The Isotope Shift of the Uranium Ka1 X Ray (open access)

The Isotope Shift of the Uranium Ka1 X Ray

Technical report. From Introduction : "The nuclear volume dependent isotope shift of optical spectral lines has long been a very useful means for studying the changes in the nuclear size or shape for different isotopes of heavy elements."
Date: June 25, 1964
Creator: Brockmeier, R.; Boehm, F. & Hatch, E. N.
System: The UNT Digital Library
An Experimental Approach to a Simplified Band Structure of the Rare Earth Metals (open access)

An Experimental Approach to a Simplified Band Structure of the Rare Earth Metals

Technical report. From Abstract : "A number of the physical properties from which we can obtain both direct and indirect information concerning the band structures of metals, have been measured for most of the rare earth metals. It was thought that it would be desirable to review ans examine these data and try to tie them together. For this purpose the very low and room temperature heat capacities, Hall coefficients, magnetic susceptibilities, spectral data and electrical resistivities were examined."
Date: February 1, 1964
Creator: Gschneider, Karl A., Jr.
System: The UNT Digital Library
The Y-Nd and Sc-Nd Phase Systems (open access)

The Y-Nd and Sc-Nd Phase Systems

Technical report. From Introduction : "In a recent study by Spedding, et al. on some rare earth alloy systems, an intermediate phase was found to form when a light rare earth (ABAC stacking) was alloyed with a heavy rare earth (ABAC stacking). This intermediate phase was found to have the structure of samarium metal with the stacking ABABCBCAC and was designated "delta". Since the cause of this rather unusual structure occurring in either samarium metal or these alloys is not known the study of these phases as some of their properties is continuing in the Ames Laboratory. It was the purpose of the present study to extend our knowledge of the composition and more of formation of these phases."
Date: February 1964
Creator: Beaudry, B. J.; Michel, M.; Daane, A. H. & Spedding, F. H.
System: The UNT Digital Library
Rare Earth Intermetallic Comounds (open access)

Rare Earth Intermetallic Comounds

From Abstract : "Some of the important properties of the rare earth intermetallic and semimetallic compounds are reviewed. ... A compilation of the crystal structures of these compounds is appended to this review."
Date: 1964
Creator: McMasters, O. D. & Gschneidner, K. A., Jr.
System: The UNT Digital Library
The Treatment of a Cesium Ore by Sulfur Chloride and Chlorine (open access)

The Treatment of a Cesium Ore by Sulfur Chloride and Chlorine

From Abstract : "A Southern Rhodesian cesium ore containing essentially pollucite was chlorinated by a gaseous mixture of sulfur chloride and chlorine at temperatures between 550 and 770°C. The optimum conditions with the fixed bed reactor used in this study were chlorination at 650°C for 4 1/2 hr with an more particle size that passes a 150 mesh sieve."
Date: 1964
Creator: Hamilton, C. B.; Young, T. L. & Wilhelm, H. A.
System: The UNT Digital Library
Tricarbalyllic Acid (Propane-1, 2, 3-Tricarboxylic Acid) (open access)

Tricarbalyllic Acid (Propane-1, 2, 3-Tricarboxylic Acid)

From report : "Tricarbalyllic acid (propane-1, 2, 3-tricarboxylic acid) has a structure similar to that of citric acid, except that it lacks the hydroxyl group attached to the middle of the carbon atom. Properties of the rare earth citrates have been used very successfully in the separation of rare earths by ion exchange methods; consequently it was deemed advisable to study the rare-earth compounds which form with the anion if triarbalyllic acid."
Date: 1964
Creator: Gupta, A. K. & Powell, J. E.
System: The UNT Digital Library
Process Simulation on a Digital Computer Using Analog Methods (open access)

Process Simulation on a Digital Computer Using Analog Methods

Technical report. From Abstract : "A system has been developed to program a digital computer in much the same manner as an analog computer is programmed. Properties of a general purpose analog computer and a digital differential analyzer are combined to yield a program which employs, as input, standard data cards prepared from a diagram analogous to an analog computer diagram. The capacity of the system is much greater than that of most analog computers, making it applicable to large simulation problems. No scaling is required. The system is compatible with the Fortran symbolic language and may be used as part of a larger digital computer program. It may be applied to the more general types of boundary value problems arising in process simulation in addition to the initial value problems ordinarily solved on analog computers. It is particularly well adapted to non-linear problems and to control problems involving large transport delays. The program operates in basic machine language and, when used by itself, requires no compilation time."
Date: July 10, 1963
Creator: Farris, George J. & Burkhart, Lawrence E.
System: The UNT Digital Library
Mass Systematics Involving Low-Lying Excited States (open access)

Mass Systematics Involving Low-Lying Excited States

Technical report. From Abstract : "A step phenomenon in the nuclidic mass excess surface associated with magic numbers N, Z = 8 and 20 is shown to exist, whereas only breaks occur at higher magic numbers. Excited states are included which reveals possible smooth trends within Shell-Model subshells."
Date: July 3, 1963
Creator: Everling, F.
System: The UNT Digital Library
Pressure-Volume-Temperature Measurements on Solids (open access)

Pressure-Volume-Temperature Measurements on Solids

From abstract: "The results of recent measurements on the equations of state of sodium and xenon are discussed. The experimental data for each of these are analyzed to show that the isothermal compressibility is solely a function of volume within experimental accuracy. The basic differences between the low temperature PV relationships for sodium and xenon are shown to be easily understandable in terms of the elementary theories of these substances. The range of experimental pressures (to 20 kbars) and temperatures (20°K to the triple point) is sufficiently great so as to produce significant changes in the lattice thermal properties in each case. These changes are indicated through the use of zero pressure heat capacity data in combination with the equation of state data to calculate the volume and temperature dependence of the Debye Θ. The result is quite spectacular for xenon, where a pressure of 20 kbars roughly doubles ΘD."
Date: May 14, 1963
Creator: Swenson, C. A.
System: The UNT Digital Library
Spectrophotometric Determination of Perchlorate (open access)

Spectrophotometric Determination of Perchlorate

Technical report. Form Abstract : "Perchlorate is extracted from aqueous solution by n-butyronitrile as ferrous 1,10-phenanthroline perchlorate. The amount of perchlorate is calculated from spectrophotometric measurement of the absorbance of the extract. Moderate to large amounts of chloride, sulfate, or nitrate cause little or no interference. Chlorate is slightly extracted but the interference can be corrected."
Date: May 10, 1963
Creator: Fritz, James S. & Campbell, Patricia A.
System: The UNT Digital Library
Trimethyllactamide (open access)

Trimethyllactamide

Technical report. From "3. Methods of Preparation" : "Pivadehyde cyanohydrin can be prepared by the reaction of pivadehyde with anhydrous HCN2 or by the sodium bisulfite process. Trimethyllactamide can be prepared by hydrolysis of pivaldehyde cyanohydrin with cold concentrated sulfuric acid. The procedure described here differs in the scale of preparation an in the use of cold fusing hydrochloric acid for hydrolizing the cyanohydrin."
Date: May 9, 1963
Creator: Powell, Jack E.
System: The UNT Digital Library
Chemical Binding in the Water Molecule (open access)

Chemical Binding in the Water Molecule

From Introduction : "This analysis partitions the electron density and the electronic pair density of the molecule into components corresponding promoted atomic states, to quasiclassical coulombic interactions of these promoted states, and to interactions resulting from the sharing of electrons between atoms."
Date: May 3, 1963
Creator: Edmiston, Clyde & Ruedenberg, Klaus, 1920-
System: The UNT Digital Library
Mass Spectrometric Evidence for the Pyridoxal-Leucine Reaction Mechanism (open access)

Mass Spectrometric Evidence for the Pyridoxal-Leucine Reaction Mechanism

From Abstract : "The mass spectrum of leucine-dn, prepared by the reaction of pyridoxal with excess leucine in D2O medium, has been established using the crucible source techniques. ... The reaction can be used for the selective α, β-deuteration of amino acids other than leucine.
Date: May 3, 1963
Creator: Junk, G. A. & Svec, H. J.
System: The UNT Digital Library
Normal Elliptic Integrals of the First and Second Kinds (open access)

Normal Elliptic Integrals of the First and Second Kinds

From Introduction : "In this paper we describe a choice of normal elliptic integrals which appears to be very well suited for use in integral tables as well as for numerical work."
Date: May 3, 1963
Creator: Carlson, B. C.
System: The UNT Digital Library
Reinvestigation of the CC Stretching and CH3 Rocking Assignments In Isopropyl and tert-Butyl Halides (open access)

Reinvestigation of the CC Stretching and CH3 Rocking Assignments In Isopropyl and tert-Butyl Halides

From report: "In a series of paper (1-3) Sheppard has analyzed the vibrational spectra of simple alkyl halides. During the course of an investigation of the spectra of similar alkyl thiocyanates certain anomalies appeared in the assignments of the CC stretching and methyl rocking vibrations in isopropyl and tert.-butyl halides."
Date: May 3, 1963
Creator: Hirschmann, R. P. & Kniseley, R. N.
System: The UNT Digital Library
The Inference of Adsorption from Differential Double Layer Capacitance Measurements (open access)

The Inference of Adsorption from Differential Double Layer Capacitance Measurements

From Abstract : "Dependence of boundary tension and capacitance at the mercury-aqueous 0.1 N HClO4 interface on polarization and organic solute concentration were determined for the colutes n-amyl alcohol and phenol. ... An earlier treatment proposed by this Laboratory based on a (non-thermodynamic) assumption of linear variation of surface charge density with coverage appears adequately justified for inference of fractional surface coverages near the electrocapillary maximum, but must be considered approximate for evaluation of molar area at full coverage in cases where linear variation of charge with coverage has not been demonstrated."
Date: April 26, 1963
Creator: Hansen, Robert S.; Kelsh, Dennis J. & Grantham, D. H.
System: The UNT Digital Library
Measurement of Thermal Properties by the Arc Image Furnace (open access)

Measurement of Thermal Properties by the Arc Image Furnace

Technical report. From Abstract : "A number of imaging furnace systems and sources are discussed with emphasis on the carbon arc image furnace. Several potential applications of the carbon arc image furnace in high temperature research are described and a new method of heat capacity determination is discussed."
Date: April 16, 1963
Creator: McMahon, W. R. & Wilder, D. R.
System: The UNT Digital Library
Design and Test of a Diaphragm Pump for Liquid Metals (open access)

Design and Test of a Diaphragm Pump for Liquid Metals

Technical report. From Abstract : "Details are provided on the construction and operation of a two-stage diaphragm pump successfully used for the first time in liquid metal service. From the results of 5,376 hr. test of the pump it was concluded that it is well suited to the pumping of liquid metals at low flow rates where pulsating flow can be tolerated and also where remote operation is required. Operating temperatures and pressures are limited only by the availability of suitable materials of construction."
Date: April 12, 1963
Creator: Westerheide, D. E. & Clifford, J. C.
System: The UNT Digital Library
High Purity Calcium (open access)

High Purity Calcium

Technical report. From Introduction : "For more than a century, methods employed in preparing calcium were based largely on electrowinning and the most successful were based on [Sir Humphrey] Davy's process. ... In general, the metal was of adequate quality for the industrial applications of the time, and although by 1940 some strides had been made in the purification of calcium, interests in the better grades of the metal were limited essentially to experimental work of academic concern."
Date: April 3, 1963
Creator: Wilhelm, H. A. & Carlson, O. N.
System: The UNT Digital Library
Crystalline Field Splittings in Holmium and Dysprosium Ethylsulfates (open access)

Crystalline Field Splittings in Holmium and Dysprosium Ethylsulfates

From report : "It has become apparent that pragmatic resonance data alone are insufficient to correctly evaluate crystal field parameters for rare-earth ethylsulfates, and that heat capacity data above 20°K are a useful aid in determining whether low lying levels obtained by absorption spectroscopy have been correctly identified."
Date: March 1963
Creator: Spedding, F. H.; Gerstein, B. C.; Haas, W. J.; Phillips, E. & Sutherland, W. L.
System: The UNT Digital Library
High Pressure Research at Low Temperatures (open access)

High Pressure Research at Low Temperatures

Two principle reasons exist for the extension of high pressure research to temperatures near absolute zero. First, the comparison of certain data with theory (such as the pressure-volume relationship) is more meaningful if the effects of thermal vibrations can be ignored. Second, there are phenomena which can be studied only at low temperatures. These include superconductivity, the properties of solid helium and other inert gases, some electronic phenomena, etc.
Date: February 24, 1963
Creator: Swenson, C. A.
System: The UNT Digital Library
Complex Systems of the Rare Earth Metals With Glycolate, Lactate, and α-Hydroxyisobutyrate Ligands (open access)

Complex Systems of the Rare Earth Metals With Glycolate, Lactate, and α-Hydroxyisobutyrate Ligands

From Abstract : "The solubilities of the individual rare earth lactates and α-hysroxyisobutyrates in water at 20 and 60° were determined for comparison with the rare earth glycolate solubilities determined earlier."
Date: February 21, 1963
Creator: Powell, J. E.; Karraker, R. H.; Kolat, R. S. & Farrell, J. L.
System: The UNT Digital Library
The Strontium-Strontium Hydride Phase System (open access)

The Strontium-Strontium Hydride Phase System

Technical report. From Abstract : "The Sr-SrH2 phase diagram was studied by thermal analysis, chemical analysis of equilibrated phases and X-ray diffraction. The maximum solubility of SrH2 in strontium metal is 38 mole % at the peritectic temperature of 880°C. Strontium metal undergoes an allotropic transformation at 555°C and melts at 768°C. A second transformation was found, at about 240°C, in samples containing hydrogen. Strontium hydride was found to have an allotropic transformation at 855°C."
Date: February 20, 1963
Creator: Peterson, D. T. & Colburn, R. P.
System: The UNT Digital Library
Gamma Ray Efficiencies for Well Type Scintillation Crystals (open access)

Gamma Ray Efficiencies for Well Type Scintillation Crystals

From Abstract : "Gamma ray efficiencies for various sized well type NaI(Ti) crystals have been calculated using an IBM 704 digital computer. The adjustable parameters in the program are the gamma ray energy, the heights and diameters of the crystal and the well, the thickness of the well lining, and the positions of the (point) source inside the well. Some typical results are presented in graphical form."
Date: February 8, 1963
Creator: Dingus, Ronald S. & Stewart, M. G.
System: The UNT Digital Library