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Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, October 1, 1979-December 31, 1979. [Pt/Rh, Ni/Rh, Ni/Pt/Rh, Ni, Ni/Ru, Ni/Pt, Ni/Co]
Twelve steam reforming catalysts were evaluated using an autothermal reforming screening unit. Duplicate tests were run with two samples to determine test variability. The samples tested contained either base metals, precious metals, or combinations of base and precious metals. The test was capable of distinguishing among samples where gross variations in composition are the main factor; for example, catalysts containing 2% by weight precious metals are more active than catalysts containing 15% by weight nickel. The results show a decrease in hydrocarbon breakthrough as the weight of nickel charged to the constant volume reactor increases. A commercial nickel catalyst, G90C, appears slightly better than some Engelhard prepared samples of equal nickel concentrations due to the higher density of G90C. Visual observation of the used catalysts show that samples containing only precious metals (Pt/Rh) did not coke during the run. The samples containing only base metals (nickel, cobalt) were coked and were magnetic. Samples containing 14.5% nickel by weight with 0.5% precious metals by weight added were not coked, were not magnetic, and had a blue colored core as compared to the black core of the virgin samples. Some speculation about deactivation mechanisms based on these observations are made.
Date:
January 1, 1980
Creator:
Yarrington, R M; Feins, I R; Hwang, H S & Mayer, C P
System:
The UNT Digital Library
Coordination/management tasks for the IEA and CCMS solar heating and cooling programs
None
Date:
January 1, 1980
Creator:
unknown
System:
The UNT Digital Library
Structural analysis of the West Hackbery No. 6 SPR storage cavern
Four separate structural analyses of the West Hackberry No. 6 SPR storage cavern are presented. One analysis covers the creep response of the cavern beginning shortly before the time when an accidental fire occurred and proceeding through the cavern recertification pressure test. The second analysis models the surface uplife that is expected during the same pressure test. The third and fourth numerical studies investigate the structural response of West Hackberry No. 6 to slabbing and a rapid pressure drop. All analyses indicate that this cavern should be structurally stable for the conditions assumed.
Date:
August 1, 1980
Creator:
Benzley, S.E.
System:
The UNT Digital Library
Numerical study of the NOL large-scale gap test
The NOL large-scale gap test has been modeled numerically using the LASL reactive hydrodynamics code 2DE with Forest Fire burn rates. The model gives good agreement between calculated and experimental critical gap values for VTQ-2 and Composition B. The calibration of peak pressure in the gap versus gap length has been obtained from these calculations, and is in good agreement with the published experimental curve. The two-dimensional nature of the gap test is evident from the curvature of the shock wave in the gap and test sample, and from the observed distance of run to detonation in the test samples.
Date:
January 1, 1980
Creator:
Bowman, A.L.
System:
The UNT Digital Library
Compilation of cores and cuttings from U. S. Government-sponsored geothermal wells
This compendium lists the repositories holding geothermal core and well cuttings from US government-sponsored geothermal wells. Also, a partial listing of cores and cutting from these wells is tabulated, along with referenced reports and location maps. These samples are available to the public for research investigations and studies, usually following submission of an appropriate request for use of the samples. The purpose of this compilation is to serve as a possible source of cores and cuttings that might aid in enhancing rock property studies in support of geothermal log interpretation.
Date:
July 1, 1980
Creator:
Mathews, M.; Gambill, D.T. & Rowley, J.C.
System:
The UNT Digital Library
Interactions of tailings leachate with local liner materials found at Canonsburg, Pennsylvania.
The mill tailings site at Canonsburg, Pennsylvania is the first mill site to receive remedial action under the Department of Energy's Uranium Mill Tailings Remedial Action Program. Part of this remedial action will require excavating the 53,500 m/sup 3/ (70,000 yd/sup 3/) of tailings on the site having a specific activity exceeding 100 pCi/g, and encapsulating these contaminated tailings in a clay-lined cell. As part of the remedial action effort, Pacific Northwest Laboratory has been studying the interactions of tailings and tailings leachate with locally occurring clays proposed for liner materials. These studies include physical and chemical characterization of amended and unamended local clays, chemical characterization of the tailings, column studies of tailings leached with deionized water, and column studies of clays contacted with tailings solutions to determine the attenuation properties of the proposed liner materials. Column studies of tailings leached with deionized water indicated that the Canonsburg tailings could represent a source of soluble radium-226 and uranium-238, several trace metals, cations, and the anions SO/sub 4/, NO/sub 3/, and Cl. Of these soluble contaminants, uranium-238, radium-226, the trace metals As and Mo, and the anions F and SO/sub 4/ were present at levels exceeding maximum concentration levels in the …
Date:
April 1, 1984
Creator:
Dodson, M.E.; Gee, G.W. & Serne, R.J.
System:
The UNT Digital Library
Search for the neutrinoless muon decay. mu. /sup +/. -->. e/sup +/. gamma
Separate muon, electron, and tau numbers are conserved in the minimal standard model of electroweak interactions with massless neutrinos. However, in many extensions to the standard model, separate lepton numbers are not expected to be conserved quantities. A new search for muon number non-conserving processes has been undertaken at the Los Alamos Meson Physics Facility (LAMPF), specifically to look for three neutrinoless decay modes of the muon. The search for the decay of a muon to an electron and a photon is discussed here. A new detector facility, located in the LAMPF stopped muon channel, was developed for this experiment. This Crystal Box detector consists of a cylindrical drift chamber surrounded by a plastic scintillator hodoscope and a large solid angle, modularized, NaI(Tl) calorimeter. The apparatus measures the trajectories, relative timing, and energies of charged particles and photons from the decays of positive muons stopped in a central target. The assembly and calibration of the detector are described, and the procedure for taking data is discussed. The sample of 1.3 million candidate events, from the first data run of the Crystal Box, was analyzed using a maximum-likelihood method. The upper limit on the branching ratio, relative to normal muon decay, …
Date:
July 1, 1985
Creator:
Wilson, S.L.
System:
The UNT Digital Library
Energy-Exchange Project
The purpose of the study was to determine what energy savings can be achieved by coordinating the resources and requirements of two facilities, the 26th Ward Water Pollution Control Plant (WPCP) and a housing development named Starrett City with its own total energy system. It was determined that three energy exchange options were economically and technically feasible. These include: the transfer of digester gas produced at the 26th Ward to the boilers at the Starrett City's total energy plant (TEP); the transfer of hot water heated at the TEP to the 26th Ward for space and process heating; and the transfer of coal effluent waste water from the 26th Ward to the condenser cooling systems at the TEP. Technical information is presented to support the findings. The report addresses those tasks of the statement of work dedicated to data acquisition, analysis, and energy conservation strategies internal to the Starrett City TEP and the community it supplies as well as to the 26th Ward WPCP. (MCW)
Date:
April 1, 1982
Creator:
unknown
System:
The UNT Digital Library
Peregrine Falcon study. Final report
Three papers are included. A separate abstract was prepared for each. (MHR)
Date:
February 1, 1980
Creator:
unknown
System:
The UNT Digital Library
State of the art of pressurized fluidized bed combustion systems
This report was prepared at the request of the Tennessee Valley Authority (TVA) to clarify the development status of the pressurized fluidized bed combustor (PFBC) and to place in perspective the problems which are yet to be solved before commercialization of the concept is practical. This report, in essence, supersedes the interim report published in 1979, Assessment of the State of the Art of Pressurized Fluidized Bed Combustion Systems. A brief overview of the PFBC concept is included citing potential advantages and disadvantages relative to atmospheric fluidized bed combustion (AFBC) and conventional pulverized coal plants. A survey of existing and developing PFBC experimental facilities is presented in some detail which includes the major accomplishments at the respective facilities. Recent data on plant emissions, turbine/gas cleanup systems, and overall efficiency are provided. Findings of several design studies are also discussed. The results of recent gas turbine and cascade tests have been encouraging although the full assessment of the accomplishments have not been made. The delay in construction of the Grimethorpe plant causes further delay in proof-testing full-size, rotating turbomachinery. Several parameters are recommended for further assessment in design studies including: (1) effect of turbine life on cost of power; and (2) …
Date:
September 1, 1980
Creator:
Graves, R.L.
System:
The UNT Digital Library
NRC plan for cleanup operations at Three Mile Island Unit 2
This NRC Plan, which defines NRC's functional role in cleanup operations at Three Mile Island Unit 2 and outlines NRC's regulatory responsibilities in fulfilling this role, is the first revision to the initial plan issued in July 1980 (NUREG-0698). Since 1980, a number of policy developments have occurred which will have an impact on the course of cleanup operations. This revision reflects these developments in the area of NRC's review and approval process with regard to cleanup operations as well as NRC's interface with the Department of Energy's involvement in the cleanup and waste disposal. This revision is also intended to update the cleanup schedule by presenting the cleanup progress that has taken place and NRC's role in ongoing and future cleanup activities.
Date:
February 1, 1982
Creator:
Lo, R. & Snyder, B.
System:
The UNT Digital Library
Aerial radiometric and magnetic survey, San Angelo National Topographic Map: Texas, West Texas Project. Final report
The results of analyses of the airborne gamma radiation and total magnetic field survey flown for the region identified as the San Angelo National Topographic Map NH14-1 are presented. The airborne data gathered are reduced by ground computer facilities to yield profile plots of the basic uranium, thorium, and potassium equivalent gamma radiation intensities, ratios of these intensities, aircraft altitude above the earth's surface, total gamma ray and earth's magnetic field intensity, correlated as a function of geologic units. The distribution of data within each geologic unit, for all surveyed map lines and tie lines, has been calculated and is included. Two sets of profiled data for each line are included, with one set displaying the above-cited data. The second set includes only flight line magnetic field, temperature, pressure, altitude data plus magnetic field data as measured at a base station. A general description of the area, including descriptions of the various geologic units and the corresponding airborne data, is included.
Date:
May 1, 1980
Creator:
unknown
System:
The UNT Digital Library
Hanford Environmental Dose Reconstruction Project Monthly Report
This monthly report summarizes the technical progress and project status for the Hanford Environmental Dose Reconstruction Project being conducted at Pacific Northwest Laboratory under the direction of a Technical Steering Panel.
Date:
November 1, 1989
Creator:
Dennis, B.S. (comp.)
System:
The UNT Digital Library
Institutional research and development, FY 1987
The Institutional Research and Development program at Lawrence Livermore National Laboratory fosters exploratory work to advance science and technology, disciplinary research to develop innovative solutions to problems in various scientific fields, and long-term interdisciplinary research in support of defense and energy missions. This annual report describes research funded under this program for FY87. (DWL)
Date:
January 1, 1987
Creator:
Struble, G. L.; Lawler, G. M.; Crawford, R. B.; Kirvel, R. D.; Peck, T. M.; Prono, J. K. et al.
System:
The UNT Digital Library
Aerial gamma ray and magnetic survey: Mississippi and Florida airborne survey, Nashville quadrangle, Tennessee, and Kentucky. Final report
The Nashville quadrangle covers a portion of the interior lowland plateau region of the Midwestern Physiographic Province. The quadrangle contains a shallow to moderately thick Paleozoic section that overlies a Precambrian basement complex. Paleozoic carbonates dominate surficial exposures. A search of available literature revealed no known uranium deposits. Fifty-five uranium anomalies were detected and are discussed briefly. Most anomalies appear to relate to cultural features. Some have relatively high uranium concentration levels that may be significant despite their correlation with culture. Magnetic data appear to illustrate complexities in the Precambrian basement.
Date:
September 1, 1980
Creator:
unknown
System:
The UNT Digital Library
Retrospective examination of geothermal environmental assessments
Since 1976, the Department of Energy (DOE) has supported a variety of programs and projects dealing with the exploration, development, and utilization of geothermal energy. This report presents an overview of the environmental impacts associated with these efforts. Impacts that were predicted in the environmental analyses prepared for the programs and projects are reviewed and summarized, along with measures that were recommended to mitigate these impacts. Also, for those projects that have gone forward, actual impacts and implemented mitigation measures are reported, based on telephone interviews with DOE and project personnel. An accident involving spills of geothermal fluids was the major environmental concern associated with geothermal development. Other important considerations included noise from drilling and production, emissions of H/sub 2/S and cooling tower drift, disposal of solid waste (e.g., from H/sub 2/S control), and the cumulative effects of geothermal development on land use and ecosystems. Mitigation measures were frequently recommended and implemented in conjunction with noise reduction; drift elimination; reduction of fugitive dust, erosion, and sedimentation; blowout prevention; and retention of wastes and spills. Monitoring to resolve uncertainties was often implemented to detect induced seismicity and subsidence, noise, drift deposition, concentrations of air and water pollutants, and effects on groundwater. …
Date:
March 1, 1984
Creator:
Webb, J. W.; Eddlemon, G. K. & Reed, A. W.
System:
The UNT Digital Library
Electronic band structure and optical properties of the cubic, Sc, Y and La hydride systems
Electronic band structure calculations are used to interpret the optical spectra of the cubic Sc, Y and La hydride systems. Self-consistent band calculations of ScH/sub 2/ and YH/sub 2/ were carried out. The respective joint densities of states are computed and compared to the dielectric functions determined from the optical measurements. Additional calculations were performed in which the Fermi level or band gap energies are rigidly shifted by a small energy increment. These calculations are then used to simulate the derivative structure in thermomodulation spectra and relate the origin of experimental interband features to the calculated energy bands. While good systematic agreement is obtained for several spectral features, the origin of low-energy interband transitions in YH/sub 2/ cannot be explained by these calculated bands. A lattice-size-dependent premature occupation of octahedral sites by hydrogen atoms in the fcc metal lattice is suggested to account for this discrepancy. Various non-self-consistent calculations are used to examine the effect of such a premature occupation. Measurements of the optical absorptivity of LaH/sub x/ with 1.6 < x < 2.9 are presented which, as expected, indicate a more premature occupation of the octahedral sites in the larger LaH/sub 2/ lattice. These experimental results also suggest that, …
Date:
January 1, 1980
Creator:
Peterman, D. J.
System:
The UNT Digital Library
Vacuum ultraviolet electronic properties of liquids. Annual progress report, 1 November 1979-31 October 1980
Areas covered are: optical and dielectric properties of hexamethyl-phosphoric triamide; photoemission from uv irradiated liquids; photon and photoelectron mean free paths in liquids; properties of Kapton films; and uv transmission of polycyclic organic molecules. (GHT)
Date:
January 1, 1980
Creator:
Painter, L.R.
System:
The UNT Digital Library
Development of 400- to 450-MHz RFQ resonator-cavity mechanical designs
In the development of the radio-frequency quadrupole (RFQ) linac, the resonator cavity's mechanical design may be a challenge similar in magnitude to that of the development of the accelerator structure itself. Experience with the all-copper 425-MHz RFQ proof-of-principle linac has demonstrated that the resonator cavity must be structurally stiff and easily tunable. This experience has led to development of copper-plated steel structures having vanes that may be moved within a cylinder for tuning. Design of a flexible vane-to-cylinder radio-frequency (rf) joint, the vane, and the cylinder has many constraints dictated by the small-diameter cavities in the 400-MHz-frequency region. Two types of flexible, mechanical vane-to-cylinder rf joints are being developed at Los Alamos: the C-seal and the rf clamp-joint.
Date:
January 1, 1982
Creator:
Hansborough, L.D.
System:
The UNT Digital Library
Murakami density limit in tokamaks and reversed-field pinches
A theoretical upper limit for the density in an ohmically heated tokamak discharge follows from the requirement that the ohmic heating power deposited in the central current-carrying channel exceed the impurity radiative cooling in this critical region. A compact summary of our results gives this limit n/sub M/ for the central density as n/sub M/ = (Z/sub e//(Z/sub e/-1)/sup 1/2/n/sub eo/ (B/sub T//1T)(1m/R) where n/sub eo/ depends strongly on the impurity species and is remarkably independent of the central electron temperature T/sub e/(0). For T/sub e/(0) approx. 1 keV, we have n/sub eo/ = 1.5 x 10/sup 14/ cm/sup -3/ for beryllium, n/sub eo/ = 5 x 10/sup 13/ cm/sup -3/ for oxygen, n/sub eo/ = 1.0 x 10/sup 13/ cm/sup -3/ for iron, and n/sub eo/ = 0.5 x 10/sup 13/ cm/sup -3/ for tungsten. The results agree quantitatively with Murakami's original observations. A similar density limit, known as the I/N limit, exists for reversed-field pinch devices and this limit has also been evaluated for a variety of impurity species.
Date:
March 1, 1984
Creator:
Perkins, F.W. & Hulse, R.A.
System:
The UNT Digital Library
Nuclear power in the Soviet Bloc
The growth of Soviet Bloc nuclear power generation to the end of the century is evaluated on the basis of policy statements of objectives, past and current nuclear power plant construction, and trends in the potential for future construction. Central to this study is a detailed examination of individual reactor construction and site development that provides specific performance data not given elsewhere. A major commitment to nuclear power is abundantly clear and an expansion of ten times in nuclear electric generation is estimated between 1980 and 2000. This rate of growth is likely to have significant impact upon the total energy economy of the Soviet Bloc including lessening demands for use of coal, oil, and gas for electricity generation.
Date:
March 1, 1982
Creator:
Davey, W.G.
System:
The UNT Digital Library
SPXCPL: two-dimensional modeling program of self-potential effects from cross-coupled fluid and heat flow (User's Guide and documentation for Version 1. 0)
The program is applicable to the calculation of self-potential effects due to fluid flow (electrokinetic effects) and heat flow (thermoelectric effects). The geological structure is two dimensional but the sources can be either finite line sources or point sources. The accuracy of the calculated potentials depends on the model discretization and the distance from the source(s). For the default mesh, the accuracy is usually a few percent at a distance of about one unit from the source. Surface boundary conditions for the primary problem require careful consideration as the form of the flow near the air-earth interface can have a profound effect on the resultant electric potentials. For temperature problems the appropriate boundary condition is a constant temperature, which is taken as zero. With this boundary condition there is a normal flux of heat at the surface and there will be induced electrical sources here, if the surface medium has a nonzero coupling coefficient. In the models, zero temperature at the surface is produced by giving the air a very large thermal conductivity.
Date:
March 1, 1982
Creator:
Sill, W. R. & Killpack, T. J.
System:
The UNT Digital Library
Gas-cooled fast breeder reactor. Quarterly progress report, February 1-April 30, 1980
Information is presented concerning the reactor vessel; reactivity control mechanisms and instrumentation; reactor internals; primary coolant circuits;core auxiliary cooling system; reactor core; systems engineering; and reactor safety and reliability;
Date:
May 1980
Creator:
unknown
System:
The UNT Digital Library
Inductively coupled plasma-atomic emission spectroscopy: a computer controlled, scanning monochromator system for the rapid determination of the elements
A computer controlled, scanning monochromator system specifically designed for the rapid, sequential determination of the elements is described. The monochromator is combined with an inductively coupled plasma excitation source so that elements at major, minor, trace, and ultratrace levels may be determined, in sequence, without changing experimental parameters other than the spectral line observed. A number of distinctive features not found in previously described versions are incorporated into the system here described. Performance characteristics of the entire system and several analytical applications are discussed.
Date:
March 1, 1980
Creator:
Floyd, M. A.
System:
The UNT Digital Library