ANALYTICAL RESULTS OF MOX COLEMANITE CONCRETE SAMPLE PBC-44.2 (open access)

ANALYTICAL RESULTS OF MOX COLEMANITE CONCRETE SAMPLE PBC-44.2

The Mixed Oxide Fuel Fabrication Facility (MFFF) will use colemanite bearing concrete neutron absorber panels credited with attenuating neutron flux in the criticality design analyses and shielding operators from radiation. The Savannah River National Laboratory is tasked with measuring the total density, partial hydrogen density, and partial boron density of the colemanite concrete. Sample PBC-44.2 was received on 9/20/2012 and analyzed. The average total density measured by the ASTM method C 642 was 2.03 g/cm{sup 3}, within the lower bound of 1.88 g/cm3. The average partial hydrogen density was 6.64E-02 g/cm{sup 3} as measured using method ASTM E 1311 and met the lower bound of 6.04E-02 g/cm{sup 3}. The average measured partial boron density was 1.70E-01 g/cm{sup 3} which met the lower bound of 1.65E-01 g/cm{sup 3} measured by the ASTM C 1301 method.
Date: December 20, 2012
Creator: Best, D.; Cozzi, A. & Reigel, M.
Object Type: Report
System: The UNT Digital Library
Thermal Analysis for Ion-Exchange Column System (open access)

Thermal Analysis for Ion-Exchange Column System

Models have been developed to simulate the thermal characteristics of crystalline silicotitanate ion exchange media fully loaded with radioactive cesium either in a column configuration or distributed within a waste storage tank. This work was conducted to support the design and operation of a waste treatment process focused on treating dissolved, high-sodium salt waste solutions for the removal of specific radionuclides. The ion exchange column will be installed inside a high level waste storage tank at the Savannah River Site. After cesium loading, the ion exchange media may be transferred to the waste tank floor for interim storage. Models were used to predict temperature profiles in these areas of the system where the cesium-loaded media is expected to lead to localized regions of elevated temperature due to radiolytic decay. Normal operating conditions and accident scenarios (including loss of solution flow, inadvertent drainage, and loss of active cooling) were evaluated for the ion exchange column using bounding conditions to establish the design safety basis. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. In-tank modeling results revealed that an idealized hemispherical mound …
Date: December 20, 2012
Creator: Lee, Si Y. & King, William D.
Object Type: Article
System: The UNT Digital Library
Simulation study of electron response amplification in coherent electron cooling (open access)

Simulation study of electron response amplification in coherent electron cooling

In Coherent Electron Cooling (CEC), it is essential to study the amplification of electron response to a single ion in the FEL process, in order to proper align the electron beam and the ion beam in the kicker to maximize the cooling effect. In this paper, we use Genesis to simulate the amplified electron beam response of single ion in FEL amplification process, which acts as Green's function of the FEL amplifier.
Date: May 20, 2012
Creator: Y., Hao & Litvinenko, V. N.
Object Type: Article
System: The UNT Digital Library
Solar Grade Silicon from Agricultural By-products (open access)

Solar Grade Silicon from Agricultural By-products

In this project, Mayaterials developed a low cost, low energy and low temperature method of purifying rice hull ash to high purity (5-6Ns) and converting it by carbothermal reduction to solar grade quality silicon (Sipv) using a self-designed and built electric arc furnace (EAF). Outside evaluation of our process by an independent engineering firm confirms that our technology greatly lowers estimated operating expenses (OPEX) to $5/kg and capital expenses (CAPEX) to $24/kg for Sipv production, which is well below best-in-class plants using a Siemens process approach (OPEX of 14/kg and CAPEX of $87/kg, respectively). The primary limiting factor in the widespread use of photovoltaic (PV) cells is the high cost of manufacturing, compared to more traditional sources to reach 6 g Sipv/watt (with averages closer to 8+g/watt). In 2008, the spot price of Sipv rose to $450/kg. While prices have since dropped to a more reasonable $25/kg; this low price level is not sustainable, meaning the longer-term price will likely return to $35/kg. The 6-8 g Si/watt implies that the Sipv used in a module will cost $0.21-0.28/watt for the best producers (45% of the cost of a traditional solar panel), a major improvement from the cost/wafer driven by the …
Date: August 20, 2012
Creator: Laine, Richard M.
Object Type: Report
System: The UNT Digital Library
Generation IV Nuclear Energy System Initiative; Air-Cooled Option Rccs Studies and NSTF Preparation. (open access)

Generation IV Nuclear Energy System Initiative; Air-Cooled Option Rccs Studies and NSTF Preparation.

None
Date: November 20, 2012
Creator: Lomperski, S.; Pointer, W.D.; Tzanos, C.P.; Wei, T.Y.C. & Kraus, A.R. (Nuclear Engineering Division)
Object Type: Report
System: The UNT Digital Library
PHYSICS RESULTS OF THE NSLS-II LINAC FRONT END TEST STAND (open access)

PHYSICS RESULTS OF THE NSLS-II LINAC FRONT END TEST STAND

The Linac Front End Test Stand (LFETS) was installed at the Source Development Laboratory (SDL) in the fall of 2011 in order to test the Linac Front End. The goal of these tests was to test the electron source against the specifications of the linac. In this report, we discuss the results of these measurements and the effect on linac performance.
Date: May 20, 2012
Creator: P., Fliller R.; Gao, F.; Yang, X.; Rose, J.; Shaftan, T. & Piel, C
Object Type: Article
System: The UNT Digital Library
Remediation Guidance for Major Airports after a Bioterrorist Attack (open access)

Remediation Guidance for Major Airports after a Bioterrorist Attack

None
Date: June 20, 2012
Creator: Carlsen, T.; Raber, E.; Macqueen, D.; Berg, L.; Coty, J.; Brown, G. et al.
Object Type: Report
System: The UNT Digital Library
Stochastic cooling in RHIC (open access)

Stochastic cooling in RHIC

The full 6-dimensional [x,x'; y,y'; z,z'] stochastic cooling system for RHIC was completed and operational for the FY12 Uranium-Uranium collider run. Cooling enhances the integrated luminosity of the Uranium collisions by a factor of 5, primarily by reducing the transverse emittances but also by cooling in the longitudinal plane to preserve the bunch length. The components have been deployed incrementally over the past several runs, beginning with longitudinal cooling, then cooling in the vertical planes but multiplexed between the Yellow and Blue rings, next cooling both rings simultaneously in vertical (the horizontal plane was cooled by betatron coupling), and now simultaneous horizontal cooling has been commissioned. The system operated between 5 and 9 GHz and with 3 x 10{sup 8} Uranium ions per bunch and produces a cooling half-time of approximately 20 minutes. The ultimate emittance is determined by the balance between cooling and emittance growth from Intra-Beam Scattering. Specific details of the apparatus and mathematical techniques for calculating its performance have been published elsewhere. Here we report on: the method of operation, results with beam, and comparison of results to simulations.
Date: May 20, 2012
Creator: M., Brennan J.; Blaskiewicz, M. & Mernick, K.
Object Type: Article
System: The UNT Digital Library
Kink instability suppression with stochastic cooling pickup and kicker (open access)

Kink instability suppression with stochastic cooling pickup and kicker

The kink instability is one of the major beam dynamics issues of the linac-ring based electron ion collider. This head-tail type instability arises from the oscillation of the electron beam inside the opposing ion beam. It must be suppressed to achieve the desired luminosity. There are various ways to suppress the instability, such as tuning the chromaticity in the ion ring or by a dedicated feedback system of the electron beam position at IP, etc. However, each method has its own limitation. In this paper, we will discuss an alternative opportunity of suppressing the kink instability of the proposed eRHIC at BNL using the existing pickup-kicker system of the stochastic cooling system in RHIC.
Date: May 20, 2012
Creator: Y., Hao; Blaskiewicz, M.; Litvinenko, V. N. & Ptitsyn, V.
Object Type: Article
System: The UNT Digital Library
Numerical Homogenization on Approach for Stokesian Suspensions. (open access)

Numerical Homogenization on Approach for Stokesian Suspensions.

In this technical report we investigate efficient methods for numerical simulation of active suspensions. The prototypical system is a suspension of swimming bacteria in a Newtonian fluid. Rheological and other macroscopic properties of such suspensions can differ dramatically from the same properties of the suspending fluid alone or of suspensions of similar but inactive particles. Elongated bacteria, such as E. coli or B. subtilis, swim along their principal axis, propelling themselves with the help of flagella, attached at the anterior of the organism and pushing it forward in the manner of a propeller. They interact hydrodynamically with the surrounding fluid and, because of their asymmetrical shape, have the propensity to align with the local flow. This, along with the dipolar nature of bacteria (the two forces a bacterium exerts on a fluid - one due to self-propulsion and the other opposing drag - have equal magnitude and point in opposite directions), causes nearby bacteria to tend to align, resulting in a intermittent local ordering on the mesoscopic scale, which is between the microscopic scale of an individual bacterium and the macroscopic scale of the suspension (e.g., its container). The local ordering is sometimes called a collective mode or collective swimming. …
Date: January 20, 2012
Creator: Haines, Brian M.; Berlyand, Leonid V. & Karpeev, Dmitry A.
Object Type: Report
System: The UNT Digital Library
2011 Annual Summary Report for the Area 3 and Area 5 Radioactive Waste Management Sites at the Nevada National Security Site, Nye County, Nevada: Review of the Performance Assessments and Composite Analyses (open access)

2011 Annual Summary Report for the Area 3 and Area 5 Radioactive Waste Management Sites at the Nevada National Security Site, Nye County, Nevada: Review of the Performance Assessments and Composite Analyses

The Maintenance Plan for the Performance Assessments and Composite Analyses for the Area 3 and Area 5 Radioactive Waste Management Sites at the Nevada Test Site (National Security Technologies, LLC, 2007a) requires an annual review to assess the adequacy of the Performance Assessments (PAs) and Composite Analyses (CAs), with the results submitted annually to U.S. Department of Energy (DOE) Office of Environmental Management. The Disposal Authorization Statements for the Area 3 and Area 5 Radioactive Waste Management Sites (RWMSs) also require that such reviews be made and that secondary or minor unresolved issues be tracked and addressed as part of the maintenance plan (DOE, 1999a; 2000). The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office performed an annual review of the Area 3 and Area 5 RWMS PAs and CAs for fiscal year (FY) 2011. This annual summary report presents data and conclusions from the FY 2011 review, and determines the adequacy of the PAs and CAs. Operational factors (e.g., waste forms and containers, facility design, and waste receipts), closure plans, monitoring results, and research and development (R and D) activities were reviewed to determine the adequacy of the PAs. Likewise, the environmental restoration activities at the …
Date: March 20, 2012
Creator: NSTec Environmental Management
Object Type: Report
System: The UNT Digital Library
Comparison of H-Mode Plasmas Diverted to Solid and Liquid Lithium Surfaces (open access)

Comparison of H-Mode Plasmas Diverted to Solid and Liquid Lithium Surfaces

Experiments were conducted with a Liquid Lithium Divertor (LLD) in NSTX. Among the goals was to use lithium recoating to sustain deuterium (D) retention by a static liquid lithium surface, approximating the ability of flowing liquid lithium to maintain chemical reactivity. Lithium evaporators were used to deposit lithium on the LLD surface. Improvements in plasma edge conditions were similar to those with lithiated graphite plasma-facing components (PFCs), including an increase in confinement over discharges without lithiumcoated PFCs and ELM reduction during H-modes. With the outer strike point on the LLD, the D retention in the LLD was about the same as that for solid lithium coatings on graphite, or about two times that achieved without lithium PFC coatings. There were also indications of contamination of the LLD surface, possibly due erosion and redeposition of carbon from PFCs. Flowing lithium may thus be needed for chemically active PFCs during long-pulse operation.
Date: July 20, 2012
Creator: R. Kaita, et. al.
Object Type: Article
System: The UNT Digital Library
Nanoimaging to Prevent and Treat Alzheimer’s and Parkinson’s Diseases. Scientific/Technical report (open access)

Nanoimaging to Prevent and Treat Alzheimer’s and Parkinson’s Diseases. Scientific/Technical report

This project will develop innovative approaches to characterization of the very early stages of protein aggregation that eventually can be translated to the development of early diagnostic tools and efficient treatments for Alzheimer’s, Parkinson’s and Huntington’s diseases. Funding will be used to acquire nanoimaging technology for nanoscale imaging, manipulation and analysis of biomedical materials to develop treatments that will repair disabled proteins and cure diseases that result from protein malfunction, specifically Alzheimer’s and Parkinson’s diseases. Expected outcomes include tests for early diagnosis and therapeutic treatments for these devastating neurological diseases. To elucidate the mechanisms of protein misfolding, we will establish an extensive program of experimental studies using a broad arsenal of advanced nanoscale and traditional techniques that will be integrated with molecular-scale modeling of protein misfolding and the nucleation of aggregate structures. To identify intracellular machinery or/and multicomponent complexes critically involved in protein misfolding, we will characterize interactions between targeted proteins and specific intracellular components or metabolites that impact on protein conformational pathways leading to protein misfolding accompanied by formation of toxic aggregated morphologies. To design innovative nanotechnology tools for the control of intracellular protein misfolding and aggregation processes, we will develop a predictive molecular scale model for intracellular protein …
Date: December 20, 2012
Creator: Yuri L. Lyubchenko, PhD, DSc
Object Type: Report
System: The UNT Digital Library
Novel technique of suppressing TBBU in high-energy ERLs (open access)

Novel technique of suppressing TBBU in high-energy ERLs

Energy recovery linacs (ERLs) are an emerging generation of accelerators that promise to revolutionize the fields of high-energy physics and photon sciences. These accelerators combine the advantages of linear accelerators with that of storage rings, and augur the delivery of electron beams of unprecedented power and quality. However, one potential weakness of these devices is transverse beam break-up instability that could severely limit the available beam current. In this paper, I propose a novel method of suppressing these dangerous effects using the chromaticity of the transverse motion. In this short paper I am able only to touch the surface of the method and a complete description of the method with all relevant derivations can be found in [1].
Date: May 20, 2012
Creator: V., Litvinenko
Object Type: Article
System: The UNT Digital Library
Developing an Operational Capabilities Index of the Emergency Services Sector (open access)

Developing an Operational Capabilities Index of the Emergency Services Sector

In order to enhance the resilience of the Nation and its ability to protect itself in the face of natural and human-caused hazards, the ability of the critical infrastructure (CI) system to withstand specific threats and return to normal operations after degradation must be determined. To fully analyze the resilience of a region and the CI that resides within it, both the actual resilience of the individual CI and the capability of the Emergency Services Sector (ESS) to protect against and respond to potential hazards need to be considered. Thus, a regional resilience approach requires the comprehensive consideration of all parts of the CI system as well as the characterization of emergency services. This characterization must generate reproducible results that can support decision making with regard to risk management, disaster response, business continuity, and community planning and management. To address these issues, Argonne National Laboratory, in collaboration with the U.S. Department of Homeland Security (DHS) Sector Specific Agency - Executive Management Office, developed a comprehensive methodology to create an Emergency Services Sector Capabilities Index (ESSCI). The ESSCI is a performance metric that ranges from 0 (low level of capabilities) to 100 (high). Because an emergency services program has a high …
Date: February 20, 2012
Creator: Collins, M. J.; Eaton, L. K.; Shoemaker, Z. M.; Fisher, R. E.; Veselka, S. N.; Wallace, K. E. et al.
Object Type: Report
System: The UNT Digital Library
ANALYSIS OF DWPF SLUDGE BATCH 6 (MACROBATCH 7) POUR STREAM GLASS SAMPLES (open access)

ANALYSIS OF DWPF SLUDGE BATCH 6 (MACROBATCH 7) POUR STREAM GLASS SAMPLES

The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 6 (SB6), also referred to as Macrobatch 7 (MB7), in June 2010. SB6 is a blend of the heel of Tank 40 from Sludge Batch 5 (SB5), H-Canyon Np transfers and SB6 that was transferred to Tank 40 from Tank 51.1 SB6 was processed using Frit 418. Sludge is received into the DWPF Chemical Processing Cell (CPC) and is processed through the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator Tank (SME). The treated sludge slurry is then transferred to the Melter Feed Tank (MFT) and fed to the melter. During processing of each sludge batch, the DWPF is required to take at least one glass sample to meet the objectives of the Glass Product Control Program (GPCP) and to complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. The DWPF requested various analyses of radioactive glass samples obtained from the melter pour stream during processing of SB6 as well as reduction/oxidation (REDOX) analysis of MFT samples to determine the impact of Argon bubbling. Sample analysis followed the Task Technical and Quality Assurance Plan (TTQAP) and an Analytical …
Date: January 20, 2012
Creator: Johnson, F.
Object Type: Report
System: The UNT Digital Library
ANALYSIS OF THE TANK 5F FINAL CHARATERIZATION SAMPLES-2011 (open access)

ANALYSIS OF THE TANK 5F FINAL CHARATERIZATION SAMPLES-2011

The Savannah River National Laboratory (SRNL) was requested by SRR to provide sample preparation and analysis of the Tank 5F final characterization samples to determine the residual tank inventory prior to grouting. Two types of samples were collected and delivered to SRNL: floor samples across the tank and subsurface samples from mounds near risers 1 and 5 of Tank 5F. These samples were taken from Tank 5F between January and March 2011. These samples from individual locations in the tank (nine floor samples and six mound Tank 5F samples) were each homogenized and combined in a given proportion into 3 distinct composite samples to mimic the average composition in the entire tank. These Tank 5F composite samples were analyzed for radiological, chemical and elemental components. Additional measurements performed on the Tank 5F composite samples include bulk density and water leaching of the solids to account for water soluble species. With analyses for certain challenging radionuclides as the exception, all composite Tank 5F samples were analyzed and reported in triplicate. The target detection limits for isotopes analyzed were based on customer desired detection limits as specified in the technical task request documents. SRNL developed new methodologies to meet these target detection …
Date: January 20, 2012
Creator: Oji, L.; Diprete, D.; Coleman, C. & Hay, M.
Object Type: Report
System: The UNT Digital Library
Design, simulation and conditioning of the fundamental power couplers for BNL SRF gun (open access)

Design, simulation and conditioning of the fundamental power couplers for BNL SRF gun

The 704 MHz SRF gun for the BNL Energy Recovery Linac (ERL) prototype uses two fundamental power couplers (FPCs) to deliver up to 1 MW of CW RF power to the half-cell cavity. To prepare the couplers for high-power RF service and process multipacting, the FPCs should be conditioned prior to installation into the gun cryomodule. A room-temperature test stand was configured for conditioning FPCs in full reflection regime with varied phase of the reflecting wave. The FPCs have been conditioned up to 250 kW in pulse mode and 125 kW in CW mode. The multipacting simulations were carried out with Track3P code developed at SLAC. The simulations matched the experimental results very well. This paper presents the FPC RF and thermal design, multipacting simulations and conditioning of the BNL gun FPCs.
Date: May 20, 2012
Creator: Xu, W.; Altinbas, Z.; Belomestnykh, S. & Ben-Zvi, Ilan
Object Type: Article
System: The UNT Digital Library
Quarterly VAP Report - April to June (open access)

Quarterly VAP Report - April to June

The purpose of this report is to provide a concise status update for value-added products (VAP) implemented by the Atmospheric Radiation Measurement Climate Research Facility. The report is divided into the following sections: (1) new VAPs for which development has begun, (2) progress on existing VAPs, (3) future VAPs that have been recently approved, (4) other work that leads to a VAP, and (5) top requested VAPs from the Data Archive. New information is highlighted in blue text. New information about processed data by the developer is highlighted in red text. The upcoming milestones and dates are highlighted in green.
Date: August 20, 2012
Creator: Sivaraman, C
Object Type: Text
System: The UNT Digital Library
Recent Improvements In Interface Management For Hanfords Waste Treatment And Immobilization Plant - 13263 (open access)

Recent Improvements In Interface Management For Hanfords Waste Treatment And Immobilization Plant - 13263

The U.S. Department of Energy (DOE), Office of River Protection (ORP) is responsible for management and completion of the River Protection Project (RPP) mission, which comprises both the Hanford Site tank farms operations and the Waste Treatment and Immobilization Plant (WTP). The RPP mission is to store, retrieve and treat Hanford's tank waste; store and dispose of treated wastes; and close the tank farm waste management areas and treatment facilities by 2047. The WTP is currently being designed and constructed by Bechtel National Inc. (BNI) for DOE-ORP. BNI relies on a number oftechnical services from other Hanford contractors for WTP's construction and commissioning. These same services will be required of the future WTP operations contractor. The WTP interface management process has recently been improved through changes in organization and technical issue management documented in an Interface Management Plan. Ten of the thirteen active WTP Interface Control Documents (ICDs) have been revised in 2012 using the improved process with the remaining three in progress. The value of the process improvements is reflected by the ability to issue these documents on schedule.
Date: November 20, 2012
Creator: Arm, Stuart T.; Pell, Michael J.; Van Meighem, Jeffery S.; Duncan, Garth M. & Harrington, Christopher C.
Object Type: Article
System: The UNT Digital Library
3D Equilibrium Effects Due to RMP Application on DIII-D (open access)

3D Equilibrium Effects Due to RMP Application on DIII-D

The mitigation and suppression of edge localized modes (ELMs) through application of resonant magnetic perturbations (RMPs) in Tokamak plasmas is a well documented phenomenon. Vacuum calculations suggest the formation of edge islands and stochastic regions when RMPs are applied to the axisymmetric equilibria. Self-consistent calculations of the plasma equilibrium with the VMEC and SPEC codes have been performed for an up-down symmetric shot in DIII-D. In these codes, a self-consistent calculation of the plasma response due to the RMP coils is calculated. The VMEC code globally enforces the constraints of ideal MHD; consequently, a continuously nested family of flux surfaces is enforced throughout the plasma domain. This approach necessarily precludes the observation of islands or field-line chaos. The SPEC code relaxes the constraints of ideal MHD locally, and allows for islands and field line chaos at or near the rational surfaces. Equilibria with finite pressure gradients are approximated by a set of discrete "ideal-interfaces" at the most irrational flux surfaces and where the strongest pressure gradients are observed. Both the VMEC and SPEC calculations are initialized from EFIT reconstructions of the plasma that are consistent with the experimental pressure and current profiles. A 3D reconstruction using the STELLOPT code, which …
Date: June 20, 2012
Creator: Lazerson, S.; Lazarus, E.; Hudson, S.; Pablant, N. & Gates, D.
Object Type: Report
System: The UNT Digital Library
Duplex Oxide Formation during Transient Oxidation of Cu-5%Ni(001) Investigated by In situ UHV-TEM and XPS (open access)

Duplex Oxide Formation during Transient Oxidation of Cu-5%Ni(001) Investigated by In situ UHV-TEM and XPS

The transient oxidation stage of a model metal alloy thin film was characterized with in situ ultra-high vacuum (UHV) transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and analytic high-resolution TEM. We observed the formations of nanosized NiO and Cu{sub 2}O islands when Cu-5a5%Ni(100) was exposed to oxygen partial pressure, pO{sub 2} = 1 x 10{sup -4} Torr and various temperatures in situ. At 350 C epitaxial Cu{sub 2}O islands formed initially and then NiO islands appeared on the surface of the Cu{sub 2}O island, whereas at 750 C NiO appeared first. XPS and TEM was used to reveal a sequential formation of NiO and then Cu{sub 2}O islands at 550 C. The temperature-dependant oxide selection may be due to an increase of the diffusivity of Ni in Cu with increasing temperature.
Date: May 20, 2012
Creator: Yang, J.C.; Starr, D.; Kang, Y.; Luo, L.; Tong, X. & Zhou, G.
Object Type: Article
System: The UNT Digital Library
Flat Plate FCG Experimental System for Material Studies (open access)

Flat Plate FCG Experimental System for Material Studies

None
Date: November 20, 2012
Creator: Goerz, D. A.; Reisman, D. B.; Javedani, J. B.; Paladichuk, J. T.; Hare, D. E.; Tallerico, L. J. et al.
Object Type: Article
System: The UNT Digital Library
APPLICATION OF COLUMN EXTRACTION METHOD FOR IMPURITIES ANALYSIS ON HB-LINE PLUTONIUM OXIDE IN SUPPORT OF MOX FEED PRODUCT SPECIFICATIONS (open access)

APPLICATION OF COLUMN EXTRACTION METHOD FOR IMPURITIES ANALYSIS ON HB-LINE PLUTONIUM OXIDE IN SUPPORT OF MOX FEED PRODUCT SPECIFICATIONS

The current mission at H-Canyon involves the dissolution of an Alternate Feedstocks 2 (AFS-2) inventory that contains plutonium metal. Once dissolved, HB-Line is tasked with purifying the plutonium solution via anion exchange, precipitating the Pu as oxalate, and calcining to form plutonium oxide (PuO{sub 2}). The PuO{sub 2} will provide feed product for the Mixed Oxide (MOX) Fuel Fabrication Facility, and the anion exchange raffinate will be transferred to H-Canyon. The results presented in this report document the potential success of the RE resin column extraction application on highly concentrated Pu samples to meet MOX feed product specifications. The original 'Hearts Cut' sample required a 10000x dilution to limit instrument drift on the ICP-MS method. The instrument dilution factors improved to 125x and 250x for the sample raffinate and sample eluent, respectively. As noted in the introduction, the significantly lower dilutions help to drop the total MRL for the analyte. Although the spike recoveries were half of expected in the eluent for several key elements, they were between 94-98% after Nd tracer correction. It is seen that the lower ICD limit requirements for the rare earths are attainable because of less dilution. Especially important is the extremely low Ga limit …
Date: March 20, 2012
Creator: Jones, M.; Diprete, D. & Wiedenman, B.
Object Type: Report
System: The UNT Digital Library