New Materials for NGNP/Gen IV (open access)

New Materials for NGNP/Gen IV

The bounding conditions were briefly summarized for the Next Generation Nuclear Plant (NGNP) that is the leading candidate in the Department of Energy Generation IV reactor program. Metallic materials essential to the successful development and proof of concept for the NGNP were identified. The literature bearing on the materials technology for high-temperature gas-cooled reactors was reviewed with emphasis on the needs identified for the NGNP. Several materials were identified for a more thorough study of their databases and behavioral features relative to the requirements ASME Boiler and Pressure Vessel Code, Section III, Division 1, Subsection NH.
Date: December 18, 2009
Creator: Swindeman, Robert W. & Marriott, Douglas L.
Object Type: Report
System: The UNT Digital Library
EM-21 ALTERNATIVE ENHANCED CHEMICAL CLEANING PROGRAM FOR SLUDGE HEEL REMOVAL (open access)

EM-21 ALTERNATIVE ENHANCED CHEMICAL CLEANING PROGRAM FOR SLUDGE HEEL REMOVAL

Preliminary studies in the EM-21 Alternative Chemical Cleaning Program have focused on understanding the dissolution of Hematite (a primary sludge heel phase) in oxalic acid, with a focus on minimizing oxalic acid usage. Literature reviews, thermodynamic modeling, and experimental results have all confirmed that pH control, preferably using a supplemental proton source, is critical to oxalate minimization. With pH control, iron concentrations as high as 0.103 M have been obtained in 0.11 M oxalic acid. This is consistent with the formation of a 1:1 (iron:oxalate) complex. The solubility of Hematite in oxalic acid has been confirmed to increase by a factor of 3 when the final solution pH decreases from 5 to below 1. This is consistent with literature predictions of a shift in speciation from a 1:3 to 1:1 as the pH is lowered. Above a solution pH of 6, little Hematite dissolves. These results emphasize the importance of pH control in optimizing Hematite dissolution in oxalic acid.
Date: December 18, 2009
Creator: Hay, M.; King, W. & Martino, C.
Object Type: Article
System: The UNT Digital Library
High Brightness Plasma-Based Soft X-ray Lasers and Applications (open access)

High Brightness Plasma-Based Soft X-ray Lasers and Applications

None
Date: December 18, 2009
Creator: Dunn, J
Object Type: Article
System: The UNT Digital Library
Coworker External Dosimetry Data for the Y-12 National Security Complex (open access)

Coworker External Dosimetry Data for the Y-12 National Security Complex

Provides background information on the Y-12 coworker external dosimetry data and includes tables with annual values that may be used in the process of assigning doses for unmonitored years of employment.
Date: December 18, 2009
Creator: McCartney KA, Watkins JP, Kerr GD, Tankersley WG
Object Type: Report
System: The UNT Digital Library
Demonstration of Datacenter Automation Software and Hardware (DASH) at the California Franchise Tax Board (open access)

Demonstration of Datacenter Automation Software and Hardware (DASH) at the California Franchise Tax Board

Control software and wireless sensors designed for closed-loop, monitoring and control of IT equipment's inlet air temperatures in datacenters were evaluated and tested while other datacenter cooling best practices were implemented. The controls software and hardware along with each best practice were installed sequentially and evaluated using a measurement and verification procedure between each measure. The results show that the overall project eliminates 475,239 kWh per year, which is 21.3percent of the baseline energy consumption of the data center. The total project, including the best practices will save $42,772 per year and cost $134,057 yielding a simple payback of 3.1 years. However, the control system alone eliminates 59.6percent of the baseline energy used to move air in the datacenter and 13.6percent of the baseline cooling energy, which is 15.2percent of the baseline energy consumption (see Project Approach, Task 1, below, for additional information) while keeping temperatures substantially within the limits recommended by ASHRAE. Savings attributed to the control system are $30,564 per year with a cost $56,824 for a simple payback of 1.9 years.
Date: December 18, 2009
Creator: Bell, Geoffrey C. & Federspiel, Clifford
Object Type: Report
System: The UNT Digital Library
2009 Exploring Giant Planets on NIF: A New Generation of Condensed Matter Workshop (open access)

2009 Exploring Giant Planets on NIF: A New Generation of Condensed Matter Workshop

None
Date: December 18, 2009
Creator: Eggert, J. H.; Robey, H. F.; Spears, B. K.; Thomas, C. A.; Weber, S. V.; Wilson, D. C. et al.
Object Type: Article
System: The UNT Digital Library
DC 12m Telescope. Preliminary Calculations. Investigation of Elevation Axis Position. (open access)

DC 12m Telescope. Preliminary Calculations. Investigation of Elevation Axis Position.

This paper examines some simple calculations of a 2D model of a telescope in order to understand how different design parameters affect the design. For the design of a telescope it is assumed that they need a design that minimizes deflections of the dish and also minimizes the size of the motors and torques needed to rotate in elevation. A common belief is that a lighter dish and minimum counterweight is desirable. However, these calculations show this is not necessarily true. The torque needed for rotation depends on the moment of inertia and if the telescope is balanced about the elevation axis. A light dish with no CW requires that the elevation axis be several meters in front of the dish (8-9m) in order to be balanced. This is not practical from a structural point of view. If the elevation axis is only 2m in front of the dish and there is no counterweight then the telescope will be unbalanced and the toruqes required will be very high - much higher than the torques needed only to overcome inertia. A heavy dish though can act as its own counterweight and the elevation axis only has to be 2-3m in front …
Date: December 18, 2009
Creator: Guarino, V. J.
Object Type: Report
System: The UNT Digital Library
A detailed kinetic modeling study of toluene oxidation in a premixed laminar flame (open access)

A detailed kinetic modeling study of toluene oxidation in a premixed laminar flame

An improved chemical kinetic model for the toluene oxidation based on experimental data obtained in a premixed laminar low-pressure flame with vacuum ultraviolet (VUV) photoionization and molecular beam mass spectrometry (MBMS) techniques has been proposed. The present mechanism consists of 273 species up to chrysene and 1740 reactions. The rate constants of reactions of toluene, decomposition, reaction with oxygen, ipso-additions and metatheses with abstraction of phenylic H-atom are updated; new pathways of C{sub 4} + C{sub 2} species giving benzene and fulvene are added. Based on the experimental observations, combustion intermediates such as fulvenallene, naphtol, methylnaphthalene, acenaphthylene, 2-ethynylnaphthalene, phenanthrene, anthracene, 1-methylphenanthrene, pyrene and chrysene are involved in the present mechanism. The final toluene model leads to an overall satisfactory agreement between the experimentally observed and predicted mole fraction profiles for the major products and most combustion intermediates. The toluene depletion is governed by metathese giving benzyl radicals, ipso-addition forming benzene and metatheses leading to C{sub 6}H{sub 4}CH{sub 3} radicals. A sensitivity analysis indicates that the unimolecular decomposition via the cleavage of a C-H bond has a strong inhibiting effect, while decomposition via C-C bond breaking, ipso-addition of H-atom to toluene, decomposition of benzyl radicals and reactions related to C{sub 6}H{sub …
Date: December 18, 2009
Creator: Tian, Zhenyu; Pitz, William J.; Fournet, Rene; Glaude, Pierre-Alexander & Battin-Leclerc, Frederique
Object Type: Article
System: The UNT Digital Library