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This report summarizes the well installation activities conducted during the federal fiscal year (FY) 1994 drilling program at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. Synopses of monitoring well construction/well development data, well location rationale, geological/hydrological observations, quality assurance/quality control methods, and health and safety monitoring are included. Two monitoring wells were installed and one piezometer installation was attempted, but not completed, during the FY 1994 drilling program. In addition, SAIC provided health and safety and geotechnical oversight for two soil borings in support of the Y-12 Underground Storage Tank (UST) Program. All new monitoring wells were developed by either a 2.0-in. diameter swab rig or by hand bailing until nonspecific indicator parameters (pH and specific conductance) attained steady-state levels. Turbidity levels were lowered, if required, to the extent practicable by continued development beyond a steady-state level of pH and conductance. All well installation was conducted following industry-standard methods and approved procedures in the Environment Surveillance Procedures Quality Control Program (Energy Systems 1988), the Resource Conservation and Recovery Act (RCRA) Groundwater Monitoring Technical Enforcement Guidance Document (EPA 1986), and Guidelines for Installation of Monitor Wells at the Y-12 Plant (Geraghty and Miller 1985). Health and safety monitoring and field …

Calcine dissolution studies were performed in FY-94,95 in order to extend the knowledge of dissolution and to obtain information necessary for scale-up design and operation. Experiments reported in this document were performed with non-radioactive and actual calcines to generate qualitative data regarding: (a) calcine dissolution rates, (b) undissolved solids settling characteristics, (c) undissolved solids heel formation, and (d) chemical treatments for undissolved solids heel dissolution. The goal of this work was to achieve complete calcine dissolution, or to determine conditions that would result in the maximum calcine dissolution. Small scale laboratory experiments (test-tube dissolutions) and a bench scale dissolver set-up were used in the effort. Results from this work show the bulk of the undissolved solids to settle at a rate of >9 inches per second when the baseline dissolution parameters are used. Baseline dissolution parameters were 100 grams of calcine being dissolved in 1 L of 5 M HNO{sub 3} at > 90 C while the solution is being vigorously and constantly mixed. This work also verified that dissolution is most complete when performed with aggressive mixing. Sequential dissolutions performed with non-radioactive and actual calcine indicate that little undissolved solids heel build-up is expected, and this small heel can …

In 1992, the mission of the Idaho Chemical Processing Plant was changed from reprocessing of spent nuclear fuels to development of technologies for conditioning of spent nuclear fuels and other high-level wastes for disposal in a geologic repository. In addition, the Department of Energy (DOE) directed Idaho National Engineering Laboratory (INEL) to develop a program plan addressing the management of radioactive contaminated scrap metal (RSM) within the DOE complex. Based on discussions with the EM-30 organization, the INEL Metal Recycle program plan was developed to address all issues of RSM management. Major options considered for RSM management were engineered interim storage, land disposal as low-level waste, and beneficial reuse/recycle. From its inception, the Metal Recycle program has emphasized avoidance of storage and disposal costs through beneficial reuse of RSM. The Metal Recycle program plan includes three major activities: Site-by-site inventory of RSM resources; validation of technologies for conversion of RSM to usable products; and identification of parties prepared to participate in development of a RSM recycle business.

This report provides a summary of work completed in FY-94 by FSU to develop and investigate the feasibility of using Raman spectroscopy with Hanford tank waste materials. Raman performance impacts from sample morphology, including the effects of absorption, particle size, density, color and refractive index, are discussed. An algorithm for relative species concentration measurement from Raman data is presented. An Algorithm for applying Raman to tank waste core screening is presented and discussed. A library of absorption and Raman spectra are presented that support this work.