Due to a need of precise thermodynamical and thermochemical data on these elements and their compounds for the understanding and correlation of the chemical behavior of these substances, this report measures the heat of the solution of neptunium metal and the heats of formation of the neptunium chlorides using a microcalorimeter to measure the heat.

Report discussing a study to determine experimentally whether a low neutron binding energy must be assigned to Kr⁸⁷ to explain the neutron emission or whether the beta-decay energy is especially high, as well as to determine the fission yield of Br⁸⁷.

This report analyzes experiments on the production of zirconium tetrafluoride and discusses the reactivity data taken after various methods.

A short survey of some of the metabolic relationships of the elements, cerium, colurbium, plutonium, strontium, yttrium, and zirconium is presented. While the results of internally deposited radium have not been investigated in these experiments, they have been extensively studies by others. Because so much is known of its biological effects, it has been included in this historical survey.

The following report describes results from a study of three types of cement (Barytes, Brookhaven, and Portland) exposed in the ORNL Reactor for periods of seven and twenty-eight days.

The reaction of alanine-1-C14 and phenylalanine-1-C14 with acetic anhydride in the presence of pyridine has been studied and the carboxyl group of the amino acid has been shown to be the exclusive source of carbon dioxide involved.

In an effort to gain information on the nature of the photon-meson and photon-nucleon interaction, a study of the artificial production of mesons by photons has been made at the Berkeley synchrotron. The major effort of this research was concentrated on a measurement of the energy and angular distribution of u+-mesons produced when the photons strike a target of liquid hydrogen. Detection of the mesons is accomplished electronically by the technique of delayed coincidence.

The complexing of lanthanum by various anions and weak acids was investigated by observing the light absorption of the complex formed with thenoyltrifluoracetone (TTA). This species showed the properties needed for a satisfactory specgtrophotometric method of analysis.

Energy values are generally accurate to 5%, except in the low energy region and except for He(3) and He(4) for which a non-relativistic conversion was made.

Monthly report of the U.S. Geological Survey's trace element investigations including an outline of field work, laboratory work, and staff activities that have been completed or are in process.

From summary: "Various thermal and mechanical properties were measured for sintered tin oxide-matrix compacts which nominally were composed of 99 per cent by weight of tin oxide, SnO2, and one per cent by weight of zinc oxide ZnO...The tin oxide body might be expected to give good service under conditions of severe thermal shock and in an oxidizing atmosphere at temperatures up to 1500°F."

Report discussing progress made by the Chemistry Division (Section C-1) of the Argonne National Laboratory for the months of April, May and June, 1951. Information is divided into "Nuclear Chemistry and Radiochemistry" and "Basic Chemistry".

Abstract: The Salt Wash member of the Jurassic Morrison formation of Mexican Cry Mesa, Lukachukai District, Arizona, was examined to determine size, grade, and distribution of contained carnotite deposits and the possibilities of developing reserves by exploratory drilling. Only three occurrences of carnotite-bearing sandstone were found in 17 miles of rim outcrop. Limited drilling is recommended in the vicinity of these exposures.

The following document provides figures with all information that describe the heavy water moderated chain reacting pile at Argonne National Laboratory.

Report issued by the Brookhaven National Laboratory discussing progress of waste concentration studies. As stated in the introduction, "the present report covers all experimental hot runs up to the time the still was turned over to the Waste Control Section for intermediate handling of laboratory D waste" (p. 1). This report includes tables, illustrations, and photographs.

Report summarizing work done by the Ames Laboratory from April, 1951 through June, 1951 in the fields of metallurgy, chemistry, physics, and engineering.

"The purpose of this memo is to set down a derivation and numerical technique for a method that can be used for criticality calculations on bare reactors containing hydrogen together with another moderator such as BeO. The method and notation are that of G. Goertzel (NDA)-1, and D. Selengut (NEPA). In the interest of the computers, the numerical technique, associated notation, and calculation form are modeled after that currently used by the ANP Physics Group for BeO moderated reactors."

Report discussing the possibility of structural damage which is most likely to lead to dangerous release of radioactive materials, as well as "the effect of sudden loss to vacuum in a device such as that described in "Engineering Analysis, Mark 2 (4-28-51)."

An active program is a present underway to develop equipment to handle liquid metals. Among the metals being studied are sodium and sodium--potassium alloy (the latter commonly referred to as NaK). In many of the systems being studied this liquid metal is pressurized by inert gas in the lines. At times it is necessary to bleed off some of this gas from the system. Although the gas is allowed to escape at a temperature at which the vapor pressure of sodium is extremely small, it has been found that excessive amounts of sodium are present in this gas stream. Either this sodium collects in the lead-off pipes from the system as a solid, threatening to block the passage in which it is found, or it passes out into the atmosphere. In order to explain the presence of such a dangerous concentration of sodium in the exit gas stream, it has been proposed that the sodium vapor present in the the system at high temperatures condenses into a mist or aerosol on cooling. This aerosol is stable and will not readily de-entrain or condense onto the surfaces over which it passes. Another possibility is that the oxygen present with the inert …

A study was conducted on the elution behavior of curium (III), americium (III), plutonium (III), actinium (III), plutonium (IV), neptunium (IV), uranium (IV), thorium (IV), neptunium (V), plutonium (VI), uranium (VI), lanthanum (III), cerium (III), europium (III), ytterbium (III), ytterium (III), strontium (II), barium (II), radium (II), cesium (I) with 3.2 M, 6.2 M, and 12.2 M HCI solutions from Dower-50 cation exchange resin columns. These elutions show that in high concentrations of hydrochloric acid the actinides form complex ions with chloride ion to a much greater extent than the lanthanides. In order to explain these results, a partial covalent character may be ascribed to the bonding in the transuranium complex ions. It is shown that a reasonable structure for such covalent bonding involves hybridization of the 5g-ortibals in the actinide elements.

Report summarizing the progress of the gasket development program during the period from November 1949 to May 1950.

Discussing a wagon drilling project carried out at Temple Mountain.

This report describes two drilling projects that were successful in discovering ore deposits at Temple Mountain.

Photocopy of a dissertation discussing natural radioactivities and half life of potassium, Rubidium, Rhenium, and Lutetium.