A Thermodynamic Study of Gaseous Oxides (open access)

A Thermodynamic Study of Gaseous Oxides

None
Date: December 1, 1953
Creator: Porter, R. F.
System: The UNT Digital Library
Physical Studies of Cell Division: Statistical Fluctuations; Effects Due to X-Radiation, Temperature, and Hydrostatic Pressure (open access)

Physical Studies of Cell Division: Statistical Fluctuations; Effects Due to X-Radiation, Temperature, and Hydrostatic Pressure

Thesis discussing "a technique for determining the generation times of individual yeast cells...the effect of x-radiation on the generation times of individual cells and their progeny..." and "attempts to synchronize cell division in a population of cells."
Date: December 9, 1954
Creator: Burns, Victor Will
System: The UNT Digital Library
Characteristics of a Lead-Glass Photon Spectrometer and its Use in Studying the Absorption of Photons and Antinucleons (open access)

Characteristics of a Lead-Glass Photon Spectrometer and its Use in Studying the Absorption of Photons and Antinucleons

Thesis analyzing a lead-glass photon spectrometer and its use in studying the absorption of photons and antinucleons.
Date: December 12, 1956
Creator: Brabant, John Michael
System: The UNT Digital Library
The Kinetics of the Complexing of Ferric Ion by Thiocyanate and Chloride Ions (open access)

The Kinetics of the Complexing of Ferric Ion by Thiocyanate and Chloride Ions

An apparatus for rapidly mixing two solutions and recording the light absorption, which was developed by Connick and Below, has been modified. The mixing characteristics were studied and models were developed in an attempt to umder stand the observed mixing phenomena. The apparatus was applied to a study of the kinetics of the reactions Fe/sup +++/ + SCN/sup -/ = FeSCN/sup ++/ and Fe/ sup +++/ Cl/sup -/ = FeCl/sup ++/ in aqueous solution, with both reactions having the forward rate law STAd(FeX/sup ++/)/dt = k/sub 1/ (Fe/sup +++/) (X/sup -/) + k/ sub 2/ (Fe/sup +++/)(X/sup -/)/(H/sup +)!, where X/sup -/ represents either SC N/ sup -/ or Cl/sup -/. The rate constants k/sub 1/ and k/sub 2/ have been measured as a function of temperature, and the heats and entropies of activation have been calculated. Mechanisms for the observed rate law have been discussed and the entropies of activation were compared with those for analogous reaction rates and with some equilibrium entropies of complexing. A rate for chloride complexing of ferric ion was obtained from nuclear magnetic resonance studies and compared with the results of the spectrophotometric kinetic study. (auth)
Date: December 1, 1957
Creator: Coppel, Claude Peter
System: The UNT Digital Library
Studies Relating to the Structure of Aluminum Hydride (open access)

Studies Relating to the Structure of Aluminum Hydride

The object of the work was to determine the molecular structure of AlH/ sub 3/, using the techniques of nuclear spin resonance.'' Attempts to prepare ether-free AlH/sub 3/ that were unsuccessful are described. Also it was not possible to observe the deuterium signal in AlH/sub 3/. It was possible, by the use of the proton signal of the ether in AlH/sub 3/, to obtain the nuclear spin resonance absorption curve for AlH/sub 3/ by subtracting out the contributions of the ether protons to the resonance signai. A model is proposed to explain the features of the nuclear spin resonance absorption curve. The existence of LiAl/ sub 2/H/sub 7/, which has been postulated elsewhere, is assumed in order to explain the datu obtained from high-resolution nuclear spin resonance experimeats. (auth)
Date: December 16, 1957
Creator: Nickerson, R. F.
System: The UNT Digital Library
Some Problems in Horizontal Two-Phase Tow-Component Flow (open access)

Some Problems in Horizontal Two-Phase Tow-Component Flow

An experimental investigation was conducted on the flow of air-water mixtures in a number of horizontal rectangular Lucite test sections, whose aspect ratios varied from two to sixteen. These test sections were assembled in various combinations to permit the study of the effect of a sudden change in flow area on the significant flow parameters. A technique was developed for measuring the volume fraction of each phase, making use of the difference of the attenuation characteristics of the liquid and the vapor for gamma radiation. This technique was evaluated making use of a number of Lucite mockups with known void distributions. Information is presented on the factors influencing the volume fractions, flow patterns, and slip ratios in the channels studied. The two-phase pressure drop is compared with existing correlations, and a relationship predicting this pressure drop, in terms of the liquid volume fraction, is derived. The energy losses associated with an abrupt expansion or contraction were studied. A correlation based on the experimental results is presented to permit the prediction of these losses. (auth)
Date: December 1, 1958
Creator: Richardson, B. L.
System: The UNT Digital Library