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Brookhaven highlights for fiscal year 1991, October 1, 1990--September 30, 1991 (open access)

Brookhaven highlights for fiscal year 1991, October 1, 1990--September 30, 1991

This report highlights Brookhaven National Laboratory's activities for fiscal year 1991. Topics from the four research divisions: Computing and Communications, Instrumentation, Reactors, and Safety and Environmental Protection are presented. The research programs at Brookhaven are diverse, as is reflected by the nine different scientific departments: Accelerator Development, Alternating Gradient Synchrotron, Applied Science, Biology, Chemistry, Medical, National Synchrotron Light Source, Nuclear Energy, and Physics. Administrative and managerial information about Brookhaven are also disclosed. (GHH)
Date: January 1, 1991
Creator: Rowe, M.S.; Cohen, A.; Greenberg, D.; Seubert, L. & Kuper, J.B.H.
System: The UNT Digital Library
Electrochemistry of Thiobacillus ferrooxidans reactions with pyrite (open access)

Electrochemistry of Thiobacillus ferrooxidans reactions with pyrite

The objective of this project is to provide the fundamental information on the mechanisms of bacterial leaching of pyrite. The knowledge of how bacterial leaching of pyrite functions is essential for design and development of a technology for coal cleaning with bacteria. The features of major electrochemical techniques will be examined to find out if any of them can provide a diagnostic information on the mechanisms of related reactions.
Date: January 1, 1992
Creator: Pesic, B.
System: The UNT Digital Library
A Novel Coal Feeder for Production of Low Sulfur Fuel (open access)

A Novel Coal Feeder for Production of Low Sulfur Fuel

During the past three months, the coal feeding system has been tested and currently undergoing evaluation at the University of Cincinnati. The system consists primarily of an auger feed tube which is used to both convey and provide desulfurization of a high sulfur coal feedstock. The coal is conveyed at temperatures ranging from 350 to 550{degrees}C and under normal atmospheric pressure. Under these mild processing conditions, the coal partially pyrolizes and emits sulfur in the form of hydrogen sulfide while maintaining a relatively high heating value in the char product. The evolved gases are evacuated from the reactor (the feed tube) to another absorbing bed where H{sub 2}S reacts with the sorbent, usually lime or limestone. The resultant sorbent utilization is substantially higher than the values found in current dry scrubbing system and the produced low-sulfur char may then be used in a conventional steam boiler.
Date: January 1, 1990
Creator: Khang, S. J. & Keener, T. C.
System: The UNT Digital Library
Sonic enhanced ash agglomeration and sulfur capture (open access)

Sonic enhanced ash agglomeration and sulfur capture

The major objective of the Phase 1 test program is to confirm the feasibility of the Manufacturing and Technology Conversion International, Inc. bimodal particle size approach to enhance particulate control by acoustic ash agglomeration. An ancillary objective of the Phase 1 effort is to demonstrate and confirm the feasibility of an acoustic field to enhance sulfur capture by increasing sorbent reactivity. Phase 1 tests are designed to cover the frequency range between 50 and 1400 Hz, establish monomodal baseline performance as a benchmark from which to measure the degree of enhancement expected from the bimodal approach, and, finally, to confirm the effectiveness of low-frequency fields over high-frequency fields for realistic particulate streams. The program will demonstrate the effectiveness of a unique approach which uses a bimodal distribution composed of large sorbent particles and fine fly ash particles to enhance ash agglomeration and sulfur capture at conditions found in direct coal-fired turbines. Under the impact of high-intensity sound waves, sorbent reactivity and utilization, it is theorized, will increase while agglomerates of fly ash and sorbents are formed which are readily collected in commercial cyclones. The work will extend the concept from the demonstration of feasibility (Phase 1), through proof-of-concept (Phase 2) …
Date: January 1, 1991
Creator: unknown
System: The UNT Digital Library
Health effects models for nuclear power plant accident consequence analysis: Low LET radiation (open access)

Health effects models for nuclear power plant accident consequence analysis: Low LET radiation

This report describes dose-response models intended to be used in estimating the radiological health effects of nuclear power plant accidents. Models of early and continuing effects, cancers and thyroid nodules, and genetic effects are provided. Weibull dose-response functions are recommended for evaluating the risks of early and continuing health effects. Three potentially lethal early effects -- the hematopoietic, pulmonary, and gastrointestinal syndromes -- are considered. In addition, models are included for assessing the risks of several nonlethal early and continuing effects -- including prodromal vomiting and diarrhea, hypothyroidism and radiation thyroiditis, skin burns, reproductive effects, and pregnancy losses. Linear and linear-quadratic models are recommended for estimating cancer risks. Parameters are given for analyzing the risks of seven types of cancer in adults -- leukemia, bone, lung, breast, gastrointestinal, thyroid, and other.'' The category, other'' cancers, is intended to reflect the combined risks of multiple myeloma, lymphoma, and cancers of the bladder, kidney, brain, ovary, uterus and cervix. Models of childhood cancers due to in utero exposure are also developed. For most cancers, both incidence and mortality are addressed. The models of cancer risk are derived largely from information summarized in BEIR III -- with some adjustment to reflect more recent …
Date: January 1, 1990
Creator: Evans, J. S.
System: The UNT Digital Library
NQR-NMR studies of higher alcohol synthesis Cu-Co catalysts (open access)

NQR-NMR studies of higher alcohol synthesis Cu-Co catalysts

Copper and cobalt are the key elements in syngas conversion catalyst systems used for higher alcohol synthesis. Their proximity and synergy sensitively control the selectivity and efficiency of the process. It is believed that their outer electronic charge distribution which is responsible for their electrical and magnetic properties might be governing their catalytic properties also. To examine the correlation between catalytic and magnetic properties, a series of copper cobalt catalysts (Co/Cu ratio 5:1 to 5:5) with and without a support were prepared. The nuclear quadrupole resonance spectrum of copper and (zero-field) nuclear magnetic resonance spectrum of cobalt and magnetization and hysteresis character of the catalyst were analyzed. Similar to the catalytic results, the magnetic results also were found to be very sensitive to the preparation technique. The results indicate possible electron exchange between copper and cobalt, and cobalt and the support Titania.
Date: January 14, 1991
Creator: unknown
System: The UNT Digital Library
High temperature ceramic membrane reactors for coal liquid upgrading (open access)

High temperature ceramic membrane reactors for coal liquid upgrading

In this project we intend to study a novel process concept, i.e, the use of ceramic membranes reactors in upgrading of coal derived liquids. Membrane reactors have been used in a number of catalytic reaction processes in order to overcome the limitations on conversion imposed by thermodynamic equilibrium. They have, furthermore, the inherent capability for combining reaction and separation in a single step. Thus they offer promise for improving and optimizing yield, selectivity and performance of processes involving complex liquids, as those typically found in coal liquid upgrading. Ceramic membranes are a new class of materials, which have shown promise in a variety of industrial applications. Their mechanical and chemical stability coupled with a wide range of operating temperatures and pressures make them suitable for environments found in coal liquid upgrading. In this project we will evaluate the performance of Sol-Gel alumina membranes in coal liquid upgrading processes under realistic temperature and pressure conditions and investigate the feasibility of using such membranes in a membrane reactor based coal liquid upgrading process. In addition, the development of novel ceramic membranes with enhanced catalytic activity for coal-liquid upgrading applications, such as carbon-coated alumina membranes, will be also investigated.
Date: January 1, 1992
Creator: Tsotsis, T.T.
System: The UNT Digital Library
Impact of Nonequilibrium Particle Temperature Considerations on Seeded Coal Combustion Plasma Properties (open access)

Impact of Nonequilibrium Particle Temperature Considerations on Seeded Coal Combustion Plasma Properties

This past quarter ending 12/30/91, the linear MHD channel simulation model has not only been completely specified but also fully modified to incorporate considerations for nonequilibrium particle temperatures. Testing of the modified model with the initial values from the first submodel (Richter's combustion zone model) and evaluation of the non-equilibrium particle temperature effect on the overall MHD performance is being held up. Reasons for the holdup is the lack of adequate response from Dr. Richter on questions about his nonequilibrium particle temperature model. These questions relate to our insistence to know precisely how the model works and also some review of the source code to ascertain that it is synchronization with our overall analytical development. We have decided to generate initial generator inlet particle parameter values by modifying the CEC code to provide particle parameter values.
Date: January 1, 1991
Creator: Oni, A. A.
System: The UNT Digital Library
Biological Production of Ethanol From Coal (open access)

Biological Production of Ethanol From Coal

The fermentation pH has been observed to be the key parameter affecting the ratio of ethanol to acetate produced by Clostridium ljungdahlii. The effects of controlled pH on cell growth and product formation by C. ljungdahlii were measured. It was found that cell concentration and acetate concentration increased with pH, while the ethanol concentration was highest at the lower pH. The molar product ratio of ethanol to acetate was 0.74 at pH 4.0, 0.39 at pH 4.5 and 0.12 at pH 5.0. Future experiments will concentrate on studying other important parameters such as agitation rate and nutrients concentrations with controlled pH as a preclude to continuous reactor studies.
Date: January 1, 1990
Creator: unknown
System: The UNT Digital Library
Biological Production of Ethanol From Coal (open access)

Biological Production of Ethanol From Coal

Research is continuing in an attempt to increase both the ethanol concentration and product ratio using C. ljungdahlii. The purpose of this report is to present data utilizing a medium prepared especially for C. ljungdahlii. Medium development studies are presented, as well as reactor studies with the new medium in batch reactors. CSTRs and CSTRs with cell recycle. The use of this new medium has resulted in significant improvements in cell concentration, ethanol concentration and product ratio.
Date: January 1, 1992
Creator: unknown
System: The UNT Digital Library
Utilization of coal-water fuels in fire-tube boilers (open access)

Utilization of coal-water fuels in fire-tube boilers

This project is a demonstration for firing coal-water slurry in a fire-tube boiler. It includes design, installation, and demonstration of the slurry firing equipment in a fire-tube boiler at the University of Alabama in Tuscaloosa. The project will be funded by the US Department of Energy with cost sharing from Jim Walter Resources and the University of Alabama. Energy and Environmental Research Corporation is the prime contractor responsible for all respects of the project. The specific objective of this contract is to demonstrate the potential for coal-water fuels to be burned effectively in fire-tube boiler designed for oil or gas. When the results of this project combined with the results of the water-tube slurry testing, a broad data base will exist that will provide valuable information for the retrofit of future boilers. 1 tab.
Date: January 1, 1991
Creator: Sommer, T. & Melick, T.
System: The UNT Digital Library
Waste Isolation Pilot Plant site environmental report for calendar year 1990 (open access)

Waste Isolation Pilot Plant site environmental report for calendar year 1990

The US Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP) Operational Environmental Monitoring Plan (OEMP) monitors a comprehensive set of parameters in order to detect any potential environmental impacts and establish baselines for future quantitative environmental impact evaluations. Surface water and groundwater, soil, and biotics are measured for background radiation. Nonradiological environmental monitoring activities include meteorological, air quality, soil properties, and the status of the local biological community. Ecological studies focus on the immediate area surrounding the site with emphasis on the salt storage pile, whereas baseline radiological surveillance covers a broader geographic area including nearby ranches, villages, and cities. Since the WIPP is still in a preoperational state, no waste has been received; therefore, certain elements required by Order DOE 5400.1 are not presented in this report. 15 figs. 19 tabs.
Date: January 1, 1990
Creator: unknown
System: The UNT Digital Library
Simulation of hanging file experiments with CALOR89 (open access)

Simulation of hanging file experiments with CALOR89

This note presents the comparison of CALOR89 simulation with the hanging file'' test measurements conducted at Fermilab during the period of Sep 91--Jan 92. The purpose of this study is to benchmark CALOR89 code against the experimental data to enhance its reliability and predictive power. Seven hanging file configurations were simulated. The measured values of e/{pi} ratio (the ratio of electron to pion signal at the same energy), hadronic and electromagnetic resolutions were compared with the simulations. The depth profiles of the hadronic and electromagnetic showers are also compared.
Date: January 1, 1992
Creator: Job, P.K.; Price, L.E.; Proudfoot, J. (Argonne National Lab., IL (United States). High Energy Physics Div.); Handler, T. (Tennessee Univ., Knoxville, TN (United States)) & Gabriel, T.A. (Oak Ridge National Lab., TN (United States))
System: The UNT Digital Library
Application of optical fluctuation diagnostics to transport studies in high temperature tokamak plasmas (open access)

Application of optical fluctuation diagnostics to transport studies in high temperature tokamak plasmas

First data was obtained from the TFTR BES system in May 1990, after the prototype 4-channel system with photomultiplier detectors from PBX-M was transferred to the TFTR Hot Cell. The system was expanded to 16 spatial channels during the Summer 1990 run period, and data of interest was obtained near the end of the run in October 1990. The most attention has been given to a radial profile data set obtained for an L-mode plasma condition in TFTR, where we characterized the nature of the long-wavelength turbulence seen by the BES diagnostic. We summarize here highlights of the initial run with BES or TFTR. We also give a progress report on support activities at UW.
Date: January 1, 1991
Creator: Fonck, R.J.
System: The UNT Digital Library
(The relationship between microstructure and magnetic properties in high-energy permanent magnets characterized by polytwinned structures) (open access)

(The relationship between microstructure and magnetic properties in high-energy permanent magnets characterized by polytwinned structures)

This report summarizes the results of a study of the relationship between microstructure and magnetic properties in a unique genre of ferromagnetic material characterized by a polysynthetically twinned structure which arises during solid state transformation. These results stem from the work over a period of approximately 27 months of a nominal 3 year grant period. The report also contains a proposal to extend the research project for an additional 3 years. The polytwinned structures produce an inhomogeneous magnetic medium in which the easy axis of magnetization varies quasi-periodically giving rise to special domain configurations which are expected to markedly influence the mechanism of magnetization reversal and hysteresis behavior of these materials in bulk or thin films. The extraordinary permanent magnet properties exhibited by the well-known Co-Pt alloys as well as the Fe-Pt and Fe-Pd systems near the equiatomic composition derive from the formation of a polytwinned microstructure.
Date: January 1, 1992
Creator: unknown
System: The UNT Digital Library
The bioenergetics of salt tolerance (open access)

The bioenergetics of salt tolerance

The aim of this project was to try to understand the adaptive mechanisms that organisms develop in order to respond to a sudden transformation in their environment to a salt shock.'' To study this problem we used a fresh water oxygenic photosynthetic cyanobacterium known as Synecoccus 6311. This organism suffers injury after this sudden exposure to high concentrations of sodium chloride equivalent to or even higher than that in sea water. Yet they are able to re-establish their photosynthetic activity which is partially injured and return to virtually normal growth rates. Identification of the temporal sequence of changes involved in adaptation to this stress was the rationale. Indeed this project employed a wide variety of biochemical and biophysical methods, including electron spin resonance techniques and nuclear magnetic resonance to study the bioenergetics and transport mechanisms, growth and energy changes in these organisms and how the structural components of the cells changed in response to adaptation to growth at high salinity. The problem has relevance for higher plants because most of the arable farmland in the work is already under use and that which is not used is usually in salite environments. Hence, understanding basic mechanisms of salt tolerance is a …
Date: January 1, 1991
Creator: Packer, L.
System: The UNT Digital Library
Radiation induced micrencephaly in guinea pigs (open access)

Radiation induced micrencephaly in guinea pigs

A brain weight deficit of about 70 mg was induced at doses of approximately 75-mGy and a deficit of 60 mg was induced at 100 mGy. This confirms the effects projected and observed by Wanner and Edwards. Although the data do not demonstrate a clear dose-response relationship between the 75-mGy and 100-mGy groups, the data are statistically consistent with a dose-response effect because of the overlapping confidence intervals. The lack of a statistically significant observation is most likely related to the small difference in doses and the limited numbers of animals examined. There are several factors that can influence the brain weight of guinea pig pups, such as caging and housing conditions, the sex of the animal, and litter size. These should be taken into account for accurate analysis. Dam weight did not appear to have a significant effect. The confirmation of a micrencephalic effect induced x rays at doses of 75-mGy during this late embryonic stage of development is consistent with the findings of small head size induced in those exposed prior to the eight week of conception at Hiroshima. This implies a mechanism for micrencephaly different from those previously suggested and lends credence to a causal relation between …
Date: January 1, 1991
Creator: Wagner, L.K.; Johnston, D.A. & Felleman, D.J.
System: The UNT Digital Library
High temperature ceramic membrane reactors for coal liquid upgrading (open access)

High temperature ceramic membrane reactors for coal liquid upgrading

In this project we will study a novel process concept, i.e., the use of ceramic membrane reactors in upgrading of coal model compounds and coal derived liquids. In general terms, the USC research team is responsible for constructing and operating the membrane reactor apparatus and for testing various inorganic membranes for the upgrading of coal derived asphaltenes and coal model compounds. The USC effort will involve the principal investigator of this project and two graduate research assistants. The ALCOA team is responsible for the preparation of the inorganic membranes, for construction and testing of the ceramic membrane modules, and for measurement of their transport properties. The ALCOA research effort will involve Dr. Paul K. T. Liu, who is the project manager of the ALCOA research team, an engineer and a technician. UNOCAL's contribution will be limited to overall technical assistance in catalyst preparation and the operation of the laboratory upgrading membrane reactor and for analytical back-up and expertise in oil analysis and materials characterization. UNOCAL is a no-cost contractor but will be involved in all aspects of the project, as deemed appropriate.
Date: January 1, 1992
Creator: Tsotsis, T.T.
System: The UNT Digital Library
Rapid quenching of molten lithium-aluminum jets in water under loss-of-control-rod-cooling conditions (open access)

Rapid quenching of molten lithium-aluminum jets in water under loss-of-control-rod-cooling conditions

A series of fifteen tests were performed to investigate the thermal interactions between molten LiAl control rod material and water under conditions prototypic of the loss-of-control-rod-cooling (LCRC) accident scenario. The experimental parameters such as melt mass, stream diameter, melt temperature and flowrate, water depth and water temperature were controlled or varied to agree with analytically determined conditions, thus insuring prototypicality of the experiments and applicability of the results. Experiments were performed in an actual Q-septifoil with web insert; the test section was one meter tall. Natural triggers were investigated in selected tests, to evaluate the self-triggering potential of this system. The self-triggering mechanisms that were investigated were thermal stratification of the water pool, two-phase flow in the water pool, and simultaneous drop of a control rod in parallel channel. Only benign interactions were observed during these tests with some evidence of pressurization in the tests with deepest and hottest water pools. There was no evidence of any explosive interactions in any of the tests, even those with natural triggers. The molten LiAl jets was found to undergo jet breakup and fragmentation; in some cases the debris hung up in the web, in other cases the debris settled into a loose …
Date: January 1, 1992
Creator: Greene, G. A.; Finfrock, C. C.; Schwarz, C. E.; Allison, D. K. & Hyder, M. L.
System: The UNT Digital Library
An organizational survey of the Strategic Petroleum Reserve. [Organizational survey in preparation for an upcoming Tiger Team Assessment] (open access)

An organizational survey of the Strategic Petroleum Reserve. [Organizational survey in preparation for an upcoming Tiger Team Assessment]

At the request of the management of the Strategic Petroleum Reserve (SPR), an Organizational Survey (OS), identical to the one that has been used prior to Tiger Team Assessments at other Department Energy facilities, was administered at SPR independent of a Tiger Team Assessment. The OS measured employees' opinions on subjects such as organizational culture, communication, commitment, group cohesion, coordination, safety, environmental issues, and job satisfaction. The result of this work was a quantitative measure of these variables at the SPR site. SPR management intends to utilize these results in their self-assessment process in preparation for an upcoming Tiger Team Assessment. This report presents these results and discusses their interpretation.
Date: January 1, 1992
Creator: Shurberg, D.A. & Haber, S.B.
System: The UNT Digital Library
Applications of mesoscopic physics (open access)

Applications of mesoscopic physics

This report discusses the following topics: Acoustical nondestructive evaluation of heterogeneous materials in the multiple scattering regime. Classical and quantum superdiffusion in a time-dependent random potential. Negative Magnetoresistance in Variable Range Hopping Conduction. Reproducible Conductance Fluctuations in Macroscopic Anderson Insulators. Feasibility of far-infared lasers using multiple semiconductor quantum wells.
Date: January 1, 1992
Creator: Feng, Shechao.
System: The UNT Digital Library
FY 90 annual research plan (open access)

FY 90 annual research plan

The National Institute for Petroleum and Energy Research (NIPER) was established by the DOE to perform contract research for government and industrial clients. The emphasis of the DOE program is immediate near- and mid-term concerns of domestic oil and gas producibility. Its primary purpose is to improve the fundamental understanding of domestic oil and gas resources and the chemical, physical, and biological phenomena that govern the occurrence and recovery of these resources in addition to their associated environmental issues. The near-term objective of the DOE program is to maintain access to resources presently being produced in domestic oil and gas fields, and to decrease the rate of decline of domestic production. NIPER projects in chemical flooding, gas injection, steam injection, and microbial EOR address near-term concerns of domestic oil production. Further, problems associated with the utilization of heavier fossil feedstocks are being addressed. The mid-term objective of the DOE program is to maximize the recovery efficiency of discovered oil and gas through improved understanding of the resource and to develop advanced extraction and instrumentation techniques. The objective also emphasizes an expanded understanding of the environment. NIPER projects dealing with the quantification of reservoir heterogeneities, pore structure analysis, and fluid flow …
Date: January 1, 1990
Creator: unknown
System: The UNT Digital Library
The role of mobile ions in fast ion conducting systems and high impact strength ceramics (open access)

The role of mobile ions in fast ion conducting systems and high impact strength ceramics

This report discusses the following topics: Polymeric systems; Lead halide-containing fast ion conducting glasses; Mixed ionic electronic conduction; Plastic crystals; and Mobile ions as a basis for high impact ceramics.
Date: January 1, 1991
Creator: Angell, C. A.
System: The UNT Digital Library
(Hadamard Raman imaging) (open access)

(Hadamard Raman imaging)

We have used newly developed holographic notch filters for obtaining both Stokes and anti-Stokes Raman images. The filters can be used as close as {plus minus}70 cm{sup {minus}1} from the Rayleigh line. We have demonstrated that they are insensitive to polarization, have 80% transmission across their clear apertures and block laser light by 10{sup 4}. The devices now have replaced sharp-cut glass filters on our microscope. We have successfully developed multispectral control and display software for the microscope. 4 refs., 3 figs.
Date: January 1, 1991
Creator: unknown
System: The UNT Digital Library