Investigating the Heating of a Potassium-Doped Aluminosilicate Ion Source Using a 1 Micron Laser (open access)

Investigating the Heating of a Potassium-Doped Aluminosilicate Ion Source Using a 1 Micron Laser

The heavy ion fusion (HIF) program is interested in developing a high brightness ion source for high energy density physics (HEDP) experiments. One possible approach to obtaining higher brightness may be to raise the surface temperature of the ion source just prior to extraction. The current ion source material being studied is a layer of potassium-doped aluminosilicate bonded to a tungsten substrate. It is speculated that if the surface temperature of the source is raised above 1200 C (from a steady-state temperature of 900 C) for time periods on the order of 100's of nanoseconds, current densities of greater than 100 mA/cm{sup 2} of ions may be achievable. Typical aluminosilicate sources produce ion current densities (either K+ or Na+ ions) of {approx}10 mA/cm{sup 2} (at 1100 C). A number of heating methods might be possible, including lasers, diode arrays, and flash lamps. Here we assume laser heating. In this preliminary study, we used the LLNL RadHeat code to model the time-temperature history of the surface when hit by laser pulses and illustrate how RadHeat can be used to optimize the surface temperature response. Also of interest is the temperature history of the interface temperature between the ceramic and the metal …
Date: December 14, 2004
Creator: Schmitt, R. C.; Meier, W. R.; Kwan, J. W.; Abbott, R. P. & Latkowski, J. F.
System: The UNT Digital Library
Evaluation of Fish Losses through Screen Gaps at Modified and Unmodified Intakes of Bonneville Dam Second Powerhouse in 2003 (open access)

Evaluation of Fish Losses through Screen Gaps at Modified and Unmodified Intakes of Bonneville Dam Second Powerhouse in 2003

This report was prepared by the Pacific Northwest National Lab., Richland, Washington, BAE Systems, Inc., a subcontractor to the U.S. Army Engineer Research and Development Center (ERDC), Vicksburg, Mississippi. This study examined the effect of gatewell modifications on the proportion of fish lost through the gap between the top of submerged traveling screens (STSs) and the ceilings of intakes in one un-modified and two modified turbine units at Bonneville Dam Second Powerhouse (B2). Combined modifications reduced the proportion of flow through the gap from 44% to 16% and increased the proportion moving up the gatewell from 56% to 84%. We used a Dual-Frequency Identification Sonar (DIDSON) acoustic camera to record proportions of juvenile salmonids moving up into the gatewell and through the gap. The acoustic camera was used to record images of fish passing up into the gatewell and through the gap for 8-h on three successive nights in every intake of units 13, 15, and 17 (i.e., 9 intakes x 3 nights = 27 nights each season). Only 28.6% of the objects detected in spring and 12.9% in summer were determined to be fish. Other objects included sticks and debris. Although the true magnitude of STS gap-loss is unknown, …
Date: June 14, 2004
Creator: Ploskey, Gene R.; Weiland, Mark A. & Schilt, Carl R.
System: The UNT Digital Library
Adaptive 4-8 Texture Hierarchies (open access)

Adaptive 4-8 Texture Hierarchies

None
Date: April 14, 2004
Creator: Hwa, L M; Duchaineau, M A & Joy, K I
System: The UNT Digital Library
D-Zero HVAC Heat Pump Controls (open access)

D-Zero HVAC Heat Pump Controls

This engineering note documents the integration of Dzero Heat Pump 1 through Heat Pump 15 into the cryo/gas process control system commonly referred to as the cryo control system. Heat pumps 1 through 15 control the ambient air temperature on the 3rd, 5th, and 6th floor office areas at Dzero. The entire Johnson HVAC control system was replaced with a Siemens control system in 1999 leaving behind the 15 heat pumps with stand-alone Johnson controllers. Now, these 15 heat pump Johnson controllers are being replaced with small stand alone Beckhoff BC9000 controllers. The Beckhoff BC9000 controllers are network able into the existing Intellution control system. The Beckhoff BC9000 controllers use the cryo private Ethernet network and an OPC driver to get data into the Intellution SCADA node databases. The BC9000 is also programmed over this same Ethernet network.
Date: April 14, 2004
Creator: Markley, Dan
System: The UNT Digital Library
Position Ring System using Anger Type Detectors (open access)

Position Ring System using Anger Type Detectors

The overall objective of our project was to develop PET scanners and imaging techniques that achieve high performance and excellent image quality. Our approach was based upon 3-D imaging (no septa) with position-sensitive Anger-logic detectors, whereby the encoding ratio of resolution elements to number of photo-multiplier tube channels is very high. This design led to a series of PET systems that emphasized cost-effectiveness and practicality in a clinical environment.
Date: December 14, 2004
Creator: Joel S. Karp, principal investigator
System: The UNT Digital Library
DIALOG: Fostering Early Career Development Across the Aquatic Sciences (open access)

DIALOG: Fostering Early Career Development Across the Aquatic Sciences

A total of 447 dissertation abstracts were received for the DIALOG V Program, with 146 individuals applying for the DIALOG V Symposium; 47 were invited and 45 have accepted. This represents a significant increase compared to the DIALOG IV Program in which 221 abstracts were registered and 124 applied for the symposium. The importance of the dissertation registration service is indicated by the increasing number of individuals who take time to register their dissertation even when they are not interested in applying to the symposium. The number of visits to the webpage has also increased significantly over the years. This also reflects graduate interest in being part of the on-line Dissertation Registry and receiving the weekly electronic DIALOG Newsletter. See http://aslo.org/phd.html for details. The DIALOG symposium reaches approximately 40 new PI's at a pivotal point in their research careers. Based on their comments, the symposium changes the way participants think, communicate, and approach their research. The science community and the general population will benefit from the perspectives these new PI's bring back to their home institutions and share with their students and colleagues. This group should act as a catalyst to move the entire field in exciting new, interdisciplinary directions. …
Date: November 14, 2004
Creator: Caroline Susan Weiler, PhD
System: The UNT Digital Library
DOE-NSF-NIH Workshop on Opportunities in THz Science, February 12-14, 2004 (open access)

DOE-NSF-NIH Workshop on Opportunities in THz Science, February 12-14, 2004

This is the report of the Workshop on Opportunities in THz Science, held on February 12-14, 2004 in Arlington, VA. This workshop brought together researchers who use or produce THz radiation for physics, chemistry, biology, medicine, and materials science to discuss new research opportunities and common resource needs. The charge from the sponsors of the workshop was to focus on basic science questions within these disciplines that have and can be answered using THz radiation.
Date: February 14, 2004
Creator: Sherwin, M.A.; Bucksbaum, P.H.; Schmuttenmaer, C. A.; Allen, J.; Biedron, S.; Carr, L. et al.
System: The UNT Digital Library
Assessing Terrorist Motivations for Attacking Critical "Chemical" Infrastructure (open access)

Assessing Terrorist Motivations for Attacking Critical "Chemical" Infrastructure

Certain types of infrastructure--critical infrastructure (CI)--play vital roles in underpinning our economy, security, and way of life. One particular type of CI--that relating to chemicals--constitutes both an important element of our nation's infrastructure and a particularly attractive set of potential targets. This is primarily because of the large quantities of toxic industrial chemicals (TICs) it employs in various operations and because of the essential economic functions it serves. This study attempts to minimize some of the ambiguities that presently impede chemical infrastructure threat assessments by providing new insight into the key motivational factors that affect terrorist organizations propensity to attack chemical facilities. Prepared as a companion piece to the Center for Nonproliferation Studies August 2004 study--''Assessing Terrorist Motivations for Attacking Critical Infrastructure''--it investigates three overarching research questions: (1) why do terrorists choose to attack chemical-related infrastructure over other targets; (2) what specific factors influence their target selection decisions concerning chemical facilities; and (3) which, if any, types of groups are most inclined to attack chemical infrastructure targets? The study involved a multi-pronged research design, which made use of four discrete investigative techniques to answer the above questions as comprehensively as possible. These include: (1) a review of terrorism and threat …
Date: December 14, 2004
Creator: Ackerman, G.; Bale, J. & Moran, K.
System: The UNT Digital Library
Vadose Zone Contaminant Fate and Transport Analysis for the 216-B-26 Trench (open access)

Vadose Zone Contaminant Fate and Transport Analysis for the 216-B-26 Trench

The BC Cribs and Trenches, part of the 200 TW 1 OU waste sites, received about 30 Mgal of scavenged tank waste, with possibly the largest inventory of 99Tc ever disposed to the soil at Hanford and site remediation is being accelerated. The purpose of this work was to develop a conceptual model for contaminant fate and transport at the 216-B-26 Trench site to support identification and development and evaluation of remediation alternatives. Large concentrations of 99Tc high above the water table implicated stratigraphy in the control of the downward migration. The current conceptual model accounts for small-scale stratigraphy; site-specific changes soil properties; tilted layers; and lateral spreading. It assumes the layers are spatially continuous causing water and solutes to move laterally across the boundary if conditions permit. Water influx at the surface is assumed to be steady. Model parameters were generated with pedotransfer functions; these were coupled high resolution neutron moisture logs that provided information on the underlying heterogeneity on a scale of 3 inches. Two approaches were used to evaluate the impact of remedial options on transport. In the first, a 1-D convolution solution to the convective-dispersive equation was used, assuming steady flow. This model was used to …
Date: October 14, 2004
Creator: Ward, Andy L.; Gee, Glendon W.; Zhang, Z. F. & Keller, Jason M.
System: The UNT Digital Library
Development of Bypassed Oil Reserves Using Behind Casing Resistivity Measurements (open access)

Development of Bypassed Oil Reserves Using Behind Casing Resistivity Measurements

Tubing and rods of the S.P. Pedro-Nepple No.1 well were pulled and the well was prepared for running of Schlumberger's Cased Hole Formation Resistivity Tool (CHFR) in selected intervals. The CHFR tool was successfully run and data was captured. The CHFR formation resistivity readings were compared to original open hole resistivity measurements. Separation between the original and CHFR resistivity curves indicate both swept and un-swept sand intervals. Both watered out sand intervals and those with higher remaining oil saturation have been identified. Due to the nature of these turbidite sands being stratigraphically continuous, both the swept and unswept layers have been correlated across to one of the four nearby offset shallow wells. As a result of the cased hole logging, one well was selected for a workover to recomplete and test suspected oil saturated shallow sand intervals. Well S.P. Pedro-Nepple No.2 was plugged back with cement excluding the previously existing production interval, squeeze cemented behind casing, selectively perforated in the shallower ''Bell'' zone and placed on production to develop potential new oil reserves and increase overall well productivity. Prior workover production averaged 3.0 BOPD for the previous six-months from the original ''Meyer'' completion interval. Post workover well production was increased …
Date: February 14, 2004
Creator: Conner, Michael G.
System: The UNT Digital Library
Classroom HVAC: Improving ventilation and saving energy -- field study plan (open access)

Classroom HVAC: Improving ventilation and saving energy -- field study plan

The primary goals of this research effort are to develop, evaluate, and demonstrate a very practical HVAC system for classrooms that consistently provides classrooms (CRs) with the quantity of ventilation in current minimum standards, while saving energy, and reducing HVAC-related noise levels. This research is motivated by the public benefits of energy efficiency, evidence that many CRs are under-ventilated, and public concerns about indoor environmental quality in CRs. This document provides a summary of the detailed plans developed for the field study that will take place in 2005 to evaluate the energy and IAQ performance of a new classroom HVAC technology. The field study will include measurements of HVAC energy use, ventilation rates, and IEQ conditions in 10 classrooms with the new HVAC technology and in six control classrooms with a standard HVAC system. Energy use and many IEQ parameters will be monitored continuously, while other IEQ measurements will be will be performed seasonally. Continuously monitored data will be remotely accessed via a LonWorks network. Instrument calibration plans that vary with the type of instrumentation used are established. Statistical tests will be employed to compare energy use and IEQ conditions with the new and standard HVAC systems. Strengths of this …
Date: October 14, 2004
Creator: Apte, Michael G.; Faulkner, David; Hodgson, Alfred T. & Sullivan, Douglas P.
System: The UNT Digital Library
Incorporation of Integral Fuel Burnable Absorbers Boron and Gadolinium into Zirconium-Alloy Fuel Clad Material (open access)

Incorporation of Integral Fuel Burnable Absorbers Boron and Gadolinium into Zirconium-Alloy Fuel Clad Material

Long-lived fuels require the use of higher enrichments of 235U or other fissile materials. Such high levels of fissile material lead to excessive fuel activity at the beginning of life. To counteract this excessive activity, integral fuel burnable absorbers (IFBA) are added to some rods in the fuel assembly. The two commonly used IFBA elements are gadolinium, which is added as gadolinium-oxide to the UO2 powder, and boron, which is applied as a zirconium-diboride coating on the UO2 pellets using plasma spraying or chemical vapor deposition techniques. The incorporation of IFBA into the fuel has to be performed in a nuclear-regulated facility that is physically separated from the main plant. These operations tend to be very costly because of their small volume and can add from 20 to 30% to the manufacturing cost of the fuel. Other manufacturing issues that impact cost and performance are maintaining the correct levels of dosing, the reduction in fuel melting point due to gadolinium-oxide additions, and parasitic neutron absorption at fuel's end-of-life. The goal of the proposed research is to develop an alternative approach that involves incorporation of boron or gadolinium into the outer surface of the fuel cladding material rather than as an …
Date: December 14, 2004
Creator: Sridharan, K.; Renk, T.J.; Lahoda, E.J. & Corradini, M.L
System: The UNT Digital Library
Material Property Estimation for Direct Detections of DNAPL using Integrated Ground-Penetrating Radar Velocity, Imaging and Attribute Analysis (open access)

Material Property Estimation for Direct Detections of DNAPL using Integrated Ground-Penetrating Radar Velocity, Imaging and Attribute Analysis

The focus of our work is direct detection of DNAPLs, specifically chlorinated solvents, via material property estimation from surface ground-penetrating radar (GPR) data. We combine sophisticated GPR processing methodology with quantitative attribute analysis and material property estimation to determine the location and extent of residual and/or pooled DNAPL in both the vadose and saturated zones. An important byproduct of our research is state-of-the-art imaging which allows us to pinpoint attribute anomalies, characterize stratigraphy, identify fracture zones, and locate buried objects. Implementation and verification of these methodologies will be a significant advance in GPR research and in meeting DOE's need for reliable in-situ characterization of DNAPL contamination. Chlorinated solvents have much lower electric permittivity and conductivity than water. An electrical property contrast is induced when solvents displace water in the sediment column resulting in an anomalous GPR signature. To directly identify zones of DNAPL contamination, we focus on three aspects of reflected wave behavior--propagation velocity, frequency dependent attenuation, and amplitude variation with offset (AVO). Velocity analysis provides a direct estimate of electric permittivity, attenuation analysis provides a measure of conductivity, and AVO behavior is used to estimate the permittivity ratio at a reflecting boundary. Areas of anomalously low electric permittivity and …
Date: June 14, 2004
Creator: Bradford, John; Smithson, Scott B. & Holbrook, W. Stephen
System: The UNT Digital Library
Field power measurements of imaging equipment (open access)

Field power measurements of imaging equipment

According to the U.S. Department of Energy, electricity use by non-PC commercial office equipment is growing at an annual rate of nearly 5 percent (AEO 2003). To help address this growth in consumption, U.S. EPA periodically updates its ENERGY STAR specifications as products and markets change. This report presents background research conducted to help EPA update the ENERGY STAR specification for imaging equipment, which covers printers, fax machines, copiers, scanners, and multifunction devices (MFDs). We first estimated the market impact of the current ENERGY STAR imaging specification, finding over 90 percent of the current market complies with the specification. We then analyzed a sample of typical new imaging products, including 11 faxes, 57 printers and 19 copiers/MFD. For these devices we metered power levels in the most common modes: active/ready/sleep/off, and recorded features that would most likely affect energy consumption. Our metering indicates that for many products and speed bins, current models consume substantially less power than the current specification. We also found that for all product categories, power consumption varied most considerably across technology (i.e. inkjet vs. laser). Although inkjet printers consumed less energy than laser printers in active, ready and sleep-mode, they consumed more power on average while …
Date: May 14, 2004
Creator: McWhinney, Marla; Homan, Gregory; Brown, Richard; Roberson, Judy; Nordman, Bruce & Busch, John
System: The UNT Digital Library
Modeling Laser Effects on the Final Optics in Simulated IFE Environments (open access)

Modeling Laser Effects on the Final Optics in Simulated IFE Environments

When laser light interacts with a material's surface, photons rapidly heat the electronic system, resulting in very fast energy transfer to the underlying atomic crystal structure. The intense rate of energy deposition in the shallow sub-surface layer creates atomic defects, which alter the optical characteristics of the surface itself. In addition, the small fraction of energy absorbed in the mirror leads to its global deformation by thermal and gravity loads (especially for large surface area mirrors). The aim of this research was to model the deformation of mirror surfaces at multiple length and time scales for applications in advanced Inertial Fusion Energy (IFE) systems. The goal is to control micro- and macro-deformations by material system and structural design. A parallel experimental program at UCSD has been set up to validate the modeling efforts. The main objective of the research program was to develop computer models and simulations for Laser-Induced Damage (LID) in reflective and transmissive final optical elements in IFE laser-based systems. A range of materials and material concepts were investigated and verified by experiments at UCSD. Four different classes of materials were considered: (1) High-reflectivity FCC metals (e.g. Cu, Au, Ag, and Al), (2) BCC metals (e.g. Mo, Ta …
Date: August 14, 2004
Creator: Ghoniem, Nasr
System: The UNT Digital Library
ADVANCED TECHNOLOGIES FOR STRIPPER GAS WELL ENHANCEMENT (open access)

ADVANCED TECHNOLOGIES FOR STRIPPER GAS WELL ENHANCEMENT

As part of Task 1 in Advanced Technologies for Stripper Gas Well Enhancement, Schlumberger Data & Consulting Services (DCS) joined with two Appalachian Basin producers, Great Lakes Energy Partners, LLC, and Belden & Blake Corporation to develop methodologies for identification and enhancement of stripper wells with economic upside potential. These industry partners previously provided us with data for more than 700 wells in northwestern Pennsylvania. Phase 1 goals of this project are to develop and validate methodologies that can quickly and cost-effectively identify underperforming wells with remediation potential. We have enhanced and streamlined our software and are using it with the latest versions of Microsoft's{trademark} Access and Excel programs. During the last quarter of 2002, Great Lakes provided us with additional data for approximately 2,200 wells located in their Cooperstown field situated in northwestern Pennsylvania. We identified approximately 130 potential remediation candidates, and Great Lakes personnel are currently reviewing this list for viable remediation. Within the last few weeks, a list of five candidates have been chosen for refract, in addition to two alternate wells. This field has provided a rigorous test of our software and analytical methods. We have processed all the information provided to us including the Cooperstown …
Date: July 14, 2004
Creator: MacDonald, Ronald J.
System: The UNT Digital Library
Retention/Diffusivity Studies in Free-Surface Flowing Liquid Lithium (open access)

Retention/Diffusivity Studies in Free-Surface Flowing Liquid Lithium

FLIRE was designed to measure the hydrogen and helium retention and diffusivity in a flowing stream of liquid lithium, and it has accomplished these goals. Retention coefficients for helium in the flowing liquid stream were 0.1-2% for flow speeds of 44 cm/s and implantation energies between 500 and 2000 eV. The energy dependence of retention is linear for the energy range considered, as expected, and the dependence of retention on flow velocity fits the expected square-root of flow speed dependence. Estimates of the helium diffusion coefficient in the flowing lithium stream were {approx} 4 x 10{sup -7} cm{sup 2}/s, and are independent of implantation energy. This value is much lower than expected, which could be due to several factors, such as mixing, bubble formation or surface film formation. In the case of hydrogen, long term retention and release mechanisms are of greatest importance, since this relates to tritium inventory in flowing lithium PFCs for fusion applications. The amount of hydride formation was measured for flowing lithium exposed to neutral deuterium gas. Thermal desorption spectroscopy (TDS) measurements indicate that the hydride concentration was between 0.1 and 0.2% over a wide range of pressures (6.5 x 10{sup -5} to 1 Torr). This …
Date: December 14, 2004
Creator: Stubbers, R. A.; Miley, G. H.; Nieto, M.; Olczak, W.; Ruzic, D. N. & Hassanein, A.
System: The UNT Digital Library
Can fuzzy logic bring complex problems into focus? Modeling imprecise factors in environmental policy (open access)

Can fuzzy logic bring complex problems into focus? Modeling imprecise factors in environmental policy

In modeling complex environmental problems, we often fail to make precise statements about inputs and outcome. In this case the fuzzy logic method native to the human mind provides a useful way to get at these problems. Fuzzy logic represents a significant change in both the approach to and outcome of environmental evaluations. Risk assessment is currently based on the implicit premise that probability theory provides the necessary and sufficient tools for dealing with uncertainty and variability. The key advantage of fuzzy methods is the way they reflect the human mind in its remarkable ability to store and process information which is consistently imprecise, uncertain, and resistant to classification. Our case study illustrates the ability of fuzzy logic to integrate statistical measurements with imprecise health goals. But we submit that fuzzy logic and probability theory are complementary and not competitive. In the world of soft computing, fuzzy logic has been widely used and has often been the ''smart'' behind smart machines. But it will require more effort and case studies to establish its niche in risk assessment or other types of impact assessment. Although we often hear complaints about ''bright lines,'' could we adapt to a system that relaxes these …
Date: June 14, 2004
Creator: McKone, Thomas E. & Deshpande, Ashok W.
System: The UNT Digital Library
Closure Plan for the E-Area Low-Level Waste Facility (open access)

Closure Plan for the E-Area Low-Level Waste Facility

To comply with the applicable requirements of the U.S. Department of Energy (US DOE), this closure plan has been developed for the E-Area Low-Level Waste Facility(LLWF). The plan is organized according to the specifications of the Format and Content Guide for U.S. Department of Energy Low-Level Waste Disposal Facility Closure Plans. Section 2 provides a brief overview of the general facility description, closure approach, closure schedule, related activities, and key assumptions. Sections 3 and 4 provide specific details of facility characteristics and the technical approach to closure, respectively, as well as supporting information. Additional schedule details are provided in Section 5. Section 6 provides a list of recommended items for consideration in association with future revisions to the E-Area LLWF Closure Plan and Performance Assessment (PA). Operation of the E-Area LLWF began with placement of the first low-level waste box within the Low Activity Waste (LAW) Vault. It is anticipated that operations will continue for at least 25 years, and that a 100-year institutional control period will follow cessation of operations. It is further anticipated that closure will be conducted in the following three phases: operational closure, interim closure, and final closure. Operational closure will be conducted during the 25 …
Date: July 14, 2004
Creator: PHIFER, MARKA.l
System: The UNT Digital Library
Mechanistic Studies of Improved Foam EOR Processes (open access)

Mechanistic Studies of Improved Foam EOR Processes

The objective of this research is to widen the application of foam to enhanced oil recovery (EOR) by investigating fundamental mechanisms of foams in porous media. This research will lay the groundwork for more applied research on foams for improved sweep efficiency in miscible gas, steam and surfactant-based EOR. Task 1 investigates the pore-scale interactions between foam bubbles and polymer molecules. Task 2 examines the mechanisms of gas trapping, and interaction between gas trapping and foam effectiveness. Task 3 investigates mechanisms of foam generation in porous media. Significant progress was made during this period on all three Tasks. Regarding Task 1, we continued comparisons of foam behavior in sandpacks with and without polymer and oil. As in our previous results, decane was moderately destabilizing to foam. Xanthan polymer did not stabilize foam in the presence of decane in this case. Rather, it appears to have destabilized foam, so that pressure gradient decreased in spite of the increase in aqueous-phase viscosity. Research on Task 2 included the first shake-down experiments with our new apparatus for gas-phase tracer tests for direct measurement of trapped-gas saturation with foam. In addition, we began to analyze CT images of gas-phase tracer in foam displacements, which …
Date: June 14, 2004
Creator: Rossen, William R.
System: The UNT Digital Library
National Alliance of Clean Energy Incubator Activities - Final Technical Report (open access)

National Alliance of Clean Energy Incubator Activities - Final Technical Report

Summary of activity related to development of the Alliance of Clean Energy Business Incubators and incubation services provided to the clean energy sector by the Advanced Technology Development Center at the Georgia Institute of Technology.
Date: December 14, 2004
Creator: Chris Downing, P.E.
System: The UNT Digital Library
Advanced Technologies for Stripper Gas Well Enhancement (open access)

Advanced Technologies for Stripper Gas Well Enhancement

This report addresses a quarterly report about the advanced technologies of stripper gas well enhancement from July 1 to September 30, 2003
Date: July 14, 2004
Creator: MacDonald, Ronald J.
System: The UNT Digital Library
Solid-Matrix Luminescence Analysis and Coupling Solid-Matrix Luminescence with Separation Methodology (open access)

Solid-Matrix Luminescence Analysis and Coupling Solid-Matrix Luminescence with Separation Methodology

In this report, the major results and conclusions of the research over the last two years and five months is considered. The report discusses the mechanistic aspects of oxygen quenching of solid-matrix phosphorescence (SMP), mechanistic aspects of moisture quenching of SMP, interactions and methodology to investigate phosphors in glucose glasses, new methods for coating filter paper for solid-phase microextraction with solid-matrix fluorescence (SMF) and SMP detection, mechanistic consideration of the heavy-atom quenching of the SMF and the enhancement of SMP of benzo[a]pyrene-DNA adducts, and new developments in liquid-liquid-liquid microextraction.
Date: June 14, 2004
Creator: Hurtubise, Robert J.
System: The UNT Digital Library
In service design by simulations (open access)

In service design by simulations

Irradiation of materials by energetic particles (e.g. electrons, ions and neutrons) is associated with very high internal power dissipation, which can drive the underlying nano- and microstructure far from normal equilibrium conditions. One of the most unusual responses in this connection is the ability of the material's nano- and microstructure to self-assemble in well-organized, two- and three-dimensional periodic arrangements. We reviewed and assessed experimental evidence and theoretical models pertaining to the physical understanding of nano- and microstructure self-organization under irradiation conditions. Experimental observations on the formation of self-organized defect clusters, dislocation loops, voids and bubbles were presented and critically assessed. Implantation of metals with energetic helium results in remarkable self-assembled bubble super-lattices with wavelengths (super-lattice parameters) in the range of 5-8 nm. Ion and neutron irradiation produce a wide variety of self-assembled 3-D defect walls and void lattices, with wavelengths that can be tailored in the range of 10's to 100's of nanometers. Theoretical models aimed at explaining these observations were introduced, and a consistent description of many features is outlined. The primary focus of the most recent modeling efforts, which are based on stability theory and concepts of non-linear dynamics, was to determine criteria for the evolution and spatial …
Date: March 14, 2004
Creator: Ghoniem, Nasr H.
System: The UNT Digital Library