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Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe4S4 surrogates
Article prepares and characterizes a small series of new [FeFe]-ase biomimics which contain a ferrocenyl diphosphine as a surrogate for the Fe₄S₄ moiety in the H-cluster of the enzyme. Mechanistic details of both proton reduction and H₂ oxidation have been studied by DFT allowing speculative reaction schemes to be developed.
Date:
June 6, 2022
Creator:
Orton, Georgia R. F.; Ghosh, Shishir; Alker, Lucy; Sarker, Jagodish C.; Pugh, David; Richmond, Michael G. et al.
System:
The UNT Digital Library
Exploring Changes in Quasar Spectral Energy Distributions across C iv Parameter Space
This article examines the UV/X-ray properties of 1378 quasars in order to link empirical correlations to theoretical models of the physical mechanisms dominating quasars as a function of mass and accretion rate.
Date:
June 6, 2022
Creator:
Rivera, Angelica B.; Richards, Gordon T.; Gallagher, Sarah C.; McCaffrey, Trevor V.; Rankine, Amy L.; Hewett, Paul C. et al.
System:
The UNT Digital Library