Electron Requirements of Bonds in Metal Borides (open access)

Electron Requirements of Bonds in Metal Borides

From abstract: "Electrical measurements have been made on CaB6, SrB6, BaB6, YB2, YB4, YB6, and YB12 for the purpose of testing models of the electronic structure of the boron atoms in the four boride types represented. The compounds CaB6, SrB6, and BaB6 were found to be semiconductors. The Hall coefficients of YB4 was also measured, but could not be interpreted because the free electron theory does not provide a theoretical value for comparison with experiment. The results are in agreement with the models proposed."
Date: May 28, 1962
Creator: Johnson, Robert W. & Daane, A. H. (Adrian Hill), 1919-
System: The UNT Digital Library
Some Observations Regarding Rare-Earth Lactates (open access)

Some Observations Regarding Rare-Earth Lactates

From abstract: "Lactates of all the rare earths except lanthanum, cerium, and praseodymium were prepared and studied. In the case of lanthanum, cerium, and praseodymium the lactates are apparently so soluble that they cannot be crystallized directly from aqueous solution. Products obtained by addition of anhydrous ethanol to sirupy solutions of the light-rare-earth lactates were not well characterized and were deliquescent. Neodymium lactate trihydrate was prepared only by the addition of alcohol to a sirupy solution. Since it was not as deliquescent as the lactates of lanthanum, cerium, and praseodymium, some of its properties could be studied. The lactates of all the other rare earths, samarium through lutetium, as well as the lactate of yttrium, separated readily from aqueous media as trihydrates--the solubility of the hydrated lactate decreasing as the atomic number of the rare earth increased. Thermal decomposition of the crystalline lactates, except those of neodymium and samarium, proceeded through dihydrated and anhydrous states to a composition corresponding roughly to LnlacCO3 at a temperature of about 290-300°C. Ln2(CO3)3 or Ln2O(Co3)2 were observed. In order to make a comparison, thermal decomposition of the rare-earth glycolates was studied also. Solubilities in water at both 20 and 60°C have been tabulated."
Date: March 28, 1962
Creator: Powell, J. E. & Farrell, J. L.
System: The UNT Digital Library