Stability and degradation in triple cation and methyl ammonium lead iodide perovskite solar cells mediated via Au and Ag electrodes (open access)

Stability and degradation in triple cation and methyl ammonium lead iodide perovskite solar cells mediated via Au and Ag electrodes

Article focuses on the fact that there are no clear mechanisms for the interaction of electrode-induced absorber degradation pathways. Furthermore, the authors hypothesize that the formation of AgI in the PSCs, leads to corrosion of the perovskite absorber, as opposed to the benign AuI when Au electrodes are used in the solar cell stack.
Date: November 3, 2022
Creator: Kranthiraja, Kakaraparthi; Parashar, Mritunjaya; Mehta, Ravindra K.; Aryal, Sujan; Temsal, Mahdi & Kaul, Anupama
System: The UNT Digital Library

Plexcitonic interactions in spherical and bi-pyramidical Au nanoparticles with monolayer WSeâ‚‚

Article describes how plasmons associated with zero-dimensional (0D) metal nanoparticles and their synergistic interactions with excitons in two-dimensional (2D) semiconductors offer opportunities for remarkable spectral tunability not otherwise evident in the pristine parent materials, which necessitates an in-depth study elucidating the nature of the plasmonic and excitonic interactions, jointly referred to as plexcitons in order to understand the foundational aspects of the light–matter interactions in hybrid 0D–2D systems. The authors examine the plexcitonic interactions of van der Waals (vdWs) hybrid structures composed of 2D WSe2 and 0D Au nanoparticles (Au-NPs) in their spherical (Au-Sp) and bi-pyramidical (Au-BP) architectures, which demonstrates that geometry-mediated response of the AuNPs provides another degree of freedom to modulate the carrier photodynamics in WSe₂.
Date: November 15, 2022
Creator: Jayanand, Kishan & Kaul, Anupama
System: The UNT Digital Library
A pseudo thermo-mechanical model linking process parameters to microstructural evolution in multilayer additive friction stir deposition of magnesium alloy (open access)

A pseudo thermo-mechanical model linking process parameters to microstructural evolution in multilayer additive friction stir deposition of magnesium alloy

Article describes how additive friction stir deposition has been proposed as a disruptive manufacturing process; involving complex thermo-mechanical mechanisms during multilayer material deposition. The primary motivation for development of the model was to seek an understanding of thermo-mechanical mechanisms and their impact on microstructural evolution during additive friction stir deposition.
Date: November 24, 2022
Creator: Sharma, Shashank; Krishna, Mani K. V.; Radhakrishnan, M.; Pantawane, Mangesh V.; Patil, Shreyash M.; Joshi, Sameehan et al.
System: The UNT Digital Library
Thermo/hydration responsive shape memory polymers with enhanced hydrophilicity for biomedical applications (open access)

Thermo/hydration responsive shape memory polymers with enhanced hydrophilicity for biomedical applications

Article states that thiol-ene/acrylate shape memory polymers (SMPs) have sufficient stiffness for facile insertion and precision placement and soften after exposure to physiological conditions to reduce the mechanical mismatch with body tissue; as a result, they have demonstrated excellent potential as substrates for various flexible bioelectronic devices, such as cochlear implants, nerve cuffs, cortical probes, plexus blankets, and spinal cord stimulators. Here, the authors report a new strategy for designing SMPs with enhanced shape recovery properties and lower moduli than previously reported SMPs under physiological conditions without sacrificing stiffness at room temperature by introducing a hydrophilic monomer.
Date: December 5, 2022
Creator: Suzuki, Yuta; Hu, Qichan; Batchelor, Benjamin; Voit, Walter & Ecker, Melanie
System: The UNT Digital Library
Quantitative estimation of closed cell porosity in low density ceramic composites using X-ray microtomography (open access)

Quantitative estimation of closed cell porosity in low density ceramic composites using X-ray microtomography

Article asserts that x-ray Microtomography is a proven tool for phase fraction analysis of multi-phase systems, provided that each phase is adequately partitioned by some means of data processing. The authors present a novel, combined methodology for accurate porosity analysis—despite these shortcomings.
Date: January 4, 2023
Creator: Smith, J. D.; Garcia, C.; Rodriguez, J. & Scharf, T. W.
System: The UNT Digital Library
Role of heterophase interfaces on local coercivity mechanisms in the magnetic Al0.3CoFeNi complex concentrated alloy (open access)

Role of heterophase interfaces on local coercivity mechanisms in the magnetic Al0.3CoFeNi complex concentrated alloy

Article describes how authors use state-of-the-art electron microscopy techniques to show that the magnetization reversal process in an Al0.3CoFeNi magnetic complex concentrated alloy (CCA), which is responsible for its coercivity, changes dramatically from a nucleation-type mechanism in the FCC+L12 state of the CCA. Their work reveals that heterophase FCC/BCC interfaces have a much stronger effect on coercivity than isostructural chemically ordered/disordered interfaces and provides a powerful guide to the rational design of microstructure to tune magnetic properties in both complex concentrated alloys and conventional magnetic alloys.
Date: January 10, 2023
Creator: Kovács, András; Venkataraman, Nithin B.; Chaudhary, V.; Dasari, Sriswaroop; Denneulin, Thibaud; Ramanujan, R. V. et al.
System: The UNT Digital Library
A Phosphonic Functionalized Biopolymer for the Sorption of Lanthanum (III) and Application in the Recovery of Rare Earth Elements (open access)

A Phosphonic Functionalized Biopolymer for the Sorption of Lanthanum (III) and Application in the Recovery of Rare Earth Elements

Authors of the article state that in the first step of their experiment, the sorption was investigated using La(III) ions before testing for the recovery of rare earth elements (REEs) from pretreated industrial acidic leachate. They infer that phosphonate groups participate in the sorption, and that the most effective sorption is at pH = 4.
Date: February 3, 2023
Creator: Hamza, Mohammed F.; Abdellah, Walid M.; Zaki, Doaa I.; Wei, Yuezhou; Althumayri, Khalid; Brostow, Witold, 1934- et al.
System: The UNT Digital Library
Molten Salt Corrosion Behavior of Dual-Phase High Entropy Alloy for Concentrating Solar Power Systems (open access)

Molten Salt Corrosion Behavior of Dual-Phase High Entropy Alloy for Concentrating Solar Power Systems

Article describes how dual-phase high entropy alloys have recently attracted widespread attention as advanced structural materials due to their unique microstructure, excellent mechanical properties, and corrosion resistance. The molten salt corrosion behavior of AlCoCrFeNi2.1 eutectic high-entropy alloy was evaluated in molten NaCl-KCl-MgCl2 salt at 450° C and 650° C in comparison to conventional duplex stainless steel 2205.
Date: February 4, 2023
Creator: Patel, Kunjal; Hasannaeimi, Vahid; Sadeghilaridjani, Maryam; Muskeri, Saideep; Mahajan, Chaitanya & Mukherjee, Sundeep
System: The UNT Digital Library
Microstructure evolution and mechanical properties in a gas tungsten arc welded Fe42Mn28Co10Cr15Si5 metastable high entropy alloy (open access)

Microstructure evolution and mechanical properties in a gas tungsten arc welded Fe42Mn28Co10Cr15Si5 metastable high entropy alloy

Article asserts that weldability studies on high entropy alloys are still relatively scarce, delaying the deployment of these materials into real-life applications, thus, there is an urgent need for in-depth studies of the weldability of these novel advanced engineering alloys. In the current work, an as-cast Fe42Mn28Co10Cr15Si5 metastable high entropy alloy was welded for the first time using gas tungsten arc welding.
Date: February 6, 2023
Creator: Shen, Jiajia; Agrawal, Priyanka; Rodrigues, Tiago A.; Lopes, J.G.; Schell, N.; He, Jinjing et al.
System: The UNT Digital Library
High-Throughput Investigation of Multiscale Deformation Mechanism in Additively Manufactured Ni Superalloy (open access)

High-Throughput Investigation of Multiscale Deformation Mechanism in Additively Manufactured Ni Superalloy

Article discusses how, in this paper, Inconel 718 (IN718) superalloy was processed by laser powder-bed fusion additive manufacturing (L-PBFAM), followed by heat treatment. Evidence of extensive deformation of twin networks and dislocation cells was revealed by transmission electron microscopy of the deformed region under the nanoindentation tip.
Date: February 17, 2023
Creator: Dhal, Abhijeet; Agrawal, Priyanka; Haridas, Ravi Sankar; Gaddam, Supreeth; Sharma, Aishani; Parganitha, Digvijay et al.
System: The UNT Digital Library
Lithium-CO2 batteries and beyond (open access)

Lithium-CO2 batteries and beyond

Article describes how Li-CO2 batteries with a theoretical energy density of 1,876 Wh kg−1 are attractive as a promising energy storage strategy and as an effective way to reduce greenhouse gas emissions by CO2 reduction and the formation of discharge product Li2CO3 and carbon. This article provides critical perspectives on the development of Li-CO2 batteries as well as a description of current issues and challenges associated with cathode catalysts, electrolyte, and anode for Li-CO2 batteries.
Date: March 3, 2023
Creator: Pathak, Anil; Adhikari, Pashupati R. & Choi, Wonbong
System: The UNT Digital Library
Laser powder bed fusion processing of a precipitation strengthenable FCC based high entropy alloy (open access)

Laser powder bed fusion processing of a precipitation strengthenable FCC based high entropy alloy

Article describes how, while additive manufacturing (AM) of single-phase solid solution based high entropy alloys (HEAs) has attracted a lot of recent attention, such processing of precipitation strengthenable multi-phase HEAs has not been actively investigated. This becomes important since AM processing results in each layer experiencing rapid solidification followed by multiple heating-cooling cycles, mimicking in situ heat treatments, potentially influencing the phase evolution.
Date: March 21, 2023
Creator: Chesetti, Advika; Banerjee, Sucharita; Dasari, Sriswaroop; Varahabhatla, S.M.; Sharma, Abhishek; Mantri, Srinivas Aditya et al.
System: The UNT Digital Library
Deformation behavior and strengthening effects of an eutectic AlCoCrFeNi2.1 high entropy alloy probed by in-situ synchrotron X-ray diffraction and post-mortem EBSD (open access)

Deformation behavior and strengthening effects of an eutectic AlCoCrFeNi2.1 high entropy alloy probed by in-situ synchrotron X-ray diffraction and post-mortem EBSD

Article describes how high energy synchrotron X-ray diffraction was used during tensile testing of an as-cast eutectic AlCoCrFeNi2.1 high entropy alloy. The authors determine for the first time the volume fractions of existing phases, and they further detail their role on the alloy deformation behavior.
Date: March 27, 2023
Creator: Shen, Jiajia; Lopes, J.G.; Zeng, Zhi; Choi, Yeon Taek; Maawad, E.; Schell, N. et al.
System: The UNT Digital Library
Room and Elevated Temperature Sliding Friction and Wear Behavior of Al0.3CoFeCrNi and Al0.3CuFeCrNi2 High Entropy Alloys (open access)

Room and Elevated Temperature Sliding Friction and Wear Behavior of Al0.3CoFeCrNi and Al0.3CuFeCrNi2 High Entropy Alloys

Article discusses how, in this study, processing–structure–property relations were systematically investigated at room and elevated temperatures for two FCC Al0.3CoFeCrNi and Al0.3CuFeCrNi2 high-entropy alloys (HEAs), also known as complex concentrated alloys (CCAs), prepared by conventional arc-melting. It was determined that both alloys exhibit FCC single-phase solid solution structure. Micro-indentation and sliding wear tests were performed to study the hardness and tribological behavior and mechanisms at room and elevated temperatures.
Date: April 2, 2023
Creator: Kadhim, Dheyaa F.; Korcherla, Manindra V. & Scharf, Thomas W.
System: The UNT Digital Library
Dynamic Motions of Topological Defects in Nematic Liquid Crystals under Spatial Confinement (open access)

Dynamic Motions of Topological Defects in Nematic Liquid Crystals under Spatial Confinement

Article discusses how topological defects (TDs) have become a sensational topic due to their significant influence on the unusual optical and physiochemical characteristics of the material. Here, authors assert how nematic liquid crystals confined in a cell exhibiting surfaces with periodic anchoring conditions containing surface topography are relied on.
Date: April 25, 2023
Creator: Pawale, Tejal; Swain, Justin; Hashemi, Mohammad Reza; Tierra, Giordano & Li, Xiao
System: The UNT Digital Library
Mapping hierarchical and heterogeneous micromechanics of a transformative high entropy alloy by nanoindentation and machine learning augmented clustering (open access)

Mapping hierarchical and heterogeneous micromechanics of a transformative high entropy alloy by nanoindentation and machine learning augmented clustering

Article describes how conventional macromechanical tests provide limited insights into complex hierarchical deformation behavior of a transformative high entropy alloy (HEA). In this work, a high throughput microstructure-micromechanical correlative study is presented by combining high-resolution nanoindentation, site-specific microscopy, and Gaussian mixture model (GMM) clustering.
Date: April 26, 2023
Creator: Dhal, Abhijeet; Haridas, Ravi Sankar; Agrawal, Priyanka; Gupta, Sanya & Mishra, R. S.
System: The UNT Digital Library
Tuning the temperature range of superelastic Ni-Ti alloys for elastocaloric cooling via thermal processing (open access)

Tuning the temperature range of superelastic Ni-Ti alloys for elastocaloric cooling via thermal processing

Article describes how caloric cooling enlisting solid-state refrigerants is potentially a promising eco-friendly alternative to conventional cooling based on vapor compression. Here, the authors have explored tuning the operation temperature range of Ni50.8Ti49.2 for elastocaloric cooling. In particular, they have studied the effect of thermal treatments (a.k.a. aging) on the transformation temperature, superelasticity, and elastocaloric effects of Ni50.8Ti49.2 shape memory alloy tubes.
Date: April 28, 2023
Creator: Yamazaki, Takahiro; Montagnoli, Andre L.; Young, Marcus L. & Takeuchi, Ichiro
System: The UNT Digital Library
A Critical Review of Laser Shock Peening of Aircraft Engine Components (open access)

A Critical Review of Laser Shock Peening of Aircraft Engine Components

Article describes how many aviation accidents are caused by the failure of aircraft engine components, and engine blades are especially vulnerable to high-cycle fatigue fracture in severe working environments as well as to impact damage caused by foreign objects. This review provides an overview of the development of LSP for use in treating aircraft engine components over the past three decades, with a brief introduction to the development of high-energy pulsed lasers for LSP.
Date: May 3, 2023
Creator: Ye, Yixuan; Zhang, Yu; Huang, Tao; Zou, Shikun; Dong, Yalin; Ding, Han et al.
System: The UNT Digital Library
Evolution of microstructure and mechanical properties in gas tungsten arc welded dual-phase Fe50Mn30Co10Cr10 high entropy alloy (open access)

Evolution of microstructure and mechanical properties in gas tungsten arc welded dual-phase Fe50Mn30Co10Cr10 high entropy alloy

Article describes how in recent years, high entropy alloys (HEAs) have been shown to be promising alternatives to common engineering alloys, depending on their composition and thermomechanical processing. In the present work, Gas Tungsten Arc Welding (GTAW) was used to achieve defect-free joints based on a novel transformation induced plasticity (TRIP) Fe50Mn30Co10Cr10 HEA.
Date: June 3, 2023
Creator: Lopes, J. G.; Agrawal, Priyanka; Shen, Jiajia; Schell, N.; Mishra, R. S. & Oliveira, J. P.
System: The UNT Digital Library
Underlying factors determining grain morphologies in high-strength titanium alloys processed by additive manufacturing (open access)

Underlying factors determining grain morphologies in high-strength titanium alloys processed by additive manufacturing

Article describes how, in recent research, additions of solute to Ti and some Ti-based alloys have been employed to produce equiaxed microstructures when processing these materials using additive manufacturing. The present study develops a computational scheme for guiding the selection of such alloying additions, and the minimum amounts required, to effect the columnar to equiaxed microstructural transitions.
Date: June 6, 2023
Creator: Nartu, Mohan S. K. K. Y.; Welk, Brian A.; Mantri, Srinivas Aditya; Taylor, Nevin L.; Viswanathan, Gopal B.; Dahotre, Narendra B. et al.
System: The UNT Digital Library
Boosting Piezoelectricity by 3D Printing PVDF-MoS2 Composite as a Conformal and High-Sensitivity Piezoelectric Sensor (open access)

Boosting Piezoelectricity by 3D Printing PVDF-MoS2 Composite as a Conformal and High-Sensitivity Piezoelectric Sensor

Article describes how additively manufactured flexible and high-performance piezoelectric devices are highly desirable for sensing and energy harvesting of 3D conformal structures. This study reports a significantly enhanced piezoelectricity in polyvinylidene fluoride (PVDF) achieved through the in situ dipole alignment of PVDF within PVDF-2D molybdenum disulfide composite by 3D printing.
Date: June 21, 2023
Creator: Islam, M.D, Nurul; Rupom, Rifat Hasan; Adhikari, Pashupati R.; Demchuk, Zoriana; Popov, Ivan; Sokolov, Alexei P. et al.
System: The UNT Digital Library
Tribocatalytically-active nickel/cobalt phosphorous films for universal protection in a hydrocarbon-rich environment (open access)

Tribocatalytically-active nickel/cobalt phosphorous films for universal protection in a hydrocarbon-rich environment

Article describes how high-contact stresses generated at the sliding interfaces during their relative movement provide a unique combination of local heating and shear- and load-induced compression conditions. The authors of the article employ the electrodeposition process to design a coating composed of a hard cobalt-phosphorous matrix with the inclusion of tribocatalytically-active nickel clusters.
Date: July 5, 2023
Creator: Shirani, Asghar; Al Sulaimi, Rawan; Macknojia, Ali Zayaan; Eskandari, Mohammad & Berman, Diana
System: The UNT Digital Library
MXene/graphene oxide nanocomposites for friction and wear reduction of rough steel surfaces (open access)

MXene/graphene oxide nanocomposites for friction and wear reduction of rough steel surfaces

Article describes how development of solid lubricant materials that render reliable performance in ambient conditions, are amenable to industrial size and design complexities, and work on engineered surfaces is reported. This report presents the holistic exploration and correlation of structure-property-processing pertaining to the advancement of solid lubrication science.
Date: July 8, 2023
Creator: Macknojia, Ali Zayaan; Ayyagari, Aditya; Shevchenko, Elena V. & Berman, Diana
System: The UNT Digital Library
Highly Pseudocapacitive Storage Design Principles of Heteroatom-Doped Graphene anode in Calcium-Ion Batteries (open access)

Highly Pseudocapacitive Storage Design Principles of Heteroatom-Doped Graphene anode in Calcium-Ion Batteries

Article describes how pseudocapacitive storage of multivalent ions, especially Ca2+, in heteroatom-doped carbon nanomaterials is promising to achieve both high energy and power densities, but there is the lack of pseudocapacitive theories that enable rational design of the materials for calcium-ion batteries.
Date: August 22, 2023
Creator: Gao, Yong; Li, Zhenglong; Weng, Pan; Cui, Wengang; Wang, Xiaowei; Yang, Yaxiong et al.
System: The UNT Digital Library