The 1,1-reductive elimination of ethane from three cis-bis(phosphine)-dimethylpalladium complexes, L/sub 2/Pd(CH/sub 3/)/sub 2/ (L = PPh/sub 3/, PPh/sub 2/,CH/sub 3/ and L/sub 2/ = Ph/sub 2/PCH/sub 2/CH/sub 2/PPh/sub 2/), and three trans analogs (L = PPh/sub 3/, PPh/sub 2/CH/sub 3/ and L/sub 2/ = 2,11-bis(diphenylphosphinomethyl)benzo(c)phenanthrene (TRANSPHOS)) was carried out. The three cis complexes underwent reductive elimination in the presence of coordinating solvents (DMSO, DMF, and THF). The trans complexes which could isomerize to cis (L = PPh/sub 3/, PPh/sub 2/CH/sub 3/) did so in polar solvents and then underwent reductive elimination. TRANSPHOS dimethylpalladium would not undergo reductive elimination of ethane. The eliminations from the cis isomers were intramolecular and displayed first order kinetics. Although TRANSPHOS dimethylpalladium(II) would not undergo a 1,1-reductive elimination of ethane, the addition of CD/sub 3/I to a DMSO solution of this complex at 25/sup 0/C rapidly produced CD/sub 3/-CH/sub 3/, implicating a transient palladium(IV) intermediate. E- and Z-bromostyrylbis(diphenylmethylphosphine)palladium(0) react with methyl lithium in THF at ambient temperature to give the E- and Z- propenylbenzenes, respectively. At -78/sup 0/C, the intermediate E- and Z-styrylmethylbis(diphenylmethylphosphine)palladium(II) complexes (9a,b) can be isolated. On raising the temperature of solutions of 9a,b in THF, E- and Z-propenylbenzenes are produced. The reductive elimination …

GEOTHERM sample file contains 225 records for Colorado. Three computer-generated indexes are found in appendices A, B, and C of this report. The indexes give one line summaries of each GEOTHERM record describing the chemistry of geothermal springs and wells in the sample file for Colorado. Each index is sorted by different variables to assist the user in locating geothermal records describing specific sites. Appendix A is sorted by the county name and the name of the source. Also given are latitude, longitude (both use decimal minutes), township, range, section, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix B is sorted by county, township, range, and section. Also given are name of source, GEOTHERM record identifier, and temperature (/sup 0/C). Appendix C is first sorted into one-degree blocks by latitude, and longitude, and then by name of source. Adjacent one-degree blocks which are published as a 1:250,000 map are combined under the appropriate map name. Also given are GEOTHERM record identifier, and temperature (/sup 0/C). A bibliography is given in Appendix D.

Efforts have been primarily directed toward evaluation of the room temperature molten salt electrolyte in terms of its overall performance for photovoltaic cells. Mass transport processes may prove to be the rate-limiting factor for such electrolytes, unless the concentration of the photo-active redox component can be increased and the solvent viscosity reduced. Acid-base surface chemistry of n-GaAs as occurs in aqueous systems, has been found present and its consequences will be further explored. The selection and optimization of PEC electrolytes is a complex task and we believe that a systems approach would facilitate in identifying the basic electrolyte properties needed. A preliminary analysis reveals that although some of the criteria for an electrolyte are definable precisely, others do require empirical experimentation. It can be concluded that relatively few electrolytes in current use are adequate and it would appear that greater efforts to develop electrolytes would be advantageous. The various types of electrolytes that could be used for PEC's have been identified. Good quality MoSe/sub 2/ single crystals can be grown and short circuit currents greater than previously reported have been achieved in an I/sub 2//I/sup -//Pt cell. A novel technique to produce photo-active films by anodization is being investigated, initially …

This report presents the results of wind-tunnel tests supported through the Solar Energy Research Institute (SERI) by the Office of Solar Thermal Technology of the US Department of Energy as part of the SERI research effort on innovative concentrators. As gravity loads on drive mechanisms are reduced through stretched-membrane technology, the wind-load contribution of the required drive capacity increases in percentage. Reduction of wind loads can provide economy in support structure and heliostat drive. Wind-tunnel tests have been directed at finding methods to reduce wind loads on heliostats. The tests investigated primarily the mean forces, moments, and the possibility of measuring fluctuating forces in anticipation of reducing those forces. A significant increase in ability to predict heliostat wind loads and their reduction within a heliostat field was achieved.

Mesaverde Group sandstone units in 13 closely-spaced wells in the central and southern Piceance Basin of Colorado were correlated utilizing wireline log response quantitatively and qualitatively. Based on these correlations, the environmental subdivisions of the Mesaverde Group were characterized as follows: (1) paralic (upper mixed-marine) zone, occurring in the uppermost Mesaverde Group, includes thick sandstone units which are interpreted to be regionally continuous, (2) fluvial zone, containing point-bars 20 to 30+ ft thick, is interpreted to be correlatable to a maximum of 6800 ft, and (3) paludal zone has insufficient data to adequately characterize the sand units. However, 63 percent of the units are correlatable across at least 139 ft. An approximation of the dimensional characteristics of Mesaverde sandstone units has potential applications in designing hydraulic fracturing treatments and estimating gas reserves more accurately. 15 figures, 2 tables.

This report presents the results of wind-tunnel tests supported through the Solar Energy Research Institute (SERI) by the Office of Solar Thermal Technology of the US Department of Energy as part of the SERI research effort on innovative concentrators. As gravity loads on drive mechanisms are reduced through stretched-membrane technology, the wind-load contribution of the required drive capacity increases in percentage. Reduction of wind loads can provide economy in support structure and heliostat drive. Wind-tunnel tests have been directed at finding methods to reduce wind loads on heliostats. The tests investigated both mean and peak forces, and moments. A significant increase in ability to predict heliostat wind loads and their reduction within a heliostat field was achieved. In addition, a preliminary review of wind loads on parabolic dish collectors was conducted, resulting in a recommended research program for these type collectors. 42 refs., 38 figs., 1 tab.

We have obtained a neutron diffraction data set for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). While the structure is still being solved, it is already clear that the hybridization at both of the ethylene carbons is sp{sup 3}. Our first interpretation of our liquid crystal NMR results had suggested a very acute H-C-H angle. We have also obtained {sup 13}C liquid crystal data for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). Liquid crystal NMR ({sup 13}C as well as {sup 1}H) spectra have been obtained for Os(CO){sub 4}(C{sub 2}H{sub 4}) and its solution structure determined, in order to test our methodology on a molecule with a rigid structure. The normal modes of Os(CO){sub 4}({mu}-C{sub 2}H{sub 4}) and its deuterated and {sup 13}C-labelled isotopomers have been completely assigned. A partial vibrational analysis of Os{sub 2}(CO){sub 8}({mu}-propene), Os{sub 2}(CO){sub 8}(trans-2-butene), and Os{sub 2}(CO){sub 8}(1-butene) has been completed. We have prepared Os(CO){sub 4}({mu}-CH{sub 2}CH{sub 2}CH{sub 2}) and its 3,3-dideuterio analog. In the course of this work the reaction of Na{sub 2}Os(CO){sub 4} with a number of 1,3-propanediol derivatives has been examined. 1,3-Propanediol ditosylate afforded much better yields of the osmacycle than did either the ditriflate or diiodide. 2,2-Dideutero-1,3-propanediol ditosylate was used to prepare the deuterium-labelled osmacyclobutane.

Analysis of 21 post-burn cores taken from the Hanna IV UCG site allows 96 m (315 ft) of overburden to be subdivided into four local stratigraphic units. The 7.6 m (25 ft) thick Hanna No. 1 coal seam is overlain by a laterally discontinuous, 3.3 m (11 ft) thick shaley mudstone (Unit A') in part of the Hanna IV site. A more widespread, 30 m (90 ft) thick well-indurated sandstone (Unit A) overlies the A' unit. Unit A is the roof rock for both of the Hanna IV cavities. Overlying Unit A is a 33 m (108 ft) thick sequence of mudstone and claystone (Unit B), and the uppermost unit at the Hanna IV site (Unit C) is a coarse-grained sandstone that ranges in thickness from 40 to 67 m (131 to 220 ft). Two elliptical cavities were formed during the two phases of the Hanna IV experiment. The larger cavity, Hanna IVa, is 45 x 15 m in plan and has a maximum height of 18 m (59 ft) from the base of the coal seam to the top of the cavity; the Hanna IVb cavity is 40 x 15 m in plan and has a maximum height of …

This report provides information on milk distribution and dairy cattle feeding practices in Nevada, Utah and portions of seven other adjacent states during the 1950s. The information was gathered to support the US Department of Energy's ''Offsite Radiation Exposure Review Project (ORERP).'' This project is charged with providing radiation dose estimates for residents of Nevada, Utah, and surrounding states from nuclear weapons testing conducted at the Nevada Test Site from 1951 through 1962. The information on milk production and distribution is essential for assessment of the internal organ doses received by people as a result of ingesting radioactive fallout-contaminated foods. The information is used as input data for Colorado State University's PATHWAY computer code which estimates the ingestion of twenty radionuclides by people relative to a given level of fallout deposition.

In 1977 a program was initiated to delineate the geological features controlling the occurrence of geothermal resources in Colorado. This program consisted of literature search, reconnaissance geologic and hydrogeologic mapping and geophysical and geochemical surveys. During 1980 and 1981 geothermal resource assessment efforts were conducted in the Cement Creek Valley south of Crested Butte. In this valley are two warm springs, Cement Creek and Ranger, about 4 mi (6.4 km) apart. The temperature of both springs is 77 to 79/sup 0/F (25 to 26/sup 0/C) and the discharge ranges from 60 to 195 gallons per minute. Due to access problems no work was conducted in the Cement Creek Warm Springs area. At Ranger Warm Springs electrical resistivity and soil mercury surveys were conducted. The warm springs are located in the Elk Mountains of west central Colorado. The bedrock of the area consists of sedimentary rocks ranging in age from Precambrian to Recent. Several faults with displacements of up to 3000 ft (194 m) are found in the area. One of these faults passes close to the Ranger Warm Springs. The electrical resistivity survey indicated that the waters of Ranger Warm Springs are moving up along a buried fault which parallels …

A 7118 ft (2170 m) deep geothermal test well was drilled on the south edge of the city of Alamosa, Colorado as part of the Department of Energy's User Coupled Confirmation Drilling Program. The project was selected on the bases of a potential direct heat geothermal resource within the Rio Grande rift graben and resource users in Alamosa. The well site was selected on the hypothesis of a buried horst along which deep thermal fluids might be rising. In addition, there were city wells that were anomalous in temperature and the location was convenient to potential application. The Alamosa No. 1 penetrated 2000 ft (610 m) of fine clastic rocks over 4000 ft (1219 m) of volcaniclastic rock resting on precambrian crystalline rock at a depth of 6370 ft (1942 m). Due to poor hole conditions, geophysical logs were not run. The stabilized bottom hole temperature was 223/sup 0/F (106/sup 0/C) with a gradient of 2.6/sup 0/F/100 ft (47/sup 0/C/km). Limited testing indicated a very low production capacity. 16 refs., 6 figs.

"This report consists of engineering details, statistics, individual borehole histories, and logistics for the 27 boreholes drilled in the project. Geophysical logs are included." (from Introduction)

"This report consists of engineering details, statistics, and logistics of the 19 boreholes drilled in the project. Geophysical logs are included on microfiche in the back of this report." (from Introduction)

We have obtained a neutron diffraction data set for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). While the structure is still being solved, it is already clear that the hybridization at both of the ethylene carbons is sp{sup 3}. Our first interpretation of our liquid crystal NMR results had suggested a very acute H-C-H angle. We have also obtained {sup 13}C liquid crystal data for Os{sub 2}(CO){sub 8}({mu}-C{sub 2}H{sub 4}). Liquid crystal NMR ({sup 13}C as well as {sup 1}H) spectra have been obtained for Os(CO){sub 4}(C{sub 2}H{sub 4}) and its solution structure determined, in order to test our methodology on a molecule with a rigid structure. The normal modes of Os(CO){sub 4}({mu}-C{sub 2}H{sub 4}) and its deuterated and {sup 13}C-labelled isotopomers have been completely assigned. A partial vibrational analysis of Os{sub 2}(CO){sub 8}({mu}-propene), Os{sub 2}(CO){sub 8}(trans-2-butene), and Os{sub 2}(CO){sub 8}(1-butene) has been completed. We have prepared Os(CO){sub 4}({mu}-CH{sub 2}CH{sub 2}CH{sub 2}) and its 3,3-dideuterio analog. In the course of this work the reaction of Na{sub 2}Os(CO){sub 4} with a number of 1,3-propanediol derivatives has been examined. 1,3-Propanediol ditosylate afforded much better yields of the osmacycle than did either the ditriflate or diiodide. 2,2-Dideutero-1,3-propanediol ditosylate was used to prepare the deuterium-labelled osmacyclobutane.

This report is an issue of the original draft copy of the "Interim Staff Report on Uranium Exploration on the Colorado Plateau", dated June 1951. The original draft copy was only recently located and is being published at this time because of the interest in the contained historical content.

From purpose of study: The Vallecito Conglomerate of the Needle Mountains area in southwestern Colorado was studied to evaluate the uranium potential of the unit and to test the applicability of the uraniferous Precambrian pebble-conglomerate exploration model in this area. The main thrust of this project is the Vallecito Conglomerate, but the Uncompahgre Formation, which is also in the Needle Mountains area has basal conglomerate that was investigated in a reconnaissance mode. Five specific objectives have been formulated to meet the overall purpose of this project, and these include: a) Determine the uranium distribution in the Vallecito Conglomerate and the basal conglomerate of the Uncompahgre Formation. b) Evaluate the uranium resources of the area to the degree possible utilizing available information and personal field investigations. c) Test the validity of application of the Precambrian quartz-pebble conglomerate model to this area. d) Recommend detailed studies and delineate drilling sites in the area to further evaluate the uranium resources if warranted. e) Recommend additional geologic, geophysical and geochemical studies which would bear directly on evaluation of uranium resources of the Precambrian pebble conglomerates in the Needle Mountains area.

From introduction: This study is part of the United States Department of Energy's National Uranium Resource Evaluation Program to understand the geologic setting, amount, and availability of uranium resources within the boundaries of the United States.

Abstract: Rainfall simulation studies were conducted in conjunction with the Denver Regional Urban Runoff Program to: (1) Compare runoff quantity and quality from two different intensities of rainfall on impervious plots having identical antecedent conditions, (2) document a first flush of constituent loads in runoff from 1,000-square-foot streetsurface plots, (3) compare runoff characteristics from a street surface subjected to simulated rainfall with those from a 69-acre urban basin of mixed land use subjected to natural rainfall, (4) perform statistical analysis of constituent loads in the runoff with several independent variables, and (5) compare the quantity and quality of runoff from 400-square-foot plots of native grasses used for pasture and subjected to simulated rainfall with that from a 405-acre basin covered with native grasses used for pasture and sub-jected to natural rainfall. The rainfall simulations conducted on the street surface showed that higher intensity simulated rainfall produced a higher percentage of runoff than lower intensity rainfall. A first flush of constituent loads occurred for most constituents in the runoff from most rainfall simulations on the street surface; however, a first flush did not occur in the runoff from simulated rainfall on the pasture. The event mean concentrations of constituents in the …

A report discussing data collected during a detailed geochemiccal survey for uranium in streams draining parts of the Browns Park and North Park formations, in Craig, Colorado

Multivariate statistical analysis to support the National Uranium Resource Evaluation and to evaluate strategic and other commercially important mineral resources

"The purpose of this project was to evaluate and assess the Miocene Browns Park Formation of a part of the Maybell district in the Sand Wash Basin in Moffat County, Colorado, as an intermediate-grade uranium resource"

Final report of the airborne gamma ray and total magnetic field survey for the Sterling quadrangle, Colorado-Nebraska-Kansas. Sections I through IV of this report present information and results associated with this specific survey. Section V gives the data acquisition and the processing procedures.

Final report of the airborne gamma ray and total magnetic field survey for the Grand Junction quadrangle, Colorado-Utah. Sections I through IV of this report present information and results associated with this specific survey. Section V gives the data acquisition and the processing procedures.

Report issued by the Bureau of Mines over studies conducted on oil-shale deposits of the Piceance Basin. The gas content of the deposits is discussed. This report includes maps, and illustrations.