Section I introduces the material contained in the rest of the report. Section II presents the origin and characteristics of humic materials as we understand them today and outlines the methods that have been used to separate and analyze these substances. Section III focuses on the general problem of metal-organic interactions and treats some of the factors that are important in chelating and complexing of metal ions by humic substances. Section IV deals specifically with the complexing of radionuclides by organic substances, treated from the standpoint of both empirical and experimental studies.

The Nevada Nuclear Waste Storage Investigations (NNWSI) project is investigating the volcanic tuff beds of Yucca Mountain, Nevada, as a potential location for a high-level radioactive waste repository. This report describes a test method (Phase II) that has been developed to measure the release of radionuclides from the waste package under simulated repository conditions, and provides information on materials interactions that may occur in the repository. The results of 13 weeks of testing using the method are presented, and an analog test is described that investigates the relationship between the test method and expected repository conditions.

Parameters and operating conditions (a stability map) were determined for which a specific slip-joint design did not cause self-excited lateral vibration of the two cantilevered, telescoping tubes forming the joint. The joint design featured a localized annular constriction. Flowrate, modal damping, tube engagement length, and eccentric positioning were among the parameters tested. Interestingly, all self-excited vibrations could be avoided by following a simple design rule: place constrictions only at the downstream end of the annular region between the tubes. Also, overall modal damping decreased with increased flowrate, at least initially, for upstream constrictions while the damping increased for downstream constrictions.

The mathematical software effort bridges the gap between the discovery of numerical algorithms and the consumption of numerical software. The spectrum of activities is surprisingly wide, including tasks often associated with numerical analysis, program design and testing, programming practices, language standards, documentation standards, software organization, distribution methods, and even the specification of arithmetic engines. This paper highlights the most important accomplishments in the field over the last twenty years. It also examines current problems and future challenges posed by the rapid advance of technology.

Tutorial description of the Warren machine with a basic introduction to the motivation of the machine and the instructions that define it. Discussion of the fairly limited extensions required to extend the machine for more general use outside of implementations of logic programming. Substantial speedups will occur due to improvements in the implementation of the basic algorithms.

A signal flow model is described that uses memory devices from combinational logic. The implementation of this model in Prolog is also presented.

This report provides a summary of theoretical and experimental studies of actinide spectra in condensed phases. Much of the work was accomplished at Argonne National Laboratory, but references to related investigations by others are included. Spectroscopic studies of the trivlent actinides are emphasized, as is the use of energy level parameters, evaluated from experimental data, to investigate systematic trends in electronic structure and other properties. Some reference is made to correlations with atomic spectra, as well as with spectra of the (II), (IV), and higher valence states.

This report contains historical information on the Li-alloy/FeS system that will be useful in its future applications. This document includes the following: (1) the chemical and electrochemical reactions for the Li-alloy/FeS system, accomplishments in past cell development efforts, and performance attained by state-of-the-art cells vs performance goals; (2) detailed drawings of state-of-the-art cell designs, documentation of cell fabrication techniques, and comparisons of alternative types of cell components (such as BN felt vs MgO powder separators, stainless vs low-carbon steel cell housings) and fabrication techniques (such as charged vs uncharged electrodes); (3) results of post-test cell analyses, including cell failure mechanisms, electrode morphology and active material distribution, and in-cell corrosion rates; (4) data from trade-off studies between specific power and energy; (5) discussion of battery design considerations (e.g., volumetric energy density, battery charger, and high-efficiency thermal insulation); (6) results of cost studies, which include materials and manufacturing costs of cells and batteries and heating costs involved in battery operation; and (7) projections of cell designs having the greatest potential for meeting electric-vehicle performance requirements.

These annual meetings bring together contractors of the Division of Chemical Sciences in its basic research program on solar photochemical energy conversion to exchange information and to give interested government officials an opportunity to assess the current status of the program. This year's meeting was joined by 12 Canadian scientists with similar interests in solar photochemistry. This volume contains the program of the meeting, a list of attendees, the abstracts of 29 formal presentations and 36 posters, and a record of questions and answers following each presentation.

This document is a formal report on the scientific workstation evaluation project. The objective of this project has been to evaluate a scientific workstation. When new computing systems appeared that exhibited the capabilities necessary to do scientific computing work at relatively low equipment cost, both the staff of the Argonne scientific divisions and we (the Computing Services staff) wished to know more about the equipment and the vendor claims.

Current status of epidemiological studies of the late effects of internal radium in humans, and mechanistic investigations of those effects.

A mathematical model is presented for flow-induced vibration of the Space Shuttle Main Engine (SSME) liquid oxygen (LOX) posts. The definition of the critical flow velocity is addressed, and detuning of the vibrations of the LOX posts is discussed. Nonuniform flow distributions in the axial and transverse directions are examined briefly, followed by upstream turbulence. The dependence of response upon post location is addressed briefly. Scruton's number, a mass-damping parameter, is defined and its value for the SSME LOX posts is given. Also discussed are the interaction of turbulent buffeting and fluidelastic instability, post arrangement, and swirlers around the posts. The differences are discussed between the quasi-static, the analytical, and the general analytical mathematical models.

Report on studies of advanced batteries, aqueous batteries, advanced fuel cells, coal utilization, methodologies for recovery of energy from municipal waste, solid and liquid desiccants, nuclear technology related to waste management, and physical chemistry of selected materials in environments simulating those of fission, fusion, and other energy systems.

A set of programs, gathered from major Argonne computer users, was run on the current generation of supercomputers: the CRAY X-MP-4, Fujitsu VP-200, and Hitachi S-810/20. The results show that a single processor of a CRAY X-MP-4 is a consistently strong performer over a wide range of problems. The Fujitsu and Hitachi excel on highly vectorized programs and offer an attractive opportunity to sites with IBM-compatible computers.

Report of the activities of the physics division at Argonne including the successful completion of Argonne Tandem-Linac Accelerator System.

This report reviews the research activities in the Mathematics and Computer Science Division at Argonne National Laboratory for the period April 1, 1984, through March 31, 1985. The body of the report discusses various projects carried out in four major areas of research: applied analysis, computational mathematics, software engineering, and advanced computing. Information on section staff, visitors, workshops, and seminars is found in the appendices.

Annual report of the environmental monitoring program at Argonne National Laboratory, discussing activities and findings of the group.

Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). This report describes activitiesdirected toward seeking alternative cathode materials to NiO for molten carbonate fuel cells.

Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). These efforts have been directed toward seeking alternative cathode materials to NiO for molten carbonate fuel cells. Particular emphasis has been placed on studying the relationship between synthesis conditions and the resistivity of doped and undoped LiFeO2 and Li2 MnO3 and on achieving a better understanding of the crystalline defect structures of the thermodynamically stable phases.

Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). This report describes studies directed toward seeking alternative cathode materials to NiO for molten carbonate fuel cells.

Quarterly report on activities of Argonne National Laboratory's Nuclear Technical Programs, including management of nuclear waste.

Quarterly report on activities of Argonne National Laboratory's Nuclear Technical Programs, including results of studies to measure the degradation of backfill materials after their exposure to temperature and humidity expected in high-level nuclear waste repositories.

Quarterly report on activities of Argonne National Laboratory's Nuclear Technical Programs, including a review of studies of the ability of backfill to inhibit groundwater flow in a nuclear waste repository.

The Radioactive Liquid Waste Treatment Facility (RLWTF) at Argonne National Laboratory-West (ANL-W) in Idaho provides improved treatment for low-level aqueous waste compared to conventional systems. A unique, patented evaporated system is used in the RLWTF. SHADE (shielded hot air drum evaporator, US Patent No. 4,305,780) is a low-cost disposable unit constructed from standard components and is self-shielded. The results of testing and recent operations indicate that evaporation rates of 2 to 6 gph (8 to 23 L/h) can be achieved with a single unit housed in a standard 30-gal (114-L) drum container. The operating experience has confirmed the design evaporation rate of 60,000 gal (227,000 L) per year, using six SHADE's.