Development of Isotope Dilution Techniques for Assay of Food Additives (open access)

Development of Isotope Dilution Techniques for Assay of Food Additives

"lsotope dilution techniques are described for the assay of chlorinated hydrocarbon pesticides and organic phosphorus pesticides in foods. Results are given for the determination of tetranitro-DDT-dianilide, dianilide of tetranitro- DDE, dieldrin, systox, and derivatives of these compounds. "
Date: October 31, 1962
Creator: Nuclear Science and Engineering Corporation
System: The UNT Digital Library
III. Crystalline Complexes of Bis(Di-2-Ethylbutylphosphinyl) Methahe With Uranium(VI) Nitrate and With Thorium Nitrate (open access)

III. Crystalline Complexes of Bis(Di-2-Ethylbutylphosphinyl) Methahe With Uranium(VI) Nitrate and With Thorium Nitrate

Technical report. From Abstract : "Bis(di-2-ethylbutylphosphinyl)methane, EBDPM, forms complexes with uranium (VI) nitrate and thorium (IV) nitrate in which EBDPM acts as a bidentate ligand and the nitrato groups appear to be coordinated. The complex with uranium (VI) is a monomer, UO2(NO3)29EBDPM), while the complex with thorium in a dimer, [Th(NO3)4]2(EBDPM)3. Both complexes are of high thermal stability."
Date: October 16, 1962
Creator: Parker, James R. & Banks, Charles V.
System: The UNT Digital Library
Separation and Spectrophotometric Determination of Rare Earths (open access)

Separation and Spectrophotometric Determination of Rare Earths

Technical report. From Summary : "At the present time arsenazo appears to be widely used for the spectrophotometric determination of rare earths. Unfortunately, the method is not selective. The separation of rare earths and yttrium from interfering elements has been studied, and the following method has been proposed. Rare earths are precipitated as fluorides using fluorides using calcium fluoride as the carrier. Thorium and zirconium are removed by extraction with thenoyltrifluoroacetone (TTA) in xylene at pH 1.3. Small amounts of residual aluminum, iron, etc. are removed by extraction with 8-quinolinolchloroform at pH 4.5. Rare earths are separated from calcium by TTA extraction at the same pH, and they are then back-extracted into 1 M nitric acid. After evaporation of the solution, the rare earths are determined spectrophotometrically with arsenazo."
Date: October 18, 1962
Creator: Onishi, Hiroshi & Banks, Charles V.
System: The UNT Digital Library
The Enhancement of Acidity of Very Weak Acids in Tertiary Butyl Alcohol (open access)

The Enhancement of Acidity of Very Weak Acids in Tertiary Butyl Alcohol

Technical report. From Abstract : "The acidity of a solution of acid, HX, and salt, MX, is affected by both the concentration of X- and M+ owing to incomplete dissociation of the salt, MX. it was possible to increase the acidity of a solution of 2,6-di-tert-butylphenol - tetrabutylammonium 2,6-di-tert-butylphenolate relative to a dilute solution of tetrabutylammonium hydroxide by increasing the tetrabutylammonium bromide content. This indicates that the dissociation constant of the hydroxide base is sufficiently large that extensive dissociation occurs in dilute solutions. The addition of tetrabutylammonium bromide is therefore recommended as a general method for increasing the acidity and improving the titration characteristics of extremely weak acids."
Date: October 22, 1962
Creator: Marple, Leland & Fritz, J. S.
System: The UNT Digital Library
Study of Metal-1.10-Phenanthroline Complex Equilibria by Potentiometric Measurement (open access)

Study of Metal-1.10-Phenanthroline Complex Equilibria by Potentiometric Measurement

Technical report. From Abstract : "The silver-1,10-phenanthroline system has been studied and the stability constants determined for the 1:1 and 2:1 complexes using the silver electrode. This known system was then used to study the complexes of 1,10-phenanthroline with other metals. The log βn values found for the over-all stoichiometric stability constants are as follows: Ag, 5.02, 12.07; Mn, 3.88, 7.04, 10.11; Cd, 5.93, 10.52, 14.30; Zn, 6.83, 12.05, 16.92. The stoichiometric stability constants determined for copper are log k2 = 6.42 and log k2k3 = 11.05."
Date: October 25, 1962
Creator: Dale, John M. & Banks, Charles V.
System: The UNT Digital Library
The Scandium-Yttrium and Scandium-Zirconium System (open access)

The Scandium-Yttrium and Scandium-Zirconium System

Technical report. From Abstract : "The scandium-yttrium and scandium-zirconium were studied by thermal and x-ray methods. Both systems are characterized by complete solid solubility in the low temperature hexagonal form and in the high temperature bcc form. In the Sc-Y system, there is a minimum in the solidus at 50 at. pct and 1365°C, while the solidus in the Sc-Zr system follows a nearly straight line relationship between the melting point of scandium and zirconium. There is a minimum in the temperature of transition from hexagonal to bcc in the Sc-Y system at 43 at. pct Y and 1175°C; while the temperature of transition is raised in the Sc-Zr system to a maximum of 1415°C at 30 at. pct Zr."
Date: October 26, 1962
Creator: Beaudry, B. J. & Daane, A. H.
System: The UNT Digital Library
Chemical Processing of Pu238 (open access)

Chemical Processing of Pu238

Technical report. From Abstract : "Plutonium (principally Pu238) was separated from neptunium, and both the plutonium and neptunium were purified from fission products and cations by a three-cycle anion exchange process."
Date: October 1962
Creator: Tetzlaff, Ralph N.
System: The UNT Digital Library