Crystalline Field Splittings in Holmium and Dysprosium Ethylsulfates (open access)

Crystalline Field Splittings in Holmium and Dysprosium Ethylsulfates

From report : "It has become apparent that pragmatic resonance data alone are insufficient to correctly evaluate crystal field parameters for rare-earth ethylsulfates, and that heat capacity data above 20°K are a useful aid in determining whether low lying levels obtained by absorption spectroscopy have been correctly identified."
Date: March 1963
Creator: Spedding, F. H.; Gerstein, B. C.; Haas, W. J.; Phillips, E. & Sutherland, W. L.
System: The UNT Digital Library
Separation of Iron by Liquid-Liquid Column Extraction (open access)

Separation of Iron by Liquid-Liquid Column Extraction

From abstract: "Iron(III) can be separated from many elements by extraction from 6 to ͟8M hydrochloric acid. The extraction is carried out by passing the aqueous hydrochloric acid solution through a column packed with 2-octanone adsorbed onto a poly-fluorocarbon resin. Fluoride, phosphate, sulfate or citrate cause no interference. Traces if iron(III) can be separated quantitatively from large amounts of copper(II) or zinc(II); traces of titanium(IV) can be separated from large amounts of iron(III)."
Date: March 21, 1962
Creator: Fritz, James S. (James Sherwood), 1924- & Hedrick, C. E.
System: The UNT Digital Library
The Mass Spectra of Some Volatile Hydrides (open access)

The Mass Spectra of Some Volatile Hydrides

From abstract: "The hydrides of group VB an VB elements, except CH4 and NH3, have been prepared and, except for PbH4 and BiH3, their mass spectra studied. Fragmentation patterns and appearance potentials of the positive ions from these hydrides are reported. The ions have been tested for excess kinetic energy and this energy was found to be negligible. The average M-H bond energies and the ΔHf° obtained from appearance potential data agree well with values obtained by other methods. Evidence is cited for the existence of distibine."
Date: March 19, 1962
Creator: Saalfeld, S. E. & Svec, Harry J. (Harry John), 1918-
System: The UNT Digital Library
Radical and Molecular Reaction Mechanisms for (γ, n) Activated c11 Reactions in Liquid Cyclohexane (open access)

Radical and Molecular Reaction Mechanisms for (γ, n) Activated c11 Reactions in Liquid Cyclohexane

From abstract: "A study has been made of the yields of gaseous products labeled with C11 from the C12(γ, n) reaction in liquid cyclohexane. The effects of variations in the radiation dose and in the concentration of dissolved iodine during irradiation on the yields of these products were studied in order to elucidate the reaction mechanisms. A reaction model was developed as a method of assessing the relative importance of radical and molecular processes. The data suggest (1) that the formation of C11 labeled CH4, C2H4 + C2H6, and C3H6 involves a hot radical process while (2) the formation of C2H2 is by a molecular reaction with cyclohexane."
Date: March 21, 1962
Creator: Rack, Edward P. & Voigt, Adolf F.
System: The UNT Digital Library
αZ Correction to the Bethe-Maximon Pair Production Cross Section (open access)

αZ Correction to the Bethe-Maximon Pair Production Cross Section

From abstract: "The first order correction in αZ to the Bethe-Maximon pair production cross section is calculated for the case where the incident photon and one of the electrons has an energy much greater than mc2. Comparison of these calculations to the experimental data of Plimpton and Hammer shows an improvement ina greement between theory and experiment of approximately a factor of 1+(αZ4π/15) for low positron kinetic energies. However, for positron kinetic energies of the order of 1 Mev no improvement is obtained."
Date: March 21, 1962
Creator: Moroi, David S. & Hammer, C. L.
System: The UNT Digital Library
͟v͟ic-Dioximes as Analytical Reagents (open access)

͟v͟ic-Dioximes as Analytical Reagents

This technical report discusses the synthesis of vic-dioximes, the analysis of vic-dioximes, the structure of vic-dioximes, the structure of metal(II)-vic-dioxime complexes, and analytical applications of this research. The report includes tables and figures that accompany the report's contents and findings.
Date: March 19, 1962
Creator: Banks, Charles V.
System: The UNT Digital Library
Electrical Properties of the Tungsten Bronzes (open access)

Electrical Properties of the Tungsten Bronzes

From abstract: "The electrical resistivity of NaxWO3, LixWO3, and KxWO3 has been measured at 300°K. The range of x-values was 0.25 < x < 0.9. All resistivities were characteristic of a metal and lie on a single curve. An extrapolation of the conductivity curve to zero conductivity indicated that the tungsten bronzes should be semiconductors for x < 0.25. The resistivities that have been measured for tungsten bronzes with x < 0.25 showed semiconducting behavior. The resistivity of LixWO3 exhibited an anomalous peak in the ρ vs Τ cuve. The Hall coefficient of Li0.37WO3 indicated one free electron per alkali atom as was previously found for NaxWO3. The Seebeck coefficient of NaxWO3 depended linearly on x[superscript]-2/3 as expected from free electron theory. The implications of these and some other data are discussed."
Date: March 21, 1962
Creator: Shanks, H. R.; Sidles, Paul Howard & Danielson, G. C.
System: The UNT Digital Library
Stability Constants and Intrinsic Solubility of Several Nickel(II)-vic-Dioxime Complexes (open access)

Stability Constants and Intrinsic Solubility of Several Nickel(II)-vic-Dioxime Complexes

This technical report discusses processes to study the stability constants and intrinsic solubility of several Nickel(II)-vic-Dioxime complexes.
Date: March 19, 1962
Creator: Banks, Charles V. & Anderson, Samuel
System: The UNT Digital Library
Thorium-Molybdenum Phase Diagram (open access)

Thorium-Molybdenum Phase Diagram

From abstract: "The phase diagram of the thorium-molybdenum alloy system has been determined to be the eutectic type with a eutectoid reaction associated with the thorium alpha-beta transformation. X-ray, thermal, electrical resistance and metallographic methods have established the eutectic point at 1380 ± 10°C and 7.0 ± 0.5 wt % molybdenum. A eutectoid reaction is proposed at 1358 ± 5°C and less than 0.1 wt % molybdenum. No solubility of thorium in molybdenum was detected at 1325°C."
Date: March 27, 1962
Creator: McMasters, O. D.; Palmer, P. E. & Larsen, W. L.
System: The UNT Digital Library
Some Observations Regarding Rare-Earth Lactates (open access)

Some Observations Regarding Rare-Earth Lactates

From abstract: "Lactates of all the rare earths except lanthanum, cerium, and praseodymium were prepared and studied. In the case of lanthanum, cerium, and praseodymium the lactates are apparently so soluble that they cannot be crystallized directly from aqueous solution. Products obtained by addition of anhydrous ethanol to sirupy solutions of the light-rare-earth lactates were not well characterized and were deliquescent. Neodymium lactate trihydrate was prepared only by the addition of alcohol to a sirupy solution. Since it was not as deliquescent as the lactates of lanthanum, cerium, and praseodymium, some of its properties could be studied. The lactates of all the other rare earths, samarium through lutetium, as well as the lactate of yttrium, separated readily from aqueous media as trihydrates--the solubility of the hydrated lactate decreasing as the atomic number of the rare earth increased. Thermal decomposition of the crystalline lactates, except those of neodymium and samarium, proceeded through dihydrated and anhydrous states to a composition corresponding roughly to LnlacCO3 at a temperature of about 290-300°C. Ln2(CO3)3 or Ln2O(Co3)2 were observed. In order to make a comparison, thermal decomposition of the rare-earth glycolates was studied also. Solubilities in water at both 20 and 60°C have been tabulated."
Date: March 28, 1962
Creator: Powell, J. E. & Farrell, J. L.
System: The UNT Digital Library