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Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes
We are making progress on our investigation of the mechanism of olefin exchange with Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8}. We are probing this system by kinetic study of the reaction of Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8} with butyl acrylate (BA) under various pressures of ethylene.
Date:
May 1, 1992
Creator:
Norton, J.R.
System:
The UNT Digital Library
Diosmacycloalkanes as Models for the Formation of Hydrocarbons From Surface Methylenes. Progress Report, November 1, 1991--October 31, 1992
We are making progress on our investigation of the mechanism of olefin exchange with Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8}. We are probing this system by kinetic study of the reaction of Os{sub 2}(C{sub 2}H{sub 4})(CO){sub 8} with butyl acrylate (BA) under various pressures of ethylene.
Date:
May 1, 1992
Creator:
Norton, J. R.
System:
The UNT Digital Library
Diosmacycloalkanes as Models for the Formation of Hydrocarbons From Surface Methylenes. Progress Report, November 1, 1992--October 31, 1993
The report is divided into: vibrational models for surface ethylidenes (on catalyst surfaces); alpha vs beta hydrogen elimination in formation of propene from an osmacyclobutane; mechanism of formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; structure of Os(CO){sub 4}(C{sub 2}H{sub 4}), an osmacyclopropane; and reaction of {mu}-oxobis [(trifluoromethanesulfanato) (phenyl)iodine(III)] with Group 14 propargyl derivatives and a propargyl ether. 16 refs, figs.
Date:
May 1, 1993
Creator:
Norton, J. R.
System:
The UNT Digital Library
Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes
The report is divided into: vibrational models for surface ethylidenes (on catalyst surfaces); alpha vs beta hydrogen elimination in formation of propene from an osmacyclobutane; mechanism of formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; structure of Os(CO)[sub 4](C[sub 2]H[sub 4]), an osmacyclopropane; and reaction of [mu]-oxobis [(trifluoromethanesulfanato) (phenyl)iodine(III)] with Group 14 propargyl derivatives and a propargyl ether. 16 refs, figs.
Date:
May 1, 1993
Creator:
Norton, J.R.
System:
The UNT Digital Library