Report containing ongoing projects and experiments undertaken by the Oak Ridge National Laboratory's Molten-Salt Reactor Program.

This is the third quarterly report on the work done under Contract AT(04-30-189, Project Agreement No.27, and covers the period August 12 to November 12, 1962.

Quarterly report describing the progress and development of improved zirconium alloys for service in superheated water and steam. This report covers the period between July 1 to September 30, 1962 and was conducted by the United States and the European Atomic Energy Community (EURATOM).

This is the second quarterly report on the work done under Contract AT(04-3)-189, Project Agreement No. 27. The results reported here have to do primarily with the loss in a rectangular (1/2" x 1-3/4") channel in the horizontal orientation, without contraction-expansion inserts.

"Short-range order coefficients were measured at 300 and 400°C for iron-aluminum alloys containing 14.8, 18.2, and 20.0 atomic per cent aluminum. These alloys exhibited a strong preference for unlike near neighbors. The short-range order was greater at the lower temperature and increased as the Fe 3Al composition was approached."

From Introduction: "The recent acceptance by physicists and chemists of new values for the fundamental constants and the continued demand for expanded and convenient tables prompted the recomputation and preparation of this volume. The authors have tried to incorporate this work a number of the more desirable features of the above-cited works, particularly with respect to their use in calculations involving: Thermodynamic properties of gases; specific heats, electrical and thermal conductivity of solids; and molecular structure and spectroscopy of diatomic and polyatomic molecules. It is the hope of the authors that formal character of this publication will insure a more adequate notice and dissemination than was accorded the earlier works, thereaby reducing the probability of still further duplication of effort."

"Theoretical calculations have been carried our for the two ordering phases which occur in the FeAl system. The statistical treatment involves first and second neighbor interaction parameters as well as a magnetic interaction between first neighbor iron atoms. The phase diagram and the amount and type of long range order for slowly cooled alloys are calculated. Further calculations include short range order for the disordered phase at three compositions and two temperatures. As expected, the short range order increases as a critical temperature is approached either in composition of in temperature."

From abstract: "The preparation of pure molybdenum(IV) bromide was accomplished conveniently by the reaction between molybdenum(III) bromide and liquid bromine at ca. 55°. Molybdenum(IV) bromide was found to be soluble in liquid bromine, and this property was utilized to separate and purify the molybdenum(IV) bromide. The solution of MoBr4 in bromine was a poor electrical conductor. No evidence was found for the formation of MoBr4 from MoBr3 and bromine vapor at 2-4 atm. and temperatures from 180 to 400°. However, MoBr4 was completely decomposed at 110-130°, in vacuo, with formation of MoBr3 and bromine."

A code (RAPTURE) was programmed for the Philco TRANSAC 2000 computer to perform calculations needed for the evaluation of Doppler Coefficients in fast reactors with degraded neuron spectra. This code computes resonance integrals, averages them over resonance parameter distributions, and computes fission and capture cross sections as a function of fuel temperature and of potential scattering cross section per absorber isotope.

From Abstract: "The results of an investigation of lightweight, precast cellular concrete planks are given. Fire tests were made of two floor and five roof specimens made up of these planks. Variables, included density of the cellular concrete, thickness and span of the planks, reinforcement, and cover for the latter."

From abstract: Seismic waves resulting from a 5 kiloton nuclear detonation 1200 feet deep in a salt bed near Carlsbad, New Mexico were measured by strong-motion seismographs operated by the Coast and Geodetic Survey on the surface in the distance range from 0.5 to 8.8 miles and underground in a potash mine 8.7 to 11.2 miles distant.

Abstract: This technical report summarizes the results of research and development tasks performed during Phase I of this contract and presents recommendations for future development work. Work is reported in the areas of plant assembly and relocation, housings and footings, waste heat dissipation, instrumentation, refueling systems, waste disposal, shielding, core nuclear thermal and hydraulic studies, gaseous waste processing (BWR), and critical experiments on a 5 x 5 array of Type 3 fuel elements.

Quarterly report describing the progress and development of improved zirconium alloys for service in superheated water and steam. This report covers the period between October 1 to December 31, 1961 and was conducted by the United States and the European Atomic Energy Community (EURATOM).