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An investigation of steric influence on the reactivity of FeV(O)(OH) tautomers in stereospecific C–H hydroxylation (open access)

An investigation of steric influence on the reactivity of FeV(O)(OH) tautomers in stereospecific C–H hydroxylation

Article describes how two new tetradentate N4 ligands (LN4), LN4 = Me2,Me2PyzTACN (1-(2-(3,5-dimethyl-1H-pyrazol-1-yl)ethyl)-4,7-dimethyl-1,4,7-triazacyclononane) and Me2,MeImTACN (1-((1-methyl-1H-imidazol-1-yl)methyl)-4,7-dimethyl-1,4,7-triazacyclononane) have been synthesized and their corresponding Fe(II) complexes [FeII(Me2,Me2PyzTACN)(CF3SO3)2], 1Pz, and [FeII(Me2,MeImTACN)(CF3SO3)2], 1Im, have been prepared and characterized. Based on these labelling studies, the steric influence exerted by each of the ligands towards the relative reactivity of the oxo ligands of the corresponding pair of Fe(V)(O)(OH) tautomers can be derived.
Date: January 5, 2023
Creator: Mitra, Mainak; Brinkmeier, Alexander; Li, Yong; Borrell, Margarida; Call, Arnau; Fillol, Julio Lloret et al.
System: The UNT Digital Library
Mapping Health Fragility and Vulnerability in Air Pollution–Monitoring Networks in Dallas–Fort Worth (open access)

Mapping Health Fragility and Vulnerability in Air Pollution–Monitoring Networks in Dallas–Fort Worth

Article describes how environmental air pollution remains a major contributor to negative health outcomes and mortality, but the relationship between socially vulnerable populations and air pollution is not well understood. This paper seeks to understand how air pollution monitor placement strategies and policy may neglect social vulnerabilities and therefore potentially underestimate exposure burdens in vulnerable populations.
Date: January 18, 2023
Creator: Northeim, Kari & Oppong, Joseph R.
System: The UNT Digital Library
Metabolic reprogramming underlies cavefish muscular endurance despite loss of muscle mass and contractility (open access)

Metabolic reprogramming underlies cavefish muscular endurance despite loss of muscle mass and contractility

Article discusses the Mexican cavefish Astyanax mexicanus, has lost moderate-to-vigorous activity following cave colonization, reaching basal swim speeds ~3.7-fold slower than their river-dwelling counterpart. Collectively, the authors reveal broad skeletal muscle changes following cave colonization, displaying an adaptive skeletal muscle phenotype reminiscent to mammalian disuse and high-fat models while simultaneously maintaining a unique capacity for sustained muscle contraction via enhanced glycogen metabolism.
Date: January 24, 2023
Creator: Olsen, Luke; Levy, Michaella; Medley, J. Kyle; Hassan, Huzaifa; Miller, Brandon; Alexander, Richard et al.
System: The UNT Digital Library
Magnetic plasma expulsion (open access)

Magnetic plasma expulsion

The article presents one scheme for what is referred to as magnetic plasma expulsion, which would prevent the plasma from entering a given region. Magnetic plasma expulsion techniques may allow instrumentation access to the interiors of plasmas. Magnetic plasma expulsion techniques may also make alternative approaches for magnetic plasma confinement possible. Particle-in-cell simulation with the Warp code is used to study magnetic plasma expulsion. Some conditions for achieving magnetic plasma expulsion are reported.
Date: January 16, 2018
Creator: Phillips, R. E. & Ordonez, Carlos A.
System: The UNT Digital Library
Upper lethal temperatures of Northern Bobwhite embryos and the thermal properties of their eggs (open access)

Upper lethal temperatures of Northern Bobwhite embryos and the thermal properties of their eggs

This article explores the upper lethal temperature for Bobwhite eggs. Results find that thermal tolerances of Northern Bobwhite embryos are high, indicating an adaptation to the naturally occurring temperature extremes in the Bobwhite's environment. However, the results also indicate that high temperatures could have plausibly contributed to the population decline observed in the Bobwhite's semi-arid range.
Date: January 1, 2012
Creator: Reyna, Kelly S. & Burggren, Warren W.
System: The UNT Digital Library
Progress in understanding and improving oil content and quality in seeds (open access)

Progress in understanding and improving oil content and quality in seeds

Article asserts that the world’s population is projected to increase by two billion by 2050, resulting in food and energy insecurity. This review provides a summary of the current knowledge of oil metabolism and discusses how photochemical activity and unconventional pathways can contribute to high carbon conversion efficiency in seeds.
Date: January 26, 2023
Creator: Sagun, Julius Ver; Yadav, Umesh P. & Alonso, Ana Paula
System: The UNT Digital Library
Application of Genome Editing in Tomato Breeding: Mechanisms, Advances, and Prospects (open access)

Application of Genome Editing in Tomato Breeding: Mechanisms, Advances, and Prospects

This article is a review presenting examples of gene editing responsible for conferring both biotic and abiotic stresses in tomato simultaneously. The literature on using this powerful technology to improve fruit quality, yield, and nutritional aspects in tomato is highlighted.
Date: January 12, 2021
Creator: Salava, Hymavathi; Thula, Sravankumar; Mohan, Vijee; Kumar, Rahul & Maghuly, Fatemeh
System: The UNT Digital Library
Production of tocotrienols in seeds of cotton (Gossypium hirsutum L.) enhances oxidative stability and offers nutraceutical potential (open access)

Production of tocotrienols in seeds of cotton (Gossypium hirsutum L.) enhances oxidative stability and offers nutraceutical potential

This article generates transgenic cotton lines expressing the barley (Hordeum vulgare) homogentisate geranylgeranyl transferase coding sequence under the control of the Brassica napus seed-specific promoter, napin. Findings may provide new opportunities for cottonseed co-products with enhanced vitamin E profile for improved shelf life and nutrition.
Date: January 25, 2021
Creator: Salimath, Shanmukh S.; Romsdahl, Trevor B.; Konda, Anji Reddy; Zhang, Wei; Cahoon, Edgar B.; Dowd, Michael K. et al.
System: The UNT Digital Library
Gas-Phase Chemistry of 1,1,2,3,3,4,4-Heptafluorobut-1-ene Initiated by Chlorine Atoms (open access)

Gas-Phase Chemistry of 1,1,2,3,3,4,4-Heptafluorobut-1-ene Initiated by Chlorine Atoms

This article uses the relative rate method to determine the rate constant for the reaction of heptafluorobut-1-ene (CF₂=CFCF₂CF₂H) with chlorine atoms in air.
Date: December 29, 2021
Creator: Sapkota, Ramesh & Marshall, Paul
System: The UNT Digital Library
The exact consistency strength of the generic absoluteness for the universally Baire sets (open access)

The exact consistency strength of the generic absoluteness for the universally Baire sets

Article describes how a set of reals is universally Baire if all of its continuous preimages in topological spaces have the Baire property. The authors show that over some mild large cardinal theory, sealing is equiconsistent with LSA-over-uB.
Date: January 18, 2023
Creator: Sargsyan, Grigor & Trang, Nam
System: The UNT Digital Library
Domestic Carnivore Interactions With Wildlife in the Cape Horn Biosphere Reserve, Chile: Husbandry and Perceptions of Impact From a Community Perspective (open access)

Domestic Carnivore Interactions With Wildlife in the Cape Horn Biosphere Reserve, Chile: Husbandry and Perceptions of Impact From a Community Perspective

This article contains results of surveys to pet owners and non-owners living in the Cape Horn Biosphere Reserve in order to understand husbandry and perceptions of impacts by unconfined, domestic carnivores.
Date: June 2, 2017
Creator: Schüttler, Elke; Saavedra-Aracena, Lorena & Jiménez, Jaime E.
System: The UNT Digital Library

Ab Initio Calculations and Kinetic Modeling of Thermal Conversion of Methyl Chloride: Implications for Gasification of Biomass

This article investigates the thermal conversion of CH₃Cl.
Date: November 8, 2017
Creator: Singla, Mellika; Rasmussen, Morten Lund; Hashemi, Hamid; Wu, Hao; Glarborg, Peter; Pelucchi, Matteo et al.
System: The UNT Digital Library
Spin Hall effect in prototype Rashba ferroelectrics GeTe and SnTe (open access)

Spin Hall effect in prototype Rashba ferroelectrics GeTe and SnTe

Article describes study investigating spin Hall effect (SHE) in two prototypical Ferroelectric Rashba semiconductors (FERSCs), GeTe and SnTe, and show that it can be large either in ferroelectric or paraelectric structure.
Date: January 24, 2020
Creator: Wang, Haihang; Gopal, Priya; Picozzi, Silvia; Curtarolo, Stefano; Buongiorno Nardelli, Marco & Sławińska, Jagoda
System: The UNT Digital Library
Multifeature analyses of vascular cambial cells reveal longevity mechanisms in old Ginkgo biloba trees (open access)

Multifeature analyses of vascular cambial cells reveal longevity mechanisms in old Ginkgo biloba trees

This article investigates age-related changes in Ginkgo biloba trees to learn more about the molecular and metabolic mechanisms underlying their longevity. The results revealed that long-lived trees have evolved compensatory mechanisms to maintain a balance between growth and aging processes.
Date: January 13, 2020
Creator: Wang, Li; Cui, Jiawen; Jin, Biao; Zhao, Jiangou; Xu, Huimin; Lu, Zhaogeng et al.
System: The UNT Digital Library
Can Market-Oriented Reform of Agricultural Subsidies Promote the Growth of Agricultural Green Total Factor Productivity? Empirical Evidence from Maize in China (open access)

Can Market-Oriented Reform of Agricultural Subsidies Promote the Growth of Agricultural Green Total Factor Productivity? Empirical Evidence from Maize in China

Article asserts that green agriculture is the future of agricultural development. The policy implication of this paper is that developing countries should actively promote the market-oriented reform of agricultural subsidies to promote green agricultural development.
Date: January 20, 2023
Creator: Ye, Feng; Yang, Zhongna; Yu, Mark; Watson, Susan & Lovell, Ashley
System: The UNT Digital Library
The impact of multifactorial stress combination on plant growth and survival (open access)

The impact of multifactorial stress combination on plant growth and survival

Article studying seedlings of wild-type and different mutants of Arabidopsis thaliana plants subjected to a multifactorial stress combination of six different stresses, each applied at a low level, and their survival, physiological and molecular responses. Findings reveal that further polluting our environment could result in higher complexities of multifactorial stress combinations that in turn could drive a critical decline in plant growth and survival.
Date: January 26, 2021
Creator: Zandalinas, Sandra I.; Sengupta, Soham; Fritschi, Felix B.; Azad, Rajeev K.; Nechushtai, Rachel & Mittler, Ron
System: The UNT Digital Library
A gene based combination test using GWAS summary data (open access)

A gene based combination test using GWAS summary data

Article describes how gene-based association tests provide a useful alternative and complement to the usual single marker association tests, especially in genome-wide association studies (GWAS). The authors propose a test named OWC based on summary statistics from GWAS data.
Date: January 3, 2023
Creator: Zhang, Jianjun; Liang, Xiaoyu; Gonzales, Samantha; Liu, Jianguo; Gao, Xiaoyi Raymond & Wang, Xuexia
System: The UNT Digital Library