"A series of high urania-content glasses were fiberized and examined for high-temperature strength properties. One glass, RX360 containing 60% U/sub 3/O/ sub 8/ by weight, had better high-temperature tensile properties than any glass previously reported. It was observed that many of the glasses studied separated into immiscible phases and that the fiberizable glass phase had lower U/sub 3/O/ sub 8/ content than the base compositions. A physical analysis of crystal structures of the devitrification products from the nuclear fuel glasses indicated that most of the crystals consisted of uranium oxide in a reduced state. By adding O/sub 2/ to molten glass, it was possible to eliminate most of this devitrification. By elimination of crystals, the fiberizing of the glass was more uniform and the glasses produced had more consistent physical properties."

"Test results indicated that graphite is not suitable for seal face material. A program to evaluate various materials and seal face geometries was initiated. A seal run using nucerite-bearium combination was carried on for six hours."

"lsotope dilution techniques are described for the assay of chlorinated hydrocarbon pesticides and organic phosphorus pesticides in foods. Results are given for the determination of tetranitro-DDT-dianilide, dianilide of tetranitro- DDE, dieldrin, systox, and derivatives of these compounds. "

"The problems discussed are those encountered in assigning unequivocal emf values to electrode systems. Three electrodes which meet the requirements for reference electrodes most adequately are considered in some detail: these are the hydrogen, silver-silver chloride, and mercury-mercurous chloride (calomel) electrodes. An assessment is presented for electrode systems for aqueous solutions, organic solvents, fused slats and biological systems."

"A compilation made as part of a research program dealing with the thermodynamics and electrical conductance of inorganic electrolytes in polar organic solvents is presented. Conductance and association constant data are included dating from 1922 through June 1962, classified both by solute and solvent. Other features include a selection of the physical properties of the most commonly-used organic solvents, a guide to alkylammonium salts studied in four or more solvents, and a survey of conductance extrapolation techniques."

"The electrical conductance of CoCl2 and CoBr2 from 10−4 to 10−1 mol/l over the temperature range 0–35°C is reported. The effects of water as trace impurity, and the halide common ion effect on conductance are examined. The properties of these solutes are also examined using spectrophotometry and transport numbers. Crystalline “solvated” compounds, of empirical formulae [CoX2(CH3CN)3]x can be separated from the saturated solutions. The magnetic susceptibilities of the crystalline substrates are in accord octahedral and tetrahedral symmetry for the cationic and anionic species in these “solvates”, the bonding in both being the spin-free type for divalent cobalt. From the optical properties of the solutions it is apparent that the “anomalous” properties of these electrolytes can be understood in a series of simultaneous processes under Mass-Law control, in which CoX2, CoX42−, Co(CH3CN)62+ and [Co(CH3CN) 62+CoX42−]° are predominant."

"Mixed Fission Products (MFP) for use as a heat source for thermoelectric generators will become increasingly available in the coming years. The Atomic Energy Commission sponsored program on solidification of nuclear wastes is now entering the hot-bench scale test phase. During this phase approximately 5000 thermal watts of two year old MFP could be produced monthly. Two different types of hot calcination pilot plants are planned for installation at the Hanford National Laboratories in the 1964 to 1966 time period. Each of these plants should be able to produce 160,000 thermal watts of two year MFP and 16,000 thermal watts of ten year MFP on a monthly basis. A full scale plant for a 15,000 Mw(e) nuclear economy is estimated to produce four to five times as much MFP as either of the pilot plants. Costs will be dependent upon AEC policy in effect at the time the plant is operating."

"Progress is reported on Phase II of a program for the development of a mixed fission product fueled thermoelectric generator. Materials studies are described in which bonded assemblies of bismuth telluride were life tested up to 3000 hours at 350 to 400 deg F hot junction temperature. Data were too inconsistent to define any satisfactory long-life bonding process. Further work is needed to eliminate the process variables. Insulation studies aimed at determining the thermal conductivity of various insulations with different fill gases under reduced pressures are described. Opacified aerogel powder appears to be very promising as an insulation medium for a diffuse heat source. A full- scale simulated test generator aimed at proving out the concept of a diffuse heat source for power generation is described. Progress on the construction of this electrically heated generator and its thermoelectric power converter is related.

"Uranium and zirconium were bonded by melting the two metals in contact with one another in a bimetallic casting process. Tensile tests of specimens containing the original zone of interface between the two metals showed that all failures were at locations other than the interface. The coefficients obtained for diffusion between molten uranium and molten zirconium varied from 2.13 cm squared per day at 3,380 degrees F. to 9.17 cm squared per day at 3,510 degrees F. the activation energy for the diffusion process was calculated to be 182,000 calories per gram mole."

"Time of flight spectrometers for the study of neutrons emitted in charged particle reactions have become important in recent years, following the development of suitable photomultiplier tubes and electronic circuits for nanosecond (ns) timing measurements. The principle of operation is simple. The particles exciting the nuclear reactions in which the neutrons are produced fall on the target in bunches of the order of a nanosecond in width. the arrival of product neutrons at a organic scintillation counter (proton recoil) detector placed a few meters from the target gives signals which can be used to determine the flight time of the neutrons from target to detector. A time-reference pule corresponding to the arrival of beam pulses at the target is required."

"Muon capture rates have been measured in a large number of the heavier elements in recent years. The amount of data available on the light elements, however, is scant. It would seem that lifetime measurements of muons in light elements would be of particular interest with regard to understanding the nuclear structure and determining the strength of the weak interaction. Furthermore, only one previous measurement of the muon capture "'isotope effect" has been done, that being for chlorine isotopes. In view of these considerations, the series of muon capture experiments reported in this paper was undertaken."

"The properties of the muon have been studied for many years and much is now known about this particle. Very accurate measurements of its mass and magnetic moment gave values in the relationship predicted by the Dirac equation and quantum electrodynamics. Experimental evidence indicating that the muon spin is 1/2 is obtained from comparison of precession measurements of the muon bound in certain mesic atoms and from observation of muonium precession. To all appearances, one would conclude that the muon behaves as an unstable electron, but as 206.76 times the mass of that electron. A study of the interaction of the muon with nuclear matter may throw more light on this problem of muon-electron equivalence."

"A method for extracting information on Regge trajectories from experimental data in the analysis of highenergy, small-angle elastic scattering is outlined."

In 1947 Bauer, and later independently Huntley (1948), pointed out that the helium content of iron meteorites as measured by Paneth and coworkers could be accounted for by the accumulation through cosmic-ray production rather then the decay of uranium and thorium. Bauer (1947) also predicted that the meteroitic helium should contain a significant proportion of He3. I was realized that by studying the effects of cosmic radiation on meteorites much could be learned about the history of meteorite and cosmic radiation. Chemical and instrumental techniques have been developed for the isolation, purification, and measurement of cosmic-ray-induced C14 in both stone and iron meteorites. The isolation of carbon from the silicate materials is done by fusion in an oxidizing flux in a vacuum system. From the iron meteorites the carbon is recovered by the decomposition of the metal in nitric acid in a closed system.

"The influence of compressive creep on the self-diffusivity of α-iron has been measured in the temperature range of 742-885°C. the diffusivity is enchanced in proportion to the strain rate, but this dependence decreases with increasing temperature. The magnitude of the strain is relatively unimportant in this connection. Strain rates from 0 to -2 x 10¯³ sec¯¹ were investigated with a corresponding increase in diffusivity up to 3 x 10³ times. The results are analyzed in terms of vacancy diffusion and the excess vacancies introduced during deformation. It is concluded that grain boundaries are the main vacancy sinks in polycrystalline iron and that the vacancy lifetime is therefore dependent on the grain size."

"Short-range order coefficients were measured at 300 and 400°C for iron-aluminum alloys containing 14.8, 18.2, and 20.0 atomic per cent aluminum. These alloys exhibited a strong preference for unlike near neighbors. The short-range order was greater at the lower temperature and increased as the Fe 3Al composition was approached."

"Theoretical calculations have been carried our for the two ordering phases which occur in the FeAl system. The statistical treatment involves first and second neighbor interaction parameters as well as a magnetic interaction between first neighbor iron atoms. The phase diagram and the amount and type of long range order for slowly cooled alloys are calculated. Further calculations include short range order for the disordered phase at three compositions and two temperatures. As expected, the short range order increases as a critical temperature is approached either in composition of in temperature."

"The diffusivities of Fe, Co, and Al in otherwise pure Au were determined by a residual activity technique. It was found that the frequency factors and activation energies of the transition elements into Au are normal relative to the values for Au self-diffusion, and suggest that lattice diffusion is operative, in contrast to the corresponding situation for the diffusion of these elements in Al. This difference in behavior is explained in terms of the marked difference in solid solubilities in the two series."

The self-diffusivities of Co60 and Ni63 in cobalt--nickel solid solutions exhibit a greater activation energy below the Curie temperature (T/sub c/) than above. Values of DELTA Q = Q (ferromagnetic) -- Q (paramagnetic) are approximately equal to RT/sub c/. This observation is interpreted to indicate that the increment in activation energy arises from an increase in the formation energy of a vacancy in the ferromagnetic lattice, with the additional binding energy arising from the interaction of a spin with the Weiss field."

"Contact conductances for three semi-smooth and rough stainless steel contacts involving six steels are determined. The procedure and equipment used are fully described, and the results are given. Graphs display thermal conductance and conductivity versus pressure and temperature."