their compatibility with process applications such as heat outlet temperature. The reactor system categories include light water, heavy water, small to medium, near term high-temperature, and far term high temperature reactors. Low temperature process systems include desalination, district heating, and tar sands and shale oil recovery. High temperature processes that support hydrogen production include steam reforming, steam cracking, hydrogen production by electrolysis, and far-term applications such as the sulfur iodine chemical process and high-temperature electrolysis. A simple static …
Date: September 1, 2009
Creator: Taylor, J'Tia Patrice & Shropshire, David E.
System: The UNT Digital Library
Dynamics of CO2 fluxes and concentrations during a shallow subsurface CO2 release (open access)

Dynamics of CO2 fluxes and concentrations during a shallow subsurface CO2 release

A field facility located in Bozeman, Montana provides the opportunity to test methods to detect, locate, and quantify potential CO2 leakage from geologic storage sites. From 9 July to 7 August 2008, 0.3 t CO2 d{sup -1} were injected from a 100-m long, {approx}2.5 m deep horizontal well. Repeated measurements of soil CO2 fluxes on a grid characterized the spatio-temporal evolution of the surface leakage signal and quantified the surface leakage rate. Infrared CO2 concentration sensors installed in the soil at 30 cm depth at 0 to 10 m from the well and at 4 cm above the ground at 0 and 5 m from the well recorded surface breakthrough of CO2 leakage and migration of CO2 leakage through the soil. Temporal variations in CO2 concentrations were correlated with atmospheric and soil temperature, wind speed, atmospheric pressure, rainfall, and CO2 injection rate.
Date: September 1, 2009
Creator: Lewicki, J. L.; Hilley, G. E.; Dobeck, L. & Spangler, L.
System: The UNT Digital Library
Eastern Wind Integration and Transmission Study -- Preliminary Findings: Preprint (open access)

Eastern Wind Integration and Transmission Study -- Preliminary Findings: Preprint

This paper reviews the Eastern Wind Integration and Transmission Study, the development of wind datasets, the transmission analysis, and the results of wind integration analysis for four scenarios.
Date: September 1, 2009
Creator: Corbus, D.; Milligan, M.; Ela, E.; Schuerger, M. & Zavadil, B.
System: The UNT Digital Library
ECOLOGICAL EFFECTS OF METALS IN STREAMS ON A DEFENSE MATERIALS PROCESSING SITE IN SOUTH CAROLINA, USA (open access)

ECOLOGICAL EFFECTS OF METALS IN STREAMS ON A DEFENSE MATERIALS PROCESSING SITE IN SOUTH CAROLINA, USA

The Savannah River Site (SRS) is a 780 km{sup 2} U.S. Department of Energy facility near Aiken SC established in 1950 to produce nuclear materials. SRS streams are 'integrators' that potentially receive water transportable contaminants from all sources within their watersheds necessitating a GIS-based watershed approach to organize contaminant distribution data and accurately characterize the effects of multiple contaminant sources on aquatic organisms. Concentrations of metals in sediments, fish, and water were elevated in streams affected by SRS operations, but contaminant exposure models for Lontra Canadensis and Ceryle alcyon indicated that toxicological reference values were exceeded only by Hg and Al. Macroinvertebrate community structure was unrelated to sediment metal concentrations. This study indicated that (1) modeling studies and field bioassessments provide a complementary basis for addressing the individual and cumulative effects of contaminants, (2) habitat effects must be controlled when assessing contaminant impacts, (3) sensitivity analyses of contaminant exposure models are helpful in apportioning sampling effort, and (4) contaminants released during fifty years of industrial operations have not resulted in demonstrable harm to aquatic organisms in SRS streams.
Date: September 1, 2009
Creator: Paller, M. & Dyer, S.
System: The UNT Digital Library
Effects of Cerium Removal from Glass on Photovoltaic Module Performance and Stability: Preprint (open access)

Effects of Cerium Removal from Glass on Photovoltaic Module Performance and Stability: Preprint

Some PV manufacturers use glass without Ce, which improves light transmission but can lower long-term stability; additional light transmission in 300-340-nm range can cause delamination ~3.8x faster.
Date: September 1, 2009
Creator: Kempe, M. D.; Moricone, T. & Kilkenny, M.
System: The UNT Digital Library
Electrolysis byproduct D2O provides a third way to mitigate CO2 (open access)

Electrolysis byproduct D2O provides a third way to mitigate CO2

Rapid atomic power deployment may be possible without using fast breeder reactors or making undue demands on uranium resource. Using by-product D2O and thorium-U233 in CANDU and RBMK piles may circumvent need for either fast breeder reactors or seawater uranium. Atmospheric CO2 is presently increasing 2.25%/year in proportion to 2.25%/year exponential fossil fuel consumption increase. Roughly 1/3 anthropologic CO2 is removed by various CO2 sinks. CO2 removal is modelled as being proportional to 45-year-earlier CO2 amount above 280 ppm-C Water electrolysis produces roughly 0.1 kg-D20/kWe-y. Material balance assumes each electrolysis stage increases D2O bottoms concentration times 3. Except for first two electrolysis stages, all water from hydrogen consumption is returned to electrolysis. The unique characteristic of this process is the ability to economically burn all deuterium-enriched H2 in vehicles. Condensate from vehicles returns to appropriate electrolysis stage. Fuel cell condensate originally from reformed natural gas may augment second-sage feed. Atomic power expansion is 5%/year, giving 55000 GWe by 2100. World primary energy increases 2.25%/y, exceeding 4000 EJ/y by 2100. CO2 maximum is roughly 600 ppm-C around year 2085. CO2 declines back below 300 ppm-C by 2145 if the 45-year-delay seawater sink remains effective.
Date: September 1, 2009
Creator: Schenewerk, William Ernest
System: The UNT Digital Library
Emittance exchange results (open access)

Emittance exchange results

The promise of next-generation light sources depends on the availability of ultra-low emittance electron sources. One method of producing low transverse emittance beams is to generate a low longitudinal emittance beam and exchange it with a large transverse emittance. Experiments are underway at Fermilab's A0 Photoinjector and ANL's Argonne Wakefield Accelerator using the exchange scheme of Kim and Sessler. The experiment at the A0 Photoinjector exchanges a large longitudinal emittance with a small transverse emittance. AWA expects to exchange a large transverse emittance with a small longitudinal emittance. In this paper we discuss recent results at A0 and AWA and future plans for these experiments.
Date: September 1, 2009
Creator: Fliller, R. P., III; /Brookhaven; Koeth, T. & /Rutgers U., Piscataway
System: The UNT Digital Library
Enhancing the ABAQUS Thermomechanics Code to Simulate Steady and Transient Fuel Rod Behavior (open access)

Enhancing the ABAQUS Thermomechanics Code to Simulate Steady and Transient Fuel Rod Behavior

A powerful multidimensional fuels performance capability, applicable to both steady and transient fuel behavior, is developed based on enhancements to the commercially available ABAQUS general-purpose thermomechanics code. Enhanced capabilities are described, including: UO2 temperature and burnup dependent thermal properties, solid and gaseous fission product swelling, fuel densification, fission gas release, cladding thermal and irradiation creep, cladding irradiation growth , gap heat transfer, and gap/plenum gas behavior during irradiation. The various modeling capabilities are demonstrated using a 2D axisymmetric analysis of the upper section of a simplified multi-pellet fuel rod, during both steady and transient operation. Computational results demonstrate the importance of a multidimensional fully-coupled thermomechanics treatment. Interestingly, many of the inherent deficiencies in existing fuel performance codes (e.g., 1D thermomechanics, loose thermo-mechanical coupling, separate steady and transient analysis, cumbersome pre- and post-processing) are, in fact, ABAQUS strengths.
Date: September 1, 2009
Creator: Williamson, R. L. & Knoll, D. A.
System: The UNT Digital Library
Exclusive High Mass Di-leptons in CDF (open access)

Exclusive High Mass Di-leptons in CDF

In the Collider Detector at Fermilab, CDF, we have measured central exclusive production, p + {bar p} {yields} p + X + {bar p}, where X is a pair of leptons or photons and nothing else. In this talk I focus on central masses M(X) > 8 GeV/c{sup 2}. We measured QED production {gamma}{gamma} {yields} e{sup +}e{sup -}, {mu}{sup +}{mu}{sup -} up to M(X) = 75 GeV/c{sup 2}, and candidates for photoproduction of Upsilons, {gamma} IP {yields} Y (1S), Y (2S), Y (3S). I report a search for exclusive photoproduction of Z-bosons, and the status of searches for exclusive two-photons: p + {bar p} {yields} p + {gamma}{gamma} + {bar p}. These measurements constrain the cross section {sigma}(p + p {yields} p + H + p) at the LHC.
Date: September 1, 2009
Creator: Albrow, Michael
System: The UNT Digital Library
Experimental Investigations into U/TRU Recovery using a Liquid Cadmium Cathode and Salt Containing High Rare Earth Concentrations (open access)

Experimental Investigations into U/TRU Recovery using a Liquid Cadmium Cathode and Salt Containing High Rare Earth Concentrations

Experimental Investigations into U/TRU Recovery using a Liquid Cadmium Cathode and Salt Containing High Rare Earth Concentrations Shelly X. Li, Steven D. Herrmann, and Michael F. Simpson Pyroprocessing Technology Department Idaho National Laboratory P.O. Box 1625, Idaho Falls, ID 83415 USA Abstract - A series of six bench-scale liquid cadmium cathode (LCC) tests was performed to obtain basic separation data with focus on the behavior of rare earth elements. The electrolyte used for the tests was a mixed salt from the Mk-IV and Mk-V electrorefiners, in which spent metal fuels from Experimental Breeder Reactor-II (EBR-II) had been processed. Rare earth (RE) chlorides, such as NdCl3, CeCl3, LaCl3, PrCl3, SmCl3, and YCl3, were spiked into the salt prior to the first test to create an extreme case for investigating rare earth contamination of the actinides collected by a LCC. For the first two LCC tests, an alloy with the nominal composition of 41U-30Pu-5Am-3Np-20Zr-1RE was loaded into the anode baskets as the feed material. The anode feed material for Runs 3 to 6 was spent ternary fuel (U-19Pu-10Zr). The Pu/U ratio in the salt varied from 0.6 to 1.3. Chemical and radiochemical analytical results confirmed that U and transuranics can be collected …
Date: September 1, 2009
Creator: Li, Shelly X.; Herrmann, Steven D. & Simpson, Michael F.
System: The UNT Digital Library