Article argues that traditional acidic oxygen evolution reaction (OER) electrocatalysts are more prone to be oxidized and corroded as results of unstable carrier structures and variable electronic states of active species, so a high-performing biochar aerogel (BA) based electrocatalyst was realistically designed and synthetized via joint utilization of the terrestrial lignin and seaweed polysaccharide as carbon sources. This work puts forward a novel and effective strategy towards the enhancement of the acidic OER process by rational regulations of the BA and the coupling effect in micro-interface.