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Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe4S4 surrogates
Article prepares and characterizes a small series of new [FeFe]-ase biomimics which contain a ferrocenyl diphosphine as a surrogate for the Fe₄S₄ moiety in the H-cluster of the enzyme. Mechanistic details of both proton reduction and H₂ oxidation have been studied by DFT allowing speculative reaction schemes to be developed.
Date:
June 6, 2022
Creator:
Orton, Georgia R. F.; Ghosh, Shishir; Alker, Lucy; Sarker, Jagodish C.; Pugh, David; Richmond, Michael G. et al.
System:
The UNT Digital Library
Correction: Systematic review on the current state of disaster preparation Simulation Exercise (SimEx)
This is a correction to an article. The original article contained an error in author spelling, which has since been amended.
Date:
June 6, 2023
Creator:
Mahdi, Syed Sarosh; Jafri, Hafsa Abrar; Allana, Raheel; Battineni, Gopi; Khawaja, Mariam; Sakina, Syeda et al.
System:
The UNT Digital Library
Exploring Changes in Quasar Spectral Energy Distributions across C iv Parameter Space
This article examines the UV/X-ray properties of 1378 quasars in order to link empirical correlations to theoretical models of the physical mechanisms dominating quasars as a function of mass and accretion rate.
Date:
June 6, 2022
Creator:
Rivera, Angelica B.; Richards, Gordon T.; Gallagher, Sarah C.; McCaffrey, Trevor V.; Rankine, Amy L.; Hewett, Paul C. et al.
System:
The UNT Digital Library
Histological features of non-alcoholic fatty liver disease revealed in response to mixed vehicle emission exposure and consumption of a high-fat diet in wildtype C57Bl/6 male mice
Article describes how non-alcoholic fatty liver disease (NAFLD) is currently plaguing the population at pandemic proportions and is expected to become more prevalent over the next decade. The authors investigated the hypothesis that exposure to a mixture of gasoline and diesel engine emissions (MVE), coupled with the concurrent consumption of a HF diet, promotes the development of a NAFLD phenotype within the liver.
Date:
June 6, 2023
Creator:
Schneider, Leah J.; Santiago, Isabella; Johnson, Bailee; Stanley, Analana Hays; Penaredondo, Bea & Lund, Amie K.
System:
The UNT Digital Library
Underlying factors determining grain morphologies in high-strength titanium alloys processed by additive manufacturing
Article describes how, in recent research, additions of solute to Ti and some Ti-based alloys have been employed to produce equiaxed microstructures when processing these materials using additive manufacturing. The present study develops a computational scheme for guiding the selection of such alloying additions, and the minimum amounts required, to effect the columnar to equiaxed microstructural transitions.
Date:
June 6, 2023
Creator:
Nartu, Mohan S. K. K. Y.; Welk, Brian A.; Mantri, Srinivas Aditya; Taylor, Nevin L.; Viswanathan, Gopal B.; Dahotre, Narendra B. et al.
System:
The UNT Digital Library