Rate constants for the aqueous oxidation of N-nitrosodimethylamine (NDMA) have been measured in aqueous phosphate-buffered solutions using Dickson-type vessels. The initial NDMA concentrations ranged from 2.5 to 2.8 ppm and reaction temperatures varied from 180 C to 220 C. Quantitation of NDMA was performed by gas chromatography-mass spectrometry (GC-MS) using selected ion monitoring (SIM). NDMA loss with concomitant production of nitrite and nitrate confirmed that mineralization of NDMA occurred, and no intermediates amenable to GC-MS were formed during the oxidation experiments. First order reaction rate constants for the loss of NDMA were determined by the integral method and the results are as follows: k{sub 1} = 5.21 x 10{sup -7} s{sup -1} at 180 C, k{sub 1} = 1.14 x 10{sup -6} s{sup -1} at 190 C, k{sub 1} = 2.05 x 10{sup -6} s{sup -1} at 200 C, k{sub 1} = 4.53 x 10{sup -6} s{sup -1} at 210 C and k{sub 1} = 8.81 x 10{sup -6} s{sup -1} at 220 C. The Arrhenius equation for this data is listed below: ln (k) = 20.21 - 15716 (1/T). The activation energy for this process is calculated to be 130.7 {+-} 3.5 kJ/mole. Extrapolating to a temperature of 125 …

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When DOE funds were exhausted in March 1995, all Phase 2 activities were placed on hold. In February 1996 a detailed cost estimate was submitted to the DOE for completing the two remaining Phase 2 Multi Annular Swirl Burner (MASB) topping combustor test campaigns; in August 1996 release was received from FETC to proceed with the two campaigns to: (1) test the MASB at proposed demonstration plant full to minimum load operating conditions; (2) identify the lower oxygen limit of the MASB; (3) demonstrate natural gas to carbonizer fuel gas switching; and (4) demonstrate operation with ''low temperature'' compressor discharge air rather than high temperature ({approx} 1600 F) vitiated air. The 18 in. MASB was last tested at the University of Tennessee Space Institute (UTSI) in a high-oxygen configuration and must be redesigned/modified for low oxygen operation. A second-generation PFB combustion plant incorporating an MASB based topping combustor has been proposed for construction at the City of Lakeland's McIntosh Power Plant under the U.S. DOE Clean Coal V Demonstration Plant Program. This plant will require the MASB to operate at oxygen levels that are lower than those previously tested. Preliminary calculations aimed at defining the operating envelope of the demonstration …

The purpose of this project was to complete the development of the laser systems and separator systems needed to investigate the potential for the economical separation of high value isotopes used in medical and industrial applications, then demonstrate this separation capability. The project was to focus on the isotopic purification of lead for use as solder in high- end electronics, and on the isotopic enrichment of thallium for medical applications. Ultimately the goal is to demonstrate the economical and technical viability of the technology for lead and thallium and to develop a more general capability for other possible isotope separation missions. Both lead and thallium are usefulapplications in this context because they require- dye lasers, solid- state lasers, and a frequency doubling capability of some of the lasers. This later capability allows access to the wavelength range 250 to 450 mn, with tunable, high- power and high repetition frequency lasers. Until recently, these wavelengths have been largely inaccessible in combination with these other laser characteristics. In addition, up to two new potential laser- isotope separation applications would be conceptually developed through a process of needs analysis and technical feasibility studies. Because of an unanticipated reduction in the size of the …

A new mold material has been developed for use in making rare-earth permanent magnet components with precise dimensions in the 10 to 1000 µm range by hot-forging. These molds are made from molds poly(methyl)methacrylate (PMMA) made by deep x-ray lithography (DXRL). An alumina bonded with colloidal silica has been developed for use in these molds. This material can be heated to 950°C without changing dimensions where it develops the strength needed to withstand the hot-fmging conditions (750°C, 100 MPa). In addition, it disintegrates in HF so that parts can be easily removed after forging.

This study confirms the feasibility of a natural gas fueled, 20 MW M-C Power integrated pressurized molten carbonate fuel cell combined in a topping cycle with a gas turbine generator plant. The high efficiency fossil power plant (HEFPP) concept has a 70% efficiency on a LHV basis. The study confirms the HEFPP has a cost advantage on a cost of electricity basis over the gas turbine based combined cycle plants in the 20 MW size range. The study also identifies the areas of further development required for the fuel cell, gas turbine generator, cathode blower, inverter, and power module vessel. The HEFPP concept offers an environmentally friendly power plant with minuscule emission levels when compared with the combined cycle power plant.

The NIF Power Conditioning System (PCS) is required to deliver -68 kJ to each of the 3840 flashlamp pairs in the NIF laser in a current pulse with a peak of -500 kA and rise time of- 150 µs. The PCS will consist of 192 modules each of which drive 20 lamp-pairs. Each module will basically be a 6 rnF capacitor bank with a nominal charge voltage of 23.5 kV which is switched by a single pressurized air gas switch to 20 RG-220 cables that are connected to individual lamp loads. In addition each module will have a number of subsystems including; a lamp pre-ionization system, power supplies, isolation circuits, trigger systems, safety dump systems, gas system, and an embedded control system. A module will also include components whose primary function is to limit fault currents and thus minimize collateral damage in faults. In the Prototype Development and Testing effort at Sandia National Laboratories all of these were integrated into a single system and proper fimctionality was demonstrated. Extensive testing was done at nominal operating levels into resistive dummy loads and some testing in fault modes was also done. A description of the system and a summary of testing is …

Specific recommendations are made to improve the lighting quality and energy efficiency of the lighting system at the Social Security Administration Frank Hagel Building in Richmond, CA. The main recommendation is to replace the recessed fluorescent lighting system in the general office area with indirect lighting. Indirect lighting will improve lighting quality, will provide an energy efficient solution and will be about the same cost as the direct lighting system originally proposed.

Scattered light at three-halves of the incident laser frequency from solid targets is observed at five different angles. When the incident laser intensity is low enough, rescattering of two plasmon decay (TPD) instability electron plasma waves by ion acoustic waves is not significant. In this regime, Thomson scattering measurements of the electron temperature and the plasma flow velocity allow quantitative comparison of the angular dependence of the spectrum to theory.

This Integrity Assessment Report (IAR) is prepared by Fluor Daniel Northwest (FDNW) for Waste Management Federal Services of Hanford, Inc., (WMH), the operations contractor; Fluor Daniel Hanford (FDH), the Hanford Site Manager; and the U. S. Department of Energy (DOE), the system owner. This IAR addresses the evaluation of Tanks 101 and 102 and other existing components located in the 219-S Waste Handling Facility. This report will be included in the Part B Permit for the 2226 Laboratory and is a portion of the integrity assessment of the overall 222-5 Laboratory radioactive liquid waste disposal system. This IAR is prepared in accordance with WAC 173-303, Dangerous Waste Regulations; Section 640(2), ''Assessment of Existing Tank Systems Integrity .''

Tank 241-C-104 has been identified as one of the first tanks to be retrieved for high-level waste pretreatment and immobilization. Retrieval of the tank waste will require dilution. Laboratory tests are needed to determine the amount of dilution required for safe retrieval and transfer of feed. The proposed laboratory tests are described in this document.

242-A Evaporator 99-1 will process approximately one million gallons of waste from tank 102-AW in June 1999. The process control Plan provides a general description of activities, which will occur during 242-A Evaporator Campaign 99-1 and to document analyses conducted to demonstrate that 102-AW waste is acceptable for processing. Predict is a registered trademark of Risk Decisions England Corporation, United Kingdom.

This supporting document delineates the process of identification, categorization, and/or classification of the WRAP facility drawings used to support facility operations and maintenance. This document provides a listing of those essential or safety related drawings which have been identified to date. All other WRAP facility drawings have been classified as general.

The Blend Down Monitoring System (BDMS) equipment sent earlier to the Ural Electrochemical Integrated Plant (UEIP) at Novouralsk, Russia, was installed and implemented successfully on February 2, 1999. The BDMS installation supports the highly enriched uranium (HEU) Transparency Implementation Program for material subject to monitoring under the HEU purchase agreement between the United States of America (USA) and the Russian Federation (RF). The BDMS consists of the Oak Ridge National Laboratory (ORNL) Fissile (uranium-235) Mass Flow Monitor (FMFM) and the Los Alamos National Laboratory (LANL) Enrichment Monitor (EM). Two BDMS�s for monitoring the Main and Reserve HEU blending process lines were installed at UEIP. Independent operation of the FMFM Main and FMFM Reserve was successfully demonstrated for monitoring the fissile mass flow as well as the traceability of HEU to the product low enriched uranium. The FMFM systems failed when both systems were activated during the calibration phase due to a synchronization problem between the systems. This operational failure was caused by the presence of strong electromagnetic interference (EMI) in the blend point. The source-modulator shutter motion of the two FMFM systems was not being properly synchronized because of EMI producing a spurious signal on the synchronization cable connecting the …

High resolution 2D imaging experiment on the saturated 18.9 nm Ni-like soft X-ray laser is presented. The imaging experiment allows measurement of the absolute output energy and intensity of the X-ray laser, while it gives detailed information on the spatial characteristics of the X-ray laser for understanding the physics and further improving the performance of the X-ray laser.

Pressure vessel and piping systems are widely used throughout industry and research laboratories and contain a very large concentration of energy, and yet, despite the fact that their design and installation comply with federal, state and local regulations and recognized industrial standards, there continue to be serious pressure equipment failures. There are many reasons for pressure equipment failure: degradation and thinning of materials with usage, aging, hidden flaws during fabrication, etc. Fortunately, periodic testing and internal and external inspections significantly improve the safety of a pressure vessel or facility. A good testing and inspection program is based on development of procedures for specific industries or types of vessels. This paper describes the elements that should be a part of a pressure testing safety program and the requirements that it should address. The program should comply with pressure safety standards and include the requirements for inspecting pressure vessels, establishing and implementing a written pressure system test work permit, maintaining safety in the testing area, developing in-place pressure testing procedures, keeping records for pressure test calculations and results, and evaluating the system's internal and external integrity.

The authors have designed, built and operated two vacuum systems for the RFQ (Radio Frequency Quadrupole) in the APT/LEDA (Accelerator Production of Tritium/Low Energy Demonstration Accelerator)linac: a cryopump system for the RFQ cavity and a non-evaporable getter (NEG) pump system for the RF window system. They were designed to provide very high hydrogen pump speed (> 2 x 10{sup 4} L/s) and sorption capacity. Both systems underwent performance tests in mock assembly before the installation. This paper presents the mock test results of both vacuum systems. It also discusses the preliminary test results from the commissioning of the APT/LEDA RFQ.

Agreements between the governments of the US and the Russian Federation for the US purchase of low enriched uranium (LEU) derived from highly enriched uranium (HEU) from dismantled Russian nuclear weapons calls for the establishment of transparency measures to provide confidence that nuclear nonproliferation goals are being met. To meet these transparency goals, the agreements call for the installation of nonintrusive US instruments to monitor the down blending of HEU to LEU. The Blend Down Monitoring System (BDMS) has been jointly developed by the Los Alamos National Laboratory (LANL) and the Oak Ridge National Laboratory (ORNL) to continuously monitor {sup 235}U enrichments and mass flow rates at Russian blending facilities. Prior to its installation in Russian facilities, the BDMS was installed and operated in a UF{sub 6} flow loop in the Paducah Gaseous Diffusion Plant simulating flow and enrichment conditions expected in a typical down-blending facility. A Russian delegation to the US witnessed the equipment demonstration in June, 1998. To conduct the demonstration in the Paducah Gaseous Diffusion Plant (PGDP), the BDMS was required to meet stringent Nuclear Regulatory Commission licensing, safety and operational requirements. The Paducah demonstration was an important milestone in achieving the operational certification for the BDMS …

The Oak Ridge National Laboratory (ORNL) Fissile Mass Flow Monitor (FMFM) was deployed at the Ural Electrochemical Integrated Plant (UEIP) highly enriched uranium (HEU) blending facility in January and February 1999 at Novouralsk in Russia for the DOE HEU Transparency Program. The FMFM provides unattended monitoring of the fissile mass flow of the uranium hexafluoride (UF{sub 6}) gas in the process lines of HEU, the low enriched uranium (LEU) blend stock, and the product LEU (P-LEU) of the blending tee non-intrusively. To do this, uranium-235 (U-235) fissions are induced in the UF{sub 6} by a thermalized and modulated californium-252 (Cf-252) neutron source placed on each process line. A set of detectors, located downstream of source, measure delayed gamma rays emitted by the resulting fission fragments. The observed delay in the time correlated measurement between the source and the detector signal provides the velocity of UF{sub 6} and its amplitude is related to the U- 235 content in UF{sub 6}. An on-line computer controls the source modulator, processes the collected detector data, and displays the results. The UEIP Main and the Reserved process lines were implemented with minor modifications. The FMFM monitors the HEU blending operation by measuring UF{sub 6} flows …

The objective of this analysis is to identify and review potential options for processing and disposing of the secondary low-level waste (LLW) that will be generated through operation of the Monitored Geologic Repository (MGR). An estimate of annual secondary LLW is generated utilizing the mechanism established in ''Secondary Waste Treatment Analysis'' (Reference 8.1) and ''Secondary Low-Level Waste Generation Rate Analysis'' (Reference 8.5). The secondary LLW quantities are based on the spent fuel and high-level waste (HLW) arrival schedule as defined in the ''Controlled Design Assumptions Document'' (CDA) (Reference 8.6). This analysis presents estimates of the quantities of LLW in its various forms. A review of applicable laws, codes, and standards is discussed, and a synopsis of those applicable laws, codes, and standards and their impacts on potential processing and disposal options is presented. The analysis identifies viable processing/disposal options in light of the existing laws, codes, and standards, and then evaluates these options in regard to: (1) Process and equipment requirements; (2) LLW disposal volumes; and (3) Facility requirements.

This document describes the method used to test design criteria for Safety Class, Intrinsically Safe leak detector system installed in 241-AN-A Valve Pit located at 200E Tank Farms. The purpose of this Procedure is to demonstrate that the pit leak detection relay cabinet and intrinsically safe probe circuit is fully operable.

This manual was prepared to provide detailed information for the operation and maintenance of the sanitary wastewater holding system. This procedure sets forth system operations which include type and frequency of required maintenance as well as system failure response procedures. The system consists of a sanitary sewage holding tank, two alarms and appurtenances necessary to provide a functional system. The maximum daily design flow is 696 liters. The holding tank is located as shown on the site plan.

This Engineering Task Plan (ETP) describes the activities associated with the installation of the corrosion probe assembly into riser WST-RISER-016 (formerly 15B) of tank 241-AN-105. The corrosion monitoring system utilizes the technique of electrochemical noise (EN) for monitoring waste tank corrosion. Typically, EN consists of low frequency (4 Hz) and small amplitude signals that are spontaneously generated by electrochemical reactions occurring at corroding or other surfaces. EN analysis is well suited for monitoring and identifying the onset of localized corrosion, and for measuring uniform corrosion rates. A typical EN based corrosion-monitoring system measures instantaneous fluctuations in corrosion current and potential between three nominally identical electrodes of the material of interest immersed in the environment of interest. Time-dependent fluctuations in corrosion current are described by electrochemical current noise, and time-dependent fluctuations of corrosion potential are described by electrochemical noise. The corrosion monitoring system is designed to detect the onset of localized corrosion phenomena if tank conditions should change to allow these phenomena to occur. In addition to the EN technique, the system also facilitates the use of the Linear Polarization Resistance (LPR) technique to collect uniform corrosion rate information. LPR measures the linearity at the origin of the polarization curve for …